scholarly journals Flexible and Conductive Bioelectrodes Based on Chitosan-Carbon Black Membranes: Towards the Development of Wearable Bioelectrodes

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 2052
Author(s):  
Mireia Buaki-Sogó ◽  
Laura García-Carmona ◽  
Mayte Gil-Agustí ◽  
Marta García-Pellicer ◽  
Alfredo Quijano-López

Wearable sensors for non-invasive monitoring constitute a growing technology in many industrial fields, such as clinical or sport monitoring. However, one of the main challenges in wearable sensing is the development of bioelectrodes via the use of flexible and stretchable materials capable of maintaining conductive and biocompatible properties simultaneously. In this study, chitosan-carbon black (CH-CB) membranes have been synthesized using a straightforward and versatile strategy and characterized in terms of their composition and their electrical and mechanical properties. In this sense, CH-CB membranes showed good conductivity and mechanical resistance thanks to the presence of carbon black, which decreases the insulating behavior of chitosan, while flexibility and biocompatibility are maintained due to the dual composition of the membrane. Thus, flexible and biocompatible conductive bioelectrodes have been developed by the combined use of CH and CB without the use of toxic reagents, extra energy input, or long reaction times. The membranes were modified using the enzymes Glucose Oxidase and Laccase in order to develop flexible and biocompatible bioelectrodes for enzymatic glucose biofuel cells (BFCs) and glucose detection. A BFC assembled using the flexible bioelectrodes developed was able to deliver 15 µW cm−2, using just 1 mM glucose as biofuel, and up to 21.3 µW·cm−2 with higher glucose concentration. Additionally, the suitability of the CH-CB membranes to be used as a glucose sensor in a linear range from 100 to 600 µM with a limit of detection (LOD) of 76 µM has been proven. Such demonstrations for energy harvesting and sensing capabilities of the developed membrane pave the way for their use in wearable sensing and energy harvesting technologies in the clinical field due to their good mechanical, electrical, and biocompatible properties.

Lab on a Chip ◽  
2018 ◽  
Vol 18 (2) ◽  
pp. 217-248 ◽  
Author(s):  
J. Heikenfeld ◽  
A. Jajack ◽  
J. Rogers ◽  
P. Gutruf ◽  
L. Tian ◽  
...  

Non-invasive wearable sensing technology extracts mechanical, electrical, optical, and chemical information from the human body.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4070
Author(s):  
Andrea Karen Persons ◽  
John E. Ball ◽  
Charles Freeman ◽  
David M. Macias ◽  
Chartrisa LaShan Simpson ◽  
...  

Standards for the fatigue testing of wearable sensing technologies are lacking. The majority of published fatigue tests for wearable sensors are performed on proof-of-concept stretch sensors fabricated from a variety of materials. Due to their flexibility and stretchability, polymers are often used in the fabrication of wearable sensors. Other materials, including textiles, carbon nanotubes, graphene, and conductive metals or inks, may be used in conjunction with polymers to fabricate wearable sensors. Depending on the combination of the materials used, the fatigue behaviors of wearable sensors can vary. Additionally, fatigue testing methodologies for the sensors also vary, with most tests focusing only on the low-cycle fatigue (LCF) regime, and few sensors are cycled until failure or runout are achieved. Fatigue life predictions of wearable sensors are also lacking. These issues make direct comparisons of wearable sensors difficult. To facilitate direct comparisons of wearable sensors and to move proof-of-concept sensors from “bench to bedside,” fatigue testing standards should be established. Further, both high-cycle fatigue (HCF) and failure data are needed to determine the appropriateness in the use, modification, development, and validation of fatigue life prediction models and to further the understanding of how cracks initiate and propagate in wearable sensing technologies.


2021 ◽  
Vol 11 (3) ◽  
pp. 1235
Author(s):  
Su Min Yun ◽  
Moohyun Kim ◽  
Yong Won Kwon ◽  
Hyobeom Kim ◽  
Mi Jung Kim ◽  
...  

The development of wearable sensors is aimed at enabling continuous real-time health monitoring, which leads to timely and precise diagnosis anytime and anywhere. Unlike conventional wearable sensors that are somewhat bulky, rigid, and planar, research for next-generation wearable sensors has been focused on establishing fully-wearable systems. To attain such excellent wearability while providing accurate and reliable measurements, fabrication strategies should include (1) proper choices of materials and structural designs, (2) constructing efficient wireless power and data transmission systems, and (3) developing highly-integrated sensing systems. Herein, we discuss recent advances in wearable devices for non-invasive sensing, with focuses on materials design, nano/microfabrication, sensors, wireless technologies, and the integration of those.


Author(s):  
Qian Zhang ◽  
Lei Gu ◽  
Ken Yang ◽  
Miah A Halim ◽  
Robert Rantz ◽  
...  

MRS Advances ◽  
2016 ◽  
Vol 1 (13) ◽  
pp. 861-867 ◽  
Author(s):  
Sanghamitra Mandal ◽  
Mohammed Marie ◽  
Omar Manasreh

ABSTRACTAn electrochemical glucose sensor based on zinc oxide (ZnO) nanorods is fabricated, characterized and tested. The ZnO nanorods are synthesized on indium titanium oxide (ITO) coated glass substrate, using the hydrothermal sol-gel technique. The working principle of the sensor under investigation is based on the electrochemical reaction taking place between cathode and anode, in the presence of an electrolyte. A platinum plate, used as the cathode and Nafion/Glucose Oxidase/ZnO nanorods/ITO-coated glass substrate used as anode, is immersed in pH 7.0 phosphate buffer solution electrolyte to test for the presence of glucose. Several amperometric tests are performed on the fabricated sensor to determine the response time, sensitivity and limit of detection of the sensor. A fast response time less than 3 s with a high sensitivity of 1.151 mA cm-2mM-1 and low limit of detection of 0.089 mM is reported. The glucose sensor is characterized using the cyclic voltammetry method in the range from -0.8 – 0.8 V with a voltage scan rate of 100 mV/s.


Sensors ◽  
2018 ◽  
Vol 18 (11) ◽  
pp. 3746 ◽  
Author(s):  
Antonio Lazaro ◽  
Ramon Villarino ◽  
David Girbau

In this article, an overview of recent advances in the field of battery-less near-field communication (NFC) sensors is provided, along with a brief comparison of other short-range radio-frequency identification (RFID) technologies. After reviewing power transfer using NFC, recommendations are made for the practical design of NFC-based tags and NFC readers. A list of commercial NFC integrated circuits with energy-harvesting capabilities is also provided. Finally, a survey of the state of the art in NFC-based sensors is presented, which demonstrates that a wide range of sensors (both chemical and physical) can be used with this technology. Particular interest arose in wearable sensors and cold-chain traceability applications. The availability of low-cost devices and the incorporation of NFC readers into most current mobile phones make NFC technology key to the development of green Internet of Things (IoT) applications.


Membranes ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 128 ◽  
Author(s):  
Yan Lyu ◽  
Shiyu Gan ◽  
Yu Bao ◽  
Lijie Zhong ◽  
Jianan Xu ◽  
...  

Wearable sensors based on solid-contact ion-selective electrodes (SC-ISEs) are currently attracting intensive attention in monitoring human health conditions through real-time and non-invasive analysis of ions in biological fluids. SC-ISEs have gone through a revolution with improvements in potential stability and reproducibility. The introduction of new transducing materials, the understanding of theoretical potentiometric responses, and wearable applications greatly facilitate SC-ISEs. We review recent advances in SC-ISEs including the response mechanism (redox capacitance and electric-double-layer capacitance mechanisms) and crucial solid transducer materials (conducting polymers, carbon and other nanomaterials) and applications in wearable sensors. At the end of the review we illustrate the existing challenges and prospects for future SC-ISEs. We expect this review to provide readers with a general picture of SC-ISEs and appeal to further establishing protocols for evaluating SC-ISEs and accelerating commercial wearable sensors for clinical diagnosis and family practice.


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