scholarly journals Effect of Ornamental Stone Waste Incorporation on the Rheology, Hydration, Microstructure, and CO2 Emissions of Ordinary Portland Cement

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 401
Author(s):  
Taylana Piccinini Scolaro ◽  
Laura Silvestro ◽  
Artur Spat Ruviaro ◽  
Afonso R. G. de Azevedo ◽  
Sergio Neves Monteiro ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Co2 Emission ◽  
Ordinary Portland Cement ◽  
Hydration Kinetics ◽  
Ornamental Stone ◽  
Co2 Equivalent ◽  
Hardened Properties ◽  
Stone Industry ◽  
Similar Yield

The ornamental stone industry generates large amounts of waste thus creating environmental and human health hazards. Thus, pastes with 0–30 wt.% ornamental stone waste (OSW) incorporated into ordinary Portland cement (OPC) were produced and their rheological properties, hydration kinetics, and mechanical properties were evaluated. The CO2 equivalent emissions related to the pastes production were estimated for each composition. The results showed that the paste with 10 wt.% of OSW exhibited similar yield stress compared to the plain OPC paste, while pastes with 20 and 30 wt.% displayed reduced yield stresses up to 15%. OSW slightly enhanced the hydration kinetics compared to plain OPC, increasing the main heat flow peak and 90-h cumulative heat values. The incorporation of OSW reduced the 1-, 3-, and 28-days compressive strength of the pastes. Water absorption results agreed with the 28 days compressive strength results, indicating that OSW increased the volume of permeable voids. Finally, OSW incorporation progressively reduced the CO2 emission per m3 of OPC paste, reaching a 31% reduction for the highest 30 wt.% OSW content. Overall, incorporating up to 10 wt.% with OSW led to pastes with comparable fresh and hardened properties as comported to plain OPC paste.

Cellulose Nanocomposites for Performance Enhancement of Ordinary Portland Cement-Based Materials

2020 ◽  
pp. 036119812095842
Author(s):  
Kavya S. Kamasamudram ◽  
Warda Ashraf ◽  
Eric N. Landis
Keyword(s):  
Compressive Strength ◽  
Flexural Strength ◽  
Portland Cement ◽  
Cement Paste ◽  
Ordinary Portland Cement ◽  
Performance Enhancement ◽  
Mechanical Performance ◽  
Early Stage ◽  
Microstructural Development ◽  
Hydration Kinetics

Cellulose nanofibril (CNF) with a high aspect ratio, elastic modulus, tensile strength, and reactive surface area is a promising nanomaterial for improving the chemo-mechanical properties of cementitious matrixes. CNFs are typically less than 0.2 mm in length and 50 nm in width, and are extracted from plants and trees. This study investigated the potential application of three types of CNF for enhancing the performance of ordinary Portland cement (OPC) pastes: pure CNF (PCNF), silica coated CNF (SCNF), and lignin-containing CNF (LCNF). The performance of the cement pastes was monitored for cement paste workability, hydration kinetics, microstructural development, and mechanical performance (compressive strength and flexural strength). The dispersion stability of CNFs measured through zeta potential showed a better dispersion for SCNF when compared with PCNF and LCNF in varied alkaline mediums. The better stability of SCNF also resulted in improved workability of the cement paste mixtures containing this type of cellulose. All of the cellulose nanomaterials accelerated the cement hydration at the early stage as a result of the nucleation effect. Such an acceleration effect was slightly higher for SCNF because of the presence of silica nanoparticles. The addition of 0.1% SCNF increased the compressive strength (90 days) by 13% when compared with the control batch and 10% compared with the PCNF batch. The addition of 0.1% of PCNF enhanced the flexural strength by 70% followed by LCNF with 40% improvement. SCNF showed little to no effect on the flexural strength.

Study on Waterproof and Water-Resistant Properties of Gypsum

2012 ◽  
Vol 476-478 ◽  
pp. 1585-1588
Author(s):  
Hong Pan ◽  
Guo Zhong Li
Keyword(s):  
Compressive Strength ◽  
Flexural Strength ◽  
Portland Cement ◽  
Water Absorption ◽  
Ordinary Portland Cement ◽  
Experimental Results ◽  
Softening Coefficient

The comprehensively modified effect of cement, VAE emulsion and self-made acrylic varnish on mechanical and water-resistant properties of gypsum sample was investigated and microstructure of gypsum sample was analyzed. Experimental results exhibit that absolutely dry flexural strength, absolutely dry compressive strength, water absorption and softening coefficient of gypsum specimen with admixture of 10% ordinary Portland cement and 6% VAE emulsion and acrylic varnish coated on its surface can respectively reach to 5.11MPa , 10.49 MPa, 8.32% and 0.63, respectively.

scholarly journals The Effect of Nano Metakaolin Material on Some Properties of Concrete

2013 ◽  
Vol 6 (1) ◽  
pp. 50-61
Author(s):  
Amer M. Ibrahem ◽  
Shakir A. Al-Mishhadani ◽  
Zeinab H.Naji
Keyword(s):  
Tensile Strength ◽  
Compressive Strength ◽  
Portland Cement ◽  
Water Absorption ◽  
Thermal Activation ◽  
Ordinary Portland Cement ◽  
Splitting Tensile Strength ◽  
Kaolin Clay ◽  
Cement Ratio ◽  
Water Cement Ratio

This investigation aimed to study the effect of nano metakaolin ( NMK ) on some properties (compressive strength ,splitting tensile strength & water absorption ) of concrete. The nano metakaolin (NMK) was prepared by thermal activation of kaolin clay for 2 hours at 750 Ċ. The cement used in this investigation consists of ordinary Portland cement (OPC). The OPC was partially substituted by NMK of ( 3, 5 & 10%) by weight of cement. The C45 concrete was prepared , using water/cement ratio ( W/c) of (0.53) .The Water absorption was tested at 28 days while the tests (compressive strength ,splitting tensile strength) were tested at ages of (7, 28, 60,& 90) days . The compressive strength and splitting tensile strength of concrete with NMK were higher than that of reference concrete with the same W/c ratio.The improvement in the compressive strength when using NMK was (42.2, 55.8 , 63.1% ) at age 28 days for ( 3%, 5%, &10% ) replacement of NMK respectively whereas the improvement in the splitting tensile strength was (0% , 36% & 46.8 %) at age of 28 days when using (3%, 5%, &10% ) NMK respectively. The improvement in the water absorption was (16.6%, 21.79%, &25.6 ) when using (3, 5, &10% )NMK.

scholarly journals Utilization of Sugarcane Bagasse Ash from Power Co-generation Boilers as a Supplementary Cementitious Material

2021 ◽  
Vol 2 (2) ◽  
Author(s):  
Safiki Ainomugisha ◽  
Bisaso Edwin ◽  
Bazairwe Annet
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Sugarcane Bagasse ◽  
Low Income ◽  
Ordinary Portland Cement ◽  
Construction Material ◽  
Sustainable Construction ◽  
Partial Replacement ◽  
Hardened Concrete ◽  
Sugarcane Bagasse Ash

Concrete has been the world’s most consumed construction material, with over 10 billion tons of concrete annually. This is mainly due to its excellent mechanical and durability properties plus high mouldability. However, one of its major constituents; Ordinary Portland Cement is reported to be expensive and unaffordable by most low-income earners. Its production contributes about 5%–8% of global CO2 greenhouse emissions. This is most likely to increase exponentially with the demand of Ordinary Portland Cement estimated to rise by 200%, reaching 6000 million tons/year by 2050.  Therefore, different countries are aiming at finding alternative sustainable construction materials that are more affordable and offer greener options reducing reliance on non-renewable sources. Therefore, this study aimed at assessing the possibility of utilizing sugarcane bagasse ash from co-generation in sugar factories as supplementary material in concrete. Physical and chemical properties of this sugarcane bagasse ash were obtained plus physical and mechanical properties of fresh and hardened concrete made with partial replacement of Ordinary Portland Cement. Cost-benefit analysis of concrete was also assessed. The study was carried using 63 concrete cubes of size 150cm3 with water absorption studied as per BS 1881-122; slump test to BS 1881-102; and compressive strength and density of concrete according to BS 1881-116. The cement binder was replaced with sugarcane bagasse ash 0%, 5%, 10%, 15%, 20%, 25% and 30% by proportion of weight. Results showed the bulk density of sugarcane bagasse ash at 474.33kg/m3, the specific gravity of 1.81, and 65% of bagasse ash has a particle size of less than 0.28mm. Chemically, sugarcane bagasse ash contained SiO2, Fe2O3, and Al2O3 at 63.59%, 3.39%, and 5.66% respectively. A 10% replacement of cement gave optimum compressive strength of 26.17MPa. This 10% replacement demonstrated a cost saving of 5.65% compared with conventional concrete. 

scholarly journals Chloride Ingress in Chemically Activated Calcined Clay-Based Cement

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Joseph Mwiti Marangu ◽  
Joseph Karanja Thiong’o ◽  
Jackson Muthengia Wachira
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Strength Development ◽  
Chloride Ingress ◽  
Calcined Clay ◽  
Apparent Diffusion Coefficients ◽  
Apparent Diffusion ◽  
Lower Porosity ◽  
Lower Chloride

Chloride-laden environments pose serious durability concerns in cement based materials. This paper presents the findings of chloride ingress in chemically activated calcined Clay-Ordinary Portland Cement blended mortars. Results are also presented for compressive strength development and porosity tests. Sampled clays were incinerated at a temperature of 800°C for 4 hours. The resultant calcined clay was blended with Ordinary Portland Cement (OPC) at replacement level of 35% by mass of OPC to make test cement labeled PCC35. Mortar prisms measuring 40 mm × 40 mm × 160 mm were cast using PCC35 with 0.5 M Na2SO4 solution as a chemical activator instead of water. Compressive strength was determined at 28th day of curing. As a control, OPC, Portland Pozzolana Cement (PPC), and PCC35 were similarly investigated without use of activator. After the 28th day of curing, mortar specimens were subjected to accelerated chloride ingress, porosity, compressive strength tests, and chloride profiling. Subsequently, apparent diffusion coefficients (Dapp) were estimated from solutions to Fick’s second law of diffusion. Compressive strength increased after exposure to the chloride rich media in all cement categories. Chemically activated PCC35 exhibited higher compressive strength compared to nonactivated PCC35. However, chemically activated PCC35 had the least gain in compressive strength, lower porosity, and lower chloride ingress in terms of Dapp, compared to OPC, PPC, and nonactivated PCC35.

Quaternary blended cement mortars containing wood ash, glass and slag powders

2021 ◽  
Author(s):  
Eethar Thanon Dawood ◽  
Marwa Saadi Mhmood
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Glass Powder ◽  
Steel Slag ◽  
Wood Ash ◽  
Supplementary Cementitious Materials ◽  
Partial Replacement ◽  
Slag Powder ◽  
Steel Slag Powder

AbstractA quaternary supplementary cementitious materials as partial replacement of ordinary Portland cement decreases CO2 emission. This paper has investigated the properties of mortars made from different quaternary blends of wood ash, steel slag powder and glass powder with ordinary Portland cement at different replacement levels of 0, 24, 25, and 30% by weight of the binder. The blended mortar mixtures tested for flow, compressive strength and density. The results showed that the flow of mortars is decreased with the combined use of steel slag powder, glass powder, and wood ash compared with control mix. Compressive strength reduced with the combination of steel slag powder, glass powder and wood ash but this reduction effects is acceptable especially at 24% replacement contain super-plasticizer compared with the ecological benefit.

scholarly journals Physical Properties of Concrete Containing Graphene Oxide Nanosheets

Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1707 ◽  
Author(s):  
Yu-You Wu ◽  
Longxin Que ◽  
Zhaoyang Cui ◽  
Paul Lambert
Keyword(s):  
Tensile Strength ◽  
Compressive Strength ◽  
Graphene Oxide ◽  
Flexural Strength ◽  
Portland Cement ◽  
Physical Properties ◽  
Ordinary Portland Cement ◽  
Construction Materials ◽  
Split Tensile Strength ◽  
Cement Pastes

Concrete made from ordinary Portland cement is one of the most widely used construction materials due to its excellent compressive strength. However, concrete lacks ductility resulting in low tensile strength and flexural strength, and poor resistance to crack formation. Studies have demonstrated that the addition of graphene oxide (GO) nanosheet can effectively enhance the compressive and flexural properties of ordinary Portland cement paste, confirming GO nanosheet as an excellent candidate for using as nano-reinforcement in cement-based composites. To date, the majority of studies have focused on cement pastes and mortars. Only limited investigations into concretes incorporating GO nanosheets have been reported. This paper presents an experimental investigation on the slump and physical properties of concrete reinforced with GO nanosheets at additions from 0.00% to 0.08% by weight of cement and a water–cement ratio of 0.5. The study demonstrates that the addition of GO nanosheets improves the compressive strength, flexural strength, and split tensile strength of concrete, whereas the slump of concrete decreases with increasing GO nanosheet content. The results also demonstrate that 0.03% by weight of cement is the optimum value of GO nanosheet dosage for improving the split tensile strength of concrete.

Alkali Activation of Granulated Blast Furnace Slag

2010 ◽  
Vol 158 ◽  
pp. 1-11 ◽  
Author(s):  
Zi Qiao Jin ◽  
Xian Jun Lu ◽  
Shu Gang Hu
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Portland Cement ◽  
Blast Furnace Slag ◽  
Ordinary Portland Cement ◽  
Hydration Product ◽  
Early Age ◽  
Hydration Products ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

In order to stimulate the potential cementitious property of granulated blast furnace slag (GBFS), the ground GBFS sample (Wei Fang Iron and Steel Corporation, China) was activated by lime and gypsum under different dosages. The results showed that lime is an effective activator for the slag, and the optimum dosage of lime is about 10% (w/w) of the slag. At the optimum dosage of lime, the 28 days compressive strength of the lime-slag paste is higher than that of 32.5 ordinary Portland cement (OPC). But, the early age strength (3 and 7 days compressive strength) of the lime-slag paste is lower than that of the OPC. Addition of gypsum can effectively improve the early age strength of the lime-slag paste. At the ratio of gypsum:lime:slag of 8.2:9.2:82.6 (w/w), both the early and long-term compressive strengths of the gypsum-lime-slag paste are higher than that of the OPC. According to XRD, TG-DTA and SEM detections of the hydration products of the lime-slag paste, the gypsum-lime-slag paste and the OPC paste, it reveals that the hydration process of the GBFS-based cementitious material is different from the ordinary Portland cement and the presence of ettringite (AFt) contributes to the early age strength of the pastes. The major hydration product of the OPC paste (<7 days) were measured as ettringite (AFt), but the AFt phase was not detected in the hydration product of the lime-slag paste and the major hydration product of the lime-slag paste was determined as amorphous CSH gel. However, AFt was detected in the hydration products of the gypsum-lime-slag paste in the early stages of hydration, and the formation of AFt is favorable for the early strength improvement of the material.

Experimental Study on Compatibility between Alkali-Free Liquid Concrete Accelerators and Cement

2013 ◽  
Vol 438-439 ◽  
pp. 102-107 ◽  
Author(s):  
Wen Kang Guo ◽  
Li Wang ◽  
Shu Yin Wang ◽  
Dao Yin Lan ◽  
Sheng Ping Li
Keyword(s):  
Mechanical Properties ◽  
Experimental Study ◽  
Compressive Strength ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Strength Ratio ◽  
Setting Times ◽  
Gypsum Content ◽  
Durability Of Concrete

This paper selected two kinds of alkali-free liquid concrete accelerators and tested their compatibility with ordinary Portland cement, Portland cement and moderate heat Portland cement by measuring the setting times, compressive strength and compressive strength ratio of samples. The results showed that the compatibility is good between alkali-free accelerators and two types of cement: ordinary Portland cement and moderate heat Portland cement. However, the compatibility of two accelerators and Portland cement are quite different, the compatibility of AFA-2 accelerator is excellent, but AFA-1 accelerator is very poor. The setting times of alkali-free accelerators is mainly influenced by the mixing materials content, gypsum content, C3A and C3S content. In order to ensure the mechanical properties and durability of concrete, the setting times of new concrete accelerator is not the shorter the better, the appropriate initial and final setting times are 1min30s~5min and 4min~ 12min respectively.

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