scholarly journals The Stabilization of Waste Funnel Glass of CRT by SiO2 Film Coating Technique

2021 ◽  
Vol 13 (16) ◽  
pp. 9096
Author(s):  
Jyh-Herng Chen ◽  
Yu-Hao Chang ◽  
Chaochin Su ◽  
Kai-Chung Hsu

The funnel glass of the CRT monitor contains about 22–28% of lead oxide, of which lead is a highly toxic species and hazardous to the environment. This study proposes a process to form a protective layer of SiO2 film coating on the funnel glass to reduce the hazardous effect of lead leaching to the environment. The film coating benefits from the advantages of the sol–gel method. There are two key procedures of the stabilization technique, including the alkaline treatment and the formation of SiO2 coating from TEOS. The results show that the funnel glass powder treated with 10 M NaOH can produce a mushy layer on the surface. The mushy layer, which comprises OH− and water, can promote the formation of the SiO2 film layer on the surface of funnel glass powder. The conditions of the SiO2 film coating proposed in this study are: alkaline treatment by 10 M NaOH, the addition ratio of TEOS and funnel glass powder 2: 1, reaction temperature 40 °C, and reaction time 1.3 h. The EDS and ESCA results show that the Pb peak intensity on the surface of funnel glass decreases with the film coating. In the TCLP test, the leaching amount for Pb of the SiO2 film coated funnel glass powders is 0.7 mg/L, which is far lower than the standard in Taiwan EPA. Based on the experimental results, the formation mechanism of the SiO2 film layer on the surface of waste funnel glass powder is proposed. This study demonstrates that the SiO2 film coating is a potentially effective method to solve the problem of the waste funnel glass.

2011 ◽  
Vol 287-290 ◽  
pp. 2199-2202
Author(s):  
Gui Qin Hou ◽  
Wen Li Zhang ◽  
Shui Jing Gao ◽  
Xiao Yan Wang

The ZnFe2O4 and TiO2 nanocomposite films was prepared by Sol-Gel method on conductive glass, and the influence factors of it’s photoelectrocatalytic performence such as the film layer, pole and voltage was investigated. The results indicated that: the photocatalytic effects of composite films with ZnFe2O4+ TiO2+ ZnFe2O4 was the best. The decomposing ratio of methyl orange with the photoelectrocatalysis of composite films at voltage 0.2-6V all increased unstably.At the same time, the distance from films to pole plank also had the effects on the photocatalytic activities of the films.


2016 ◽  
Author(s):  
S. A. Syed Nuzul Fadzli ◽  
S. Roslinda ◽  
Firuz Zainuddin ◽  
Hamisah Ismail

2016 ◽  
Vol 852 ◽  
pp. 939-942 ◽  
Author(s):  
Xiu Xia Zhang ◽  
Jun Xia Wen ◽  
Rong Fan ◽  
Dao Jie Jiang ◽  
Xiu Li Lou ◽  
...  

nanoDiamond was mixed with ethylic cellulose and other Material to form to paste. A series of sol-gel nanoDiamond film with different proportions were designed test intentionally. nanoDiamond film was fabricated on Aluminum substrates using two-steps sintering process. The moving terminal of the variable super-capacitor was the shaft which throughout each of monolithic capacitor plate. The low melting point glass powder possesses giant permittivity, low dielectric loss, good thermal stability and dielectric constant in a wide temperature range which applied very broad prospects in microelectronics. The low melting point glass powder was mixed with carboxymethyl cellulose and deionized water to paste. The low melting point glass powder insulation thick-film was fixed on nanoDiamond film .In this paper, the insulation thick-film preparation: sintering at 578K to 588K and keeping 11.5 h to 12.5 h. A variable super-capacitor was designed based on nanoDiamond film electrode and low melting point glass powder insulation thick. Insulation thickness was prepared on uniform nanodiamond film to increase insulation super-capacitor between the two plates.


Author(s):  
Kausturi Chatterjee ◽  
Soma Ray ◽  
Baishakhi Pal ◽  
Kalyan Adhikary ◽  
Utpal Gangopadhyay ◽  
...  

2008 ◽  
Vol 8 (2) ◽  
pp. 878-886 ◽  
Author(s):  
Beril K. Erdural ◽  
Alp Yurum ◽  
Ufuk Bakir ◽  
Gurkan Karakas

Nanostructured titania particles were synthesized by using hydrothermal processing and the photocatalytic antimicrobial activities were characterized. Both sol–gel synthesized and commercial TiO2 (anatase) samples were processed with two step hydrothermal treatments, under alkaline and neutral conditions. Scanning Electron Microscope (SEM) images showed that alkaline treatment yields nanofibers and lamellar structured particles from the commercial anatase and sol–gel synthesized samples respectively. Further treatment of nanofibers and nanostructured lamellar particles with distilled water results with crystal growth and the formation of nano structured bipyramidal crystalline particles. The photocatalytic antimicrobial activities of the samples were determined against Escherichia coli under irradiation. It was observed that the samples treated under alkaline conditions have improved activity than the original anatase samples. Limited activity and resulting time lag in bacterial inactivation were observed for hydrothermally treated samples with distilled water. However, a post treatment comprising the UV irradiation in aqueous conditions enhanced the photocatalytic activity.


1988 ◽  
Vol 121 ◽  
Author(s):  
Scott Reed ◽  
Carol Ashley

ABSTRACTFront-surface metal mirrors were coated with a variety of sol-gel derived glass films for preliminary evaluation as protective coatings for silver. Optical measurements (hemispherical, diffuse and specular reflectance) were used to characterize changes in the mirror resulting from the application of the sol, subsequent processing, or environmental testing. The abrasion resistance of the films was determined on sol-gel coated silicon wafers per ASTM procedures. The mirrors were exposed to outdoor environments in Albuquerque, N.M., as well as accelerated testing in H2SO4, with periodic monitoring of optical properties. A two layer coating scheme, consisting of a thin primary protective layer of sputter deposited SiO2 followed by a thicker sol-gel overcoat, was also evaluated.


2010 ◽  
Vol 92 ◽  
pp. 131-137 ◽  
Author(s):  
Qiu Hua Yuan ◽  
Pei Xin Zhang ◽  
Li Gao ◽  
Hai Lin Peng ◽  
Xiang Zhong Ren ◽  
...  

The crystallization behavior of MgO-Al2O3-SiO2 glass-ceramics by sol-gel technology was investigated by using x-ray diffraction (XRD), differential thermal analysis (DTA), Scanning electron microscopy (SEM). The results showed that: (1)α-cordierite phase was precipitated when the green body was calcined at 1050°C, and α-cordierite of high purity and stability could be formed at 1100°C; (2) Adding an appropriate amount of low melting point glass powder into the green body may provide liquid-phase environment during the sintering process, which will help enhance the tightness density of glass-ceramic, and thus improve its flexural strength.


2018 ◽  
Vol 9 (4) ◽  
pp. 777-782 ◽  
Author(s):  
Rupeshkumar V. Ramani ◽  
Bharat M. Ramani ◽  
Anjana D. Saparia ◽  
Chirag Savaliya ◽  
K.N. Rathod ◽  
...  

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