scholarly journals Fretting Wear Behavior and Photoelectron Spectroscopy (XPS) Analysis of a Ti/TiN Multilayer Film Deposited on Depleted Uranium

Materials ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 1538 ◽  
Author(s):  
Shengfa Zhu ◽  
Yanping Wu ◽  
Zhengyang Li ◽  
Liping Fang ◽  
Anyi Yin ◽  
...  

Depleted uranium has been widely applied in nuclear energy fields. However, its poor corrosion and wear resistance restrict its applications. A titanium/titanium nitride (Ti/TiN) multilayer film was deposited on a uranium surface to improve its fretting wear resistance. Fretting wear tests were carried out using a pin-on-disc configuration. The fretting behaviors of uranium and the Ti/TiN film were investigated under different normal loads. With the normal load increasing, the mode of fretting wear gradually transformed from slip region (SR) to mixed fretting region (MFR) and then to partial slip region (PSR). It is illustrated that the normal load had an obvious effect on the fretting wear behavior. The friction coefficients of both uranium and Ti/TiN multilayer film decreased with the increase of the normal load. In SR, the main wear mechanisms were delamination and abrasion for uncoated uranium, and delamination and oxidation for uranium coated with the Ti/TiN multilayer film. Photoelectron spectroscopy (XPS) analysis also showed that the Ti/TiN coating was oxidized and formed TiO2 during fretting wear. The wear depth of naked uranium was much greater than that of coated uranium, which demonstrated that the Ti/TiN multilayer film could effectively improve the wear properties of uranium.

Author(s):  
Liangliang Sheng ◽  
Xiangtao Deng ◽  
Hao Li ◽  
Yuxuan Ren ◽  
Guoqing Gou ◽  
...  

In this work, an in-situ XPS analysis test combined self-designed high precision fretting wear tester was carried out to study the fretting wear behavior and the resulting tribo-oxidation of thermal-oxidation film on Ti6Al4V titanium alloy under the varied working atmosphere. The fretting-induced tribo-oxidation under the air and vacuum ([Formula: see text] Pa) environment was analyzed and its response on the resulting fretting wear resistance and damage mechanism was discussed. Results show that the working environment plays a significant role in the formation of tribo-oxidation and then determining the fretting wear resistance. Thermal-oxidation film in the vacuum atmosphere shows a better fretting wear resistance than that in the air atmosphere for all fretting regimes, except for partial slip regime (PSR) where there is an equivalent fretting wear resistance. Compared with the substrate Ti6Al4V titanium alloy, the thermal-oxidation film in the vacuum atmosphere performs a good protection for titanium alloy, especially for slip regime (SR), but not applied for air atmosphere.


2019 ◽  
Vol 2019 ◽  
pp. 1-15
Author(s):  
Ibrohim A. Rustamov ◽  
Ozoda Sh. Sabirova ◽  
Zixi Wang ◽  
Yuming Wang

Tribological behavior of the Inconel X-750 alloy disk subjected to fretting against the GCr15 steel ball was investigated in an ambient laboratory air with relative humidity of 55–65%. A high-frequency oscillating Optimol SRV 4 tribometer was employed to execute dry fretting tests in the partial and gross slip regimes under constant 100 N normal load. Tests were carried out for 10, 30, and 90 minutes, and the friction forces vs. displacement amplitudes were monitored during the test duration. Posttest examinations were conducted utilizing advanced tools such as 3D optical surface profiler, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX). The main objective was to obtain wear scar evolutions, frictional properties, and degradation mechanisms under the different running conditions over time. It was found that fretting wear behaviors of friction pairs were strongly influenced by fretting regimes. Degradation evolutions were greatly influenced by fretting time during partial slip regimes, i.e., evolving from asperity deformation and slight damage to the fatigue crack and material transfer. However, the combination of adhesive, abrasive, delamination, and wear oxidation mechanisms was repeated during the entire gross slip fretting process.


PLoS ONE ◽  
2017 ◽  
Vol 12 (4) ◽  
pp. e0175084 ◽  
Author(s):  
Yan-Ping Wu ◽  
Zheng-Yang Li ◽  
Sheng-Fa Zhu ◽  
Lei Lu ◽  
Zhen-Bing Cai

2019 ◽  
Vol 141 (10) ◽  
Author(s):  
Mengjiao Wang ◽  
Yunxia Wang ◽  
Jianzhang Wang ◽  
Na Fan ◽  
Fengyuan Yan

Super duplex stainless steel (SDSS) has excellent mechanical properties and corrosion resistance. However, currently, there are few researches conducted on its fretting wear performance. This paper studies the influence of different heat treatment temperatures and medium environment on the fretting wear performance of SAF 2507 SDSS. Results show that the combined effect of the sigma phase and seawater lubrication can significantly improve the wear resistance of SAF 2507 SDSS. After treated with different heat treatment temperatures, different contents of sigma phases are precipitated out of SAF 2507 SDSS, which improves the wear resistance of the material to different degrees. In addition, the fretting wear performance of SAF 2507 SDSS also relates to the lubrication medium. In air, the friction and wear performance of SAF 2507 SDSS is poor, while in seawater, solution and corrosion products that acted as a lubricant dramatically improve the wear resistance of the material. Under the combined action of heat treatment and seawater lubrication medium, the friction coefficient and wear reduce by 70% and 91%, respectively.


Author(s):  
Dongbo Wei ◽  
Fengkun Li ◽  
Xiangfei Wei ◽  
Tomasz Liskiewicz ◽  
Krzysztof J Kubiak ◽  
...  

In this study, surface Cr-Nb alloying was realized on γ-TiAl using double glow plasma hollow cathode discharge technique. An inter-diffusion layer was generated under the surface, composed of Cr2Nb intermetallic compounds. After Cr-Nb alloying, the surface nanohardness of γ-TiAl increased from 5.65 to 11.61 GPa. The surface H/E and H3/E2 increased from 3.37 to 5.98 and from 0.64 to 4.15, respectively. Cr-Nb alloying and its effect on fretting wear were investigated. The surface treatment resulted in improved plastic deformation and fretting wear resistance of γ-TiAl. The fretting wear test showed that an average friction coefficient of γ-TiAl against Si3N4 ball was significantly decreased after Cr-Nb alloying. The fluctuation of friction coefficient during running-in stage was significantly improved. The friction behavior of both γ-TiAl before and after Cr-Nb alloying could be divided into distinctive stages including formation of debris, flaking, formation of crack, and delamination. It was observed that the high hardness, resistance to plastic deformation, and fatigue resistance of γ-TiAl after Cr-Nb alloying could inhibit the formation of debris and delamination during friction test. The fretting wear scar area and the maximum wear scar depth were decreased, indicating that the wear resistance of γ-TiAl has been greatly improved after Cr-Nb alloying. The results indicated that plasma surface Cr-Nb alloying is an effective way for improving the fretting wear resistance of γ-TiAl in aviation area.


1997 ◽  
Vol 119 (1) ◽  
pp. 36-42 ◽  
Author(s):  
Z. R. Zhou ◽  
L. Vincent

Fretting-wear and fretting-fatigue loadings can both result in wear (material loss) and in crack nucleation and propagation (fatigue process). This paper deals with cracking induced by small amplitude displacements in the case of aeronautic aluminium alloys. The two sets of fretting maps are introduced: running condition fretting map is composed of partial slip (sticking), mixed fretting and gross sliding regime; material response fretting map is associated with two macro-degradation modes. Crack nucleation and propagation are analysed for every fretting regime. The mixed fretting regime appeared most detrimental with regards to fatigue cracking. Slip amplitude and normal load main effects discussed for fretting wear can be used to justify the fatigue limit decrease often obtained for fretting fatigue experiments.


Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1618 ◽  
Author(s):  
Zhaohuan Song ◽  
Songhao Zhao ◽  
Tao Jiang ◽  
Junjie Sun ◽  
Yingjun Wang ◽  
...  

In this work, a multiphase microstructure consisting of nanobainte, martensite, undissolved spherical carbide, and retained blocky austenite has been prepared in an Al-alloyed high carbon steel. The effect of the amount of nanobainite on the dry sliding wear behavior of the steel is studied using a pin-on-disc tester with loads ranging from 25–75 N. The results show that, there is no significant differences in specific wear rate (SWR) for samples with various amounts of nanobainite when the normal load is 25 N. While, the SWR firstly decreases and then increases with increasing the amount of nanobainite, and the optimum wear resistance is obtained for samples with 60 vol.% nanobainite, when the applied load increases to 50 and 75 N. The improved wear resistance is attributed to the peak hardness increment resulted from the transformation of retained austenite to martensite, work hardening, along with amorphization and nanocrystallization of the worn surface. In addition, the highest toughness of the samples with 60 vol.% nanobainite is also proven to play a positive role in resisting sliding wear. EDS (energy dispersion spectrum) and XRD (X-ray diffraction) examinations reveal that the predominant failure mechanism is oxidative wear.


2018 ◽  
Vol 28 (8) ◽  
pp. 1593-1601 ◽  
Author(s):  
Yan-ping WU ◽  
Zheng-yang LI ◽  
Wen-jin YANG ◽  
Sheng-fa ZHU ◽  
Xian-dong MENG ◽  
...  

Author(s):  
Anitha Santhoshi Madugula ◽  
B. Murali Krishna ◽  
G. Swaminaidu

Red mud emerges as the major waste material during the production of alumina from bauxite and its potential as a filler material in metal matrices has not yet been reported. In view of this, an attempt is made to explore the possibility of making a class of wear resistant metal matrix hybrid composites with nano-structured red mud and micro sized fly ash particles as reinforcement. The micro-sized red mud particles have been modified to nano-structured red mud using high energy ball milling and after 30 hours of milling, the size was reduced from 100 microns to 30 nm. Composites were fabricated by stir casting and experiments were conducted under laboratory condition to assess the wear characteristics of AA2024- 15 wt% fly ash (micro-sized) and varying fractions (2 wt%, 4 wt% and 6 wt%) red mud (nano-structured) hybrid composites under different working conditions in pure sliding mode on a pin-on-disc machine. Tests were conducted with sliding speeds of 200 rpm, 400 rpm and 600 rpm at loads of 10N, 20N and 30N. The increased frictional thrust at higher load results in increased de-bonding and caused easy removal of material and hence the wear rate is increased with increase in normal load. The wear resistance of the composite is increased with increase in red mud fraction. This is due to the increase in surface energy and inter-atomic bonding with increase in nano-structured red mud fraction. The addition of redmud particles to the matrix phase causes dispersion strengthening and hence the strength as well. Wear resistance is increased with increase in redmud fraction.


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