scholarly journals Pyrolysis of RDF and Catalytic Decomposition of the Produced Tar in a Char Bed Secondary Reactor as an Efficient Source of Syngas

Processes ◽  
2022 ◽  
Vol 10 (1) ◽  
pp. 90
Author(s):  
Bogusław Kusz ◽  
Dariusz Kardaś ◽  
Łukasz Heda ◽  
Bartosz Trawiński

One of the technical limitations of refuse-derived fuel (RDF) pyrolysis is the high content of tar in its gas products. In order to resolve this problem, a two-stage RDF pyrolysis with a catalyst based on char from RDF pyrolysis is proposed. This paper presents the results of municipal waste pyrolysis beginning in an oven heated to 480 °C and ending with catalytic tar cracking carried out in the temperature range from 800 to 1000 °C. Thermal and catalytic pyrolysis with a char catalyst containing a minimum of 6% Fe resulted in increases in the CO and H2 contents in gas products and decreases in CO2 and CH4. At 1000 °C, the mass ratio of gaseous products to liquids was greater than 6. The residence time of the gases in the catalytic zone was about 3–5 s. The reactor was a good source of hydrogen and carbon monoxide.

2022 ◽  
Vol 227 ◽  
pp. 107129
Author(s):  
Pu Yang ◽  
Dening Jia ◽  
Bingcheng Lin ◽  
Xiuzheng Zhuang ◽  
Xiaotao Bi

Author(s):  
Samit J. Pethe ◽  
Michael L. Britt ◽  
Scott A. Morrison

Wheelabrator Technologies Inc. (WTI) operates a waste-to-energy facility in Portsmouth, Virginia. At full capacity, a total of 2,000 tons/day of refuse derived fuel (RDF) can be fired in four identical boilers to generate a total of 600,000 lb/hr of steam and 60 MW of electricity. The boilers were originally designed to co-fire RDF and coal; however, coal burning capability was removed a few years after commissioning. The plant provides all of the process/heating steam and the majority of the electrical power to the nearby Norfolk Naval Shipyard. Historically, the boilers had not been able to reliably achieve carbon monoxide (CO) emissions compliance. CO emissions experienced during normal boiler operation would be more than twice the mandated emission limit. WTI’s goal was to improve the boilers’ CO emissions performance while achieving sustained boiler operation at higher steam generation and RDF firing rates. WTI contracted Jansen Combustion and Boiler Technologies, Inc. (JANSEN) to evaluate the operation of the boilers, to assess the overall feasibility of meeting WTI’s goals, and to develop design concepts to overcome boiler limitations. The project was initiated by an engineering site visit where boiler operating data was collected and evaluated to develop a baseline of boiler operation. Current and new combustion system arrangements were evaluated with Computational Fluid Dynamics (CFD) modeling. The results confirmed that the root cause of the poor CO emissions performance was the inadequate penetration and mixing of the original overfire air (OFA) system (comprised of multiple rows of small ports on the front and rear furnace walls). CFD modeling also showed increased CO emissions to result from non-uniform RDF delivery profiles generated by the original fuel distributors that were installed at a high elevation over the grate. Modeling of the furnace with larger and fewer OFA nozzles placed on the side walls in an interlaced pattern, and the installation of “new-style” RDF distributors at a lower elevation where the boiler’s original coal distributors formerly were located was shown to significantly improve CO burnout. From December 2010 to May 2011, the new combustion systems were installed on all four boilers. Subsequent testing has shown that CO levels have been lowered by more than 70% and boiler availability has been significantly improved. Nitrogen oxides (NOx) emissions, although slightly higher following the upgrade, are still within the NOx compliance limit. This paper describes the process that led to a successful project, including: data collection and analyses, CFD modeling, equipment design and supply, operator training, and start-up assistance.


1930 ◽  
Vol 3 (3) ◽  
pp. 241-251 ◽  
Author(s):  
J. C. McLennan F.R.S. ◽  
J. V. S. Glass B.A.

This paper deals with the action of cathode rays on gases and gas mixtures. Methane, methane-oxygen mixtures, carbon monoxide and carbon monoxide-oxygen mixtures were examined. Methane gave small percentages of hydrogen and ethane. Methane and oxygen mixtures gave as gaseous products, carbon monoxide, carbon dioxide and hydrogen, the only other products being water and formic acid. The relative proportions of the products do not vary widely under a wide variation of conditions.The reaction was found to be of the first order with respect to pressure. The reaction rate increases linearly with the voltage up to a certain value, after which it becomes nearly independent of the voltage.The action of cathode rays on carbon monoxide produces carbon dioxide and a solid brown suboxide which is extremely soluble in water, and its composition corresponds to a formula (C3O)n. If the carbon monoxide is moist, no visible amount of solid or liquid is found and there is less carbon dioxide.Carbon monoxide-oxygen mixtures under the action of cathode rays form carbon dioxide. Presence of water vapor has a retarding effect on the reaction. For mixtures of the same composition the reaction rate is proportional to the total pressure. For dry mixtures the product increases with the carbon monoxide present; when moist it is much less, and independent of the carbon monoxide.


Polymers ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1682 ◽  
Author(s):  
Bin Yang ◽  
Ming Chen

Pyrolysis and gasification have gradually become the main means to dispose of automobile shredder residue (ASR), since these methods can reduce the volume and quality of landfill with lower cost and energy recovery can be conducted simultaneously. As the ASR pyrolysis process is integrated, the results of pyrolysis reactions of organic components and the interaction among polymeric components can be clarified by co-pyrolysis thermogravimetric experiments. The results show that the decomposition mechanisms of textiles and foam are markedly changed by plastic in the co-pyrolysis process, but the effect is not large for rubber and leather. This effect is mainly reflected in the pyrolysis temperature and pyrolysis rate. The pyrolytic trend and conversion curve shape of the studied ASR can be predicted by the main polymeric components with a parallel superposition model. The pyrolytic product yields and characterizations of gaseous products were analyzed in laboratory-scale non-isothermal pyrolysis experiments at finished temperatures of 500 °C, 600 °C, and 700 °C. The results prove that the yields of pyrolytic gas products are determined by the thermal decomposition of organic substances in the ASR and final temperature.


2015 ◽  
Vol 1092-1093 ◽  
pp. 907-911
Author(s):  
Ya Wei Cai ◽  
Hua Min Tang ◽  
Xin Gang Wang ◽  
Lian Yuan Wang ◽  
Hai Yan Zhu

Chlorine-based or per-oxygen-based decontaminants could be used for destruction of cyanide ion in the emergency management of leakage. During destruction, poisonous gases like ClCN and HCN were often produced. It may lead to serious damage for personal safety and quality of environment. In this study, the amount of gaseous products of ClCN and HCN during destruction of KCN by hypochlorite solutions and peroxyl acid were first measured. And quantitative risks assessments correspond to different damage criterions were established. Results showed that toxic HCN gas would form once KCN aqueous exposed to atmosphere. And different decontaminants would result in different hazardous gasses. Chlorine-based decontaminants reacted with KCN would cause toxic gas of ClCN, and it lead to relatively larger depth of damage. It would cause medial lethal depth of damage under certain conditions, such as higher concentration of decontaminant, lower flow speed, higher temperature and large volume of KCN being destructed. For per-oxygen-based decontaminants, toxic HCN gas produced would cause relatively smaller depth of damage.


2017 ◽  
Vol 467 (4) ◽  
pp. 3848-3855 ◽  
Author(s):  
M. Daprà ◽  
P. Noterdaeme ◽  
M. Vonk ◽  
M. T. Murphy ◽  
W. Ubachs

2020 ◽  
Vol 17 (5) ◽  
pp. 2386-2392
Author(s):  
Hwanseok Lee ◽  
Taewoo Kim ◽  
Dae‐Seung Cho ◽  
Sanghyeon Yoon ◽  
Hyun‐Gyoo Shin ◽  
...  

2014 ◽  
Vol 1010-1012 ◽  
pp. 952-955 ◽  
Author(s):  
Yan Meng Gong ◽  
Shu Zhong Wang ◽  
Xing Ying Tang

Co-pyrolysis of polyethylene plastic and cellulose as models for medical waste had been studied on a supercritical water batch reactor. The results show that temperature, reaction time, pressure and the mass ratio of water to organic matter have some degree impact on the conversion rate, oil yield and gasification efficiency. Conversion and gasification efficiency reached the maximum values at 440 °C. The content of H2 in the gaseous products rose significantly between 25 MPa~27 MPa. As reaction time increased, conversion and gasification efficiency increased, but oil yield decreased. The composition of gaseous products was affected greatly by the mass ratio of water to organic matter. Adding K2CO3 and Ca (OH)2 as catalyst, the reaction was promoted obviously.


The catalytic decomposition of allyl alcohol has been studied by Ipatiev, who passed the vapour through a brass tube filled with brass filings maintained at 600° C. He found hydrogen and acrolein, some propylene and carbon monoxide, with a little divinyl in the reaction products, showing that under these conditions of elevated temperature very little hydrogenation of the double bond of the unsaturated alcohol takes place. Sabatier and Senderensf used reduced copper as catalyst at temperatures varying from 180-300° C. They found that a yield of over 50 per cent, of propionaldehyde could be obtained and only a little acrolein and hydrogen. The lower temperature seems to favour the production of the saturated aldehyde. The observations of Moureu and Boismenu have shown that acrolein is very appreciably hydrogenated by copper at temperatures between 110 and 250° C. At 300° C. the destruction of the acrolein is very rapid. It is evident, therefore, that there are two reactions to be followed in the initial stages of the dehydrogenation of allyl alcohol by copper CH 2 ═ CH . CH 2 OH— ↗CH 3 . CH 2 . CHO ↘ CH 2 = CH. CHO + H 2 A detailed study was made of these two reactions to attempt to throw light on the state of the adsorbed molecules, and to consider in detail the mechanism of the two reactions and the connection between them.


Carbon ◽  
1969 ◽  
Vol 7 (1) ◽  
pp. 47-57 ◽  
Author(s):  
W.R. Ruston ◽  
M. Warzee ◽  
J. Hennaut ◽  
J. Waty

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