scholarly journals Effect of Graphene Oxide/Graphene Hybrid on Mechanical Properties of Cement Mortar and Mechanism Investigation

Nanomaterials ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 113 ◽  
Author(s):  
Hongfang Sun ◽  
Li Ling ◽  
Zhili Ren ◽  
Shazim Ali Memon ◽  
Feng Xing

This paper evaluated the effect of graphene oxide/graphene (GO/GR) hybrid on mechanical properties of cement mortar. The underlying mechanism was also investigated. In the GO/GR hybrid, GO was expected to act as a dispersant for GR while GR was used as reinforcement in mortar due to its excellent mechanical properties. For the mortar specimen, flexural and compressive strength were measured at varied GO to GR ratios of 1:0, 3:1, 1:1, 1:3, and 0:1 by keeping the total amount of GO and GR constant. The underlying mechanism was investigated through the dispersibility of GR, heat releasing characteristics during hydration, and porosity of mortar. The results showed that GO/GR hybrid significantly enhanced the flexural and compressive strength of cement mortars. The flexural strength reached maximum at GO:GR = 1:1, where the enhancement level was up to 23.04% (28 days) when compared to mortar prepared with only GO, and up to 15.63% (7 days) when compared to mortar prepared with only GR. In terms of compressive strength, the enhancement level for GO:GR = 3:1 was up to 21.10% (3 days) when compared with that of mortar incorporating GO only. The enhancement in compressive strength with mortar at GO:GR = 1:1 was up to 14.69% (7-day) when compared with mortar incorporating GR only. In addition to dispersibility, the compressive strength was also influenced by other factors, such as the degree of hydration, porosity, and pore size distribution of mortar, which made the mortars perform best at different ages.

2010 ◽  
Vol 168-170 ◽  
pp. 190-194 ◽  
Author(s):  
Zhen Jun Wang ◽  
Rui Wang ◽  
Yu Bin Cheng

In this paper, styrene-butadiene polymer emulsion SD622S was adopted to modify cement mortar; mechanical properties of cement mortars were studied and microstructures was analyzed by means of Scanning Electron Microscope (SEM) and Specific Surface Area & Pore Distribution Analyzer. The results show that in contrast to ordinary cement mortar, if water to cement ratio (W/C) is constant, compressive strength of modified cement mortar can decrease, while flexural strength and toughness, ratio of compressive strength to flexural strength, increase with the increase of polymer to cement ratio in mass (P/C) at 7 and 28 curing days. With the increase of P/C, net structure made from polymer and cement hydration products is developed and pore whose size is smaller than 200Å begins to increase, which indicates pore diameters in modified cement mortar change to be finer. So microstructures of modified cement mortar become denser and display higher toughness.


2020 ◽  
Vol 38 (10A) ◽  
pp. 1522-1530
Author(s):  
Rawnaq S. Mahdi ◽  
Aseel B. AL-Zubidi ◽  
Hassan N. Hashim

This work reports on the incorporation of Flint and Kaolin rocks powders in the cement mortar in an attempt to improve its mechanical properties and produce an eco-friendly mortar. Flint and Kaolin powders are prepared by dry mechanical milling. The two powders are added separately to the mortars substituting cement partially. The two powders are found to improve the mechanical properties of the mortars. Hardness and compressive strength are found to increase with the increase of powders constituents in the cement mortars. In addition, the two powders affect water absorption and thermal conductivity of the mortar specimens which are desirable for construction applications. Kaolin is found to have a greater effect on the mechanical properties, water absorption, and thermal conductivity of the mortars than Flint. This behavior is discussed and analyzed based on the compositional and structural properties of the rocks powders.


2021 ◽  
Vol 13 (8) ◽  
pp. 4546
Author(s):  
Kaiyue Zhao ◽  
Peng Zhang ◽  
Bing Wang ◽  
Yupeng Tian ◽  
Shanbin Xue ◽  
...  

Cement-based materials prepared with activated water induced by a magnetic field or electric field represent a possible solution to environmental issues caused by the worldwide utilization of chemical admixtures. In this contribution, electric- and magnetic-activated water have been produced. The workability and mechanical properties of cement mortar prepared with this activated water have been investigated. The results indicate that the pH and absorbance (Abs) values of the water varied as the electric and magnetic field changed, and their values increased significantly, exhibiting improved activity compared with that of the untreated water. In addition, activated water still retains activity within 30 min of the resting time. The fluidity of the cement paste prepared with electric-activated water was significantly larger than that of the untreated paste. However, the level of improvement differed with the worst performance resulting from cement paste prepared with alternating voltage activated water. In terms of mechanical properties, both compressive strength and flexural strength obtained its maximum values at 280 mT with two processing cycles. The compressive strength increased 26% as the curing time increased from 7 days to 28 days and flexural strength increased by 31%. In addition, through the introduction of magnetic-activated water into cement mortar, the mechanical strength can be maintained without losing its workability when the amount of cement is reduced.


Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2136
Author(s):  
Shaokang Zhang ◽  
Ru Wang ◽  
Linglin Xu ◽  
Andreas Hecker ◽  
Horst-Michael Ludwig ◽  
...  

This paper studies the influence of hydroxyethyl methyl cellulose (HEMC) on the properties of calcium sulfoaluminate (CSA) cement mortar. In order to explore the applicability of different HEMCs in CSA cement mortars, HEMCs with higher and lower molar substitution (MS)/degree of substitution (DS) and polyacrylamide (PAAm) modification were used. At the same time, two kinds of CSA cements with different contents of ye’elimite were selected. Properties of cement mortar in fresh and hardened states were investigated, including the fluidity, consistency and water-retention rate of fresh mortar and the compressive strength, flexural strength, tensile bond strength and dry shrinkage rate of hardened mortar. The porosity and pore size distribution were also analyzed by mercury intrusion porosimetry (MIP). Results show that HEMCs improve the fresh state properties and tensile bond strength of both types of CSA cement mortars. However, the compressive strength of CSA cement mortars is greatly decreased by the addition of HEMCs, and the flexural strength is decreased slightly. The MIP measurement shows that HEMCs increase the amount of micron-level pores and the porosity. The HEMCs with different MS/DS have different effects on the improvement of tensile bond strength in different CSA cement mortars. PAAm modification can improve the tensile bond strength of HEMC-modified CSA cement mortar.


2018 ◽  
Vol 27 (3) ◽  
pp. 348-354 ◽  
Author(s):  
Jakub Jura ◽  
Małgorzata Ulewicz

The article presents the results of research aimed at using glass waste and ash from biomass. The tests were carried out for cement mortars samples with using glass cullet, ash from biomass and using both wastes in 50/50 proportions. The physical and mechanical properties of the standard mortar and modified mortars were tested. Standard mortar and cement mortar samples were made in which 10, 20 and 30% of the cement mass was used as part of the standard sand. The samples were made of CEM I 42.5R. Mortars containing fly ash addition had an increased compressive strength and a smaller drop in compressive strength after frost resistance tests than standard mortar. The use of glass cullet in the amount of up to 20% did not reveal any changes in the mechanical properties of mortars, but using them in a larger amount resulted in unfavorable results. The use of a mixture of these two waste materials did not improve the results. The research has shown the possibility of using this waste to modify cement mortars.


2014 ◽  
Vol 548-549 ◽  
pp. 1663-1666
Author(s):  
Fu Xing Wang ◽  
Guo Zhong Li ◽  
Juan Chen

The effect of admixtures on the mechanical properties of recycled fine aggregate cement mortar was studied. The result indicated that compared with blank samples the 28d flexural strength, the compressive strength and osmotic pressure of cement mortar were increased by 15.6%, 35.5%, 41.1% respectively when adding silicone waterproofing agent 0.2wt%, naphdalin series water reducer 1.0wt%, polycarboxylate superplasticizer 0.8wt%. The micro-morphology and hydration products of mortar specimens was observed by SEM, XRD respectively.


2013 ◽  
Vol 539 ◽  
pp. 244-248
Author(s):  
De Zhi Wang ◽  
Yin Yan Zhang ◽  
Yun Fang Meng

Water requirement of normal consistency, setting time and soundness of cement pastes mixed with SiO2 and CaCO3 nanoparticle and the flexural strength and compressive strength of cement mortars mixed with SiO2 and CaCO3 nanoparticles were experimentally studied. Results indicated that the added nano-SiO2 and nano-CaCO3 with a mass account of 4.0 wt. % decreased the setting time and increased the water requirement of normal consistency, flexural strength and compressive strength. And these nanoscaled mineral admixtures did not have a negative impact on cement soundness. The optimal replacement levels of cement by SiO2 and CaCO3 nanoparticles for producing cement mortar with improved strength were 2.0 and 4.0 wt.% respectively.


2010 ◽  
Vol 168-170 ◽  
pp. 1886-1890 ◽  
Author(s):  
Zheng Mao Ye ◽  
Wen Chen ◽  
Xin Cheng

The impermeability and other performance of sulphoaluminate cement were studied, which mixed with redispersible polymer powders. With the help of SEM and mercury intrusion apparatus, the morphology of the hydrates and the pore structure of the cement mortars were observed. The impermeability mechanism of redispersible polymer powders in sulphoaluminate cement mortar was analyzed. The results show that sulphoaluminate cement mortar could be modified by adding redispersible polymer powders. The flexural strength of sulphoaluminate cement mortar could be increased by adding redispersible polymer powders, and compressive strength of sulphoaluminate cement mortar could also be increased to a certain extent. When the mass fraction of redispersible polymer powders was 0.9%, the flexural strength and compressive strength reached 9.2 MPa and 52.5 MPa. When small amount of redispersible polymer powders was added, the impermeability of modified sulphoaluminate cement mortar was improved significantly. When the mass fraction of redispersible polymer powders exceeded 0.9%, impermeability of Sulphoaluminate cement mortar would not be improved significantly. Due to redispersible powders gap filling and film forming, the interface of cement and aggregate is more closed, total porosity decreased and unharmful porosity increased when redispersible polymer powders is added.


2021 ◽  
Vol 13 (7) ◽  
pp. 3697
Author(s):  
Hui Chen ◽  
Xin Huang ◽  
Rui He ◽  
Zhenheng Zhou ◽  
Chuanqing Fu ◽  
...  

In this work, the relationships between the mechanical properties (i.e., compressive strength and flexural strength) and loading speed of polypropylene fiber (PPF)-incorporated cement mortar at different ages (before 28 days) were studied. A total of 162 cubic samples for compressive strength tests and 162 cuboid samples for flexural strength tests were casted and tested. Analytical relationships between the sample properties (i.e., sample age, PPF content, and loading speed) and compressive and flexural strength were proposed based on the experimental data, respectively. Of the predicted compressive and flexural strength results, 70.4% and 75.9% showed less than 15% relative error compared with the experimental results, respectively.


Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 517
Author(s):  
Pengfei Li ◽  
Wei Lu ◽  
Xuehui An ◽  
Li Zhou ◽  
Sanlin Du

In this study, an analysis of the influence of polymer modification on the mechanical behavior, porosity, and microstructure of mortar is carried out. Epoxy latexes contents of 5%, 10%, 15%, and 20% of cement were employed in the preparation of cement mortars based on the same workability. The specimens were subjected to dry, wet, and wet–dry curing regimes. Compressive strength, flexural strength, Mercury intrusion porosimetry (MIP), and scanning electronic microscope (SEM) tests were conducted to analyze the effect of epoxy latexes on the mechanical property and porosity of modified mortars. Based on the compressive strength test results, a quantitative method was established to calculated the degree of hydration and polymerization. The results show that the mechanical behavior and porosity property of epoxy latexes modified mortar are influenced by the degree of hydration, the degree of polymerization, and the volume changing effect of mortar. The polymerization of epoxy latexes could improve the flexural strength of the mortar. The macropores of specimens tended to decrease with the increase of the degree of epoxy latexes polymerization and cement hydration. In practical engineering, it is necessary to ensure the degree of hydration and increase the polymerization rate. Thus, the wet–dry curing regime is recommended.


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