scholarly journals Combined Experimental and Theoretical Insights into the Corrosion Inhibition Activity on Carbon Steel Iron of Phosphonic Acids

Molecules ◽  
2020 ◽  
Vol 26 (1) ◽  
pp. 135
Author(s):  
Aurelia Visa ◽  
Nicoleta Plesu ◽  
Bianca Maranescu ◽  
Gheorghe Ilia ◽  
Ana Borota ◽  
...  
Keyword(s):  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Density Functional ◽  
Energy Gap ◽  
Electrochemical Impedance ◽  
Charge Transfer Resistance ◽  
Phosphonic Acids ◽  
Transfer Resistance ◽  
Potential Map ◽  
Chlorine Ions

The inhibition effect of N,N′-phosphonomethylglycine (PMG) and vinyl phosphonic acid (VPA) on the 3% NaCl acidic solution corrosion of carbon steel iron was studied at different immersion times by potentiodynamic polarization, electrochemical impedance spectroscopy, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, and computational methods. It is found from the polarization studies that PMG and VPA behave as mixed-type inhibitors in NaCl. Values of charge transfer resistance (Rct) and double layer capacitance (Cdl) in the absence and presence of inhibitors are determined. The PMG and VPA inhibitors were capable of inhibiting the corrosion process up to ≈91% and ≈85%, respectively. In the presence of PMG, the synergic effect of chlorine ions was observed. Density functional theory (DFT) was engaged to establish the adsorption site of PMG, VPA, and their deprotonated states. For studied compounds, the resulted values of ELUMO, EHOMO, energy gap (∆E), dipole moment (μ), electronic hardness (η), global softness (σ), electrophilic index (ω), and the electronic potential map are in concordance with the experimental data results regarding their corrosion inhibition behavior and adsorption on the metal surface.

Some Anionic Surfactants as Corrosion Inhibitors for Carbon Steel in Hydrochloric Acid Solution

2018 ◽  
Vol 786 ◽  
pp. 134-148 ◽  
Author(s):  
Rania Assem ◽  
A.S. Fouda ◽  
A.A. Ibrahim ◽  
M. Saadawy
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Acid Solution ◽  
Hydrochloric Acid Solution ◽  
Anionic Surfactants ◽  
Electrochemical Impedance ◽  
Charge Transfer Resistance ◽  
Polarization Data ◽  
Transfer Resistance ◽  
Carbon Steel Surface

The corrosion inhibition effect of some anionic surfactants (Diisononyl phthalate (A), N-oleyl-1, 3-propane –diamine (B), and Sodium lauryl sulphate (C)) on the corrosion of carbon steel in 1M hydrochloric acid solution were studied by chemical method (weight loss) and electrochemical methods (potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). From the results, it was clear that these surfactants are good inhibitors for corrosion of carbon steel in 1M HCl solution. Their inhibition depends mainly on their concentrations and temperature of solution. Polarization data revealed that these surfactants act as mixed type inhibitors. The surfactants adsorptions were found to follow Langmuir’s adsorption isotherm. The thermodynamic parameters of activation and adsorption were calculated and discussed. Adsorption of used surfactants led to a reduction in the double layer capacitance (Cdl) and an increase in the charge transfer resistance (Rct). All measurements used confirmed the adsorption of the surfactants used on carbon steel surface. Confirmation of these various independent techniques proved validity of the obtained data.

THE INFLUENCE OF GRAIN SIZE OF PURE IRON METAL ON CORROSION INHIBITION IN PRESENCE OF SODIUM NITRITE

2012 ◽  
Vol 05 ◽  
pp. 793-800 ◽  
Author(s):  
VAHID AFSHARI ◽  
CHANGIZ DEHGHANIAN
Keyword(s):  
Grain Size ◽  
Aqueous Solutions ◽  
Corrosion Inhibition ◽  
Sodium Nitrite ◽  
Active Sites ◽  
Electrochemical Impedance ◽  
Standard Free Energy ◽  
Charge Transfer Resistance ◽  
Free Energy Of Adsorption ◽  
Transfer Resistance

The effects of grain size reduction on the corrosion inhibition of sodium nitrite were investigated using polarization curves and electrochemical impedance spectroscopy (EIS). Nanocrystalline iron (~ 45 nm) was produced by pulse electrodeposition using citric acid bath. The grain size of a nanocrystalline surface was analyzed by X-ray diffractometry (XRD) and field emission scanning electron microscopy (FESEM). The most intensive first-order peak (211) of the XRD patterns was taken for detailed analysis using a Gaussian fitting curve. The tests were carried out in 25 mg / l NaCl + 57 mg / l Na 2 SO 4 with different concentration of sodium nitrite aqueous solutions. The results revealed that due to the adsorption process which leads to the formation of a protective layer with a greater charge transfer resistance the inhibition effect and corrosion protection of sodium nitrite inhibitor in near-neutral aqueous solutions increased as the grain size decreased from microcrystalline to nanocrystalline. The standard free energy of adsorption ( ΔGads ) revealed a strong interaction between inhibitor and nanocrystalline surface. This was attributed to the increased number of the active sites caused by nanocrystalline surface.

scholarly journals Electrochemical Study on Corrosion Inhibition of Copper in Hydrochloric Acid Medium and the Rotating Ring-Disc Voltammetry for Studying the Dissolution

2011 ◽  
Vol 2011 ◽  
pp. 1-8 ◽  
Author(s):  
A. K. Satpati ◽  
A. V. R. Reddy
Keyword(s):  
Hydrochloric Acid ◽  
Acid Medium ◽  
Corrosion Inhibition ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Standard Free Energy ◽  
Charge Transfer Resistance ◽  
Standard Free Energy Change ◽  
Transfer Resistance ◽  
Hydrochloric Acid Medium

Dissolution characteristics of copper in hydrochloric acid medium and the effect of 4-amino 1,2,4-triazole (ATA) on the corrosion process have been studied using conventional electrochemical techniques and rotating ring-disc electrodes (RRDEs). Corrosion potential () and corrosion current density () were obtained by Tafel extrapolation methods. Charge transfer resistance () and double-layer capacitance () were obtained from the electrochemical impedance spectroscopy (EIS). ATA was shown to be an effective inhibitor for the copper-corrosion inhibition in acid medium. The corrosion rate was retarded in presence of inhibitors mainly because of the adsorption of the inhibitor on the electrode surface. Adsorption of the inhibitor on the metal surface was found to follow the Langmuir adsorption isotherm. Standard free energy change of the adsorption process () was calculated to be −54.3 kJ mol−1; such a large negative value of suggests the prescence of a chemisorption process.

Corrosion Resistant Layers Produced in Vacuum Titanizing Process on a Low Carbon Steel Surface Coated Electrolytically with Cobalt

2014 ◽  
Vol 223 ◽  
pp. 110-118 ◽  
Author(s):  
Ewa Kasprzycka
Keyword(s):  
Corrosion Resistance ◽  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Charge Transfer Resistance ◽  
Electrolytic Deposition ◽  
Low Carbon ◽  
Transfer Resistance ◽  
Diffusion Layers ◽  
Passive Current

Diffusion layers produced on low-carbon steel and iron surfaces by means of vacuum titanizing process have been studied. A new technological process combining a vacuum titanizing with a preliminary electrolytic deposition of cobalt has been proposed to increase the corrosion resistance of layers. As a result, diffusion duplex layers of a Ti+Co type on the low-carbon steel and iron surfaces have been obtained. The layers microstructure, their thickness, phase composition and concentration depth profiles of elements in the diffusion zone of these layers have been investigated. Microstructure studies of these layers were performed by metallographic microscopy, X-ray diffraction, and a SEM electron microscope with a BSE and an EDS spectrometer. In addition, the layers hardness and their corrosion resistance have been determined. Corrosion measurements were performed in 0.1 M H2SO4 by means of potentiodynamic polarization and electrochemical impedance tests. The highest corrosion resistance was observed for steel samples with the Ti+Co type duplex layers, which showed the least passive current density and the highest charge transfer resistance, whereas the titanized layers, and the steel without any layer, corroded actively.

Improvement of Ti/RuO2–IrO2 Anode Lifetime and Electrocatalytical Properties by Using an Eco-Friendly Thermal Decomposition Method Using Polyvinyl Alcohol as Solvent

2019 ◽  
Author(s):  
Charlys Bezerra ◽  
Géssica Santos ◽  
Marilia Pupo ◽  
Maria Gomes ◽  
Ronaldo Silva ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Polyvinyl Alcohol ◽  
High Efficiency ◽  
Electrochemical Impedance ◽  
Pechini Method ◽  
Low Cost ◽  
Charge Transfer Resistance ◽  
Transfer Resistance ◽  
Calcination Temperatures ◽  
Service Lifetime

<p>Electrochemical oxidation processes are promising solutions for wastewater treatment due to their high efficiency, easy control and versatility. Mixed metal oxides (MMO) anodes are particularly attractive due to their low cost and specific catalytic properties. Here, we propose an innovative thermal decomposition methodology using <a>polyvinyl alcohol (PVA)</a> as a solvent to prepare Ti/RuO<sub>2</sub>–IrO<sub>2</sub> anodes. Comparative anodes were prepared by conventional method employing a polymeric precursor solvent (Pechini method). The calcination temperatures studied were 300, 400 and 500 °C. The physical characterisation of all materials was performed by X-ray diffraction and scanning electron microscopy coupled with energy dispersive spectroscopy, while electrochemical characterisation was done by cyclic voltammetry, accelerated service lifetime and electrochemical impedance spectroscopy. Both RuO<sub>2</sub> and IrO<sub>2</sub> have rutile-type structures for all anodes. Rougher and more compact surfaces are formed for the anodes prepared using PVA. Amongst temperatures studied, 300 °C using PVA as solvent is the most suitable one to produce anodes with expressive increase in voltammetric charge (250%) and accelerated service lifetime (4.3 times longer) besides reducing charge-transfer resistance (8 times lower). Moreover, the electrocatalytic activity of the anodes synthesised with PVA toward the Reactive Blue 21 dye removal in chloride medium (100 % in 30 min) is higher than that prepared by Pechini method (60 min). Additionally, the removal total organic carbon point out improved mineralisation potential of PVA anodes. Finally, this study reports a novel methodology using PVA as solvent to synthesise Ti/RuO<sub>2</sub>–IrO<sub>2</sub> anodes with improved properties that can be further extended to synthesise other MMO compositions.</p>

scholarly journals Electrochemical Immunosensor for the Quantification of S100B at Clinically Relevant Levels Using a Cysteamine Modified Surface

Sensors ◽  
2021 ◽  
Vol 21 (6) ◽  
pp. 1929
Author(s):  
Alexander Rodríguez ◽  
Francisco Burgos-Flórez ◽  
José D. Posada ◽  
Eliana Cervera ◽  
Valtencir Zucolotto ◽  
...  
Keyword(s):  
Frequency Analysis ◽  
Surface Characterization ◽  
Electrochemical Impedance ◽  
Limit Of Detection ◽  
Neuronal Damage ◽  
Charge Transfer Resistance ◽  
Single Frequency ◽  
Response Analysis ◽  
Transfer Resistance ◽  
Therapeutic Decisions

Neuronal damage secondary to traumatic brain injury (TBI) is a rapidly evolving condition, which requires therapeutic decisions based on the timely identification of clinical deterioration. Changes in S100B biomarker levels are associated with TBI severity and patient outcome. The S100B quantification is often difficult since standard immunoassays are time-consuming, costly, and require extensive expertise. A zero-length cross-linking approach on a cysteamine self-assembled monolayer (SAM) was performed to immobilize anti-S100B monoclonal antibodies onto both planar (AuEs) and interdigitated (AuIDEs) gold electrodes via carbonyl-bond. Surface characterization was performed by atomic force microscopy (AFM) and specular-reflectance FTIR for each functionalization step. Biosensor response was studied using the change in charge-transfer resistance (Rct) from electrochemical impedance spectroscopy (EIS) in potassium ferrocyanide, with [S100B] ranging 10–1000 pg/mL. A single-frequency analysis for capacitances was also performed in AuIDEs. Full factorial designs were applied to assess biosensor sensitivity, specificity, and limit-of-detection (LOD). Higher Rct values were found with increased S100B concentration in both platforms. LODs were 18 pg/mL(AuES) and 6 pg/mL(AuIDEs). AuIDEs provide a simpler manufacturing protocol, with reduced fabrication time and possibly costs, simpler electrochemical response analysis, and could be used for single-frequency analysis for monitoring capacitance changes related to S100B levels.

scholarly journals Influence of HAP on the Morpho-Structural Properties and Corrosion Resistance of ZrO2-Based Composites for Biomedical Applications

Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 202
Author(s):  
Réka Barabás ◽  
Carmen Ioana Fort ◽  
Graziella Liana Turdean ◽  
Liliana Bizo
Keyword(s):  
Electrochemical Impedance ◽  
Artificial Saliva ◽  
Synergetic Effect ◽  
Composite Layer ◽  
Charge Transfer Resistance ◽  
Processing Route ◽  
Dental Alloys ◽  
Metallic Electrode ◽  
Transfer Resistance ◽  
X Ray

In the present work, ZrO2-based composites were prepared by adding different amounts of antibacterial magnesium oxide and bioactive and biocompatible hydroxyapatite (HAP) to the inert zirconia. The composites were synthesized by the conventional ceramic processing route and morpho-structurally analyzed by X-ray powder diffraction (XRPD) and scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS). Two metallic dental alloys (i.e., Ni–Cr and Co–Cr) coated with a chitosan (Chit) membrane containing the prepared composites were exposed to aerated artificial saliva solutions of different pHs (i.e., 4.3, 5, 6) and the corrosion resistances were investigated by electrochemical impedance spectroscopy technique. The obtained results using the two investigated metallic dental alloys shown quasi-similar anticorrosive properties, having quasi-similar charge transfer resistance, when coated with different ZrO2-based composites. This behavior could be explained by the synergetic effect between the diffusion process through the Chit-composite layer and the roughness of the metallic electrode surface.

scholarly journals Corrosion behaviors of 316 stainless steel and Inconel 625 alloy in chloride molten salts for solar energy storage

2020 ◽  
Vol 39 (1) ◽  
pp. 340-350
Author(s):  
Mingjing Wang ◽  
Song Zeng ◽  
Huihui Zhang ◽  
Ming Zhu ◽  
Chengxin Lei ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Molten Salt ◽  
Electrochemical Impedance ◽  
Charge Transfer Resistance ◽  
Inconel 625 ◽  
Transfer Resistance ◽  
316 Stainless Steel ◽  
Corrosion Rates ◽  
Inconel 625 Alloy ◽  
Corrosion Behaviors

AbstractCorrosion behaviors of 316 stainless steel (316 ss) and Inconel 625 alloy in molten NaCl–KCl–ZnCl2 at 700°C and 900°C were investigated by immersion tests and electrochemical methods, including potentiodynamic polarization and electrochemical impedance spectroscopy. X-ray diffraction and scanning electron microscopy/energy dispersive spectroscopy were used to analyze the phases and microstructures of the corrosion products. Inconel 625 alloy and 316 ss exhibited high corrosion rates in molten chlorides, and the corrosion rates of these two alloys accelerated when the temperature increased from 700°C to 900°C. The results of the electrochemical tests showed that both alloys exhibited active corrosion in chloride molten salt, and the current density of 316 ss in chloride molten salt at 700°C was 2.756 mA/cm−2, which is about three times the value for Inconel 625 alloy; and the values of the charge transfer resistance (Rt) for Inconel 625 were larger than those for 316 ss. The corrosion of these two alloys is owing to the preferred oxidation of Cr in chloride molten salt, and the corrosion layer was mainly ZnCr2O4 which was loose and porous and showed poor adherence to metal.

scholarly journals Deciphering the Disaggregation Mechanism of Amyloid Beta Aggregate by 4-(2-Hydroxyethyl)-1-Piperazinepropanesulfonic Acid Using Electrochemical Impedance Spectroscopy

Sensors ◽  
2021 ◽  
Vol 21 (3) ◽  
pp. 788
Author(s):  
Hien T. Ngoc Le ◽  
Sungbo Cho
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Specific Binding ◽  
Amyloid Β ◽  
Electrochemical Measurement ◽  
Charge Transfer Resistance ◽  
Chemical Agent ◽  
Transfer Resistance ◽  
K Value

Aggregation of amyloid-β (aβ) peptides into toxic oligomers, fibrils, and plaques is central in the molecular pathogenesis of Alzheimer’s disease (AD) and is the primary focus of AD diagnostics. Disaggregation or elimination of toxic aβ aggregates in patients is important for delaying the progression of neurodegenerative disorders in AD. Recently, 4-(2-hydroxyethyl)-1-piperazinepropanesulfonic acid (EPPS) was introduced as a chemical agent that binds with toxic aβ aggregates and transforms them into monomers to reduce the negative effects of aβ aggregates in the brain. However, the mechanism of aβ disaggregation by EPPS has not yet been completely clarified. In this study, an electrochemical impedimetric immunosensor for aβ diagnostics was developed by immobilizing a specific anti-amyloid-β (aβ) antibody onto a self-assembled monolayer functionalized with a new interdigitated chain-shaped electrode (anti-aβ/SAM/ICE). To investigate the ability of EPPS in recognizing AD by extricating aβ aggregation, commercially available aβ aggregates (aβagg) were used. Electrochemical impedance spectroscopy was used to probe the changes in charge transfer resistance (Rct) of the immunosensor after the specific binding of biosensor with aβagg. The subsequent incubation of the aβagg complex with a specific concentration of EPPS at different time intervals divulged AD progression. The decline in the Rct of the immunosensor started at 10 min of EPPS incubation and continued to decrease gradually from 20 min, indicating that the accumulation of aβagg on the surface of the anti-aβ/SAM/ICE sensor has been extricated. Here, the kinetic disaggregation rate k value of aβagg was found to be 0.038. This innovative study using electrochemical measurement to investigate the mechanism of aβagg disaggregation by EPPS could provide a new perspective in monitoring the disaggregation periods of aβagg from oligomeric to monomeric form, and then support for the prediction and handling AD symptoms at different stages after treatment by a drug, EPPS.

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