scholarly journals Mineralogy of a High-Temperature Skarn, in High CO2 Activity Conditions: The Occurrence from Măgureaua Vaţei (Metaliferi Massif, Apuseni Mountains, Romania)

Minerals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 677
Author(s):  
Ştefan Marincea ◽  
Delia-Georgeta Dumitraş ◽  
Cristina Sava ◽  
Frédéric Hatert ◽  
Fabrice Dal Bo
Keyword(s):  
Solid Solution ◽  
High Temperature ◽  
Upper Cretaceous ◽  
Contact Metamorphism ◽  
High Co2 ◽  
Shallow Level ◽  
Apuseni Mountains ◽  
Hydrothermal Stage ◽  
Metamorphic Assemblage ◽  
Hydrothermal Event

A shallow-level monzodioritic to quartz-monzodioritic pluton of the Upper Cretaceous age caused contact metamorphism of Tithonic–Kimmeridgian reef limestones at Măgureaua Vaţei (Metaliferi Massif, Apuseni Mountains, Romania). The preserved peak metamorphic assemblage includes gehlenite (Ak 33.64–38.13), monticellite, wollastonite-2M, Ti-poor calcic garnet, and Ca-Tschermak diopside (with up to 11.15 mol.% Ca-Tschermak molecule). From the monzodioritic body to the calcitic marble, the periplutonic zoning can be described as: monzodiorite/agpaitic syenite-like inner endoskarn/wollastonite + perovskite + Ti-poor grossular + Al-rich diopside/wollastonite + Ti-poor grossular + diopside + vesuvianite/gehlenite + wollastonite + Ti poor grossular + Ti-rich grossular (outer endoskarn)/wollastonite + vesuvianite + garnet (inner exoskarn)/wollastonite + Ti-rich garnet + vesuvianite + diopside (outer exoskarn)/calcitic marble. Three generations of Ca garnets could be identified, as follows: (1) Ti-poor grossular (Grs 53.51–81.03 mol.%) in equilibrium with gehlenite; (2) Ti-rich grossular (Grs 51.13–53.47 mol.%, with up to 19.97 mol.% morimotoite in solid solution); and (3) titanian andradite (Grs 32.70–45.85 mol.%), with up to 29.15 mol.% morimotoite in solid solution. An early hydrothermal stage produced retrogression of the peak paragenesis toward vesuvianite, hydroxylellestadite (or Si-substituted apatite), clinochlore, “hibschite” (H4O4-substituted grossular). A late hydrothermal event induced the formation of lizardite, chrysotile, dickite, thaumasite, okenite and tobermorite. A weathering paragenesis includes allophane, C-S-H gels and probably portlandite, unpreserved because of its transformation in aragonite then calcite. Overprints of these late events on the primary zoning are quite limited.

High-Temperature Instability of A Cr2Nb-Nb(Cr) Microlaminate Composite

1996 ◽  
Vol 54 ◽  
pp. 374-375
Author(s):  
M. Larsen ◽  
R.G. Rowe ◽  
D.W. Skelly
Keyword(s):  
Heat Treatment ◽  
Solid Solution ◽  
High Temperature ◽  
Elevated Temperatures ◽  
Aircraft Engine ◽  
Lattice Parameter ◽  
Microstructural Stability ◽  
Elevated Temperature Strength ◽  
Cross Sectional ◽  
Bcc Structure

Microlaminate composites consisting of alternating layers of a high temperature intermetallic compound for elevated temperature strength and a ductile refractory metal for toughening may have uses in aircraft engine turbines. Microstructural stability at elevated temperatures is a crucial requirement for these composites. A microlaminate composite consisting of alternating layers of Cr2Nb and Nb(Cr) was produced by vapor phase deposition. The stability of the layers at elevated temperatures was investigated by cross-sectional TEM.The as-deposited composite consists of layers of a Nb(Cr) solid solution with a composition in atomic percent of 91% Nb and 9% Cr. It has a bcc structure with highly elongated grains. Alternating with this Nb(Cr) layer is the Cr2Nb layer. However, this layer has deposited as a fine grain Cr(Nb) solid solution with a metastable bcc structure and a lattice parameter about half way between that of pure Nb and pure Cr. The atomic composition of this layer is 60% Cr and 40% Nb. The interface between the layers in the as-deposited condition appears very flat (figure 1). After a two hour, 1200 °C heat treatment, the metastable Cr(Nb) layer transforms to the Cr2Nb phase with the C15 cubic structure. Grain coarsening occurs in the Nb(Cr) layer and the interface between the layers roughen. The roughening of the interface is a prelude to an instability of the interface at higher heat treatment temperatures with perturbations of the Cr2Nb grains penetrating into the Nb(Cr) layer.

ALTEMP HX

Alloy Digest ◽  
1993 ◽  
Vol 42 (10) ◽  
Keyword(s):  
Heat Treatment ◽  
Solid Solution ◽  
Fracture Toughness ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Base Alloy ◽  
Heat Treating ◽  
Nickel Base Alloy ◽  
Temperature Performance ◽  
Nickel Base

Abstract ALTEMP HX is an austenitic nickel-base alloy designed for outstanding oxidation and strength at high temperatures. The alloy is solid-solution strengthened. Applications include uses in the aerospace, heat treatment and petrochemical markets. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as fracture toughness and creep. It also includes information on low and high temperature performance, and corrosion resistance as well as forming, heat treating, and joining. Filing Code: Ni-442. Producer or source: Allegheny Ludlum Corporation.

INCO ALLOY 330

Alloy Digest ◽  
1992 ◽  
Vol 41 (5) ◽  
Keyword(s):  
Heat Treatment ◽  
Solid Solution ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Heat Treating ◽  
High Temperature Alloy ◽  
Nickel Iron ◽  
Temperature Performance ◽  
Inco Alloy ◽  
Iron Chromium

Abstract INCO ALLOY 330 is a nickel/iron/chromium austenitic alloy, not hardenable by heat treatment. It is a solid solution strengthened high-temperature alloy. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Ni-403. Producer or source: Inco Alloys International Inc..

INCONEL ALLOY 601

Alloy Digest ◽  
1970 ◽  
Vol 19 (4) ◽  
Keyword(s):  
Solid Solution ◽  
Fracture Toughness ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Physical Properties ◽  
Heat Treating ◽  
Solid Solution Alloy ◽  
Process Industries ◽  
Inconel Alloy ◽  
Nickel Chromium

Abstract INCONEL Alloy 601 is a nickel-chromium solid-solution alloy with excellent high-temperature properties which make it attractive for many application in aerospace and process industries. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as fracture toughness and creep. It also includes information on corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: Ni-152. Producer or source: Huntington Alloy Products Division, An INCO Company.

STOODY 4

Alloy Digest ◽  
1977 ◽  
Vol 26 (4) ◽  
Keyword(s):  
Solid Solution ◽  
Compressive Strength ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Physical Properties ◽  
Heat Treating ◽  
Tungsten Alloy ◽  
High Temperature Strength ◽  
Cobalt Chromium ◽  
Temperature Performance

Abstract STOODY 4 is a cobalt-chromium-tungsten alloy with excellent high-temperature strength and excellent resistance to corrosion. This alloy derives its high-temperature strength from the high tungsten-to-carbon ratio which allows a large percentage of tungsten to remain in solid solution. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and compressive strength. It also includes information on high temperature performance and corrosion resistance as well as heat treating, machining, and joining. Filing Code: Co-75. Producer or source: WRAP Division, Stoody Company.

PYROMET 538

Alloy Digest ◽  
1970 ◽  
Vol 19 (12) ◽  
Keyword(s):  
Solid Solution ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Physical Properties ◽  
Tensile Properties ◽  
Oxidation Resistance ◽  
Heat Treating ◽  
Temperature Performance ◽  
Technology Corporation ◽  
Carpenter Technology Corporation

Abstract PYROMET 538 is a solid-solution strengthened, austenitic alloy with a desirable combination of strength, corrosion resistance, oxidation resistance, and economy. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SS-247. Producer or source: Carpenter Technology Corporation.

scholarly journals Effect of the Fe2O3 Addition Amount on Dephosphorization of Hot Metal with Low Basicity Slag by High-Temperature Laboratorial Experiments

Metals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 417
Author(s):  
Wenkui Yang ◽  
Jian Yang ◽  
Yanqiu Shi ◽  
Zhijun Yang ◽  
Fubin Gao ◽  
...  
Keyword(s):  
Solid Solution ◽  
High Temperature ◽  
Theoretical Calculation ◽  
Oxygen Potential ◽  
Oxygen Activity ◽  
Hot Metal ◽  
Rich Phase ◽  
Addition Amount

In this paper, the influence of the Fe2O3 addition amount on the dephosphorization of hot metal at 1623 K with the slag of the low basicity (CaO/SiO2) of about 1.5 was investigated by using high-temperature laboratorial experiments. With increasing the Fe2O3 addition amount from 5 to 30 g, the contents of [C], [Si], [Mn] and [P] in the hot metal at the end of dephosphorization are decreased and the corresponding removal ratios increase. In dephosphorization slags, the phosphorus mainly exists in the form of the nCa2SiO4–Ca3(PO4)2 solid solution in the phosphorus-rich phase and the value of coefficient n decreases from 20 to 1. Furthermore, the oxygen potential and activity at the interface between the slag and hot metal are increased. When the oxygen potential and the oxygen activity at the interface are greater than 0.72 × 10−12 and 7.1 × 10−3, respectively, the dephosphorization ratio begins to increase rapidly. When the Fe2O3 addition amount is increased to 30 g, the ratio of the Fe2O3 addition amount to theoretical calculation consumption is around 175%, and the dephosphorization ratio reaches the highest value of 83.3%.

Self-propagating high-temperature synthesis microalloying of MoSi2 with Nb and V

2003 ◽  
Vol 18 (8) ◽  
pp. 1842-1848 ◽  
Author(s):  
F. Maglia ◽  
C. Milanese ◽  
U. Anselmi-Tamburini ◽  
Z. A. Munir
Keyword(s):  
Solid Solution ◽  
High Temperature ◽  
Tetragonal Phase ◽  
Synthesis Method ◽  
The Self ◽  
Alloying Elements ◽  
Alloying Element ◽  
Temperature Synthesis ◽  
Starting Mixture ◽  
High Temperature Synthesis

Microalloying of MoSi2 to form Mo(1−x)MexSi2 (Me = Nb or V) was investigated by the self-propagating high-temperature synthesis method. With alloying element contents up to 5 at.%, a homogeneous C11b solid solution was obtained. For higher contents of alloying elements, the product contained both the C11b and the hexagonal C40 phases. The relative amount of the C40 phase increases with an increase in the content of alloying metals in the starting mixture. The alloying element content in the hexagonal C40 Mo(1−x)MexSi2 phase was nearly constant at a level of about 12 at.% for all starting compositions. In contrast, the content of the alloying elements in the tetragonal phase is considerably lower (around 4 at.%) and increases slightly as the Me content in the starting mixture is increased.

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