scholarly journals Polyanilines as New Sorbents for Hydrocarbons Removal from Aqueous Solutions

Materials ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2161
Author(s):  
Cristina Della Pina ◽  
Maria Antonietta De Gregorio ◽  
Pierluisa Dellavedova ◽  
Ermelinda Falletta

Water remediation from hydrocarbons is crucial to reduce health risks. Numerous costly and, sometimes, sophisticated methods were proposed over the years. Herein, an innovative green procedure for porous polyanilines preparation is reported. Polyaniline (PANI) was synthesized by three different approaches ranging from traditional to more eco-friendly ones. Thermal, optical and morphological features of the resulting materials were investigated along with their surface properties. Finally, PANIs were tested as sorbents for hydrocarbons removal from waterbodies. Although an overall fast and high sorption efficiency is always observed, the effective hydrocarbons abatement performed by ‘green’ PANIs is particularly welcome in the context of environmental protection. Moreover, the sorption efficiency retention after five-run recycling tests suggests potential applications in wastewater remediation.

Chemosphere ◽  
2020 ◽  
Vol 243 ◽  
pp. 125330 ◽  
Author(s):  
Shafaqat Ali ◽  
Muhammad Rizwan ◽  
Muhammad Bilal Shakoor ◽  
Asim Jilani ◽  
Rameez Anjum

Author(s):  
Jure Žigon ◽  
Marko Petrič ◽  
Sebastian Dahle

A correction to this paper has been published: https://doi.org/10.1007/s00107-021-01724-z


Agriculture ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 714
Author(s):  
Vladimír Frišták ◽  
Martin Pipíška ◽  
Vladimír Turčan ◽  
Stephen M. Bell ◽  
Haywood Dail Laughinghouse ◽  
...  

Elevated or unnatural levels of arsenic (As) and phosphorus (P) concentrations in soils and waterbodies from anthropogenic sources can present significant hazards for both natural ecosystems and human food production. Effective, environmentally friendly, and inexpensive materials, such as biochar, are needed to reduce mobility and bioavailability of As and P. While biochar features several physicochemical properties that make it an ideal contaminant sorbent, certain modifications such as mineral-impregnation can improve sorption efficiencies for targeted compounds. Here, we conducted sorption experiments to investigate and quantify the potential utility of magnesium (Mg) for improving biochar sorption efficiency of P and As. We synthesized a Mg-modified walnut shells-derived biochar and characterized its ability to remove As and P from aqueous solutions, thereby mitigating losses of valuable P when needed while, at the same time, immobilizing hazardous As in ecosystems. SEM-EDX, FTIR and elemental analysis showed morphological and functional changes of biochar and the formation of new Mg-based composites (MgO, MgOHCl) responsible for improved sorption potential capacity by 10 times for As and 20 times for P. Sorption efficiency was attributed to improved AEC, higher SSA, chemical forms of sorbates and new sorption site formations. Synthetized Mg-composite/walnut shell-derived biochar also removed >90% of P from real samples of wastewater, indicating its potential suitability for contaminated waterbody remediation.


RSC Advances ◽  
2015 ◽  
Vol 5 (113) ◽  
pp. 92885-92892 ◽  
Author(s):  
Hong Guo ◽  
Shufen Zhang ◽  
Zinong Kou ◽  
Shangru Zhai ◽  
Wei Ma ◽  
...  

Different heavy metals present simultaneously in aqueous solutions should be separated to promote environmental protection.


2021 ◽  
pp. 218-245
Author(s):  
R. Jasrotia

The decreasing levels of consumable water on earth have been a serious issue and this issue makes the researchers and scientists develop new technologies for the purification of polluted water. Several reports have been carried on wastewater remediation by utilizing spinel ferrite-based nanoparticles and their composites. The spinel ferrites-based nanoparticles utilized for wastewater treatment was cost effective, chemically stable, easily retrieved and reusable. The present work addresses the various fabrication techniques for the preparation of spinel ferrite-based nanoparticles and their utilization for the removal of organic and inorganic pollutants through the adsorption paths.


1970 ◽  
Vol 91 (5) ◽  
pp. 448-452 ◽  
Author(s):  
Masakatu HATO ◽  
Masamichi FUJIHIRA ◽  
Haruo NAKAYAMA ◽  
Koza SHINODA

1999 ◽  
Vol 39 (8) ◽  
pp. 139-146
Author(s):  
R. Y. Stefanova

The kinetics of removal of zinc ions from aqueous solutions by a modified acrylnitrile copolymer containing carboxyl and amino groups has been investigated. The dependence of the rate of removal on the intensity of stirring, the size of the sorbent's particles, the initial concentration of metal ions and the temperature of the solution have been established. Attempts have been made to identify the rate limiting step and to determine the batch kinetic parameters. The limiting conditions of the transition from external to intraparticle diffusion step of mass transfer in a sorption system have been determined. The coefficients of intraparticle diffusion and the energy of activation of the sorption process have been established. The data obtained in this work show that the modified polymer with a high sorption capacity and very good kinetic characteristics can be successfully used for removal of heavy metal ions from water solutions and industrial wastewaters.


2018 ◽  
Vol 3 (11) ◽  
Author(s):  
Justin Pothoof ◽  
Michal Ruprecht ◽  
Ben D. Sliwinski ◽  
Ben M. Sosnowski ◽  
Polly R. Fitzgerald ◽  
...  

Abstract Two molecules, each including tris-2-amino-ethyleneamine (tren), have been produced using a Schiff’s base condensation and long-chain, aliphatic aldehydes. The syntheses are straightforward and can be run in air at ambient temperature. The ability of these molecules to complex with metal ions makes them good candidates for water remediation. The ability of these ligands to hold metal ions in 0.03 M non-aqueous solutions was unexpected. Their syntheses and characterization are discussed.


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