scholarly journals Evaluation of Mechanical and Shrinkage Behavior of Lowered Temperatures Cementitious Mortars Mixed with Nitrite–Nitrate Based Accelerator

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3686
Author(s):  
Yusuke Tomita ◽  
Akira Yoneyama ◽  
Heesup Choi ◽  
Masumi Inoue ◽  
Jihoon Kim ◽  
...  
Keyword(s):  
Calcium Nitrate ◽  
Frost Damage ◽  
Cold Weather ◽  
Early Age ◽  
Calcium Nitrite ◽  
Concrete Hydration ◽  
Early Strength ◽  
Main Components ◽  
Nitrite Nitrate ◽  
Shrinkage Behavior

Recently, calcium nitrite (Ca(NO2)2) and calcium nitrate (Ca(NO3)2) have been increasingly used as the main components of salt- and alkali-free anti-freezing agents, for promoting concrete hydration in cold-weather concreting. With an increase in the amount of nitrite-based accelerator, the hydration of C3A, C3S, and βC2S in the cement is accelerated, thereby improving its early strength and effectively preventing the initial frost damage. Meanwhile, with an increase in the amount of nitrite-based accelerator, the expansion and shrinkage of the concrete—and, therefore, the crack occurrence—are expected to increase. In this study, various experiments were conducted on shrinkage, crack initiation, and the development of mortar containing a considerable amount of a nitrite-based accelerator. The result confirmed that, as the amount of nitrite-based accelerator was increased, the shrinkage was increased, and cracking in early age was more likely to occur, compared to the cases without the addition of this accelerator.

scholarly journals Physicochemical Study on the Strength Development Characteristics of Cold Weather Concrete Using a Nitrite–Nitrate Based Accelerator

Materials ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 2706 ◽  
Author(s):  
Heesup Choi ◽  
Masumi Inoue ◽  
Hyeonggil Choi ◽  
Jihoon Kim ◽  
Yuhji Sudoh ◽  
...  
Keyword(s):  
Calcium Nitrate ◽  
Hydrate Formation ◽  
Cold Weather ◽  
Strength Development ◽  
Early Age ◽  
Hydration Reaction ◽  
Wide Range ◽  
Formation Behavior ◽  
Early Strength ◽  
Nitrite Nitrate

There has recently been an increased use of anti-freezing agents that are primarily composed of salt- and alkali-free calcium nitrite (Ca(NO2)2) and calcium nitrate (Ca(NO3)2) to promote the hydration reaction of concrete in cold weather concreting. Nitrite–nitrate based accelerators accelerate the hydration of C3A and C3S in cement more quickly when their quantities are increased, thereby boosting the concrete’s early strength and effectively preventing early frost damage. However, the connection between the hydrate formation behavior and the strength development characteristic over time has yet to be clearly identified. Therefore, in this study, a wide range of physicochemical reviews were carried out to clarify the relationship between the hydrate formation behavior and the strength development characteristics, both at an early age and at later ages, which results from the addition of nitrite–nitrate based accelerators to concrete in varying amounts. These accelerators also act as anti-freezing agents. The results show that an increased quantity of nitrite–nitrate based accelerators caused an increase in the early strength of the concrete. This was due to the formation of nitrite and nitrate hydrates in large amounts, in addition to ettringite containing SO42, which is generated during the hydration reaction of normal Portland cement at an early age. On the other hand, at later ages, there was a rise in nitrite and nitrate hydrates with needle crystal structures exhibiting brittle fracture behavior. A decrease in C–S–H gel and Ca(OH)2 hydrates, deemed to have caused a decline in strength on Day 3 and thereafter, was also observed.

scholarly journals Effect of a Nitrite/Nitrate-Based Accelerator on the Strength Development and Hydrate Formation in Cold-Weather Cementitious Materials

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 1006
Author(s):  
Akira Yoneyama ◽  
Heesup Choi ◽  
Masumi Inoue ◽  
Jihoon Kim ◽  
Myungkwan Lim ◽  
...  
Keyword(s):  
Calcium Nitrate ◽  
Hydrate Formation ◽  
Frost Damage ◽  
Cementitious Materials ◽  
Heat Of Hydration ◽  
Cold Weather ◽  
Strength Development ◽  
Hardened Cement ◽  
Tricalcium Aluminate ◽  
Nitrite Nitrate

Recently, there has been increased use of calcium-nitrite and calcium-nitrate as the main components of chloride- and alkali-free anti-freezing agents to promote concrete hydration in cold weather concreting. As the amount of nitrite/nitrate-based accelerators increases, the hydration of tricalcium aluminate (C3A phase) and tricalcium silicate (C3S phase) in cement is accelerated, thereby improving the early strength of cement and effectively preventing initial frost damage. Nitrite/nitrate-based accelerators are used in larger amounts than usual in low temperature areas below −10 °C. However, the correlation between the hydration process and strength development in concrete containing considerable nitrite/nitrate-based accelerators remains to be clearly identified. In this study, the hydrate composition (via X-ray diffraction and nuclear magnetic resonance), pore structures (via mercury intrusion porosimetry), and crystal form (via scanning electron microscopy) were determined, and investigations were performed to elucidate the effect of nitrite/nitrate-based accelerators on the initial strength development and hydrate formation of cement. Nitrite/nitrate-AFm (aluminate-ferret-monosulfate; AFm) was produced in addition to ettringite at the initial stage of hydration of cement by adding a nitrite/nitrate-based accelerator. The amount of the hydrates was attributed to an increase in the absolute amounts of NO2− and NO3− ions reacting with Al2O3 in the tricalcium aluminate (C3A phase). Further, by effectively filling the pores, it greatly contributed to the enhancement of the strength of the hardened cement product, and the degree of the contribution tended to increase with the amount of addition. On the other hand, in addition to the occurrence of cracks due to the release of a large amount of heat of hydration, the amount of expansion and contraction may increase, and it is considered necessary to adjust the amount used for each concrete work.

Advanced Early Strength Agent Development and Mechanism Analysis

2011 ◽  
Vol 261-263 ◽  
pp. 323-327 ◽  
Author(s):  
Yun Zhong Shi ◽  
Qi Wang ◽  
Peng Song ◽  
Li Li Jia
Keyword(s):  
Cement Hydration ◽  
Calcium Nitrate ◽  
Xrd Analysis ◽  
Mechanism Analysis ◽  
Mineral Formation ◽  
Early Strength ◽  
Main Components ◽  
Further Development ◽  
Agent Development

Preparation of advanced early strength agent ,the main components including organic A, organic B and calcium nitrate. Then tested advanced early strength agent performance for concrete. Though text, we find, the compressive strength and flexural strength of the specimen, use of the advanced early strength agent is greatly improved than with its much better not to use advanced early strength agent. With the passage of time, advanced early strength agent added does not make the strength of concrete worse, but better.Use SEM and XRD analysis technology text advanced early strength agent by adding performances of concrete, including the degree of cement hydration, the morphology of hydration products and the composition of mineral formation. analysis of the role of advanced early strength agents from the perspective of the mechanism. Identified advanced early strength agent impact on the cement hydration, for the further development of early strength agent to provide a theoretical basis.

Vulnerability of sweet cherry cultivars to continuous periods of spring frosts in Plovdiv, Bulgaria

2020 ◽  
Vol 12 (4) ◽  
pp. 348-352
Author(s):  
S. Malchev ◽  
S. Savchovska
Keyword(s):  
Sweet Cherry ◽  
Weather Conditions ◽  
Frost Damage ◽  
Cold Weather ◽  
Bud Burst ◽  
Intermediate Group ◽  
Air Temperatures ◽  
Wide Range ◽  
Group Form ◽  
Sweet Cherry Cultivars

Abstract. The periods with continuous freezing air temperatures reported during the spring of 2020 (13 incidents) affected a wide range of local and introduced sweet cherry cultivars in the region of Plovdiv. They vary from -0.6°C on March 02 to -4.9°C on March 16-17. The duration of influence of the lowest temperatures is 6 and 12 hours between March 16 and 17. The inspection of fruit buds and flowers was conducted twice (on March 26 and April 08) at different phenological stages after continuous waves of cold weather conditions alternated with high temperatures. During the phenological phase ‘bud burst’ (tight cluster or BBCH 55) some of the flowers in the buds did not develop further making the damage hardly detectable. The most damaged are hybrid El.28-21 (95.00%), ‘Van’ (91.89%) and ‘Bing’ (89.41%) and from the next group ‘Lapins’ (85.98%) and ‘Rosita’ (83.33%). A larger intermediate group form ‘Kossara’ (81.67%), ‘Rozalina’ (76.00%), ‘Sunburst’ (75.00%), ‘Bigarreau Burlat’ (69.11%) and ‘Kuklenska belitza’ (66.67%). Candidate-cultivar El.17-90 ‘Asparuh’ has the lowest frost damage values of 55.00% and El.17-37 ‘Tzvetina’ with damage of 50.60%.

scholarly journals Effect of Calcium Nitrate on the Properties of Portland–Limestone Cement-Based Concrete Cured at Low Temperature

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1611
Author(s):  
Gintautas Skripkiūnas ◽  
Asta Kičaitė ◽  
Harald Justnes ◽  
Ina Pundienė
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Setting Time ◽  
Calcium Nitrate ◽  
Curing Temperature ◽  
Hardened Concrete ◽  
Cement Pastes ◽  
Initial Setting Time ◽  
Initial Setting ◽  
Early Strength

The effect of calcium nitrate (CN) dosages from 0 to 3% (of cement mass) on the properties of fresh cement paste rheology and hardening processes and on the strength of hardened concrete with two types of limestone-blended composite cements (CEM II A-LL 42.5 R and 42.5 N) at different initial (two-day) curing temperatures (−10 °C to +20 °C) is presented. The rheology results showed that a CN dosage up to 1.5% works as a plasticizing admixture, while higher amounts demonstrate the effect of increasing viscosity. At higher CN content, the viscosity growth in normal early strength (N type) cement pastes is much slower than in high early strength (R type) cement pastes. For both cement-type pastes, shortening the initial and final setting times is more effective when using 3% at +5 °C and 0 °C. At these temperatures, the use of 3% CN reduces the initial setting time for high early strength paste by 7.4 and 5.4 times and for normal early strength cement paste by 3.5 and 3.4 times when compared to a CN-free cement paste. The most efficient use of CN is achieved at −5 °C for compressive strength enlargement; a 1% CN dosage ensures the compressive strength of samples at a −5 °C initial curing temperature, with high early strength cement exceeding 3.5 MPa but being less than the required 3.5 MPa in samples with normal early strength cement.

Very early age concrete hydration characterization monitoring using piezoceramic based smart aggregates

2013 ◽  
Vol 22 (8) ◽  
pp. 085025 ◽  
Author(s):  
Qingzhao Kong ◽  
Shuang Hou ◽  
Qing Ji ◽  
Y L Mo ◽  
Gangbing Song
Keyword(s):  
Early Age ◽  
Concrete Hydration ◽  
Early Age Concrete

Effects of Nano-CaCO3 on the Compressive Strength and Microstructure of High Strength Concrete in Different Curing Temperature

2011 ◽  
Vol 121-126 ◽  
pp. 126-131 ◽  
Author(s):  
Qing Lei Xu ◽  
Tao Meng ◽  
Miao Zhou Huang
Keyword(s):  
Compressive Strength ◽  
Low Temperature ◽  
High Strength Concrete ◽  
High Strength ◽  
Curing Temperature ◽  
Test Results ◽  
Strength Concrete ◽  
Calcium Nitrite ◽  
Orientation Index ◽  
Early Strength

In this paper, effects of nano-CaCO3 on compressive strength and Microstructure of high strength concrete in standard curing temperature(21±1°C) and low curing temperature(6.5±1°C) was studied. In order to improve the early strength of the concrete in low temperature, the early strength agent calcium nitrite was added into. Test results indicated that 0.5% dosage of nano-CaCO3 could inhibit the effect of calcium nitrite as early strength agent, but 1% and 2% dosage of nano-CaCO3 could improve the strength of the concrete by 13% and 18% in standard curing temperature and by 17% and 14% in low curing temperature at the age of 3days. According to the XRD spectrum, with the dosage up to 1% to 2%, nano-CaCO3 can change the orientation index significantly, leading to the improvement of strength of concrete both in standard curing temperature and low curing temperature.

Effect of Saturation Degree on Concrete Deterioration due to Freeze-Thaw Action

2011 ◽  
Vol 477 ◽  
pp. 404-408 ◽  
Author(s):  
Wen Cui Yang ◽  
Yong Ge ◽  
Bao Sheng Zhang ◽  
Jie Yuan
Keyword(s):  
Frost Resistance ◽  
Water Pressure ◽  
High Water ◽  
Frost Damage ◽  
Critical Value ◽  
Cold Weather ◽  
Saturation Degree ◽  
Freeze Thaw ◽  
Air Content ◽  
The Difference

Freezing-thawing durability of cement concrete is extremely important in cold weather, to better understand mechanism of frost damage and air-entraining，saturation degree of pores in concrete and its relation with frost resistance were studied in this paper. Concrete specimens with different saturation degree from 0 to 100% were prepared used a sealed tin with a high water pressure pump. Then these specimens were subjected to six freezing-thawing cycles and the relative dynamic modulus of elasticity was examined. The results showed that critical saturation degree of concrete with water- binder ratio of 0.30 and 0.47, air content of 1%, 4% and 6% were from 0.60 to 0.80. When its saturation degree exceeded the critical value, concrete was deteriorated significantly after only six freeze-thaw cycles. The critical saturation degree was mainly related to the air content of concrete mixture, and it decreased with the increasing of air content. The difference between the saturation degree and the critical value can be used to evaluate potential frost resistance of concrete, and its result was consistent with the result of frost tests very well.

scholarly journals The effect of spring frosts on the nectar production and the bee visitation of fruit trees

2000 ◽  
Vol 6 (1) ◽  
Author(s):  
P. Benedek ◽  
J. Nyéki ◽  
I. Amtmann ◽  
F. Bakcsa ◽  
J. Iváncsics ◽  
...  
Keyword(s):  
Tree Species ◽  
Fruit Trees ◽  
Frost Damage ◽  
Fruit Tree ◽  
Wild Plants ◽  
Cold Weather ◽  
Nectar Production ◽  
Spring Frost ◽  
Fruit Orchards ◽  
Spring Frosts

Fruit tree species suffered very strong spring frosts in 1997 in Hungary. This caused partial or total damages at buds and flowers depending on site and time of blooming. It was demonstrated at a number of experiments that frost and cold weather also strongly affected the nectar production of surviving flowers. No or very little amount of nectar was measured in flowers first of all of early blooming fruit tree species (apricot) but also of pear and apple in some places. In spite of this fact intensive honeybee visitation was detected in the flowers of fruit trees that suffered partial frost damage only at those sites where honeybee colonies were placed in or at the experimental plantations and the lack of sufficient amount of nectar did not affected bee behaviour seriously on fruit flowers. This means that bad nectar production failed to affect bee visitation of fruit trees definitely. The reason for this was the fact that not only fruit trees but another early bee plants (wild plants, too) suffered frost damage. Accordingly, in lack of forage bees intensively searched for food at blooming fruit trees with some living flowers. Consequently, there was an acceptable yield at those plantations where bud and flower damage was not complete. Accordingly, intensive bee visitation (that is moving additional bee colonies to overpopulate fruit orchards with honeybees) can be an effective tool to decrease or eliminate the detrimental effect of spring frost on the yield of fruit trees where bud or fruit damage is not too high.  

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