Sensing of Furfural by Molecularly Imprinted Polymers on Plasmonic and Electrochemical Platforms

The goal of this work is to test the possibility of selective detection of furfural (2-FAL) in aqueous solutions, with a molecularly imprinted polymer (MIP) receptor exploiting two different transduction methods, for food safety applications. In particular, sensors with electrochemical and surface plasmon resonance (SPR) transduction are considered. Two concentration ranges could be investigated by the different sensing approaches since the detectable concentration level depends on the sensitivity of the detection technique employed. The determination of 2-FAL at different concentration levels in the aqueous medium of interest, as for example beverages, is becoming a very crucial task not only for the relevance of furanic compounds in affecting the flavor but also for their possible toxic and carcinogenic effects on the human beings. For these reasons, their determination by a fast, easy and low-cost method is of interest. The sensor methods here proposed appears to be particularly suitable, since, although together and not individually, they allow the determination in a wide concentration range.

Download Full-text

Magnetic molecularly imprinted polymers–silver nanoparticle based micro-solid phase extraction for the determination of polycyclic aromatic hydrocarbons in water samples

RSC Advances ◽

10.1039/c6ra08499k ◽

2016 ◽

Vol 6 (60) ◽

pp. 54702-54708 ◽

Cited By ~ 11

Author(s):

Mostafa Khajeh ◽

Marzieh Sharifirad ◽

Mousa Bohlooli ◽

Mansour Ghaffari-Moghaddam

Keyword(s):

Silver Nanoparticle ◽

Aromatic Hydrocarbons ◽

Molecularly Imprinted Polymers ◽

Solid Phase ◽

Imprinted Polymer ◽

Molecularly Imprinted ◽

Magnetic Molecularly Imprinted Polymer ◽

Magnetic Molecularly Imprinted Polymers ◽

Polycyclic Aromatic

In this study, an efficient and sensitive magnetic molecularly imprinted polymer–silver nanoparticle (MMIPS) system was successfully synthesized.

Download Full-text

A chemiluminescence sensor for determination of lysozyme using magnetic graphene oxide multi-walled carbon nanotube surface molecularly imprinted polymers

RSC Advances ◽

10.1039/c5ra20845a ◽

2016 ◽

Vol 6 (15) ◽

pp. 12391-12397 ◽

Cited By ~ 9

Author(s):

Yanhui Wang ◽

Huimin Duan ◽

Leilei Li ◽

Xiaojiao Wang ◽

Jianbo Li ◽

...

Keyword(s):

Graphene Oxide ◽

Carbon Nanotube ◽

Molecularly Imprinted Polymers ◽

High Selectivity ◽

Imprinted Polymer ◽

Magnetic Graphene Oxide ◽

Molecularly Imprinted ◽

Magnetic Graphene ◽

Multi Walled Carbon Nanotube

In this paper, a new chemiluminescence sensor possessing high selectivity and sensitivity was established for determination of lysozyme using magnetic graphene oxide–multi-walled carbon nanotube surface molecularly imprinted polymer.

Download Full-text

Determination of sialic acid in serum samples by dispersive solid-phase extraction based on boronate-affinity magnetic hollow molecularly imprinted polymer sorbent

RSC Advances ◽

10.1039/c9ra00511k ◽

2019 ◽

Vol 9 (10) ◽

pp. 5394-5401 ◽

Cited By ~ 7

Author(s):

Wei Huang ◽

Xingyu Hou ◽

Yukui Tong ◽

Miaomiao Tian

Keyword(s):

Sialic Acid ◽

Molecularly Imprinted Polymers ◽

Solid Phase ◽

Phase Extraction ◽

Dispersive Solid Phase Extraction ◽

Imprinted Polymer ◽

Serum Samples ◽

Molecularly Imprinted ◽

Imprinted Polymers

Boronate-affinity magnetic hollow molecularly imprinted polymers were prepared with sialic acid (SA) as a template to selectively extract SA from serum samples coupled with HPLC-UV.

Download Full-text

Application of hollow porous molecularly imprinted polymers using K2Ti4O9 coupled with SPE-HPLC for the determination of celecoxib in human urine samples: optimization by central composite design (CCD)

Analytical Methods ◽

10.1039/c7ay00547d ◽

2017 ◽

Vol 9 (21) ◽

pp. 3200-3212 ◽

Cited By ~ 13

Author(s):

S. Ansari

Keyword(s):

Molecularly Imprinted Polymers ◽

High Performance ◽

Solid Phase ◽

Trace Determination ◽

Phase Extraction ◽

Imprinted Polymer ◽

Molecularly Imprinted ◽

Imprinted Polymers ◽

Central Composite

Trace determination of celecoxib by hollow porous molecularly imprinted polymer and solid-phase extraction (HPMIP-SPE) coupled with high-performance liquid chromatography with UV detection (HPLC/UV).

Download Full-text

Preparation of nicotine surface molecularly imprinted polymers for selective solid-phase extraction of nicotine from zero-level refill liquids of electronic cigarettes

Analytical Methods ◽

10.1039/c8ay00616d ◽

2018 ◽

Vol 10 (29) ◽

pp. 3637-3644 ◽

Cited By ~ 9

Author(s):

Juanjuan Xie ◽

Bo Zhou ◽

Tiandong Zhang ◽

Xiaoying Zeng ◽

Mochou Yang ◽

...

Keyword(s):

Solid Phase Extraction ◽

Molecularly Imprinted Polymers ◽

Solid Phase ◽

Electronic Cigarettes ◽

Phase Extraction ◽

Imprinted Polymer ◽

Molecularly Imprinted ◽

Imprinted Polymers ◽

Zero Level

Preparation of surface molecularly imprinted polymer for the determination of nicotine in the zero-level refill liquids of electronic cigarettes.

Download Full-text

ANALYSIS OF SULFACHLOROPYRIDAZINE AND SULFAPYRIDINE BY HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY WITH MOLECULARLY IMPRINTED POLYMER AS THE STATIONARY PHASE

Biomedical Engineering Applications Basis and Communications ◽

10.4015/s1016237209001647 ◽

2009 ◽

Vol 21 (06) ◽

pp. 457-460 ◽

Cited By ~ 2

Author(s):

Tzu-Tai Lee ◽

Ing-Bang Huang ◽

Ching-Chiang Hwang

Keyword(s):

Stationary Phase ◽

Molecularly Imprinted Polymers ◽

High Performance ◽

High Performance Liquid Chromatographic ◽

Imprinted Polymer ◽

Molecularly Imprinted ◽

Liquid Chromatographic Method ◽

Separation Factors ◽

Liquid Chromatographic

A simple and sensitive high performance liquid chromatographic method for simultaneous determination of sulfachloropyridazine and sulfapyridine has been developed. This method was developed by using self-prepared molecularly imprinted polymers (MIPs) as the stationary phase. The polymers were prepared by a noncovalent method with sulfachloropyridazine as the template, methacrylic acid as the functional monomer and ethylene glycoldimethacrylate as the cross-linker in the presence of chloroform as the solvent. In order to compare the chromatographic data from the stationary phase, the retention time of sulfachloropyridazine and sulfapyridine was given. The separation factors (α) were 1.79–1.89 that showed that the MIPs were able to recognize sulfachloropyridazine and sulfapyridine.

Download Full-text

A fluorescent molecularly imprinted polymer sensor synthesized by atom transfer radical precipitation polymerization for determination of ultra trace fenvalerate in the environment

RSC Advances ◽

10.1039/c6ra11632a ◽

2016 ◽

Vol 6 (84) ◽

pp. 81346-81353 ◽

Cited By ~ 10

Author(s):

Wenjuan Han ◽

Lin Gao ◽

Xiuying Li ◽

Liang Wang ◽

Yongsheng Yan ◽

...

Keyword(s):

Molecularly Imprinted Polymer ◽

Molecularly Imprinted Polymers ◽

Optical Detection ◽

Precipitation Polymerization ◽

Atom Transfer ◽

Imprinted Polymer ◽

Molecularly Imprinted ◽

Imprinted Polymers ◽

Ultra Trace

In this study, novel fluorescence molecularly imprinted polymers (FMIPs) were prepared via atom transfer radical precipitation polymerization (ATRPP) for the optical detection of trace fenvalerate (FE).

Download Full-text

Selective Determination of Metformin in Urine Sample Based on Molecularly Imprinted Polymer-Chemiluminescence Sensor

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.550-553.798 ◽

2012 ◽

Vol 550-553 ◽

pp. 798-801

Author(s):

Yan Xiong ◽

Ying Huang ◽

Zhong Bin Ye ◽

Chen Chen ◽

Zhu Jun Zhang

Keyword(s):

Molecularly Imprinted Polymers ◽

Limit Of Detection ◽

Imprinted Polymer ◽

Molecularly Imprinted ◽

Selective Determination ◽

Metformin Concentration ◽

On Line ◽

Flow Injection Chemiluminescence ◽

Excellent Stability

A flow-injection chemiluminescence (FI-CL) sensor for metformin determination based on recognition materials of molecularly imprinted polymers (MIP) is reported. The sensor was fabricated by packing the MIP particles into a V-shape flow cell. Metformin could be selectively on-line adsorbed by the MIPs and then sensed by its great enhancing effect on the weak CL reaction between N-bromosuccinimide (NBS) and fluorescein. The CL intensity was linear to metformin concentration in the range from 2×10−8 to 8×10−6 g•mL−1 and the limit of detection (L.O.D.) was 6×10−9 g•mL−1 (3σ). The sensor showed high selectivity, improved sensitivity and excellent stability and reversibility compared with the CL method without using MIPs. The lifetime of the sensor was investigated and MIPs could be reused for more than 200 times. The sensor has been directly applied to determine metformin in human urine.

Download Full-text

Single Drop Detection of Furfural in Wine by an SPR-Optical Fiber-MIP Based Sensor

Proceedings ◽

10.3390/iecb2020-07028 ◽

2020 ◽

Vol 60 (1) ◽

pp. 22

Author(s):

Maria Pesavento ◽

Nunzio Cennamo ◽

Luigi Zeni ◽

Letizia De Maria ◽

Giancarla Alberti ◽

...

Keyword(s):

Optical Fiber ◽

Food Samples ◽

Human Beings ◽

Single Drop ◽

Imprinted Polymer ◽

Practical Applications ◽

Carcinogenic Effects ◽

The One ◽

Mip Sensor

A surface plasmon resonance (SPR) platform, based on a D-shaped plastic optical fiber (POF), combined with a biomimetic receptor, i.e., a molecularly imprinted polymer (MIP), is proposed to detect 2-furaldheide (2-FAL) in fermented beverages such as wine. The determination of 2-FAL in food samples is becoming a very crucial task, on the one hand for its role in the flavor and on the other in relation to its toxic and carcinogenic effects on human beings. The proposed sensing device is easy to use and cheap; it has been tested successfully for the detection and quantification of substances of interest in different fields, such as health, the environment and industry. The possibility of performing single-drop measurements is a further favorable aspect for practical applications. As an example, the use of an SPR-MIP sensor for the analysis of 2-FAL in wine, in a concentration range useful for practical applications, is here described.

Download Full-text