Development of Ti-12Mo-8Nb Alloy for Biomedical Application

2017 ◽  
Vol 899 ◽  
pp. 191-194
Author(s):  
Sinara Borborema Gabriel ◽  
Jessica Peixoto da Silva Kassya ◽  
Caroline Miranda Jacinto ◽  
Leizy Pâmela Oliveira dos Santos ◽  
Carlos Angelo Nunes ◽  
...  
Keyword(s):  
Young’S Modulus ◽  
Biomedical Application ◽  
Young's Modulus ◽  
High Vacuum ◽  
High Strength ◽  
Microstructural Characterization ◽  
Β Phase ◽  
Beta Titanium ◽  
Heat Treated ◽  
Alloy Heat

Several beta titanium alloys were developed for biomedical applications due to the combination of low elasticity modulus, high strength, fatigue resistance and good ductility with excellent corrosion resistance. In this regard, a new metastable beta titanium Ti-12Mo-8Nb alloy was developed, as an alternative for the traditional Ti-6Al-4V alloy, with the substitution of vanadium and aluminum for molybdenum and niobium. The objective of this work was to present the microstructural characterization and mechanical properties of the Ti-12Mo-8Nb alloy, heat treated for 1h at 950oC under high vacuum and then water quenched. The microstructure of the alloy was characterized by X-ray diffraction and optical microscopy. Vickers microhardness and nanoindentation were performed for determination of hardness, Young’s modulus and the ratio of hardness to Young’s modulus. The Ti-12Mo-8Nb microstructure consisted of β phase and the values obtained for the ratio of hardness to Young’s modulus were higher than the Ti-6Al-4V alloy.

Electrochemical Behavior of Hot Treated Ti-12Mo-8Nb Alloy

2018 ◽  
Vol 930 ◽  
pp. 368-373
Author(s):  
Aline Raquel Vieira Nunes ◽  
Sinara Borborema Gabriel ◽  
Leonardo Sales Araújo ◽  
Carlos Angelo Nunes ◽  
Luiz Henrique de Almeida
Keyword(s):  
Mechanical Properties ◽  
Electrochemical Behavior ◽  
High Vacuum ◽  
High Strength ◽  
Passive Layer ◽  
The Body ◽  
Cytotoxic Effects ◽  
Β Phase ◽  
Beta Titanium ◽  
Heat Treated

Several beta titanium alloys are finding ever-increasing applications in biomaterials, due to the combination of its mechanical properties including low elasticity modulus, high strength, fatigue resistance and good ductility with improved corrosion resistance. In this regard, a new beta titanium Ti-12Mo-8Nb alloy was developed as an alternative to the traditional alloy Ti-6Al-4V. Studies have shown that the release of vanadium (V) and aluminum (Al) ions in the human body may cause cytotoxic effects and neurological disorders, respectively. Additionally, this new alloy presented higher ratio of hardness to elastic modulus, as compared to the commercial Ti-6Al-4V alloy. This paper presents the electrochemical behavior and mechanical properties of the Ti-12Mo-8Nb heat treated at 950 oC for 1h under high vacuum and then water quenched. The electrochemical behavior was carried through potentiodynamic polarization curves using Ringer's solution to simulate the body fluid. The Ti-12Mo-8Nb alloy presented a microstructure consisting of β phase with good mechanical properties and a passive layer was formed.

Mechanical Properties of Ti-Cr-Sn-Zr Alloys

2010 ◽  
Vol 638-642 ◽  
pp. 635-640 ◽  
Author(s):  
Yonosuke Murayama ◽  
Shuichi Sasaki ◽  
Hisamichi Kimura ◽  
Akihiko Chiba
Keyword(s):  
Mechanical Properties ◽  
Young’S Modulus ◽  
Biomedical Application ◽  
Young's Modulus ◽  
Mechanical Twinning ◽  
Β Phase ◽  
Low Modulus ◽  
Deformation Modes ◽  
Zr Alloy ◽  
Zr Alloys

Low modulus β Ti alloys are attractive for biomedical application. This work examines the mechanical properties of Ti-Cr-Sn-Zr system alloys, especially the effect of the varying alloy composition on the microstructure, the Young’s modulus and the deformation mechanism.The Young’s modulus of the alloy varies with the composition, which variation is caused mainly from the competition between the meta-stable β phase and ω phase.The deformation modes of the Ti-Cr-Sn-Zr alloy, which are the mechanical twinning, the deformation by slip and the deformation-induced transformation, also change depending on the composition of the alloy. The minimum of the Young’s modulusof the Ti-Cr-Sn-Zr alloy in this experiment was shown in the composition where the microstructure of the alloy changes from the martensitic structure to the meta-stable β structure.

A METALLURGICAL OVERVIEW OF TI – BASED ALLOY IN BIOMEDICAL APPLICATIONS

2015 ◽  
Vol 76 (7) ◽  
Author(s):  
Nur Hidayatul Nadhirah Elmi Azham Shah ◽  
Mazyan Yahaya ◽  
Maheran Sulaiman ◽  
Muhammad Hussain Ismail
Keyword(s):  
Young’S Modulus ◽  
Biomedical Application ◽  
Young's Modulus ◽  
Stress Shielding ◽  
Young Modulus ◽  
Processing Technique ◽  
Shielding Effect ◽  
Β Phase ◽  
Ti Alloys ◽  
Α Phase

Titanium (Ti)-based alloys are prominently used in biomedical application. This review paper emphasizes on some of the important aspects of the Ti-alloys in terms of metallurgical aspects, manufacturing routes and biocompatibility. Two kinds of structure are reviewed namely dense and porous, both differs in terms of purpose and satisfies different needs. This advancement of materials and equipment helps to improve the quality of life for patients and alleviate their health problems. Metallic materials, mainly Ti-based alloys have been used commercially as bone implant owing to its promising mechanical properties, biocompatibility and bioactivity. The outmost important issue in manufacturing  of  this  alloy  is  the  impurity  contents,  specifically  oxygen  and  carbon  which contribute   to decreasing in material performance of the alloy attributed from the formation of unwanted  oxide compounds such as TiO2 and  TiC. Another issue is the mismatch value of the Young’s modulus between the metallic implant and bone that result in stress shielding effect.  The structure of Ti-based  alloy is  mainly comprised of α-phase, β-phase or a combination of  both that result in variation of Young’s modulus ranging from 45 -110 GPa. Compared to α-phase Ti alloy, the β-phase rich alloys may exhibit lower value of Young modulus through the right processing technique. Therefore, the development of β-phase Ti-alloys has been researched progressively in line with the need of low Young’s modulus that suit for implant applications.

Structure, Microstructure, and Selected Mechanical Properties of Ti-Zr-Mo Alloys for Biomedical Applications

2014 ◽  
Vol 922 ◽  
pp. 75-80 ◽  
Author(s):  
Diego Rafael Nespeque Correa ◽  
Pedro Akira Bazaglia Kuroda ◽  
Carlos Roberto Grandini
Keyword(s):  
Mechanical Properties ◽  
Young’S Modulus ◽  
Biomedical Applications ◽  
Biomedical Application ◽  
Young's Modulus ◽  
Microstructural Analysis ◽  
Melting Furnace ◽  
High Hardness ◽  
Mechanical Analysis ◽  
Β Phase

New titanium alloys for biomedical applications have been developed primarily with the addition of Nb, Ta, Mo, and Zr, because those elements stabilize the β phase and they don’t cause cytotoxicity in the organism. The objective of this paper is to analyze the effect of molybdenum on the structure, microstructure, and selected mechanical properties of Ti-15Zr-xMo (x = 5, 10, 15, and 20 wt%) alloys. The samples were produced in an arc-melting furnace with inert argon atmosphere, and they were hot-rolled and homogenized. The samples were characterized using chemical, structural, and microstructural analysis. The mechanical analysis was made using Vickers microhardness and Young’s modulus measurements. The compositions of the alloys were sensitive to the molybdenum concentration, indicating the presence of α’+α”+β phases in the Ti-15Zr-5Mo alloy, α”+β in the Ti-15Zr-10Mo alloy, and β phase in the Ti-15Zr-15Mo and Ti-15Zr-20Mo alloys. The mechanical properties showed favorable values for biomedical application in the alloys presenting high hardness and low Young’s modulus compared with CP-Ti.

Effects of Nb Content on Young’s Modulus and Tensile Property of Ti-30Ta Alloy for Biomedical Applications

2011 ◽  
Vol 197-198 ◽  
pp. 32-35
Author(s):  
Yun Neng Wang ◽  
Yun Qing Ma ◽  
Shui Yuan Yang ◽  
Xu Liang Liu ◽  
Cui Ping Wang ◽  
...  
Keyword(s):  
Tensile Properties ◽  
Young’S Modulus ◽  
Tensile Property ◽  
Biomedical Applications ◽  
Young's Modulus ◽  
High Strength ◽  
Young’S Moduli ◽  
Β Phase ◽  
Nb Content ◽  
Nb Addition

The effects of Nb addition on microstructures, Young’s moduli, tensile properties of Ti-30Ta-xNb (x = 21, 24, 27, 30, wt. %) alloys were investigated in this study. The results show that dual phases containing β phase and a little α" martensite were observed when x = 21 and 24, whereas single β phase is present when x = 27 and 30. A minimum Young’s modulus of 52.13 GPa was obtained in Ti-30Ta-21Nb alloy. Ti-30Ta-xNb alloys exhibit high strength-to-modulus ratios, showing their great potentials to develop as new candidates for biomedical applications.

scholarly journals A 3D-Printed Ultra-Low Young’s Modulus β-Ti Alloy for Biomedical Applications

Materials ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 2792 ◽  
Author(s):  
Massimo Pellizzari ◽  
Alireza Jam ◽  
Matilde Tschon ◽  
Milena Fini ◽  
Carlo Lora ◽  
...  
Keyword(s):  
Young’S Modulus ◽  
Biomedical Applications ◽  
Young's Modulus ◽  
Total Elongation ◽  
Potential Candidate ◽  
Β Phase ◽  
Grade 5 ◽  
Heat Treated ◽  
Columnar Grains ◽  
3D Printed

The metastable β-Ti21S alloy is evaluated as a potential candidate for biomedical parts. Near fully dense (99.75 ± 0.02%) samples are additively manufactured (that is, 3D-printed) by laser powder-bed fusion (L-PBF). In the as-built condition, the material consists of metastable β-phase only, with columnar grains oriented along the building direction. The material exhibits an extremely low Young’s modulus (52 ± 0.3 GPa), which was never reported for this type of alloy. The combination of good mechanical strength (σy0.2 = 709 ± 6 MPa, ultimate tensile strength (UTS) = 831 ± 3 MPa) and high total elongation during tensile test (21% ± 1.2%) in the as-built state, that is, without any heat treatment, is close to that of the wrought alloy and comparable to that of heat treated Ti grade 5. The good biocompatibility attested by cytotoxicity tests confirms its great suitability for biomedical applications.

scholarly journals Achieving high strength and low Young’s modulus by controlling the beta stabilizers content in Ti-Nb-Ta-Zr-O alloys

2020 ◽  
Vol 321 ◽  
pp. 05013
Author(s):  
D. Preisler ◽  
J. Stráský ◽  
M. Janovská ◽  
H. Becker ◽  
P. Harcuba ◽  
...  
Keyword(s):  
Young’S Modulus ◽  
Oxygen Content ◽  
Young's Modulus ◽  
High Strength ◽  
Beta Phase ◽  
High Oxygen Content ◽  
Beta Titanium ◽  
Nb Content ◽  
High Microhardness ◽  
Metastable Beta

High strength and low Young’s modulus is the desired combination of mechanical properties for the endoprostheses material. Metastable beta titanium alloys are promising materials for this application. In this study, four Ti-xNb-6Ta-7Zr-0.7O (wt.%) alloys were prepared where Nb content ranged from 26 to 35 wt. %. All alloys contained pure beta phase. The high oxygen content causes high microhardness (330 HV), hence also the strength, while decreasing content of Nb leads to lower electrons per atom (e/a) ratio. The e/a ratio affects the Young’s modulus which is highest (76 GPa) in Ti-35Nb-6Ta-7Zr-0.7O alloy with e/a=4.31 and the lowest (64 GPa) in Ti-26Nb-6Ta-7Zr-0.7O with e/a=4.24. Such evolution of Young’s modulus is in accordance with existing literature data, however, in comparison with other works, the Ti-26Nb-6Ta-7Zr-0.7O alloy shows double microhardness when compared to alloys with similar Young’s modulus. Therefore, the approach of using controlled oxygen content for alloy design is very promising for development of biocompatible metastable beta Ti alloy for endoprostheses production.

scholarly journals First principles computation of composition dependent elastic constants of omega in titanium alloys: implications on mechanical behavior

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
R. Salloom ◽  
S. A. Mantri ◽  
R. Banerjee ◽  
S. G. Srinivasan
Keyword(s):  
Mechanical Properties ◽  
Young’S Modulus ◽  
First Principles ◽  
Young's Modulus ◽  
Group Vi ◽  
Group V ◽  
Β Phase ◽  
Ti Alloys ◽  
Ω Phase ◽  
Stabilizer Concentration

AbstractFor decades the poor mechanical properties of Ti alloys were attributed to the intrinsic brittleness of the hexagonal ω-phase that has fewer than 5-independent slip systems. We contradict this conventional wisdom by coupling first-principles and cluster expansion calculations with experiments. We show that the elastic properties of the ω-phase can be systematically varied as a function of its composition to enhance both the ductility and strength of the Ti-alloy. Studies with five prototypical β-stabilizer solutes (Nb, Ta, V, Mo, and W) show that increasing β-stabilizer concentration destabilizes the ω-phase, in agreement with experiments. The Young’s modulus of ω-phase also decreased at larger concentration of β-stabilizers. Within the region of ω-phase stability, addition of Nb, Ta, and V (Group-V elements) decreased Young’s modulus more steeply compared to Mo and W (Group-VI elements) additions. The higher values of Young’s modulus of Ti–W and Ti–Mo binaries is related to the stronger stabilization of ω-phase due to the higher number of valence electrons. Density of states (DOS) calculations also revealed a stronger covalent bonding in the ω-phase compared to a metallic bonding in β-phase, and indicate that alloying is a promising route to enhance the ω-phase’s ductility. Overall, the mechanical properties of ω-phase predicted by our calculations agree well with the available experiments. Importantly, our study reveals that ω precipitates are not intrinsically embrittling and detrimental, and that we can create Ti-alloys with both good ductility and strength by tailoring ω precipitates' composition instead of completely eliminating them.

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