scholarly journals Chemical Modification of Poly(butylene trans-1,4-cyclohexanedicarboxylate) by Camphor: A New Example of Bio-Based Polyesters for Sustainable Food Packaging

Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2707
Author(s):  
Giulia Guidotti ◽  
Gianfranco Burzotta ◽  
Michelina Soccio ◽  
Massimo Gazzano ◽  
Valentina Siracusa ◽  
...  
Keyword(s):  
Chemical Modification ◽  
Food Packaging ◽  
Tensile Tests ◽  
Point Of View ◽  
Random Copolymers ◽  
Sustainable Food ◽  
X Ray Scattering ◽  
Plastic Materials ◽  
First Time ◽  
Camphoric Acid

Among the several actions contributing to the development of a sustainable society, there is the eco-design of new plastic materials with zero environmental impact but that are possibly characterized by properties comparable to those of the traditional fossil-based plastics. This action is particularly urgent for food packaging sector, which involves large volumes of plastic products that quickly become waste. This work aims to contribute to the achievement of this important goal, proposing new bio-based cycloaliphatic polymers based on trans-1,4-cyclohexanedicarboxylic acid and containing different amount of camphoric acid (from 0 to 15 mol %), a cheap and bio-based building block. Such chemical modification was conducted in the melt by avoiding the use of solvents. The so-obtained polymers were processed in the form of films by compression molding. Afterwards, the new and successfully synthesized random copolymers were characterized by molecular (NMR spectroscopy and GPC analysis), thermal (DSC and TGA analyses), diffractometric (wide angle X-ray scattering), mechanical (through tensile tests), and O2 and CO2 barrier point of view together with the parent homopolymer. The article aims to relate the results obtained with the amount of camphoric moiety introduced and to present, the different microstructure in the copolymers in more detail; indeed, in these samples, a different crystalline form developed (the so-called β-PBCE). This latter form was the kinetically favored and less packed one, as proven by the lower equilibrium melting temperature determined for the first time by Baur’s equation.

Thanato-Laboratorien. Theorien von Tod und Sterben und Elias Canettis Buch gegen den Tod

2020 ◽  
Vol 4 (1) ◽  
pp. 67-86
Author(s):  
Elisabeth Heyne
Keyword(s):  
Human Life ◽  
Death And Dying ◽  
Point Of View ◽  
Visual Images ◽  
Elias Canetti ◽  
History Of ◽  
Series Of Experiments ◽  
First Time ◽  
Textual Form ◽  
Or History

AbstractAlthough visual culture of the 21th century increasingly focuses on representation of death and dying, contemporary discourses still lack a language of death adequate to the event shown by pictures and visual images from an outside point of view. Following this observation, this article suggests a re-reading of 20th century author Elias Canetti. His lifelong notes have been edited and published posthumously for the first time in 2014. Thanks to this edition Canetti's short texts and aphorisms can be focused as a textual laboratory in which he tries to model a language of death on experimental practices of natural sciences. The miniature series of experiments address the problem of death, not representable in discourses of cultural studies, system theory or history of knowledge, and in doing so, Canetti creates liminal texts at the margins of western concepts of (human) life, science and established textual form.

A Nabatean port on the Red Sea: note on the pottery finds from al-Qusayr (al-Wajh, Saudi Arabia)

2020 ◽  
Author(s):  
Caroline Durand
Keyword(s):  
Saudi Arabia ◽  
19Th Century ◽  
Red Sea ◽  
Point Of View ◽  
The Other ◽  
Trade Routes ◽  
Other Hand ◽  
Roman Egypt ◽  
Pottery Sherds ◽  
First Time

Al-Qusayr is located 40 km south of modern al-Wajh, roughly 7 km from the eastern Red Sea shore. This site is known since the mid-19th century, when the explorer R. Burton described it for the first time, in particular the remains of a monumental building so-called al-Qasr. In March 2016, a new survey of the site was undertaken by the al-‘Ula–al-Wajh Survey Project. This survey focused not only on al-Qasr but also on the surrounding site corresponding to the ancient settlement. A surface collection of pottery sherds revealed a striking combination of Mediterranean and Egyptian imports on one hand, and of Nabataean productions on the other hand. This material is particularly homogeneous on the chronological point of view, suggesting a rather limited occupation period for the site. Attesting contacts between Mediterranean merchants, Roman Egypt and the Nabataean kingdom, these new data allow a complete reassessment of the importance of this locality in the Red Sea trade routes during antiquity.

Ground state molecular parameters of phosphine, PH3, from the simultaneous analysis of the high-resolution infrared, microwave and submillimeterwave spectra

1985 ◽  
Vol 50 (11) ◽  
pp. 2480-2492 ◽  
Author(s):  
Soňa Přádná ◽  
Dušan Papoušek ◽  
Jyrki Kauppinen ◽  
Sergei P. Belov ◽  
Andrei F. Krupnov ◽  
...  
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Ground State ◽  
Unitary Transformation ◽  
Point Of View ◽  
Acoustic Detection ◽  
Molecular Parameters ◽  
Microwave Spectrometer ◽  
Fourier Transform Spectra ◽  
First Time

Fourier transform spectra of the ν2 band of PH3 have been remeasured with 0.0045 cm-1 resolution. Ground state combination differences from these data have been fitted simultaneously with the microwave and submillimeterwave data to determine the ground state spectroscopical parameters of PH3 including the parameters of the Δk = ± 3n interactions. The correlation between the latter parameters has been discussed from the point of view of the existence of two equivalent effective rotational operators which are related by a unitary transformation. The ΔJ = 0, +1, ΔK = 0 (A1 ↔ A2, E ↔ E) rotational transitions in the ν2 and ν4 states have been measured for the first time by using a microwave spectrometer and a radiofrequency spectrometer with acoustic detection.

scholarly journals An exceptionally preserved conulariid from Ordovician erratics of Northern European Lowlands

PalZ ◽  
2021 ◽  
Author(s):  
Consuelo Sendino ◽  
Martin M. Bochmann
Keyword(s):  
Internal Structure ◽  
Late Pleistocene ◽  
Point Of View ◽  
Three Dimensions ◽  
Northern European ◽  
Current Location ◽  
Transport Direction ◽  
First Time ◽  
Erratic Boulder

AbstractA conulariid preserved in three dimensions from Ordovician fluvioglacial erratics of the Northern European Lowlands (North German Plain) is described under open nomenclature. It is assigned to the genus Conularia with similarities to Baltoscandian conulariids. The lithology of the erratic boulder and fauna contained in it provide important information on the origin and transport direction of the sediment preserved in a kame from the Saalian glaciation. This paper deals with the site of origin of the boulder in Baltoscandia analysing the comprised palaeofauna, from a palaeostratigraphic and palaeogeographic point of view, from its deposition in Ordovician times until its arrival at its current location in the Late Pleistocene. It also reveals for the first time the internal structure of the conulariid aperture.

scholarly journals Fractional isospectral and non-isospectral AKNS hierarchies and their analytic methods for N-fractal solutions with Mittag-Leffler functions

2021 ◽  
Vol 2021 (1) ◽  
Author(s):  
Bo Xu ◽  
Yufeng Zhang ◽  
Sheng Zhang
Keyword(s):  
Spectral Problem ◽  
Fractional Order ◽  
Point Of View ◽  
Adjoint Equations ◽  
Scattering Data ◽  
Bilinear Method ◽  
Soliton Equation ◽  
Scattering Transform ◽  
First Time ◽  
Hirota Bilinear

AbstractAblowitz–Kaup–Newell–Segur (AKNS) linear spectral problem gives birth to many important nonlinear mathematical physics equations including nonlocal ones. This paper derives two fractional order AKNS hierarchies which have not been reported in the literature by equipping the AKNS spectral problem and its adjoint equations with local fractional order partial derivative for the first time. One is the space-time fractional order isospectral AKNS (stfisAKNS) hierarchy, three reductions of which generate the fractional order local and nonlocal nonlinear Schrödinger (flnNLS) and modified Kortweg–de Vries (fmKdV) hierarchies as well as reverse-t NLS (frtNLS) hierarchy, and the other is the time-fractional order non-isospectral AKNS (tfnisAKNS) hierarchy. By transforming the stfisAKNS hierarchy into two fractional bilinear forms and reconstructing the potentials from fractional scattering data corresponding to the tfnisAKNS hierarchy, three pairs of uniform formulas of novel N-fractal solutions with Mittag-Leffler functions are obtained through the Hirota bilinear method (HBM) and the inverse scattering transform (IST). Restricted to the Cantor set, some obtained continuous everywhere but nondifferentiable one- and two-fractal solutions are shown by figures directly. More meaningfully, the problems worth exploring of constructing N-fractal solutions of soliton equation hierarchies by HBM and IST are solved, taking stfisAKNS and tfnisAKNS hierarchies as examples, from the point of view of local fractional order derivatives. Furthermore, this paper shows that HBM and IST can be used to construct some N-fractal solutions of other soliton equation hierarchies.

Cutin‐Inspired Polymers and Plant Cuticle‐like Composites as Sustainable Food Packaging Materials

2021 ◽  
pp. 161-198
Author(s):  
Susana Guzmán‐Puyol ◽  
Antonio Heredia ◽  
José A. Heredia‐Guerrero ◽  
José J. Benítez
Keyword(s):  
Food Packaging ◽  
Plant Cuticle ◽  
Packaging Materials ◽  
Sustainable Food ◽  
Food Packaging Materials

Information-based decoding of the coupling among human brain activity and movement paths

2021 ◽  
pp. 1-10
Author(s):  
Shahul Mujib Kamal ◽  
Norazryana Mat Dawi ◽  
Hamidreza Namazi
Keyword(s):  
Brain Activity ◽  
Point Of View ◽  
Physiological Signals ◽  
Human Walking ◽  
Eeg Signals ◽  
Rehabilitation Science ◽  
Information Contents ◽  
First Time ◽  
The Brain ◽  
Brain Reaction

BACKGROUND: Walking like many other actions of a human is controlled by the brain through the nervous system. In fact, if a problem occurs in our brain, we cannot walk correctly. Therefore, the analysis of the coupling of brain activity and walking is very important especially in rehabilitation science. The complexity of movement paths is one of the factors that affect human walking. For instance, if we walk on a path that is more complex, our brain activity increases to adjust our movements. OBJECTIVE: This study for the first time analyzed the coupling of walking paths and brain reaction from the information point of view. METHODS: We analyzed the Shannon entropy for electroencephalography (EEG) signals versus the walking paths in order to relate their information contents. RESULTS: According to the results, walking on a path that contains more information causes more information in EEG signals. A strong correlation (p= 0.9999) was observed between the information contents of EEG signals and walking paths. Our method of analysis can also be used to investigate the relation among other physiological signals of a human and walking paths, which has great benefits in rehabilitation science.

Determination of Bio Content in Polymers used in the Packaging of food Products

Radiocarbon ◽  
2019 ◽  
Vol 61 (6) ◽  
pp. 1973-1981
Author(s):  
C Telloli ◽  
A Rizzo ◽  
C Canducci ◽  
P Bartolomei
Keyword(s):  
Food Packaging ◽  
Liquid Scintillation ◽  
Scintillation Counting ◽  
Operational Parameters ◽  
Original Design ◽  
Plastic Materials ◽  
Different Types ◽  
Scintillation Method

ABSTRACTThe ENEA Radiocarbon Laboratory (Bologna, Italy) has been operating since 1985; it is the oldest among such laboratories operating in Italy and has been active for about 30 years in the field of dating of different types of samples with the radiocarbon (14C) liquid scintillation method. This study shows the detailed procedure for radiocarbon analysis on bioplastic materials by means of the synthesis of benzene, which includes CO2 production and purification, synthesis of acetylene, and synthesis and collection of benzene. The changes made to the original design of the synthesis procedures and the operational parameters adopted to optimize the combustion of the plastic materials are described. The measurement of 14C activity was performed using the liquid scintillation counting technique by a QuantulusTM 1220 low-background counter. The δ13C content was compared with the percentage of 14C concentration for the characterization of the bio content in plastic used in the food packaging.

Mesoscopic structure of SiC fibers by neutron and x-ray scattering

1996 ◽  
Vol 11 (5) ◽  
pp. 1169-1178 ◽  
Author(s):  
Kentaro Suzuya ◽  
Michihiro Furusaka ◽  
Noboru Watanabe ◽  
Makoto Osawa ◽  
Kiyohito Okamura ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Volume Fraction ◽  
X Rays ◽  
X Ray ◽  
Sic Fibers ◽  
X Ray Scattering ◽  
Mesoscopic Structure ◽  
Angle Scattering ◽  
Momentum Transfer Range ◽  
First Time

Mesoscopic structures of SiC fibers produced from polycarbosilane by different methods were studied by diffraction and small-angle scattering of neutrons and x-rays. Microvoids of a size of 4–10 Å in diameter have been observed for the first time by neutron scattering in a medium momentum transfer range (Q = 0.1–1.0 Å−1). The size and the volume fraction of β–SiC particles were determined for fibers prepared at different heat-treatment temperatures. The results show that wide-angle neutron scattering measurements are especially useful for the study of the mesoscopic structure of multicomponent materials.

Determination of In-plane Shear Strength of Unidirectional Composite Materials Using the Off-axis Three-point Flexure and Off-axis Tensile Tests

2010 ◽  
Vol 44 (21) ◽  
pp. 2487-2507 ◽  
Author(s):  
G. Vargas ◽  
F. Mujika
Keyword(s):  
Shear Strength ◽  
Composite Materials ◽  
Tensile Tests ◽  
Unidirectional Composite ◽  
Point Of View ◽  
Experimental Point ◽  
Plane Shear ◽  
Lift Off ◽  
Flexure Test

The aim of this work is to compare from an experimental point of view the determination of in-plane shear strength of unidirectional composite materials by means of two off-axis tests: three-point flexure and tensile. In the case of the off-axis three-point flexure test, the condition of small displacements and the condition of lift-off between the specimen and the fixture supports have been taken into account. Some considerations regarding stress and displacement fields are presented. The in-plane shear characterization has been performed on a carbon fiber reinforced unidirectional laminate with several fiber orientation angles: 10°, 20°, 30°, and 45°. Test conditions for both off-axis experimental methods, in order to ensure their applicability, are presented. Off-axis flexure test is considered more suitable than off-axis tensile test for the determination of in-plane shear strength.

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