scholarly journals Mineralogical Evidence for Partial Melting and Melt-Rock Interaction Processes in the Mantle Peridotites of Edessa Ophiolite (North Greece)

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 120 ◽  
Author(s):  
Aikaterini Rogkala ◽  
Petros Petrounias ◽  
Basilios Tsikouras ◽  
Panagiota Giannakopoulou ◽  
Konstantin Hatzipanagiotou
Keyword(s):  
Partial Melting ◽  
Mantle Wedge ◽  
Oceanic Lithosphere ◽  
Upper Jurassic ◽  
Northern Greece ◽  
Rock Interaction ◽  
Oceanic Spreading ◽  
Mantle Peridotites ◽  
Mineral Compositions ◽  
Ocean Ridge

The Edessa ophiolite complex of northern Greece consists of remnants of oceanic lithosphere emplaced during the Upper Jurassic-Lower Cretaceous onto the Palaeozoic-Mesozoic continental margin of Eurasia. This study presents new data on mineral compositions of mantle peridotites from this ophiolite, especially serpentinised harzburgite and minor lherzolite. Lherzolite formed by low to moderate degrees of partial melting and subsequent melt-rock reaction in an oceanic spreading setting. On the other hand, refractory harzburgite formed by high degrees of partial melting in a supra-subduction zone (SSZ) setting. These SSZ mantle peridotites contain Cr-rich spinel residual after partial melting of more fertile (abyssal) lherzolite with Al-rich spinel. Chromite with Cr# > 60 in harzburgite resulted from chemical modification of residual Cr-spinel and, along with the presence of euhedral chromite, is indicative of late melt-peridotite interaction in the mantle wedge. Mineral compositions suggest that the Edessa oceanic mantle evolved from a typical mid-ocean ridge (MOR) oceanic basin to the mantle wedge of a SSZ. This scenario explains the higher degrees of partial melting recorded in harzburgite, as well as the overprint of primary mineralogical characteristics in the Edessa peridotites.

scholarly journals Multi-stage Reactive Formation of Troctolites in Slow-spreading Oceanic Lithosphere (Erro–Tobbio, Italy): a Combined Field and Petrochemical Study

2019 ◽  
Vol 60 (5) ◽  
pp. 873-906 ◽  
Author(s):  
Valentin Basch ◽  
Elisabetta Rampone ◽  
Laura Crispini ◽  
Carlotta Ferrando ◽  
Benoit Ildefonse ◽  
...  
Keyword(s):  
Fractional Crystallization ◽  
Oceanic Lithosphere ◽  
Rock Interaction ◽  
Crystallographic Preferred Orientation ◽  
Compositional Evolution ◽  
Fine Grained ◽  
Interaction Processes ◽  
Multi Stage ◽  
Mineral Compositions ◽  
Melt Composition

Abstract Many recent studies have investigated the replacive formation of troctolites from mantle protoliths and the compositional evolution of the percolating melt during melt–rock interaction processes. However, strong structural and geochemical constraints for a replacive origin have not yet been established. The Erro–Tobbio impregnated mantle peridotites are primarily associated with a hectometre-size troctolitic body and crosscutting gabbroic dykes, providing a good field control on melt–rock interaction processes and subsequent magmatic intrusions. The troctolitic body exhibits high inner complexity, with a host troctolite (Troctolite A) crosscut by a second generation of troctolitic metre-size pseudo-tabular bodies (Troctolite B). The host Troctolite A is characterized by two different textural types of olivine, corroded deformed millimetre- to centimetre-size olivine and fine-grained rounded undeformed olivine, both embedded in interstitial to poikilitic plagioclase and clinopyroxene. Troctolite A shows melt–rock reaction microstructures indicative of replacive formation after percolation and impregnation of mantle dunites by a reactive melt. The evolution of the texture and crystallographic preferred orientation (CPO) of olivine are correlated and depend on the melt/rock ratio involved in the impregnation process. A low melt/rock ratio allows the preservation of the protolith structure, whereas a high melt/rock ratio leads to the disaggregation of the pre-existing matrix. The mineral compositions in Troctolite A define reactive trends, indicative of the buffering of the melt composition by assimilation of olivine during impregnation. The magmatic Troctolite B bodies are intruded within the pre-existing Troctolite A and are characterized by extreme textural variations of olivine, from decimetre-size dendritic to fine-grained euhedral crystals embedded in poikilitic plagioclase. This textural variability is the result of olivine assimilation during melt–rock reaction and the correlated increase in the degree of undercooling of the percolating melt. In the late gabbroic intrusions, mineral compositions are consistent with the fractional crystallization of melts modified after the reactive crystallization of Troctolites A and B. The Erro–Tobbio troctolitic body has a multi-stage origin, marked by the transition from reactive to fractional crystallization and diffuse to focused melt percolation and intrusion, related to progressive exhumation. During the formation of the troctolitic body, the melt composition was modified and controlled by assimilation and concomitant crystallization reactions occurring at low melt supply. Similar processes have been described in ultraslow-spreading oceanic settings characterized by scarce magmatic activity.

Petrogenesis of Ordovician granitoids in Western Kunlun, NW Tibetan Plateau: Insights into the evolution of the Proto-Tethys Ocean

2020 ◽  
Author(s):  
Peng Wang ◽  
Guochun Zhao ◽  
Yigui Han ◽  
Qian Liu ◽  
Jinlong Yao ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
Partial Melting ◽  
Fractional Crystallization ◽  
Mantle Wedge ◽  
Saturation Index ◽  
Oceanic Lithosphere ◽  
Quartz Diorite ◽  
The North ◽  
Western Kunlun ◽  
Granitoid Intrusions

Granitoid rocks are universal in continental crust and are of special significance in understanding tectonic settings. This paper presents detailed zircon U-Pb dating, Hf isotope, whole-rock geochemistry, and Sr-Nd-Pb isotope analyses, and mineralogy of two Ordovician granitoid intrusions and one quartz diorite intrusion in Western Kunlun, NW Tibetan Plateau. The Yutian Complex is composed of diverse rock suites, including monzogabbros, quartz monzodiorites, monzogranites, and monzodioritic enclaves. These suites have similar rock formation ages (447−440 Ma) and minerals, e.g., amphibole grains from different suites belonging to pargasite. Moreover, they exhibit geochemical similarities, such as broadly parallel trace-element patterns characterized by enrichments in light rare earth elements and large ion lithophile elements, and depletions in high field strength elements, which are typical features of arc rocks. Furthermore, the studied samples display homogeneous zircon Hf values, e.g., εHf(t) = −1 to −3, and whole-rock isotopic compositions, e.g., εNd(t) = −4 to −6. Thus, they were most likely derived from a mantle wedge enriched by subducted sediments and fluids, which then evolved into different suites through fractional crystallization of hornblende and plagioclase. The ca. 440 Ma North Yutian quartz diorite intrusion, with an average of εHf(t) value of −6, was a product of the partial melting of mafic lower crust through slightly fractional crystallization of hornblende. In contrast, the ca. 470 Ma Aqiang granodiorite intrusion has εHf(t) values varying from −5 and −2, but it has heterogeneous petrological and geochemical features. It is considered to be a product of the partial melting of the overriding mantle wedge modified by fluids derived from the subducted Proto-Tethys slab and some mixed crustal materials. The Aqiang samples belong to the slightly fractionated I-type series, but they have variable alumina saturation index (ASI = molar Al2O3/[CaO − 3.33 × P2O5 + Na2O + K2O]) values (0.74−1.03) due to variable peraluminous biotite contents. The different suites in the Yutian Complex display low ASI values (<1) controlled by sources and fractional crystallization. The Yutian Complex and the North Yutian intrusion were emplaced during the southward subduction of the Proto-Tethys oceanic lithosphere, and the Aqiang intrusion was emplaced in response to the northward subduction.

scholarly journals ON THE RELATIVELY COMPOSITIONAL HOMOGENEITY OF ALBANIAN EASTERN OPHIOLITIC BELT

2017 ◽  
Vol 50 (4) ◽  
pp. 1789
Author(s):  
Α. Çina
Keyword(s):  
Upper Mantle ◽  
Oceanic Lithosphere ◽  
Upper Jurassic ◽  
Sharp Separation ◽  
Mantle Peridotites ◽  
Compositional Homogeneity ◽  
Ophiolitic Belt ◽  
Mirdita Zone ◽  
Geological Units ◽  
Shed Light

Ophiolitic formation of Albanides, named as Mirdita zone, represents a compactsegment of oceanic lithosphere of Middle-Upper Jurassic. Based on petrographic,geochemical and metalogenical features two types of belts are distinguished: westernMORB and eastern SSZ types. In fact, structural and geological units as well as manyother elements have shed light on lack of a sharp separation between the two belts.Recent investigations have evidenced that different ultramafic massifs of westernophiolitic formation, represent an evident variation of their composition fromharzburgite to lherzolitic -types. This composition reflects a different grade of partialmelting of upper mantle. Peridotites show a high variability, from 0.3 - 3.8 wt.%Al2O3, varying from small to highly extreme depleted peridotite.On the contrary, Albanian eastern belt, it seems to be formed by a more homogeneoushartzburgitic mantle.Detailed petrologic and metallogenic investigations have evidenced that this beltchanges also from one massif to another, naturally at a smaller level, therefore it iseasier to be named relatively homogeneous. It is distinguished by a higher meltingdegree, chiefly of hartzburgitic-type, characterized by whole and thick ultramaficsection, as well as by metalogenic variety, mostly of metallurgic-type of chromitemineralization. It is supposed that rock-forming and mineraluzation processes havebeen developed not uniformly along the ophiolitic belt.

Numerical simulation of subduction zone pressure-temperature-time paths: constraints on fluid production and arc magmatism

1991 ◽  
Vol 335 (1638) ◽  
pp. 341-353 ◽  
Keyword(s):  
Heat Transfer ◽  
Partial Melting ◽  
Subduction Zone ◽  
Subduction Zones ◽  
Mantle Wedge ◽  
Thermal Structure ◽  
Oceanic Lithosphere ◽  
Transfer Model ◽  
Temperature Time ◽  
Subducting Slab

The location and sequence of metamorphic devolatilization and partial melting reactions in subduction zones may be constrained by integrating fluid and rock pressure-temperature-time ( P-T-t ) paths predicted by numerical heat-transfer models with phase diagrams constructed for metasedimentary, metabasaltic, and ultramafic bulk compositions. Numerical experiments conducted using a two-dimensional heat transfer model demonstrate that the primary controls on subduction zone P-T-t paths are: (1) the initial thermal structure; (2) the amount of previously subducted lithosphere; (3) the location of the rock in the subduction zone; and (4) the vigour of mantle wedge convection induced by the subducting slab. Typical vertical fluid fluxes out of the subducting slab range from less than 0.1 to 1 (kg fluid) m -2 a -1 for a convergence rate of 3 cm a -1 . Partial melting of the subducting, amphibole-bearing oceanic crust is predicted to only occur during the early stages of subduction initiated in young (less than 50 Ma) oceanic lithosphere. In contrast, partial melting of the overlying mantle wedge occurs in many subduction zone experiments as a result of the infiltration of fluids derived from slab devolatilization reactions. Partial melting in the mantle wedge may occur by a twostage process in which amphibole is first formed by H 2 O infiltration and subsequently destroyed as the rock is dragged downward across the fluid-absent ‘hornblende-out’ partial melting reaction.

scholarly journals Depletion of the upper mantle by convergent tectonics in the Early Earth

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
A. L. Perchuk ◽  
T. V. Gerya ◽  
V. S. Zakharov ◽  
W. L. Griffin
Keyword(s):  
Partial Melting ◽  
Oceanic Crust ◽  
Upper Mantle ◽  
Subduction Zones ◽  
Convergence Rates ◽  
Oceanic Lithosphere ◽  
Early Earth ◽  
Plate Convergence ◽  
Depleted Mantle ◽  
Mantle Peridotites

AbstractPartial melting of mantle peridotites at spreading ridges is a continuous global process that forms the oceanic crust and refractory, positively buoyant residues (melt-depleted mantle peridotites). In the modern Earth, these rocks enter subduction zones as part of the oceanic lithosphere. However, in the early Earth, the melt-depleted peridotites were 2–3 times more voluminous and their role in controlling subduction regimes and the composition of the upper mantle remains poorly constrained. Here, we investigate styles of lithospheric tectonics, and related dynamics of the depleted mantle, using 2-D geodynamic models of converging oceanic plates over the range of mantle potential temperatures (Tp = 1300–1550 °C, ∆T = T − Tmodern = 0–250 °C) from the Archean to the present. Numerical modeling using prescribed plate convergence rates reveals that oceanic subduction can operate over this whole range of temperatures but changes from a two-sided regime at ∆T = 250 °C to one-sided at lower mantle temperatures. Two-sided subduction creates V-shaped accretionary terrains up to 180 km thick, composed mainly of highly hydrated metabasic rocks of the subducted oceanic crust, decoupled from the mantle. Partial melting of the metabasic rocks and related formation of sodic granitoids (Tonalite–Trondhjemite–Granodiorite suites, TTGs) does not occur until subduction ceases. In contrast, one sided-subduction leads to volcanic arcs with or without back-arc basins. Both subduction regimes produce over-thickened depleted upper mantle that cannot subduct and thus delaminates from the slab and accumulates under the oceanic lithosphere. The higher the mantle temperature, the larger the volume of depleted peridotites stored in the upper mantle. Extrapolation of the modeling results reveals that oceanic plate convergence at ∆T = 200–250 °C might create depleted peridotites (melt extraction of > 20%) constituting more than half of the upper mantle over relatively short geological times (~ 100–200 million years). This contrasts with the modeling results at modern mantle temperatures, where the amount of depleted peridotites in the upper mantle does not increase significantly with time. We therefore suggest that the bulk chemical composition of upper mantle in the Archean was much more depleted than the present mantle, which is consistent with the composition of the most ancient lithospheric mantle preserved in cratonic keels.

The Heterogeneous Tethyan Oceanic Lithosphere of the Alpine Ophiolites

Elements ◽  
2021 ◽  
Vol 17 (1) ◽  
pp. 23-28 ◽  
Author(s):  
Elisabetta Rampone ◽  
Alessio Sanfilippo
Keyword(s):  
Oceanic Lithosphere ◽  
Passive Margin ◽  
Crustal Material ◽  
Crustal Accretion ◽  
Mantle Dynamics ◽  
Western Tethys ◽  
Mantle Peridotites ◽  
Slow Spreading ◽  
Tethys Ocean ◽  
Basaltic Crust

The Alpine–Apennine ophiolites are lithospheric remnants of the Jurassic Alpine Tethys Ocean. They predominantly consist of exhumed mantle peridotites with lesser gabbroic and basaltic crust and are locally associated with continental crustal material, indicating formation in an environment transitional from an ultra-slow-spreading seafloor to a hyperextended passive margin. These ophiolites represent a unique window into mantle dynamics and crustal accretion in an ultra-slow-spreading extensional environment. Old, pre-Alpine, lithosphere is locally preserved within the mantle sequences: these have been largely modified by reaction with migrating asthenospheric melts. These reactions were active in both the mantle and the crust and have played a key role in creating the heterogeneous oceanic lithosphere in this branch of the Mesozoic Western Tethys.

Melt Percolation, Melt-Rock Reaction and Oxygen Fugacity in Supra-Subduction Zone Mantle and Lower Crust from the Leka Ophiolite Complex, Norway

2021 ◽  
Author(s):  
Brian O’Driscoll ◽  
Julien Leuthold ◽  
Davide Lenaz ◽  
Henrik Skogby ◽  
James M D Day ◽  
...  
Keyword(s):  
Single Crystal ◽  
Subduction Zone ◽  
Oxygen Fugacity ◽  
Lower Crust ◽  
Oceanic Lithosphere ◽  
Ophiolite Complex ◽  
Global Comparison ◽  
Oceanic Spreading ◽  
Melt Percolation ◽  
Lower Crustal

Abstract Samples of peridotites and pyroxenites from the mantle and lower crustal sections of the Leka Ophiolite Complex (LOC; Norway) are examined to investigate the effects of melt-rock reaction and oxygen fugacity variations in the sub-arc oceanic lithosphere. The LOC is considered to represent supra-subduction zone (SSZ) oceanic lithosphere, but also preserves evidence of pre-SSZ magmatic processes. Here we combine field and microstructural observations with mineral chemical and structural analyses of different minerals from the major lithologies of the LOC. Wehrlite and websterite bodies in both the mantle and lower crust contain clinopyroxene likely formed at a pre-SSZ stage, characterised by high Al, high Cr, low Mg crystal cores. These clinopyroxenes also exhibit low Al, low Cr, high Mg outer rims and intracrystalline dissolution surfaces, indicative of reactive melt percolation during intrusion and disruption of these lithologies by later, SSZ-related, dunite-forming magmas. Chromian-spinel compositional variations correlate with lithology; dunite-chromitite Cr-spinels are characterised by relatively uniform and high TiO2 and Al2O3, indicating formation by melt-rock reaction associated with SSZ processes. Harzburgite Cr-spinel compositions are more variable but preserve a relatively high Al2O3, low TiO2 endmember that may reflect crystallisation in a pre-SSZ oceanic spreading centre setting. An important finding of this study is that the LOC potentially preserves the petrological signature of a transition between oceanic spreading centre processes and subsequent supra-subduction zone magmatism. Single crystal Cr-spinel Fe3+/ΣFe ratios calculated on the basis of stoichiometry (from electron microprobe [EPMA] and crystal structural [X-ray diffraction; XRD] measurements) correlate variably with those calculated by point-source (single crystal) Mössbauer spectroscopy. Average sample EPMA Fe3+/ΣFe ratios overestimate or underestimate the Mössbauer-derived values for harzburgites, and always overestimate the Mössbauer Fe3+/ΣFe ratios for dunites and chromitites. The highest Fe3+/ΣFe ratios, irrespective of method of measurement, are therefore generally associated with dunites and chromitites, and yield calculated log(fO2)FMQ values of up to ~+1.8. While this lends support to the formation of the dunites and chromitites during SSZ-related melt percolation in the lower part of the LOC, it also suggests that these melts were not highly oxidised, compared to typical arc basalts (fO2FMQ of >+2). This may in turn reflect the early (forearc) stage of subduction zone activity preserved by the LOC and implies that some of the arc tholeiitic and boninitic lava compositions preserved in the upper portion of the ophiolite are not genetically related to the mantle and lower crustal rocks, against which they exhibit tectonic contacts. Our new data also have implications for the use of ophiolite chromitites as recorders of mantle oxidation state through time; a global comparison suggests that the Fe3+/ΣFe signatures of ophiolite chromitites are likely to have more to do with local environmental petrogenetic conditions in sub-arc systems than large length-scale mantle chemical evolution.

Platinum-group element geochemistry of intraplate basalts from the Aleppo Plateau, NW Syria

2012 ◽  
Vol 150 (3) ◽  
pp. 497-508 ◽  
Author(s):  
GEORGE S.-K. MA ◽  
JOHN MALPAS ◽  
JIAN-FENG GAO ◽  
KUO-LUNG WANG ◽  
LIANG QI ◽  
...  
Keyword(s):  
Partial Melting ◽  
Middle Miocene ◽  
Primitive Mantle ◽  
Element Geochemistry ◽  
Alkali Basalts ◽  
Melt Extraction ◽  
Mid Ocean Ridge ◽  
Order Of Magnitude ◽  
Platinum Group ◽  
Ocean Ridge

AbstractEarly–Middle Miocene intraplate basalts from the Aleppo Plateau, NW Syria have been analysed for their platinum-group elements (PGEs). They contain extremely low PGE abundances, comparable with most alkali basalts, such as those from Hawaii, and mid-ocean ridge basalts. The low abundances, together with high Pd/Ir, Pt/Ir, Ni/Ir, Cu/Pd, Y/Pt and Cu/Zr are consistent with sulphide fractionation, which likely occurred during partial melting and melt extraction within the mantle. Some of the basalts are too depleted in PGEs to be explained solely by partial melting of a primitive mantle-like source. Such ultra-low PGE abundances, however, are possible if the source contains some mafic lithologies. Many of the basalts also exhibit suprachondritic Pd/Pt ratios of up to an order of magnitude higher than primitive mantle and chondrite, an increase too high to be attributable to fractionation of spinel and silicate minerals alone. The elevated Pd/Pt, associated with a decrease in Pt but not Ir and Ru, are also inconsistent with removal of Pt-bearing PGE minerals or alloys, which should have concurrently lowered Pt, Ir and Ru. In contrast, melting of a metasomatized source comprising sulphides whose Pt and to a lesser extent Rh were selectively mobilized through interaction with silicate melts, may provide an explanation.

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