Effect of Coating and Low Viscosity Oils on Piston Ring Friction under Mixed Regime of Lubrication through Analytical Modelling

This paper presents the impact of coating topography in piston ring-liner conjunction under mixed regime of lubrication using low viscosity oils. The study provides a time efficient analytical model including mixed-hydrodynamics regime of lubrication under different contact conditions. The method modified the expressions of the contact load and area of Greenwood-Tripp model in order to capture the real asperities interaction into contact. The model represents the tribological behavior of a thin top ring at Top Dead Centre, where boundary and mixed conditions are predominant. Electroplated CrN and PVD TiN coated rings were studied to predict the ring friction. The results are compared with an uncoated steel ring. The CrN coating shows slighter coefficient of friction, due to the coating morphology and roughness parameters. The TiN coating presents thicker lubricant films and higher coefficient of friction because the surface topography is quite rough with high peaks. This can be explained because of the major contribution of the roughness parameter and asperity slope in the boundary friction prediction.

Personality and territoriality in theory and in Belgium

Language policy debates regularly refer to the principles of personality and territoriality. Yet the precise meaning of these principles remains unclear. In this contribution, I conceptualize these principles as poles of a continuum between official bilingualism (instantiating the personality principle) and official unilingualism (exemplifying the territoriality principle), with a mixed regime in between (which grants a certain territorial primacy to a language, but allows exceptions based on linguistic affiliation). The question of the determination of particular points on the continuum cannot be separated from the metaterritorial question of the boundaries of the units within which those principles apply. Application of this ‘continuum model’ to Belgium draws attention to three language-political regimes. The first invokes a strict personality principle (Brussels). The second follows the strict territoriality principle (almost all municipalities in Flanders and Wallonia). The third is a mixed regime (a total of 27 ‘municipalities with facilities’ where one language enjoys primacy but speakers of another language enjoy certain linguistic ‘facilities’). The article also analyses the manner in which these regimes were historically established in Belgium in combination with a delineation of the language border and the division of the country into four language areas.

Tribological Behavior of Novel CNTs-Based Lubricant Grease in Steady-State and Fretting Sliding Conditions

The tribological behavior of novel 7.5 wt% carbon nanotube-based lubricant greases in PAO (polyalphaolefin) oil with and without 1.0 wt% MoS2, together with several other commercial greases such as calcium, lithium, were studied. The test results showed a marked reduction of frictional coefficient achieved by the CNTs based grease samples with an average benefit of around 30% compared to conventional greases. The steady state test under 1.00 GPa average contact pressure in a mixed lubrication regime and the fretting test showed the best results in terms of friction reduction obtained by CNTs greases. Steady state tests at higher average contact pressure of 1.67 GPa proved to have a lower friction coefficient for CNTs grease containing MoS2; otherwise CNTs grease without MoS2 showed an average value of CoF comparable to calcium and lithium greases, both in a boundary and a mixed regime. The protection against wear, a considerable decrease (−60%) of reference parameter was measured with CNTs grease with MoS2 (NLGI 2) in comparison with the worst conventional grease and −22% in comparison with the best conventional grease. The data indicated that our novel carbon nanotube greases show superior tribological properties and will have promising applications in the corresponding industry.

The Effect of Displacement Amplitude on Fretting Wear Behavior and Damage Mechanism of Alloy 690 in Different Gaseous Atmospheres

The effect of displacement amplitude on fretting wear behavior and damage mechanisms of alloy 690 in air and nitrogen atmospheres was investigated in detail. The results showed that in air, the friction coefficient gradually increased with the increase in displacement amplitude which conformed to the universal law. In nitrogen, however, it had the highest point at the displacement amplitude of 60 μm due to very strong adhesion. Whether in air or nitrogen, the wear volume gradually increased with the increase in displacement amplitude. The wear volume in air was larger than that in nitrogen except at 30 μm. At 30 μm, the wear volume in air was slightly smaller. With an increase in displacement amplitude, a transformation of fretting running status between partial slip, mixed stick-slip, and final gross slip occurred along with the change of Ft-D curves from linear, to elliptic, to, finally, parallelogrammical. Correspondingly, the fretting regime changed from a partial slip regime to a mixed regime to a gross slip regime. With the increase in displacement amplitude, the transition from partial slip to gross slip in nitrogen was delayed as compared with in air due to the strong adhesion actuated by low oxygen content in a reducing environment. Whether in air or nitrogen, the competitive relation between fretting-induced fatigue and fretting-induced wear was prominent. The cracking velocity was more rapid than the wear. Fretting-induced fatigue dominated at 30 μm in air but at 30–60 μm in nitrogen. Fretting-induced wear won the competition at 45–90 μm in air but at 75–90 μm in nitrogen.

Spectral Broadening in a Continuously Pumped Singly Resonant Second-Harmonic Cavity

Optical frequency comb synthesizers with a wide spectral range are an essential tool for many research areas such as spectroscopy, precision metrology, optical communication, and sensing. Recent studies have demonstrated the direct generation of frequency combs, via second-order processes, that are centered on two different spectral regions separated by an octave. Here, we present the capability of optical quadratic frequency combs for broad-bandwidth spectral emission in unexplored regimes. We consider comb formation under phase-matched conditions in a continuous-wave pumped singly resonant second-harmonic cavity, with large intracavity power and control of the detuning over several cavity line widths. The spectral analysis reveals quite distinctive sidebands that arise far away from the pump, singularly or in a mixed regime together with narrowband frequency combs. Notably, by increasing the input power, the optical frequency lines evolve into widely spaced frequency clusters, and at maximum power, they appear in a wavelength range spanning up to 100 nm. The obtained results demonstrate the power of second-order nonlinearities for direct comb production within a wide range of pump wavelengths.

Idealized Simulations of Mei-yu Rainfall in Taiwan under Uniform Southwesterly Flow using A Could-Resolving Model

In this study, idealized cloud-resolving simulations are performed for horizontally uniform and steady southwesterly flow at fixed direction/speed combinations to investigate rainfall characteristics and the role of the complex topography in Taiwan during the Mei-yu season, without the influence of a front or other disturbances. Eight directions (180° to 285°, every 15°) and eight speeds (5 to 22.5 m s−1, every 2.5 m s−1) are considered, and near-surface relative humidity (RH) is also altered (from 55–100 %) in a subset of these tests to further investigate the effects of moisture content, yielding a total 109 experiments each having a integration length of 50 h. Three rainfall regimes that correspond to different ranges of the wet Froude number (Frw) are identified from the idealized simulations (with a grid size of 2 km). The low-Frw regime (Frw ≤ ~0.3) where the island circulation from thermodynamic effects during daytime is the main cause of rainfall in local afternoon. The lower the wind speed (and Frw), the more widespread and amount of rainfall. On the other hand, the high-Frw regime (Frw ≥ ~0.4) occurs when the flow at least 12.5 m s−1 impinges on Taiwan terrain at a large angle to favor the flow-over scenario. Thus, topographic rainfall production becomes dominant through mechanical uplift of unstable air. In this scenario, the faster and wetter the flow, the heavier the rainfall on the windward slopes, with the most favorable direction from 240°–255°. Between the two regimes above, a third and mixed regime also exists. The idealized results are discussed for their applicability to the real atmosphere.

β-Zeolite Assisted Lignin-First Fractionation in a Flow-Through Reactor

<p>Lignin is one of the main constituents of lignocellulosic biomass, whose valorization is essential for an economically feasible biorefinery process scheme. In the present work, a hydrogen-free one step catalytic fractionation of woody biomass using commercial b-zeolite as catalyst in a flow-through reactor was carried out, leading to a maximum aromatic monomer yield of 20.5 wt.%. Birch, spruce and walnut shells were used and compared as lignocellulosic feedstocks. Relevant insights in the reaction mechanism were obtained through 2D HSQC NMR analysis, revealing that b-O-4 cleavage is catalyzed by the zeolite. To optimize system operation, a rate limiting step analysis was performed by using different reactor configurations. It was found that the system operated in a mixed regime where the rates of both solvolytic delignification and zeolite-based depolymerization/dehydration affect the net rate of aromatic monomer production. Oxalic acid addition was found to enhance monomer production at moderate concentrations by improving solvolysis; however, it caused structural changes to the zeolite leading to lower monomer yields at higher concentrations. Zeolite stability was assessed through catalyst recycling and characterization using NH₃-TPD, XRD, N₂ physisorption and TGA. Main catalyst deactivation mechanisms were found to be coking and leaching, respectively leading to larger pore size and lower concentration of acid sites.</p>

β-Zeolite Assisted Lignin-First Fractionation in a Flow-Through Reactor

<p>Lignin is one of the main constituents of lignocellulosic biomass, whose valorization is essential for an economically feasible biorefinery process scheme[1]. In the present work, a hydrogen-free one step catalytic fractionation of woody biomass using commercial b-zeolite as catalyst in a flow-through reactor was carried out, leading to a maximum aromatic monomer yield of 20.5 wt.%. Birch, spruce and walnut shells were used and compared as lignocellulosic feedstocks. Relevant insights in the reaction mechanism were obtained through 2D HSQC NMR analysis, revealing that b-O-4 cleavage is catalyzed by the zeolite. To optimize system operation, a rate limiting step analysis was performed by using different reactor configurations. It was found that the system operated in a mixed regime where the rates of both solvolytic delignification and zeolite-based depolymerization/dehydration affect the net rate of aromatic monomer production. Oxalic acid addition was found to enhance monomer production at moderate concentrations by improving solvolysis; however, it caused structural changes to the zeolite leading to lower monomer yields at higher concentrations. Zeolite stability was assessed through catalyst recycling and characterization using NH₃-TPD, XRD, N₂ physisorption and TGA. Main catalyst deactivation mechanisms were found to be coking and leaching, respectively leading to larger pore size and lower concentration of acid sites.</p>

β-Zeolite Assisted Lignin-First Fractionation in a Flow-Through Reactor

<p>Lignin is one of the main constituents of lignocellulosic biomass, whose valorization is essential for an economically feasible biorefinery process scheme[1]. In the present work, a hydrogen-free one step catalytic fractionation of woody biomass using commercial b-zeolite as catalyst in a flow-through reactor was carried out, leading to a maximum aromatic monomer yield of 20.5 wt.%. Birch, spruce and walnut shells were used and compared as lignocellulosic feedstocks. Relevant insights in the reaction mechanism were obtained through 2D HSQC NMR analysis, revealing that b-O-4 cleavage is catalyzed by the zeolite. To optimize system operation, a rate limiting step analysis was performed by using different reactor configurations. It was found that the system operated in a mixed regime where the rates of both solvolytic delignification and zeolite-based depolymerization/dehydration affect the net rate of aromatic monomer production. Oxalic acid addition was found to enhance monomer production at moderate concentrations by improving solvolysis; however, it caused structural changes to the zeolite leading to lower monomer yields at higher concentrations. Zeolite stability was assessed through catalyst recycling and characterization using NH₃-TPD, XRD, N₂ physisorption and TGA. Main catalyst deactivation mechanisms were found to be coking and leaching, respectively leading to larger pore size and lower concentration of acid sites.</p>