scholarly journals Chemical Modification of Cellulose Microfibres to Reinforce Poly(methyl methacrylate) Used for Dental Application

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3807 ◽  
Author(s):  
Joanna Taczała ◽  
Jacek Sawicki ◽  
Joanna Pietrasik

The mechanical properties of dental acrylic resins have to be improved in the case of a thin denture plate. This can be achieved by cellulose addition, playing the role of active filler. But to provide the excellent dispersion of cellulose microfibres within the hydrophobic polymer matrix, its surface has to be modified. Cellulose microfibres with average length from 8 to 30 μm were modified with octyltriethoxysilane and (3-methacryloxypropyl)methyldimethoxysilane. The latter also participated in the polymerisation reaction of methyl methacrylate. Dental composites were prepared following the general procedure provided by the supplier. The successful modification of the microfibres led to the improved compatibility of the cellulose and poly(methyl methacrylate). The fibres after modification were uniformly distributed within the matrix, resulting in the improved mechanical performance of obtained materials. Cellulose microfibres are good candidates for the dental materials to be used as the active filler. The simple and straightforward approach for the cellulose modifications with silanes provides good potential for its future practical application.

2021 ◽  
pp. 251659842110388
Author(s):  
Ankit Rathi ◽  
S. I. Kundalwal

In this study, the tensile properties of two-phase and three-phase graphene/ZrO2-hybrid poly (methyl methacrylate) (PMMA) nanocomposites are investigated by developing finite element model using ANSYS. Primarily, the effective elastic properties of two- and three-phase graphene/ZrO2-hybrid PMMA nanocomposites (GRPCs) are estimated by developing mechanics of material (MOM) model. Results indicated that the effective elastic properties of GRPCs increase with an increase in the volume fraction of graphene. Also, the stiffness of GRPCs is increased by 78.12% with increasing in the volume fraction of graphene from 0.1 to 0.5 Vf. The incorporation of an additional ZrO2 interphase significantly improved the mechanical performance of resulting GRPCs.


2012 ◽  
Vol 531 ◽  
pp. 153-156
Author(s):  
Ren Gui Peng ◽  
Cheng En He ◽  
Wei Tang ◽  
Yue E Liu ◽  
Ying Kui Yang

Poly(n-butyl acrylate) grafted silica nanoparticles were compounded with poly(methyl methacrylate) to yield silica/polymer composites with the improved dispersion of silica and interfacial adhesion with the matrix, thus showing increases in storage modulus and glass transition temperature.


2002 ◽  
Vol 17 (10) ◽  
pp. 2507-2513 ◽  
Author(s):  
P. A. O'Rourke Muisener ◽  
L. Clayton ◽  
J. D'Angelo ◽  
J. P. Harmon ◽  
A. K. Sikder ◽  
...  

Single-wall carbon nanotube (SWNT)/poly(methyl methacrylate) (PMMA) composites were fabricated and exposed to ionizing radiation for a total dose of 5.9 Mrads. Neat nanotube paper and pure PMMA were also exposed for comparison, and nonirradiated samples served as controls. A concentration of 0.26 wt% SWNT increased the glass transition temperature (Tg), the Vickers hardness number, and modulus of the matrix. Irradiation of the composite did not significantly change the Tg, the Vickers hardness number, or the modulus; however, the real and imaginary parts of the complex permittivity increased after irradiation. The dielectric properties were found to be more labile to radiation effects than mechanical properties.


2020 ◽  
Vol 10 (11) ◽  
pp. 4007 ◽  
Author(s):  
Flores-Arriaga Juan Carlos ◽  
García-Contreras Rene ◽  
Villanueva-Sánchez Germán ◽  
Acosta-Torres Laura Susana

Poly(methyl methacrylate) (PMMA) is a widely used polymer for dental applications, and it is mainly used in the fabrication of dental prostheses. In an increasing number of these applications, the risk of suffering bacterial or fungal infection is higher than 60% among oral-prosthesis users. Some authors have reported the failure of other implants in the human body due to biofilm formation on the surface (mainly for total hip implants). In the dental field, the formation of bacterial and fungal biofilms on prosthesis’s surface is the etiologic factor for stomatitis, mainly caused by Candida albicans and bacteria such as Staphylococcus epidermidis, Staphylococcus aureus, Pseudomonas aeruginosa and Enterococcus faecalis, as well as many others. The antibacterial and antifungal properties of silver nanoparticles (AgNPs) have been widely reported, and their use in dental materials can prevent oral infections, such as candidiasis and stomatitis, and promote better oral health in dental-prosthesis users. They can even be used in other biomedical applications that require controlling biofilm formation on surfaces. In this review, the reported studies that use composites of PMMA and AgNPs (PMMA-AgNPs) for dental applications are listed and checked, with the aim of gaining a wider perspective of the use and application of this approach in the dental field.


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