scholarly journals Fluorescent CQD-Doped Styrene Acrylic Emulsion Coating Film with Enhanced Optical Properties

2021 ◽  
Vol 23 (1) ◽  
pp. 60
Author(s):  
Xiaohui Wang ◽  
Li Xu ◽  
Rui Yang ◽  
Runzhou Huang ◽  
Haiyan Mao
Keyword(s):  
Optical Properties ◽  
Carbon Quantum Dots ◽  
Coating Film ◽  
Coating Films ◽  
Acrylic Emulsion ◽  
Practical Applications ◽  
Wood Processing ◽  
Hydrothermal Approach ◽  
High Fluorescence ◽  
Average Size

Styrene acrylic emulsions (SAEs) have emerged as a promising material for water-based coatings. However, they are still limited by their own defects in practical applications, poor weatherability, and degradation of performance at lower or higher temperatures. Here, we introduce a facile approach to producing fluorescent carbon quantum dots (CQDs) from wood processing residues and fabricating fluorescent CQD/SAE coating films via emulsion-casting. The addition of the fluorescent CQDs enhanced the optical performance of the CQD/SAE coating films. The fluorescent CQDs were prepared via a hydrothermal approach and were obtained after heating at 180 °C for 6 h at a reaction concentration of 50 mg/mL. The synthesized CQDs resulted in a high fluorescence, and the CQDs had an average size of 1.63 nm. Various concentrations of the fluorescent CQDs were doped into the SAE coating film, which improved its optical properties. We also characterized and discussed the products and then explored their optical properties. This study presents the potential of fluorescent CQD/SAE coating films for applications in anti-counterfeiting coatings, fluorescent adhesives, and papermaking.

Magnetic and Magneto-Optical Properties of Al Substituted Bi-RIG Particles Dispersed in a Plastic Binder

1998 ◽  
Vol 517 ◽  
Author(s):  
T. Hirano ◽  
K. Yoshida ◽  
Y. Yamazaki ◽  
T. Namikawa ◽  
M. Kishi
Keyword(s):  
Optical Properties ◽  
Figure Of Merit ◽  
Coating Film ◽  
Storage Medium ◽  
Coating Films ◽  
Al Content ◽  
Dispersed Particles ◽  
Magnetic Compensation ◽  
Nano Size ◽  
Annealing Method

AbstractNano-size R2BiAlxFe5-xO12(R: Dy, Gd, Th) particles were prepared with a coprecipitation and annealing method. The coating films of the particles were prepared with a coating technique. The magnetic and magneto-optical properties of the particles and films were investigated. The coercive forceHcof the particles and films was increased and saturation magnetizationMs. dropped with the Al contentx. TheHcof the coating films was about 200 Oe at the compositions of dispersed particles for which theMswas almost zero. These results suggest that the increase was made with magnetic compensation. The BiTb2A10.6Fe4.4O12coating film shows Faraday rotation spectra. The figure of merit of the film is about 0.5 at 520 nm. The coating BiTb2A10.6Fe4.4O12film is one of the candidate materials for a new economical magneto-optical storage medium.

scholarly journals Formation of Carbon Quantum Dots via Hydrothermal Carbonization: Investigate the Effect of Precursors

Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 986
Author(s):  
Md Rifat Hasan ◽  
Nepu Saha ◽  
Thomas Quaid ◽  
M. Toufiq Reza
Keyword(s):  
Quantum Dots ◽  
Optical Properties ◽  
Microcrystalline Cellulose ◽  
Uv Light ◽  
Synthesis Method ◽  
Hydrothermal Carbonization ◽  
Carbon Quantum Dots ◽  
Medical Diagnostics ◽  
Particle Size Range ◽  
Wide Range

Carbon quantum dots (CQDs) are nanomaterials with a particle size range of 2 to 10 nm. CQDs have a wide range of applications such as medical diagnostics, bio-imaging, biosensors, coatings, solar cells, and photocatalysis. Although the effect of various experimental parameters, such as the synthesis method, reaction time, etc., have been investigated, the effect of different feedstocks on CQDs has not been studied yet. In this study, CQDs were synthesized from hydroxymethylfurfural, furfural, and microcrystalline cellulose via hydrothermal carbonization at 220 °C for 30 min of residence time. The produced CQDs showed green luminescence behavior under the short-wavelength UV light. Furthermore, the optical properties of CQDs were investigated using ultraviolet-visible spectroscopy and emission spectrophotometer, while the morphology and chemical bonds of CQDs were investigated using transmission electron microscopy and Fourier-transform infrared spectroscopy, respectively. Results showed that all CQDs produced from various precursors have absorption and emission properties but these optical properties are highly dependent on the type of precursor. For instance, the mean particle sizes were 6.36 ± 0.54, 5.35 ± 0.56, and 3.94 ± 0.60 nm for the synthesized CQDs from microcrystalline cellulose, hydroxymethylfurfural, and furfural, respectively, which appeared to have similar trends in emission intensities. In addition, the synthesized CQDs experienced different functionality (e.g., C=O, O-H, C-O) resulting in different absorption behavior.

scholarly journals Towards practical applications of quantum emitters in boron nitride

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
M. Koperski ◽  
K. Pakuła ◽  
K. Nogajewski ◽  
A. K. Dąbrowska ◽  
M. Tokarczyk ◽  
...  
Keyword(s):  
Optical Properties ◽  
Boron Nitride ◽  
Vapour Phase ◽  
Emission Characteristics ◽  
Vapour Phase Epitaxy ◽  
Practical Applications ◽  
Metalorganic Vapour Phase Epitaxy ◽  
Polydimethylsiloxane Films ◽  
Background Luminescence ◽  
Quantum Emitters

AbstractWe demonstrate quantum emission capabilities from boron nitride structures which are relevant for practical applications and can be seamlessly integrated into a variety of heterostructures and devices. First, the optical properties of polycrystalline BN films grown by metalorganic vapour-phase epitaxy are inspected. We observe that these specimens display an antibunching in the second-order correlation functions, if the broadband background luminescence is properly controlled. Furthermore, the feasibility to use flexible and transparent substrates to support hBN crystals that host quantum emitters is explored. We characterise hBN powders deposited onto polydimethylsiloxane films, which display quantum emission characteristics in ambient environmental conditions.

scholarly journals Preparation of Cellulose-Based Fluorescent Materials as Coating Pigment by Use of DMSO/DBU/CO2 System

2021 ◽  
Author(s):  
Qinghua Cao ◽  
Jinyue Dai ◽  
Xin Bao ◽  
Zhenyu Zhang ◽  
Fei Liu ◽  
...  
Keyword(s):  
Uv Light ◽  
Tensile Modulus ◽  
Coating Film ◽  
Coating Films ◽  
Fluorescence Response ◽  
Mild Conditions ◽  
Fluorescent Materials ◽  
Bright Color ◽  
Molecular Skeleton ◽  
Quenching Phenomenon

Abstract A series of cellulose-based fluorescent materials are prepared under relative mild conditions by use of the DMSO/DBU/CO2 system to utilize as coating pigments. Through the observation under 365nm UV light, the cellulose-based fluorescent materials exhibit good fluorescence response and bright color. Furthermore, due to the limitation of the molecular skeleton of cellulose, the intrinsic aggregation caused quenching phenomenon commonly existed in conventional organic fluorescent pigments can be effectively inhibited, which is very helpful to retain good fluorescence response in epoxy-based coating material and its coating films. Moreover, the addition of cellulose-based fluorescent materials also increases the mechanical properties of the coating film. The increase of tensile strength and tensile modulus respectively reaches ~39% and ~66%. Solvent resistance and thermal property of the coating films generally remain unchanged. The fabrication of cellulose-based fluorescent materials in DMSO/DBU/CO2 system provides a feasible way to develop the functional application of cellulose.

scholarly journals A Study on the Annealing Ambient Effect on the Anti-Pollution Characteristics of Functional Film for PV Modules

2018 ◽  
Vol 8 (11) ◽  
pp. 2285
Author(s):  
Sejin Jung ◽  
Jung Kim ◽  
Jang Ko ◽  
Wonseok Choi
Keyword(s):  
Contact Angle ◽  
Mechanical Characteristics ◽  
Spray Coating ◽  
Light Transmittance ◽  
Process Conditions ◽  
Coating Film ◽  
Coating Films ◽  
Functional Coating ◽  
Pollution Characteristics ◽  
Pv Modules

In this study, functional coating film was fabricated on glass for photovoltaic (PV) modules to improve the anti-pollution characteristics of PV modules. The functional coating film applied to a glass substrate through the spray coating method was annealed at 300 °C for 10 min in H2, N2, Ar, O2, and vacuum ambient. The contact angle of the coated surface was measured and it was confirmed that the anti-pollution characteristics were improved as the contact angle decreased. The light transmittance was measured and it exhibited the most excellent characteristics in vacuum. The hardness and adhesion were measured as the mechanical characteristics and they were all excellent regardless of the annealing ambient. Based on the analyzed characteristics, the process conditions of functional coating films were optimized to improve the anti-pollution and mechanical characteristics. If the coating process optimized in this study is applied to PV modules based on these results, improvement in the anti-pollution characteristics can be expected.

scholarly journals N-methyl mesoporphyrin IX as a highly selective light-up probe for G-quadruplex DNA

2019 ◽  
Vol 23 (11n12) ◽  
pp. 1195-1215 ◽  
Author(s):  
Ariana Yett ◽  
Linda Yingqi Lin ◽  
Dana Beseiso ◽  
Joanne Miao ◽  
Liliya A. Yatsunyk
Keyword(s):  
Optical Properties ◽  
Small Molecules ◽  
Genomic Stability ◽  
Water Soluble ◽  
Biological Processes ◽  
Binding Properties ◽  
Quadruplex Dna ◽  
Dna Structures ◽  
G Quadruplex ◽  
High Fluorescence

[Formula: see text]-methyl mesoporphyrin IX (NMM) is a water-soluble, non-symmetric porphyrin with excellent optical properties and unparalleled selectivity for G-quadruplex (GQ) DNA. G-quadruplexes are non-canonical DNA structures formed by guanine-rich sequences. They are implicated in genomic stability, longevity, and cancer. The ability of NMM to selectively recognize GQ structures makes it a valuable scaffold for designing novel GQ binders. In this review, we survey the literature describing the GQ-binding properties of NMM as well as its wide utility in chemistry and biology. We start with the discovery of the GQ-binding properties of NMM and the development of NMM-binding aptamers. We then discuss the optical properties of NMM, focusing on the light-switch effect — high fluorescence of NMM induced upon its binding to GQ DNA. Additionally, we examine the affinity and selectivity of NMM for GQs, as well as its ability to stabilize GQ structures and favor parallel GQ conformations. Furthermore, a portion of the review is dedicated to the applications of NMM-GQ complexes as biosensors for heavy metals, small molecules ([Formula: see text] ATP and pesticides), DNA, and proteins. Finally and importantly, we discuss the utility of NMM as a probe to investigate the roles of GQs in biological processes.

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