scholarly journals A Study of the Effects of Al, Cr, Hf, and Ti Additions on the Microstructure and Oxidation of Nb-24Ti-18Si Silicide Based Alloys

Materials ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 1579 ◽  
Author(s):  
Jack Nelson ◽  
Mohammad Ghadyani ◽  
Claire Utton ◽  
Panos Tsakiropoulos
Keyword(s):  
Solid Solution ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Isothermal Oxidation ◽  
Bulk Alloy ◽  
Simultaneous Addition ◽  
Hardening Effect ◽  
Heat Treated ◽  
Alloy Oxidation ◽  
Negative Effect

In Nb-silicide based alloys Al, Cr, Hf, and Ti additions are crucial for achieving balance of properties. It is not known how the simultaneous addition of Hf with Al and Ti, or Hf with Al, Cr, and Ti affects macrosegregation, and how the alloying affects hardness, Young’s modulus and bulk alloy oxidation, and contamination of the solid solution Nbss and the Nb5Si3 compound by oxygen. Two alloys with nominal compositions (at.%) Nb-24Ti-18Si-5Al-5Hf (alloy NbSiTiHf-5Al) and Nb-24Ti-18Si-5Al-5Cr-5Hf (alloy NbSiTiHf-5Al-5Cr) were studied in the as-cast and heat-treated conditions and after isothermal oxidation at 800 and 1200 °C and were compared with similar alloys without Hf. In both alloys there was macrosegregation of Si and Ti, which was more severe in NbSiTiHf-5Al. Both alloys formed Nbss+βNb5Si3 eutectic. The Nbss was stable and its Al and Cr concentrations increased with increasing Ti concentration. In both conditions the βNb5Si3 was observed in the alloys NbSiTiHf-5Al and NbSiTiHf-5Al-5Cr, and the γNb5Si3 only in the alloy NbSiTiHf-5Al. In both heat-treated alloys, separate Hf-rich Nb5Si3 grains were formed. The Si and Al concentrations in Nb5Si3 respectively decreased and increased with increasing Ti concentration. Al and Cr had a stronger hardening effect in the Nbss than Al, Cr, and Hf. Al, Cr, and Ti had a stronger negative effect on the Young’s modulus of the Nbss compared with Al, Cr, Hf, and Ti. When Nb was substituted by Ti, Cr, and Hf, and Si by Al in the βNb5Si3, the Young’s modulus was reduced compared with the unalloyed silicide. At 800 °C both alloys did not exhibit catastrophic pest-oxidation after 100 h. The Nbss and Nb5Si3 were contaminated by oxygen in both alloys, the former more severely. At 1200 °C the scales spalled-off, more severely in the alloy NbSiTiHf-5Al, where substrate that was heavily contaminated by oxygen below the scale also spalled-off. In both alloys the contamination of Nb5Si3 and Nbss by oxygen was more severe compared with 800 °C, but the silicides were not contaminated by oxygen in their bulk. The Nbss was not contaminated by oxygen only in the bulk of the alloy NbSiTiHf-5Al-5Cr.

Highly Flexible Die Attach Adhesives for MEMS packages

2012 ◽  
Vol 2012 (1) ◽  
pp. 001169-001177 ◽  
Author(s):  
Tobias Königer
Keyword(s):  
Mechanical Stress ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Assembly Process ◽  
Processing Times ◽  
Heat Curing ◽  
Die Attach ◽  
Negative Effect ◽  
Dual Curing ◽  
Flexible Die

Die attach materials for most MEMS packages must be highly flexible as temperature changes during the assembly process and application may lead to thermo-mechanical stress as a consequence of dissimilar coefficients of thermal expansion of substrate, chip and adhesive. Thermo-mechanical stress results in a distortion of the signal characteristics of the extremely stress-sensitive MEMS device. Within the scope of this paper, highly flexible heat-curing adhesives with a Young's modulus down to 5 MPa (0.725 ksi) at room temperature were developed. DMTA measurements show that temperature storage at +120 °C (+248 °F) does not cause the adhesive to embrittle, which would have a negative effect on the MEMS package's reliability. After storage at +120 °C (+248 °F) for up to 1000 h, no increase in Young's modulus can be observed. The adhesives cure at extremely low temperatures down to +100 °C (+212 °F), which reduces stress development during the assembly process. In addition, the adhesives have very process-friendly properties. Processing times of more than one week can be achieved. The option of dual curing enables preliminary light fixation of the chip within just seconds.

scholarly journals On the Microstructure and Properties of Nb-12Ti-18Si-6Ta-5Al-5Cr-2.5W-1Hf (at.%) Silicide-Based Alloys with Ge and Sn Additions

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3719
Author(s):  
Jiang Zhao ◽  
Claire Utton ◽  
Panos Tsakiropoulos
Keyword(s):  
Solid Solution ◽  
Design Methodology ◽  
Isothermal Oxidation ◽  
Chemical Compositions ◽  
Weight Changes ◽  
Parabolic Oxidation ◽  
Goal Condition ◽  
Heat Treated ◽  
Order Of Magnitude ◽  
Solution Volume

The microstructures and properties of the alloys JZ3 (Nb-12.4Ti-17.7Si-6Ta-2.7W-3.7Sn-4.8Ge-1Hf-4.7Al-5.2Cr) and JZ3+(Nb-12.4Ti-19.7Si-5.7Ta-2.3W-5.7Sn-4.9Ge-0.8Hf-4.6Al-5.2Cr) were studied. The densities of both alloys were lower than the densities of Ni-based superalloys and many of the refractory metal complex concentrated alloys (RCCAs) studied to date. Both alloys had Si macrosegregation and the same phases in their as cast and heat treated microstructures, namely βNb5Si3, αNb5Si3, A15-Nb3X (X = Al, Ge, Si, Sn), C14-Cr2Nb and solid solution. W-rich solid solutions were stable in both alloys. At 800 °C only the alloy JZ3 did not show pest oxidation, and at 1200 °C a thin and well adhering scale formed only on JZ3+. The alloy JZ3+ followed parabolic oxidation with rate constant one order of magnitude higher than the single crystal Ni-superalloy CMSX-4 for the first 14 h of oxidation. The oxidation of both alloys was superior to that of RCCAs. Both alloys were predicted to have better creep at the creep goal condition compared with the superalloy CMSX-4. Calculated Si macrosegregation, solid solution volume fractions, chemical compositions of solid solution and Nb5Si3, weight changes in isothermal oxidation at 800 and 1200 °C using the alloy design methodology NICE agreed well with the experimental results.

scholarly journals Microstructures and Isothermal Oxidation of the Alumina Scale Forming Nb1.45Si2.7Ti2.25Al3.25Hf0.35 and Nb1.35Si2.3Ti2.3Al3.7Hf0.35 Alloys

Materials ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 759 ◽  
Author(s):  
Mohammad Ghadyani ◽  
Claire Utton ◽  
Panos Tsakiropoulos
Keyword(s):  
Solid Solution ◽  
Cast Alloy ◽  
Alumina Scale ◽  
Isothermal Oxidation ◽  
Intermetallic Alloys ◽  
High Entropy ◽  
Heat Treated ◽  
Composite Silicide ◽  
Definition Of ◽  
Selection Of

Coating system(s) will be required for Nb-silicide based alloys. Alumina forming alloys that are chemically compatible with the Nb-silicide based alloy substrate could be components of such systems. The intermetallic alloys Nb1.45Si2.7Ti2.25Al3.25Hf0.35 (MG5) and Nb1.35Si2.3Ti2.3Al3.7Hf0.35 (MG6) were studied in the cast, heat treated and isothermally oxidised conditions at 800 and 1200 °C to find out if they are αAl2O3 scale formers. A (Al/Si)alloy versus Nb/(Ti + Hf)alloy map, which can be considered to be a map for Multi-Principle Element or Complex Concentrated Nb-Ti-Si-Al-Hf alloys, and a [Nb/(Ti + Hf)]Nb5Si3 versus [Nb/(Ti + Hf)]alloy map were constructed making use of the alloy design methodology NICE and data from a previously studied alloy, and were used to select the alloys MG5 and MG6 that were expected (i) not to pest, (ii) to form αAl2O3 scale at 1200 °C, (iii) to have no solid solution, (iv) to form only hexagonal Nb5Si3 and (v) to have microstructures consisting of hexagonal Nb5Si3, Ti5Si3, Ti5Si4, TiSi silicides, and tri-aluminides and Al rich TiAl. Both alloys met the requirements (i) to (v). The alumina scale was able to self-heal at 1200 °C. Liquation in the alloy MG6 at 1200 °C was linked with the formation of a eutectic like structure and the TiAl aluminide in the cast alloy. Key to the oxidation of the alloys was the formation (i) of “composite” silicide grains in which the Nb5Si3 core was surrounded by the Ti5Si4 and TiSi silicides, and (ii) of tri-aluminides with high Al/Si ratio, particularly at 1200 °C and very low Nb/Ti ratio forming in-between the “composite” silicide grains. Both alloys met the “standard definition” of high entropy alloys (HEAs). Compared with HEAs with bcc solid solution and intermetallics, the VEC values of both the alloys were outside the range of reported values. The parameters VEC,  and  of Nb-Ti-Si-Al-Hf coating alloys and non-pesting Nb-silicide based alloys were compared and trends were established. Selection of coating alloys with possible “layered” structures was discussed and alloy compositions were proposed.

Young's modulus of heat-treated carbons: A theory for nongraphitizing carbons

Carbon ◽  
1993 ◽  
Vol 31 (2) ◽  
pp. 333-339 ◽  
Author(s):  
F.G. Emmerich ◽  
C.A. Luengo
Keyword(s):  
Young’S Modulus ◽  
Young's Modulus ◽  
Heat Treated

Effects of Hydrogen Absorption on the Mechanical Properties of Zr-Nb Alloys

2007 ◽  
Vol 1043 ◽  
Author(s):  
Shunichiro Nishioka ◽  
Masato Ito ◽  
Hiroaki Muta ◽  
Masayoshi Uno ◽  
Shinsuke Yamanaka
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Young’S Modulus ◽  
Hydrogen Content ◽  
Hydrogen Absorption ◽  
Room Temperature ◽  
Young's Modulus ◽  
Characteristic Vibration ◽  
Young’S Moduli ◽  
Vibration Technique

AbstractYoung's moduli of hydrogenated Zr-Nb alloys were evaluated by using a multiple elastometer in the temperature range from room temperature to 773 K, based on the cantilever characteristic vibration technique. The decreasing rate of Young's modulus against the temperature was independent on the additive amount of Nb. The Young's modulus for the hydrogen solid solution of Zr-Nb alloys decreased and that those for the alloys with partially precipitated hydride slightly changed with increasing hydrogen content in both of Zr-1.0Nb and Zr-2.5Nb. The decreasing rates with hydrogen content of hydrogen solid solution of Zr-Nb alloys were almost same as that of Zr hydrogen solid solution. This result was considered because all specimens largely consisted of α-zirconium in which the solute hydrogen was found to decrease the Young's modulus.

Development of Ti-12Mo-8Nb Alloy for Biomedical Application

2017 ◽  
Vol 899 ◽  
pp. 191-194
Author(s):  
Sinara Borborema Gabriel ◽  
Jessica Peixoto da Silva Kassya ◽  
Caroline Miranda Jacinto ◽  
Leizy Pâmela Oliveira dos Santos ◽  
Carlos Angelo Nunes ◽  
...  
Keyword(s):  
Young’S Modulus ◽  
Biomedical Application ◽  
Young's Modulus ◽  
High Vacuum ◽  
High Strength ◽  
Microstructural Characterization ◽  
Β Phase ◽  
Beta Titanium ◽  
Heat Treated ◽  
Alloy Heat

Several beta titanium alloys were developed for biomedical applications due to the combination of low elasticity modulus, high strength, fatigue resistance and good ductility with excellent corrosion resistance. In this regard, a new metastable beta titanium Ti-12Mo-8Nb alloy was developed, as an alternative for the traditional Ti-6Al-4V alloy, with the substitution of vanadium and aluminum for molybdenum and niobium. The objective of this work was to present the microstructural characterization and mechanical properties of the Ti-12Mo-8Nb alloy, heat treated for 1h at 950oC under high vacuum and then water quenched. The microstructure of the alloy was characterized by X-ray diffraction and optical microscopy. Vickers microhardness and nanoindentation were performed for determination of hardness, Young’s modulus and the ratio of hardness to Young’s modulus. The Ti-12Mo-8Nb microstructure consisted of β phase and the values obtained for the ratio of hardness to Young’s modulus were higher than the Ti-6Al-4V alloy.

Temperature dependences of the Young's modulus and internal friction of heat-treated silicon

1970 ◽  
Vol 13 (3) ◽  
pp. 366-370
Author(s):  
L. N. Aleksandrov ◽  
M. I. Zotov ◽  
F. L. �del'man
Keyword(s):  
Internal Friction ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Heat Treated ◽  
Temperature Dependences

scholarly journals A 3D-Printed Ultra-Low Young’s Modulus β-Ti Alloy for Biomedical Applications

Materials ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 2792 ◽  
Author(s):  
Massimo Pellizzari ◽  
Alireza Jam ◽  
Matilde Tschon ◽  
Milena Fini ◽  
Carlo Lora ◽  
...  
Keyword(s):  
Young’S Modulus ◽  
Biomedical Applications ◽  
Young's Modulus ◽  
Total Elongation ◽  
Potential Candidate ◽  
Β Phase ◽  
Grade 5 ◽  
Heat Treated ◽  
Columnar Grains ◽  
3D Printed

The metastable β-Ti21S alloy is evaluated as a potential candidate for biomedical parts. Near fully dense (99.75 ± 0.02%) samples are additively manufactured (that is, 3D-printed) by laser powder-bed fusion (L-PBF). In the as-built condition, the material consists of metastable β-phase only, with columnar grains oriented along the building direction. The material exhibits an extremely low Young’s modulus (52 ± 0.3 GPa), which was never reported for this type of alloy. The combination of good mechanical strength (σy0.2 = 709 ± 6 MPa, ultimate tensile strength (UTS) = 831 ± 3 MPa) and high total elongation during tensile test (21% ± 1.2%) in the as-built state, that is, without any heat treatment, is close to that of the wrought alloy and comparable to that of heat treated Ti grade 5. The good biocompatibility attested by cytotoxicity tests confirms its great suitability for biomedical applications.

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