scholarly journals Preparation and Thermal Conductivity of Epoxy Resin/Graphene-Fe3O4 Composites

Materials ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2013
Author(s):  
Zhong Wu ◽  
Jingyun Chen ◽  
Qifeng Li ◽  
Da-Hai Xia ◽  
Yida Deng ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Thermal Conductivity ◽  
Thermal Stability ◽  
Epoxy Resin ◽  
Thermomechanical Properties ◽  
Packaging Materials ◽  
Mass Ratio ◽  
Degree Of Orientation ◽  
Ep Matrix ◽  
Electrical Insulation Properties

By modifying the bonding of graphene (GR) and Fe3O4, a stable structure of GR-Fe3O4, namely magnetic GR, was obtained. Under the induction of a magnetic field, it can be orientated in an epoxy resin (EP) matrix, thus preparing EP/GR-Fe3O4 composites. The effects of the content of GR and the degree of orientation on the thermal conductivity of the composites were investigated, and the most suitable Fe3O4 load on GR was obtained. When the mass ratio of GR and Fe3O4 was 2:1, the thermal conductivity could be increased by 54.8% compared with that of pure EP. Meanwhile, EP/GR-Fe3O4 composites had a better thermal stability, dynamic thermomechanical properties, and excellent electrical insulation properties, which can meet the requirements of electronic packaging materials.

Preparation and characterization of surface modified boron nitride epoxy composites with enhanced thermal conductivity

RSC Advances ◽  
2014 ◽  
Vol 4 (83) ◽  
pp. 44282-44290 ◽  
Author(s):  
Jun Hou ◽  
Guohua Li ◽  
Na Yang ◽  
Lili Qin ◽  
Maryam E. Grami ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Thermal Stability ◽  
Boron Nitride ◽  
High Thermal Conductivity ◽  
Epoxy Composites ◽  
Surface Modified ◽  
Enhanced Thermal Conductivity ◽  
Electrical Insulation Properties

The fabricated surface modified boron nitride epoxy composites exhibit high thermal conductivity, superior thermal stability and good mechanical properties while retaining good electrical insulation properties.

Enhanced Thermal Conductivity for Graphene Nanoplatelets/Epoxy Resin Composites

2017 ◽  
Vol 10 (1) ◽  
Author(s):  
Dahai Zhu ◽  
Yu Qi ◽  
Wei Yu ◽  
Lifei Chen ◽  
Mingzhu Wang ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Epoxy Resin ◽  
Mass Fraction ◽  
Great Influence ◽  
Graphene Nanoplatelets ◽  
Resin Matrix ◽  
Heat Conducting ◽  
Factors Affecting ◽  
Molding Method ◽  
Ep Matrix

Graphene nanoplatelets (GNPs) have excellent thermal conductivity. It can significantly improve the heat-conducting property of epoxy resin (EP) matrix. In this paper, the GNPs/EP composites were successfully prepared by using ultrasonication and the cast molding method. The prepared GNPs/EP composites were systematically characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and thermal conductivity analyzer. Some factors affecting the thermal transfer performance of the composites were discussed. The defoamation has great influence on the thermal conductivity of composite. There is a nearly linear relationship between the mass fraction and the thermal conductivity of composite when the mass fraction of GNPs is below 4.3%. The results show that when the mass fraction of GNPs is 4.3% with crushing time of 2 s, the thermal conductivity of GNPs/EP composite is up to 0.99 W/m K. The thermal conductivity is increased by 9.0% compared with that without pulverization treatment (0.91 W/m K). When it is ground three times, the thermal conductivity of composite reaches the maximum (1.06 W/m K) and it is increased by 307.7% compared with that of epoxy resin matrix.

Thermomechanical properties of silica–epoxy nanocomposite modified by hyperbranched polyester: A molecular dynamics simulation

2021 ◽  
pp. 095400832110323
Author(s):  
Jianwen Zhang ◽  
Dongwei Wang ◽  
Lujia Wang ◽  
Wanwan Zuo ◽  
Xiaohua Ma ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Molecular Dynamics ◽  
Glass Transition ◽  
Epoxy Resin ◽  
Silica Surface ◽  
Thermomechanical Properties ◽  
Dynamics Simulation ◽  
Hyperbranched Polyester ◽  
Pure Epoxy ◽  
Epoxy Nanocomposite

In this article, pure epoxy resin and silica–epoxy nanocomposite models were established to investigate the effects of hyperbranched polyester on microstructure and thermomechanical properties of epoxy resin through molecular dynamics simulation. Results revealed that the composite of silica can improve the thermomechanical properties of nanocomposites, including the glass transition temperature, thermal conductivity, and elastic modulus. Moreover, the thermomechanical properties were further enhanced through chemical modification on the silica surface, where the effectiveness was the best through grafting hyperbranched polyester on the silica surface. Compared with pure epoxy resin, the glass transition temperature of silica–epoxy composite modified by silica grafted with hyperbranched polyester increased by 38 K. The thermal conductivity increased with the increase of temperature and thermal conductivity at room temperature increased to 0.4171 W/(m·K)−1 with an increase ratio of 94.3%. Young’s modulus, volume modulus, and shear modulus all fluctuated as temperature rise with a down overall trend. They increased by 44.68%, 29.52%, and 36.65%, respectively, when compared with pure epoxy resin. At the same time, the thermomechanical properties were closely related to the microstructure such as fractional free volume (FFV), mean square displacement (MSD), and binding energy. Silica surface modification by grafting hyperbranched polyester reduced the FFV value and MSD value most and strengthened the combination of silica and epoxy resin matrix the best, resulting in the best thermomechanical properties.

Improved Thermal Conductivities of Epoxy Resins Containing Surface Functionalized BN Nanosheets

NANO ◽  
2018 ◽  
Vol 13 (11) ◽  
pp. 1850133 ◽  
Author(s):  
Ling Weng ◽  
HeBing Wang ◽  
Xiaorui Zhang ◽  
Lizhu Liu ◽  
Hexin Zhang
Keyword(s):  
Thermal Conductivity ◽  
Epoxy Resins ◽  
Hexagonal Boron Nitride ◽  
Electrical Insulation ◽  
Coupling Agents ◽  
Thermal And Mechanical Properties ◽  
Silane Coupling Agents ◽  
Silane Coupling ◽  
Ep Matrix ◽  
Electrical Insulation Properties

The hexagonal boron nitride nanosheets (BN) were firstly treated by silane coupling agents 3-aminopropyltriethoxysilane (KH550) and 3-glycidoxypropyl-trimethoxysilane (KH560) to introduce some amino and epoxy (EP) groups on the BN surface. These modified BN nanosheets were incorporated into an EP matrix to prepare BN@KH560/EP composites with excellent thermal conductivity and electrical insulation properties. Results showed that the thermal conductivity of BN@KH560/EP composite with 20[Formula: see text]vol% BN dosage was found to be 0.442[Formula: see text]W/(m[Formula: see text]K), which was 81% higher than that of pure EP resin. Both BN/EP composites treated by KH550 and KH560 showed rather good electrical insulation properties, although the dielectric constant of BN@KH550/EP composites were slightly higher than BN@KH560/EP composites. Moreover, BN@KH560/EP composites also showed better thermal and mechanical properties than that of BN@KH550/EP composites.

Graphene Nanoplatelets/Epoxy Resin Composites With High Thermal Conductivity

2016 ◽  
Author(s):  
Yu Qi ◽  
Wei Yu ◽  
Li-Fei Chen ◽  
Hua-qing Xie ◽  
Ming-Zhu Wang
Keyword(s):  
Thermal Conductivity ◽  
Epoxy Resin ◽  
Mass Fraction ◽  
Graphene Nanoplatelets ◽  
Resin Matrix ◽  
Heat Conducting ◽  
Molding Method ◽  
Thermal Transfer ◽  
Conducting Property ◽  
Ep Matrix

Graphene nanoplatelets (GNPs) are a kind of material with excellent thermal conductivity. It can significantly improve the heat-conducting property of epoxy resin (EP) matrix. In this study, GNPs/EP composites were prepared by ultrasonication and the cast molding method. The effect of optimization in the preparation process on the thermal transfer performance of the composites was discussed. The pulverizing time of GNPs and three-roll grinder grinding of composites were considered. The results indicated that when the mass fraction of GNPs was 4.3%, in its pulverizing time of 2s, the thermal conductivity of GNPs/EP composites was up to 0.99 W/m·K, and it was increased by 9% compared with non-pulverization treatment. However, after pulverizing two seconds and grinding three times, the thermal conductivity of the composite reached the maximum (1.06 W/m·K) when the mass fraction of GNPs was 4.3%, and it was finally increased by 307.7% compared with epoxy resin matrix.

scholarly journals Effect of Particle Sizes of Nickel Powder on Thermal Conductivity of Epoxy Resin-Based Composites under Magnetic Alignment

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 1990
Author(s):  
Zheng Jin ◽  
Fei Liang ◽  
Wenzhong Lu ◽  
Jinhang Dai ◽  
Shunliang Meng ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Thermal Conductivity ◽  
Particle Size ◽  
Aluminum Nitride ◽  
Epoxy Resin ◽  
Nickel Powder ◽  
Chain Structure ◽  
Particle Sizes ◽  
Anisotropic Thermal Conductivity ◽  
Powder Particles

Magnetically oriented three-phase composite systems of epoxy resin, aluminum nitride, and nickel have been prepared, the thermal conductivity of composites filled with nickel powder with different particle sizes and content under different applied magnetic fields was studied. The vibrating scanning magnetometer (VSM) and scanning electron microscopy (SEM) were applied to investigate the dispersion of nickel powder in the composites. The results showed that the anisotropic thermal conductivity of the composites treated by applied magnetic field forming chain structure is obtained. The epoxy resin-based composites filled with 30 vol% aluminum nitride with particle size of 1 μm and 2 vol% nickel powder with particle size of 1 μm and aligned with vertical magnetic field have the highest thermal conductivity (1.474 W/mk), which increases the thermal conductivity of the composites by 737% and 58% compared to the pure epoxy resin (0.2 W/mk) and the composites filled with 30 vol% aluminum nitride (0.933 W/mk). In addition, we simulated the influence of nickel powder particles with different particle sizes and arrangements on the thermal conductivity of the composite material in COMSOL Multiphysics software, and the results were consistent with the experimental results.

Thermal-conductivity properties of liquid-crystalline epoxy resin cured under a magnetic field

2003 ◽  
Vol 41 (14) ◽  
pp. 1739-1743 ◽  
Author(s):  
Miyuki Harada ◽  
Mitsukazu Ochi ◽  
Masayuki Tobita ◽  
Tohru Kimura ◽  
Tsukasa Ishigaki ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Thermal Conductivity ◽  
Epoxy Resin ◽  
Liquid Crystalline ◽  
Liquid Crystalline Epoxy

A novel nanosilica/graphene oxide hybrid and its flame retarding epoxy resin with simultaneously improved mechanical, thermal conductivity, and dielectric properties

2015 ◽  
Vol 3 (18) ◽  
pp. 9826-9836 ◽  
Author(s):  
Rui Wang ◽  
Dongxian Zhuo ◽  
Zixiang Weng ◽  
Lixin Wu ◽  
Xiuyan Cheng ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Thermal Stability ◽  
Graphene Oxide ◽  
Dielectric Properties ◽  
Epoxy Resin ◽  
Flame Retardancy

A novel nanosilica/graphene oxide hybrid was prepared, which can simultaneously improve the typical properties (dielectric, thermal conductivity, thermal stability, and mechanical properties) and flame retardancy of epoxy resin.

scholarly journals Mechanical, Thermal, and Electrical Properties of BN–Epoxy Composites Modified with Carboxyl-Terminated Butadiene Nitrile Liquid Rubber

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1548 ◽  
Author(s):  
Xingming Bian ◽  
Rui Tuo ◽  
Wei Yang ◽  
Yiran Zhang ◽  
Qing Xie ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Thermal Stability ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Epoxy Resin ◽  
Epoxy Composite ◽  
Resin Matrix ◽  
Liquid Rubber

Filled high thermal conductivity epoxy composite solves the problem of the low thermal conductivity of the epoxy resin itself, but the addition of the thermal conductive filler reduces the mechanical properties of the composite, which limits its application in the field of high voltage insulation. In this work, carboxyl-terminated butadiene nitrile liquid rubber (CTBN) was used to toughen the boron nitride-epoxy hybrid system, and the effects of different contents of CTBN on the mechanical properties, thermal conductivity, glass transition temperature, thermal stability, and dielectric properties of the composites were investigated. The results showed that when the content of CTBN was 5–15 wt.%, the CTBN formed a dispersed island structure in the epoxy resin matrix. The toughness of the composite increased by about 32%, the breakdown strength was improved, and the thermal conductivity was about 160% higher than that of pure epoxy resin. As the CTBN content increased, the glass transition temperature and thermal stability of the composite decreased and the dielectric constant and the dielectric loss increased. When the CTBN content is 10–15 wt.%, a toughened epoxy composite material with better comprehensive properties is obtained.

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