scholarly journals Development and Characterization of Activated Carbon from Olive Pomace: Experimental Design, Kinetic and Equilibrium Studies in Nimesulide Adsorption

Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6820
Author(s):  
Íris Nunes Raupp ◽  
Alaor Valério Filho ◽  
Aline Lemos Arim ◽  
Ana Rosa Costa Muniz ◽  
Gabriela Silveira da Rosa
Keyword(s):  
Activated Carbon ◽  
Experimental Design ◽  
Emerging Contaminants ◽  
Environmental Concern ◽  
Industrial Effluents ◽  
Raw Material ◽  
Olive Pomace ◽  
Equilibrium Studies ◽  
Adequate Treatment ◽  
Charge Potential

The lack of adequate treatment for the removal of pollutants from domestic, hospital and industrial effluents has caused great environmental concern. Therefore, there is a need to develop materials that have the capacity to treat these effluents. This work aims to develop and characterize an activated charcoal from olive pomace, which is an agro-industrial residue, for adsorption of Nimesulide in liquid effluent and to evaluate the adsorption kinetics and equilibrium using experimental design. The raw material was oven dried at 105 °C for 24 h, ground, chemically activated in a ratio of 1:0.8:0.2 of olive pomace, zinc chloride and calcium hydroxide and thermally activated by pyrolysis in a reactor of stainless steel at 550 °C for 30 min. The activated carbon was characterized by Fourier Transform Infrared (FTIR) spectroscopy, X-ray Diffractometry (XRD), Brunauer, Emmett and Teller (BET) method, Thermogravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), density and zero charge potential analysis. The surface area obtained was 650.9 m2 g−1. The kinetic and isothermal mathematical models that best described the adsorption were PSO and Freundlich and the highest adsorption capacity obtained was 353.27 mg g−1. The results obtained showed the good performance of activated carbon produced from olive pomace as an adsorbent material and demonstrated great potential for removing emerging contaminants such as Nimesulide.

Effects of activated carbon on treatment of photo-processing waste by sulfur-oxidizing bacteria

1997 ◽  
Vol 35 (7) ◽  
pp. 187-195 ◽  
Author(s):  
Binle Lin ◽  
K. Futono ◽  
A. Yokoi ◽  
M. Hosomi ◽  
A. Murakami
Keyword(s):  
Activated Carbon ◽  
Treatment Effectiveness ◽  
Environmental Concern ◽  
Type Systems ◽  
Continuous Treatment ◽  
Processing Waste ◽  
Treatment Technology ◽  
Adsorption Effect ◽  
Sulfur Oxidizing ◽  
Sulfur Oxidizing Bacteria

Establishing economic treatment technology for safe disposal of photo-processing waste (PW) has most recently become an urgent environmental concern. This paper describes a new biological treatment process for PW using sulfur-oxidizing bacteria (SOB) in conjunction with activated carbon (AC). Batch-type acclimation and adsorption experiments using SOB/PAC, SOB/PNAC, and SOB reactor type systems demonstrated that AC effectively adsorbs the toxic/refractory compounds which inhibit thiosulfate oxidization of SOB in PW. Thus, to further clarify the effect of AC, we performed a long-term (≈ 160 d) continuous-treatment experiment on 4- to 8-times dilution of PW using a SOB/GAC system which simulated a typical wastewater treatment system based on an aerobic activated sludge process that primarily uses acclimated SOB. The thiosulfate load and hydraulic retention time (HRT) were fixed during treatment such that they ranged from 0.8-3.7 kg S2O32-/l/d and 7.7-1.9 d, respectively. As expected, continuous treatment led to breakthrough of the adsorption effect of GAC. Renewing the GAC and continuing treatment for about 10 d demonstrated good treatment effectiveness.

scholarly journals Study on Adsorption Properties of Modified Corn Cob Activated Carbon for Mercury Ion

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4483
Author(s):  
Yuyingnan Liu ◽  
Xinrui Xu ◽  
Bin Qu ◽  
Xiaofeng Liu ◽  
Weiming Yi ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Photoelectron Spectroscopy ◽  
Adsorption Process ◽  
Physical Adsorption ◽  
Raw Material ◽  
Order Kinetic ◽  
Mercury Ions ◽  
Corn Cob ◽  
Adsorption Time ◽  
X Ray

In this study, corn cob was used as raw material and modified methods employing KOH and KMnO4 were used to prepare activated carbon with high adsorption capacity for mercury ions. Experiments on the effects of different influencing factors on the adsorption of mercury ions were undertaken. The results showed that when modified with KOH, the optimal adsorption time was 120 min, the optimum pH was 4; when modified with KMnO4, the optimal adsorption time was 60 min, the optimal pH was 3, and the optimal amount of adsorbent and the initial concentration were both 0.40 g/L and 100 mg/L under both modified conditions. The adsorption process conforms to the pseudo-second-order kinetic model and Langmuir model. Scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and Zeta potential characterization results showed that the adsorption process is mainly physical adsorption, surface complexation and ion exchange.

Ouricuri (Syagrus coronata) fiber: a novel biosorbent to remove methylene blue from aqueous solutions

2016 ◽  
Vol 75 (1) ◽  
pp. 106-114 ◽  
Author(s):  
Lucas Meili ◽  
Társila Santos da Silva ◽  
Daniely Carlos Henrique ◽  
João Inácio Soletti ◽  
Sandra Helena Vieira de Carvalho ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Experimental Design ◽  
Aqueous Solutions ◽  
Adsorption Capacity ◽  
Adsorption Process ◽  
Fiber Diameter ◽  
Aqueous Media ◽  
Process Efficiency ◽  
Maximum Adsorption Capacity ◽  
Equilibrium Studies

In this work, the potential of ouricuri (Syagrus coronata) fiber as a novel biosorbent to remove methylene blue (MB) from aqueous solutions was investigated. The fiber was prepared and characterized according to the fundamental features for adsorption. A 23 experimental design was used to evaluate the effects of adsorbent dosage (M), fiber diameter (D) and agitation (A) on the adsorption capacity. In the more adequate conditions, kinetic and equilibrium studies were performed. The experimental design results showed that M = 10 g L−1), D = 0.595 mm and A = 200 rpm were the more adequate conditions for MB adsorption. Based on the kinetic study, it was found that the adsorption process was fast, being the equilibrium was attained at about 5 min, with 90% of color removal. The isotherm was properly represented by the Sips model, and the maximum adsorption capacity was 31.7 mg g−1. In brief, it was demonstrated that ouricuri fiber is an alternative biosorbent to remove MB from aqueous media, taking into account the process efficiency and economic viewpoint.

Study of elimination of emerging contaminants by adsorption using activated carbon of coconut (amoxicillin - penicillin - theobromine)

2021 ◽  
Author(s):  
Badr Bouhcain ◽  
Fouad El Mansouri ◽  
Jamal Brigui ◽  
Santiago Gutiérrez Ruiz ◽  
José Maria Quiroga Alonso ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Emerging Contaminants

Emerging Contaminants of Environmental Concern: Source, Transport, Fate, and Treatment

2010 ◽  
Vol 14 (1) ◽  
pp. 2-20 ◽  
Author(s):  
Song Yan ◽  
S. Bala Subramanian ◽  
R. D. Tyagi ◽  
Rao Y. Surampalli ◽  
Tian C. Zhang
Keyword(s):  
Emerging Contaminants ◽  
Environmental Concern

scholarly journals PENGARUH PENAMBAHAN KARBON AKTIF DARI KULIT SINGKONG TERHADAP PENURUNAN KADAR MANGAN (Mn) DALAM AIR DENGAN BEBERAPA VARIASI KONSENTRASI

2019 ◽  
Vol 7 (2) ◽  
pp. 96
Author(s):  
Darmawati Darmawati ◽  
Syarifah Maulidar ◽  
Khairun Nisa
Keyword(s):  
Activated Carbon ◽  
Spectrophotometric Method ◽  
Carbon Concentration ◽  
Raw Material ◽  
Manganese Concentration ◽  
Manganese Reduction ◽  
Cassava Peels ◽  
Cassava Peel ◽  
Banda Aceh

The study aims to find out about the possibility of utilizing cassava peel waste as raw material for making activated carbon to reduce levels of Manganese in water. This study also wants to see the effect of variations in the concentration of activated carbon from cassava peels on decreasing levels of Manganese in water. This research was conducted at the Laboratory of the Akademi Analis Kesehatan Pemerintah Aceh and at the UPTD Laboratorium Kesehatan Banda Aceh on 3-11 March 2016. Manganese was analysed using the persulfate method while the Manganese was examinated by the spectrophotometric method. The sample used is an artificial sample by adding MnSO4 to water. The variation of activated carbon concentration added is 2 gr, 3 gr, and 4 gr. The results are that with the addition of 2 grams of activated carbon the percentage of Manganese reduction was 70.37%, the addition of 3 grams of activated carbon decreased Manganese concentration by 86.59%, while the addition of 4 grams of activated carbon reduced the percentage of Manganese to 92.33%. It can be concluded that the higher the concentration of activated carbon added, the higher the decrease in levels of Manganese in the water.

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