scholarly journals Facile Synthesis of 3D Printed Tailor-Shape Electrode PLA-GnP for Electrochemical Sensing

2021 ◽  
Vol 4 (1) ◽  
pp. 34
Author(s):  
Denesh Mohan ◽  
Farrah Aida Arris ◽  
Mohd Shaiful Sajab ◽  
Nurul Nasuha Mansor
Keyword(s):  
Fused Deposition Modeling ◽  
Flow Behavior ◽  
Electron Flow ◽  
Differential Pulse ◽  
Electrochemical Sensing ◽  
Fused Deposition ◽  
Polymer Electrodes ◽  
3D Printed ◽  
Printed Materials ◽  
Voltammetry Methods

: Additive manufacturing (AM) has made enormous advancements in technology and materials development, and attention is required for the development of functionalized printed materials. AM can assist in manufacturing complex designed tailored-shaped electrodes efficiently for electrochemical sensing in the food industry. Herein, we used commercial fused deposition modeling (FDM) filament and polylactic acid (PLA) for FDM 3D printing of a self-designed electrode with minimal time and cost compared to commercial electrodes. Surface functionalization on the 3D printed PLA electrode was conducted using GnP to enhance the electrical conductivity. Scanning electron microscopy confirmed the homogenized surface coating of GnP that provides electron flow behavior for the 3D printed electrode. The electrochemically functionalized 3D printed electrode was tested against standard 3-monochloropropane-1,2-diol (3-MCPD) with known concentrations and characterized using cyclic voltammetry and differential pulse voltammetry methods. The results showed a basis for the promising application of detecting and quantifying 3-MCPD, a food contaminant known for its potential of being carcinogenic. The fabrication of functionalized 3D printed polymer electrodes paves the way for the development of complete 3D-printable electrochemical systems.

scholarly journals Stabilization of Electrospun Nanofiber Mats Used for Filters by 3D Printing

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1618 ◽  
Author(s):  
Kozior ◽  
Trabelsi ◽  
Mamun ◽  
Sabantina ◽  
Ehrmann
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Water Pressure ◽  
Volume Ratio ◽  
Fused Deposition ◽  
Rigid Objects ◽  
Deposition Modeling ◽  
3D Printed ◽  
Printed Materials ◽  
Nanofiber Mats

Electrospinning is a well-known technology used to create nanofiber mats from diverse polymers and other materials. Due to their large surface-to-volume ratio, such nanofiber mats are often applied as air or water filters. Especially the latter, however, have to be mechanically highly stable, which is challenging for common nanofiber mats. One of the approaches to overcome this problem is gluing them on top of more rigid objects, integrating them in composites, or reinforcing them using other technologies to avoid damage due to the water pressure. Here, we suggest another solution. While direct 3D printing with the fused deposition modeling (FDM) technique on macroscopic textile fabrics has been under examination by several research groups for years, here we report on direct FDM printing on nanofiber mats for the first time. We show that by choosing the proper height of the printing nozzle above the nanofiber mat, printing is possible for raw polyacrylonitrile (PAN) nanofiber mats, as well as for stabilized and even more brittle carbonized material. Under these conditions, the adhesion between both parts of the composite is high enough to prevent the nanofiber mat from being peeled off the 3D printed polymer. Abrasion tests emphasize the significantly increased mechanical properties, while contact angle examinations reveal a hydrophilicity between the original values of the electrospun and the 3D printed materials.

Exploiting limitations of fused deposition modeling to enhance mixing in 3D printed microfluidic devices

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Mojtaba Zeraatkar ◽  
Marco Donato de Tullio ◽  
Alessio Pricci ◽  
Francesco Pignatelli ◽  
Gianluca Percoco
Keyword(s):  
Fused Deposition Modeling ◽  
Flow Behavior ◽  
Content Type ◽  
Mixing Performance ◽  
Fused Deposition ◽  
Ridge Height ◽  
Geometrical Features ◽  
Deposition Modeling ◽  
3D Printed ◽  
Transverse Movement

Purpose The purpose of this study is to introduce an alternative construction for microfluidic micromixers, where the effect of the extruded filaments in the fused deposition modeling (FDM) technique is used to enhance mixing performance identified as a challenge in microfluidic micromixers. Design/methodology/approach A simple Y-shaped micromixer was designed and printed using FDM technique. Experimental and numerical studies were conducted to investigate the effect of the extruded filaments on the flow behavior. The effects of the extruded width (LW), distance between adjacent filaments (b) and filament height (h1) are investigated on the mixing performance and enhancing mixing in the fabricated devices. The performance of fabricated devices in mixing two solutions was tested at flow rates of 5, 10, 20, 40, 80 and 150 µL/min. Findings The experimental results showed that the presence of geometrical features on microchannels, because of the nature of the FDM process, can act as ridges and generate a lateral transform through the transverse movement of fluids along the groove. The results showed the effect of increasing ridge height on the transverse movement of the fluids and, therefore, chaotic mixing over the ridges. In contrast, in the shallow ridge, diffusion is the only mechanism for mixing, which confirms the numerical results. Originality/value The study presents an exciting aspect of FDM for fabrication of micromixers and enhance mixing process. In comparison to other methods, no complexity was added in fabrication process and the ridges are an inherent property of the FDM process.

scholarly journals Design and Manufacturing of Si-Based Non-Oxide Cellular Ceramic Structures through Indirect 3D Printing

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 471
Author(s):  
Ghenwa El Chawich ◽  
Joelle El Hayek ◽  
Vincent Rouessac ◽  
Didier Cot ◽  
Bertrand Rebière ◽  
...  
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Surface Defects ◽  
Low Cost ◽  
Dip Coating ◽  
Surface Finishing ◽  
Oxide Ceramic ◽  
Fused Deposition ◽  
3D Printed ◽  
Printed Materials

Additive manufacturing of Polymer-Derived Ceramics (PDCs) is regarded as a disruptive fabrication process that includes several technologies such as light curing and ink writing. However, 3D printing based on material extrusion is still not fully explored. Here, an indirect 3D printing approach combining Fused Deposition Modeling (FDM) and replica process is demonstrated as a simple and low-cost approach to deliver complex near-net-shaped cellular Si-based non-oxide ceramic architectures while preserving the structure. 3D-Printed honeycomb polylactic acid (PLA) lattices were dip-coated with two preceramic polymers (polyvinylsilazane and allylhydridopolycarbosilane) and then converted by pyrolysis respectively into SiCN and SiC ceramics. All the steps of the process (printing resolution and surface finishing, cross-linking, dip-coating, drying and pyrolysis) were optimized and controlled. Despite some internal and surface defects observed by topography, 3D-printed materials exhibited a retention of the highly porous honeycomb shape after pyrolysis. Weight loss, volume shrinkage, roughness and microstructural evolution with high annealing temperatures are discussed. Our results show that the sacrificial mold-assisted 3D printing is a suitable rapid approach for producing customizable lightweight highly stable Si-based 3D non-oxide ceramics.

scholarly journals The Influence of Raster Angle and Moisture Content on the Mechanical Properties of PLA Parts Produced by Fused Deposition Modeling

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 237
Author(s):  
Mohammed Algarni
Keyword(s):  
Mechanical Properties ◽  
Moisture Content ◽  
Fused Deposition Modeling ◽  
Tensile Tests ◽  
Fused Deposition ◽  
Raster Angle ◽  
Deposition Modeling ◽  
3D Printed ◽  
Printed Materials ◽  
Manufacturing Parameters

The additive manufacturing (AM) processes and technologies of 3D-printed materials and components using fused deposition modeling (FDM) are currently very popular and widely used for building parts and prototypes. Many manufacturing parameters can affect the strength and strain of the manufactured parts. The manufacturing parameters may be altered to reach an optimum setting for highly effective parts or components. This research studies the influence of the raster angle and the moisture content percentages on the mechanical properties of 3D printed polylactic acid (PLA) material. The three raster angles tested in this research were 0°, 45°, and 90°. The moisture content of the PLA material was altered to verify its effect on the mechanical properties. Twenty-seven specimens were subjected to tensile tests to examine the effect of different manufacturing parameters. The results show the specimens with a 90° raster angle and 10% moisture content have the optimum strength and strain mechanical properties.

Biodegradable 3D Printed Polymer Microneedles for Transdermal Drug Delivery

2018 ◽  
Author(s):  
Michael A. Luzuriaga ◽  
Danielle R. Berry ◽  
John C. Reagan ◽  
Ronald A. Smaldone ◽  
Jeremiah J. Gassensmith
Keyword(s):  
Drug Delivery ◽  
3D Printing ◽  
Transdermal Drug Delivery ◽  
Fused Deposition Modeling ◽  
Fused Deposition ◽  
Modeling Software ◽  
Deposition Modeling ◽  
3D Printed ◽  
Microfabrication Technique ◽  
Mechanical Strengths

Biodegradable polymer microneedle (MN) arrays are an emerging class of transdermal drug delivery devices that promise a painless and sanitary alternative to syringes; however, prototyping bespoke needle architectures is expensive and requires production of new master templates. Here, we present a new microfabrication technique for MNs using fused deposition modeling (FDM) 3D printing using polylactic acid, an FDA approved, renewable, biodegradable, thermoplastic material. We show how this natural degradability can be exploited to overcome a key challenge of FDM 3D printing, in particular the low resolution of these printers. We improved the feature size of the printed parts significantly by developing a post fabrication chemical etching protocol, which allowed us to access tip sizes as small as 1 μm. With 3D modeling software, various MN shapes were designed and printed rapidly with custom needle density, length, and shape. Scanning electron microscopy confirmed that our method resulted in needle tip sizes in the range of 1 – 55 µm, which could successfully penetrate and break off into porcine skin. We have also shown that these MNs have comparable mechanical strengths to currently fabricated MNs and we further demonstrated how the swellability of PLA can be exploited to load small molecule drugs and how its degradability in skin can release those small molecules over time.

scholarly journals Quality Control in 3D Printing: Accuracy Analysis of 3D-Printed Models of Patient-Specific Anatomy

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 1021
Author(s):  
Bernhard Dorweiler ◽  
Pia Elisabeth Baqué ◽  
Rayan Chaban ◽  
Ahmed Ghazy ◽  
Oroa Salem
Keyword(s):  
Wall Thickness ◽  
Large Scale ◽  
Fused Deposition Modeling ◽  
Vascular Anatomy ◽  
3D Models ◽  
Patient Specific ◽  
Stl File ◽  
Fused Deposition ◽  
3D Printed ◽  
The Mean

As comparative data on the precision of 3D-printed anatomical models are sparse, the aim of this study was to evaluate the accuracy of 3D-printed models of vascular anatomy generated by two commonly used printing technologies. Thirty-five 3D models of large (aortic, wall thickness of 2 mm, n = 30) and small (coronary, wall thickness of 1.25 mm, n = 5) vessels printed with fused deposition modeling (FDM) (rigid, n = 20) and PolyJet (flexible, n = 15) technology were subjected to high-resolution CT scans. From the resulting DICOM (Digital Imaging and Communications in Medicine) dataset, an STL file was generated and wall thickness as well as surface congruency were compared with the original STL file using dedicated 3D engineering software. The mean wall thickness for the large-scale aortic models was 2.11 µm (+5%), and 1.26 µm (+0.8%) for the coronary models, resulting in an overall mean wall thickness of +5% for all 35 3D models when compared to the original STL file. The mean surface deviation was found to be +120 µm for all models, with +100 µm for the aortic and +180 µm for the coronary 3D models, respectively. Both printing technologies were found to conform with the currently set standards of accuracy (<1 mm), demonstrating that accurate 3D models of large and small vessel anatomy can be generated by both FDM and PolyJet printing technology using rigid and flexible polymers.

scholarly journals Controlling magnetic properties of 3D-printed magnetic elastomer structures via fused deposition modeling

AIP Advances ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 025223
Author(s):  
Thomas M. Calascione ◽  
Nathan A. Fischer ◽  
Thomas J. Lee ◽  
Hannah G. Thatcher ◽  
Brittany B. Nelson-Cheeseman
Keyword(s):  
Magnetic Properties ◽  
Fused Deposition Modeling ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
3D Printed

scholarly journals Pressure Orientation-Dependent Recovery of 3D-Printed PLA Objects with Varying Infill Degree

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1275 ◽  
Author(s):  
Guido Ehrmann ◽  
Andrea Ehrmann
Keyword(s):  
Shape Memory ◽  
Fused Deposition Modeling ◽  
Static Load ◽  
Shape Memory Polymer ◽  
Applied Pressure ◽  
Poly Lactic Acid ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
Load Tests ◽  
3D Printed

Poly(lactic acid) is not only one of the most often used materials for 3D printing via fused deposition modeling (FDM), but also a shape-memory polymer. This means that objects printed from PLA can, to a certain extent, be deformed and regenerate their original shape automatically when they are heated to a moderate temperature of about 60–100 °C. It is important to note that pure PLA cannot restore broken bonds, so that it is necessary to find structures which can take up large forces by deformation without full breaks. Here we report on the continuation of previous tests on 3D-printed cubes with different infill patterns and degrees, now investigating the influence of the orientation of the applied pressure on the recovery properties. We find that for the applied gyroid pattern, indentation on the front parallel to the layers gives the worst recovery due to nearly full layer separation, while indentation on the front perpendicular to the layers or diagonal gives significantly better results. Pressing from the top, either diagonal or parallel to an edge, interestingly leads to a different residual strain than pressing from front, with indentation on top always firstly leading to an expansion towards the indenter after the first few quasi-static load tests. To quantitatively evaluate these results, new measures are suggested which could be adopted by other groups working on shape-memory polymers.

scholarly journals Mechanical Characterization and Thermodynamic Analysis of Laser-Polished Landscape Design Products Using 3D Printing

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2601
Author(s):  
Yue Ba ◽  
Yu Wen ◽  
Shibin Wu
Keyword(s):  
Surface Roughness ◽  
3D Printing ◽  
Fused Deposition Modeling ◽  
High Surface ◽  
Landscape Design ◽  
Laser Polishing ◽  
Fused Deposition ◽  
Design Structure ◽  
3D Printed ◽  
Stability And Accuracy

Recent innovations in 3D printing technologies and processes have influenced how landscape products are designed, built, and developed. In landscape architecture, reduced-size models are 3D-printed to replicate full-size structures. However, high surface roughness usually occurs on the surfaces of such 3D-printed components, which requires additional post-treatment. In this work, we develop a new type of landscape design structure based on the fused deposition modeling (FDM) technique and present a laser polishing method for FDM-fabricated polylactic acid (PLA) mechanical components, whereby the surface roughness of the laser-polished surfaces is reduced from over Ra 15 µm to less than 0.25 µm. The detailed results of thermodynamics and microstructure evolution are further analyzed during laser polishing. The stability and accuracy of the results are evaluated based on the standard deviation. Additionally, the superior tensile and flexural properties are examined in the laser-polished layer, in which the ultimate tensile strength (UTS) is increased by up to 46.6% and the flexural strength is increased by up to 74.5% compared with the as-fabricated components. Finally, a real polished landscape model is simulated and optimized using a series of scales.

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