scholarly journals Dielectric Tunability Properties in (110)-Oriented Epitaxial 0.5Ba(Ti0.8Zr0.2)O3-0.5(Ba0.7Ca0.3)TiO3 Thin Films Prepared by PLD Method

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4771
Author(s):  
Bing Luo ◽  
Yiwen Xu ◽  
Fuzeng Zhang ◽  
Tingting Wang ◽  
Yingbang Yao

Epitaxial 0.5Ba(Ti0.8Zr0.2)O3-0.5(Ba0.7Ca0.3)TiO3 (BZT-BCT) thin films with single-crystal perovskite structure have been grown by pulsed laser deposition (PLD) on the (110) SrRuO3/SrTiO3 substrates. Temperature-dependent dielectric measurements show obvious characteristics of a diffused phase transition. Typical P-E hysteresis loops with a distinct ferroelectric imprint phenomenon are observed in these BZT-BCT thin films with a remnant polarization of 2.0 μC/cm2 and coercive field of 187 kV/cm. Small leakage currents (<1 × 10−6 A/cm2) are obtained in these thin films under an electrical field of 240 MV/m. These BZT-BCT thin films have shown large dielectric tunability values ranging from 75.8% to 85.7%, under a wide temperature range from 200 K to 330 K and a frequency range between 100 Hz and 100 kHz, which shows their good temperature and frequency stability. Such excellent dielectric tunability properties in these (110)-oriented BZT-BCT thin films promise their great potentials in practical phase shifter applications.

1998 ◽  
Vol 541 ◽  
Author(s):  
Tingkai Li ◽  
Fengyan Zhang ◽  
Sheng Teng Hsu

AbstractOne transistor memory devices have been proposed recently. To meet the needs of one transistor memory applications, C-axis oriented Pb5Ge3O11 (PGO) thin films were prepared using metalorganic chemical vapor deposition (MOCVD) and rapid thermal processing (RTP). It was found that the nucleation of C-axis Pb5Ge3O11 phase started at a deposition temperature below 400°C and grain growth dominated at 500°C or above. With increasing annealing temperature, the remanent polarization (Pr) and coercive field (Ec) values increased, and the hysteresis loops of the Pb5Ge3O11 films were well saturated and symmetrical after the post-annealing. The C-axis PGO thin film showed good ferroelectric properties at 5V: 2Pr and 2Ec values were 2.0 - 4.0 µC/cm2 and 90 - 110 kV/cm, respectively. The films also showed excellent fatigue characteristics: no fatigue was observed up to 1 × 109 switching cycles. The retention and imprint properties have also been studied. The leakage currents of the PGO films were 2 - 5 × 10−7 A/cm2 at 100 kV/cm and dielectric constants were 40 - 70. The high quality MOCVD Pb5Ge3O11 films can be used for single transistor ferroelectric memory devices.


2005 ◽  
Vol 482 ◽  
pp. 391-394
Author(s):  
T. Podgrabinski ◽  
Petr Slepička ◽  
V. Rybka ◽  
Václav Švorčík

Permittivity of about 1 µm thin films prepared from polymethylmetactrylate (PMMA) solution doped with 20 % of diphenyl sulfoxide was studied. Permittivity of the films was measured as a function of the temperature. The measurement of the dependence of polarization on electrical field was performed using a standard Sawyer-Tower circuit. The presence of the dopant increases the composite permittivity namely above the PMMA glass transition temperature. Hysteresis loops observed on the measured polarization vs. electrical field dependence indicate easier and more pronounced polarizability of the composite comparing to pristine PMMA.


1995 ◽  
Vol 381 ◽  
Author(s):  
James Baker-Jarvis ◽  
Chriss A. Jones

AbstractA review of the most common methods of permittivity measurements on thin films, printed-wiring and circuit boards, and substrates is presented. Transmission-line techniques, coaxial apertures, open resonators, surface-wave modes, and dielectric resonators methods are examined. The frequency range of applicability and typical uncertainties associated with the methods are summarized.


2004 ◽  
Vol 19 (6) ◽  
pp. 1638-1642
Author(s):  
S.T. Zhang ◽  
J.P. Li ◽  
Y.F. Chen ◽  
Z.G. Liu ◽  
N.B. Ming

Polycrystalline (Pb0.75La0.25)TiO3 (PLT25) thin films have been fabricated on Pt/Ti/SiO2/Si substrates by pulsed laser deposition. The room-temperature structures and dielectric properties are studied by x-ray diffraction, scanning electron microscopy, and HP4294A impedance/phase analyzer. The temperature-dependent ferroelectric properties are systematically investigated by using a RT66A ferroelectric tester combined with a temperature-controllable vacuum chamber. For well-saturated hysteresis loops, with the temperature decrease from 295 to 97 K, the coercive field (Ec) and remanent polarization (Pr) increase and the saturated polarization (Ps) is almost temperature-independent. However, this is not the case for the unsaturated hysteresis loops. Temperature-dependent fatigue-resistance of the PLT25 films is also experimentally established: after 2.22 × 109 switching cycles, the nonvolatile polarizationdecreases 38% when measured at room-temperature and it decreases 15% at 97 K. The nature and population of point defects and their effects on the subtle variations of the Ec, Ps, Pr, and fatigue-resistance against temperature are discussed in detail.


2015 ◽  
Vol 2 (3-4) ◽  
pp. 157-162
Author(s):  
Peng-Xiao Nie ◽  
Yi-Ping Wang ◽  
Ying Yang ◽  
Guo-Liang Yuan ◽  
Wei Li ◽  
...  

Abstract In this paper, high-quality multiferroic (1-x)BiFeO3-xYMnO3 (x=0.05, 0.10, 0.15) thin films were successfully epitaxially grown on (001)SrTiO3 substrates with La0.67Sr0.33MnO3 buffered layers by pulsed laser deposition (PLD). X-ray diffraction shows the thin films are all single-phase perovskite with preferential orientation along the (001) direction. The (002) diffraction angles of thin films (from 0 to 0.15) shift to right, indicating the decrease of lattice parameters. All YMnO3-doped thin films exhibit strong upward self-poling via piezoelectric force microscope (PFM) measurement. Saturated ferroelectric hysteresis loops of thin films cannot be obtained even at the frequency of 50 kHz because of large leakage currents. It is noted that BFO-YMO thin films exhibit ferroelectricity considering the PFM and ferroelectric test. The magnetization measurements show that all BiFeO3-based films exhibit weak ferromagnetic behaviors with saturated magnetization at room temperature. The enhancement of magnetization was observed because of YMO doping, with the maximum saturation magnetization (M s) of 17.07 emu/cm3 in x=0.10 thin film.


2002 ◽  
Vol 7 (2) ◽  
pp. 45-52
Author(s):  
L. Jakučionis ◽  
V. Kleiza

Electrical properties of conductive thin films, that are produced by vacuum evaporation on the dielectric substrates, and which properties depend on their thickness, usually are anisotropic i.e. they have uniaxial anisotropy. If the condensate grow on dielectric substrates on which plane electrical field E is created the transverse voltage U⊥ appears on the boundary of the film in the direction perpendicular to E. Transverse voltage U⊥ depends on the angle γ between the applied magnetic field H and axis of light magnetisation. When electric field E is applied to continuous or grid layers, U⊥ and resistance R of layers are changed by changing γ. It means that value of U⊥ is the measure of anisotropy magnitude. Increasing voltage U0 , which is created by E, U⊥ increases to certain magnitude and later decreases. The anisotropy of continuous thin layers is excited by inequality of conductivity tensor components σ0 ≠ σ⊥. The reason of anisotropy is explained by the model which shows that properties of grain boundaries are defined by unequal probability of transient of charge carrier.


2021 ◽  
Author(s):  
Seiichiro Ariyoshi ◽  
Satoshi Ohnishi ◽  
Hikaru Mikami ◽  
Hideto Tsuji ◽  
Yuki Arakawa ◽  
...  

Poly(L-lactide) (PLLA) was investigated by Fourier transform terahertz (THz) spectroscopy over the frequency range of 1.0 – 8.5 THz. THz absorption spectra were acquired for PLLA samples isothermally crystallized at...


Photonics ◽  
2021 ◽  
Vol 8 (3) ◽  
pp. 76
Author(s):  
Mikhail K. Khodzitsky ◽  
Petr S. Demchenko ◽  
Dmitry V. Zykov ◽  
Anton D. Zaitsev ◽  
Elena S. Makarova ◽  
...  

The terahertz frequency range is promising for solving various practically important problems. However, for the terahertz technology development, there is still a problem with the lack of affordable and effective terahertz devices. One of the main tasks is to search for new materials with high sensitivity to terahertz radiation at room temperature. Bi1−xSbx thin films with various Sb concentrations seem to be suitable for such conditions. In this paper, the terahertz radiation influence onto the properties of thermoelectric Bi1−xSbx 200 nm films was investigated for the first time. The films were obtained by means of thermal evaporation in vacuum. They were affected by terahertz radiation at the frequency of 0.14 terahertz (THz) in the presence of thermal gradient, electric field or without these influences. The temporal dependencies of photoconductivity, temperature difference and voltage drop were measured. The obtained data demonstrate the possibility for practical use of Bi1−xSbx thin films for THz radiation detection. The results of our work promote the usage of these thermoelectric materials, as well as THz radiation detectors based on them, in various areas of modern THz photonics.


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