scholarly journals Application of Natural Clinoptilolite for Ammonium Removal from Sludge Water

Molecules ◽  
2020 ◽  
Vol 26 (1) ◽  
pp. 114
Author(s):  
Stephan Wasielewski ◽  
Eduard Rott ◽  
Ralf Minke ◽  
Heidrun Steinmetz
Keyword(s):  
Industrial Wastewater ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Substrate Inhibition ◽  
High Stress ◽  
Kinetic Studies ◽  
Digested Sludge ◽  
Ammonium Removal ◽  
Higher Temperature ◽  
Natural Clinoptilolite

Sludge water (SW) arising from the dewatering of anaerobic digested sludge causes high back loads of ammonium, leading to high stress (inhibition of the activity of microorganisms by an oversupply of nitrogen compounds (substrate inhibition)) for wastewater treatment plants (WWTP). On the other hand, ammonium is a valuable resource to substitute ammonia from the energy intensive Haber-Bosch process for fertilizer production. Within this work, it was investigated to what extent and under which conditions Carpathian clinoptilolite powder (CCP 20) can be used to remove ammonium from SW and to recover it. Two different SW, originating from municipal WWTPs were investigated (SW1: c0 = 967 mg/L NH4-N, municipal wastewater; SW2: c0 = 718–927 mg/L NH4-N, large industrial wastewater share). The highest loading was achieved at 307 K with 16.1 mg/g (SW1) and 15.3 mg/g (SW2) at 295 K. Kinetic studies with different specific dosages (0.05 gCLI/mgNH4-N), temperatures (283–307 K) and pre-loaded CCP 20 (0–11.4 mg/g) were conducted. At a higher temperature a higher load was achieved. Already after 30 min contact time, regardless of the sludge water, a high load up to 7.15 mg/g at 307 K was reached, achieving equilibrium after 120 min. Pre-loaded sorbent could be further loaded with ammonium when it was recontacted with the SW.

Influence of pyrolysis temperature on production of digested sludge biochar and its application for ammonium removal from municipal wastewater

2019 ◽  
Vol 209 ◽  
pp. 927-936 ◽  
Author(s):  
Yao Tang ◽  
Md Samrat Alam ◽  
Kurt O. Konhauser ◽  
Daniel S. Alessi ◽  
Shengnan Xu ◽  
...  
Keyword(s):  
Municipal Wastewater ◽  
Pyrolysis Temperature ◽  
Digested Sludge ◽  
Ammonium Removal

Evaluating the stabilisation degree of digested sewage sludge: investigations at four municipal wastewater treatment plants

2006 ◽  
Vol 53 (8) ◽  
pp. 81-90 ◽  
Author(s):  
V. Parravicini ◽  
E. Smidt ◽  
K. Svardal ◽  
H. Kroiss
Keyword(s):  
Wastewater Treatment ◽  
Sewage Sludge ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Municipal Wastewater Treatment ◽  
Digested Sludge ◽  
Aerobic Conditions ◽  
Specific Oxygen Uptake Rate ◽  
Municipal Wastewater Treatment Plants ◽  
Digested Sewage Sludge

Further reduction of volatile suspended solids (VSS) during a post-stabilisation step was applied to evaluate the stabilisation degree of digested sewage sludge. For this purpose digested sludge was collected at four municipal wastewater treatment plants (WWTPs) and further stabilised in lab-scale chemostat reactors either under anaerobic or aerobic conditions. Experimental results showed that even in adequately digested sludge a consistent amount of VSS was degraded during aerobic post-stabilisation. It seems that aerobic conditions play a significant role during degradation of residual VSS. Additionally, specific VSS production (gVSS/peCOD110.d) as well as specific oxygen uptake rate were shown to be suitable parameters to assess the degree of sludge stabilisation at WWTPs. Fourier transform infrared spectroscopy was used to reveal changes in the sludge composition. Spectra of treated and untreated sludge samples indicated that the major component of residual VSS in stabilised sludge for instance consisted of biomass, while cellulose was absent.

scholarly journals Evaluation of the Efficiency of Wastewater Treatment Plants in the Removal of Common Antibiotics from Municipal Wastewater in Hamadan, Iran

2017 ◽  
Vol 4 (1) ◽  
pp. 10921-10921 ◽  
Author(s):  
Reza Shokoohi ◽  
Abdollah Dargahi ◽  
Razieh Khamutian ◽  
Yaser Vaziri
Keyword(s):  
Wastewater Treatment ◽  
Removal Efficiency ◽  
Industrial Wastewater ◽  
High Performance ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Solid Phase ◽  
Aquatic Environments ◽  
Direct And Indirect Effects ◽  
Major Health

The presence of antibiotics in the environment, especially aquatic environments, is a major health and environmental concern.Wastewater treatment plants play an important role in the treatment of municipal and industrial wastewater and removal of contaminants.The aim of this study was to determine the concentration of prevalent antibiotics in municipal wastewater of Hamadan,Iran and to evaluate the removal efficiency of wastewater treatment plants. During 3 months (April, May, and June 2016), a total of 12 composite influent and effluent samples were collected from the wastewater treatment plants. Solid-phase extraction (SPE) was used for preparing the samples, which were then analyzed using high-performance liquid chromatography (HPLC) with UV detection.Based on the analysis of 6 antibiotics, three antibiotics, including amoxicillin, imipenem, and cefixime, were detected, and their concentrations were measured at 1.6, 10.7, and 5.8 ug/L, respectively. The removal efficiency of these antibiotics in wastewater treatment plants was 55.66%, 34.01%, and 24.33%, respectively. Due to the presence of examined antibiotics in the effluent and influent wastewater treatment plants, they might cause direct and indirect effects on human health and environment if proper measures are not taken by the authorities. Since the removal of these antibiotics from wastewater treatment plants is relatively poor, it is suggested to use advanced wastewater treatment plants to reduce antibiotics in effluent wastewater and decrease the adverse effects of these micropollutants.

Microbial Degradation of Nitrobenzene by Immobilized Cells of Micrococcus luteus

2012 ◽  
Vol 599 ◽  
pp. 52-59 ◽  
Author(s):  
Yue Qi ◽  
Chun Li Zheng ◽  
Ya Ting Zhang
Keyword(s):  
Polyurethane Foam ◽  
Industrial Wastewater ◽  
High Salinity ◽  
Immobilized Cells ◽  
Micrococcus Luteus ◽  
Kinetic Studies ◽  
Batch Experiments ◽  
Higher Temperature ◽  
Freely Suspended ◽  
Suspended Cells

Micrococcus luteus Z3 was immobilized in polyurethane foam and its ability to degrade nitrobenzene was investigated. Batch experiments showed that polyurethane-foam-immobilized cells possessed a higher degradation capacity. Compared to freely suspended cells (FSC), immobilized cells degraded nitrobenzene more efficiently under alkali and acid conditions, as well as higher temperature. Kinetic studies revealed that higher concentrations of nitrobenzene were better tolerated and more quickly degraded by immobilized cells. Moreover, in the presence of NaCl (≤10%, w/v) immobilized cells exhibited better tolerance toward salinity. Therefore immobilization of Z3 in polyurethane foam could be a promising method for treating nitrobenzene industrial wastewater, especially with high salinity.

scholarly journals Empirical model for predicting concentrations of refractory hydrophobic organic compounds in digested sludge from municipal wastewater treatment plants

2009 ◽  
Vol 6 (6) ◽  
pp. 544 ◽  
Author(s):  
Randhir P. Deo ◽  
Rolf U. Halden
Keyword(s):  
Wastewater Treatment ◽  
Organic Compounds ◽  
Empirical Model ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Environmental Pollutants ◽  
Treatment Plant ◽  
Municipal Wastewater Treatment ◽  
Hydrophobic Organic Compounds ◽  
Digested Sludge

Environmental context. Tens of thousands of manmade chemicals are discharged into municipal wastewaters on a continual basis by consumers around the world but surprisingly little is known about the occurrence and fate of these substances in the environment. The present study furnishes an easily applicable model that can help to predict the presence and concentration of manmade chemicals in digested municipal sludge (biosolids) destined for disposal on land. The new tool can be used to prescreen and identify in chemical databases potential environmental pollutants. Abstract. An empirical model is presented allowing for the prediction of concentrations of hydrophobic organic compounds (HOCs) prone to accumulate and persist in digested sludge (biosolids) generated during conventional municipal wastewater treatment. The sole input requirements of the model are the concentrations of the individual HOCs entering the wastewater treatment plant in raw sewage, the compound’s respective pH-dependent octanol-water partitioning coefficient (DOW), and an empirically determined fitting parameter (pfit) that reflects persistence of compounds in biosolids after accounting for all potential removal mechanisms during wastewater treatment. The accuracy of the model was successfully confirmed at the 99% confidence level in a paired t test that compared predicted concentrations in biosolids to empirical measurements reported in the literature. After successful validation, the resultant model was applied to predict levels of various HOCs for which occurrence data in biosolids thus far are lacking.

scholarly journals A Review of Pretreatment Methods to Enhance Solids Reduction during Anaerobic Digestion of Municipal Wastewater Sludges and the Resulting Digester Performance: Implications to Future Urban Biorefineries

2020 ◽  
Vol 10 (24) ◽  
pp. 9141
Author(s):  
Bimi Shrestha ◽  
Rafael Hernandez ◽  
Dhan Lord B. Fortela ◽  
Wayne Sharp ◽  
Andrei Chistoserdov ◽  
...  
Keyword(s):  
Anaerobic Digestion ◽  
Industrial Wastewater ◽  
Alternative Energy ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Organic Loading Rate ◽  
Attractive Alternative ◽  
The Us ◽  
Disposal Options ◽  
Wastewater Sludges

The rapid increase in the population is expected to result in the approaching of design capacity for many US wastewater treatment plants (WWTPs) over the next decade. WWTPs treat both municipal and industrial wastewater influents, resulting in the production of biosolids after digestion. Biogas, a potential recovered alternative energy source, is also produced as an output from successful anaerobic digestion. More than 7M of dry tons/year of biosolids produced in the US are most often disposed in either landfills or land-applied (~80%). These options are becoming more challenging to implement due to increases in transportation costs and tipping fees, decreases in the availability of landfill/landfarm space, and most importantly, increased regulations. This situation is strongly encouraging WWTPs to find alternatives for the disposal of biosolids. Developing alternative management/disposal options for biosolids are evolving. One of the most attractive alternative option from a sustainability perspective are biorefineries (converts waste to commercial products), which are a fast-growing option given the push toward circular urban source economies (little to no waste generation). Anaerobic digestion has been widely applied in WWTPs to reduce the volume of activated sludge due to its low energy requirements, effective handling of fluctuations due to organic loading rate, relative flexibility with temperature and pH changes, and since biogas is produced that can be transformed into energy. Various pretreatment methods for waste sludges prior to digestion that have been studied to reduce solids production and increase the energetic content of the biogas are presented and discussed. Solids handling and management, which comprises ~60% of the operational cost of a WWTP, is estimated to save more than $100 M annually by achieving at least 20% reduction in the annual production of biosolids within the US. This review incorporates an assessment of various pretreatment methods to optimize the anaerobic digestion of waste sludges with a focus on maximizing both biosolids reduction and biogas quality.

Study on Variation Trends of Heavy Metals Contents in Process of Sludge Energy Utilization

2012 ◽  
Vol 610-613 ◽  
pp. 198-202
Author(s):  
Ying Xie ◽  
Tao Zhang ◽  
Chong Li Xu ◽  
Yuan Feng Hui ◽  
Wen Jing Ou Yang
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Municipal Wastewater Treatment ◽  
Digested Sludge ◽  
Metal Contents ◽  
The Mean ◽  
Municipal Wastewater Treatment Plants

Application of sludge-to-energy is an important direction for disposal of sludge, and it is necessary to provide the contents change of heavy metals in sludge. Through sampling in situ and analysis in laboratory, distributions of seven heavy metals in five kinds of sludge, which were come from wastewater treatment plant of Jilin Petrochemical Company of Petro China, were studied, and contents change of heavy metals in the course of sludge-to-energy were analyzed. The results were compared with the other sludge in the factory and municipal wastewater treatment plants and the national standard. The results showed that the heavy metal contents are different in the different sludge, and the mean is Fe>Cu>Zn>Mn>Pb >Cr>Cd, the total content distributions from high to low is incinerated sludge, chemical sludge, activated sludge, neutralization sludge, digested sludge. Contents of Cu and Zn exceeded the the mean of 44 municipal wastewater treatment plants and GB18918-2002. After biogas of digested sludge and energy of incinerated sludge were recovered, heavy metal contents exceeded in varying degrees, which were paid more attention for treatment and utilization.

Toluene in sewage and sludge in wastewater treatment plants

2013 ◽  
Vol 69 (1) ◽  
pp. 128-134 ◽  
Author(s):  
Bozena Mrowiec
Keyword(s):  
Volatile Fatty Acids ◽  
Municipal Wastewater ◽  
High Efficiency ◽  
Wastewater Treatment Plants ◽  
Anaerobic Sludge ◽  
Digested Sludge ◽  
Sludge Digestion ◽  
External Sources ◽  
Secondary Settling ◽  
Year 2000

Toluene is a compound that often occurs in municipal wastewater ranging from detectable levels up to 237 μg/L. Before the year 2000, the presence of the aromatic hydrocarbons was assigned only to external sources. The Enhanced Biological Nutrients Removal Processes (EBNRP) work according to many different schemes and technologies. For high-efficiency biological denitrification and dephosphatation processes, the presence of volatile fatty acids (VFAs) in sewage is required. VFAs are the main product of organic matter hydrolysis from sewage sludge. However, no attention has been given to other products of the process. It has been found that in parallel to VFA production, toluene formation occurred. The formation of toluene in municipal anaerobic sludge digestion processes was investigated. Experiments were performed on a laboratory scale using sludge from primary and secondary settling tanks of municipal treatment plants. The concentration of toluene in the digested sludge from primary settling tanks was found to be about 42,000 μg/L. The digested sludge supernatant liquor returned to the biological dephosphatation and denitrification processes for sewage enrichment can contain up to 16,500 μg/L of toluene.

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