scholarly journals Chemical, Thermal, and Rheological Performance of Asphalt Binder Containing Plastic Waste

2021 ◽  
Vol 13 (24) ◽  
pp. 13887
Author(s):  
Rosa Veropalumbo ◽  
Francesca Russo ◽  
Cristina Oreto ◽  
Giovanna Giuliana Buonocore ◽  
Letizia Verdolotti ◽  
...  
Keyword(s):  
Mechanical Performance ◽  
Asphalt Binder ◽  
Thermo Gravimetric Analysis ◽  
Asphalt Mixture ◽  
Viscoelastic Behavior ◽  
Road Construction ◽  
Plastic Waste ◽  
Gravimetric Analysis ◽  
Modified Bitumen ◽  
Scanning Calorimetry

In order to meet the environmental needs caused by large plastic waste accumulation, in the road construction sector, an effort is being made to integrate plastic waste with the function of polymer into asphalt mixtures; with the purpose of improving the mechanical performance of the pavement layers. This study focuses on the effect of a recycled mixture of plastic waste on the chemical, thermal, and rheological properties of designed asphalt blends and on the identification of the most suitable composition blend to be proposed for making asphalt mixture through a dry modification method. Thermo-gravimetric analysis, differential scanning calorimetry, and Fourier transform infrared spectroscopy analysis were carried out to investigate the effect of various concentrations and dimensions of plastic waste (PW) on the neat binder (NB). The frequency sweep test and the multiple stress creep and recovery test were performed to analyze the viscoelastic behavior of the asphalt blends made up of PW in comparison with NB and a commercial modified bitumen (MB). It has been observed that the presence of various types of plastic materials having different melting temperatures does not allow a total melting of PW powder at the mixing temperatures. However, the addition of PW in the asphalt blend significantly improved the aging resistance without affecting the oxidation process of the plastic compound present in the asphalt blend. Furthermore, when the asphalt blend mixed with 20% PW by the weight of bitumen is adopted into the asphalt mixture as polymer, it improves the elasticity and strengthens the mixture better than the mixture containing MB.

Optimization of Curing Conditions and Nanofiller Incorporation for Production of High Performance Laminated Kevlar/Epoxy Nanocomposites

2018 ◽  
Author(s):  
Abdel-Hamid I. Mourad ◽  
Mouza S. Al Mansoori ◽  
Lamia A. Al Marzooqi ◽  
Farah A. Genena ◽  
Nizamudeen Cherupurakal
Keyword(s):  
Oil And Gas ◽  
Mechanical Performance ◽  
Thermo Gravimetric Analysis ◽  
Applied Pressure ◽  
Curing Temperature ◽  
Gravimetric Analysis ◽  
Epoxy Nanocomposites ◽  
Scanning Calorimetry ◽  
Curing Conditions ◽  
Weight Percentage

Kevlar composite materials are getting scientific interest in repairing of oil and gas pipelines in both offshore and onshore due to their unique properties. Curing is one of the major factor in deciding the final mechanical performance of laminated Kevlar/epoxy nanocomposites. The parameters such as curing time, temperature and applied pressure during the hot pressing will affect chemistry of crosslinking of the epoxy matrix and interaction of epoxy with the Kevlar fiber. The present study is carried out to evaluate the optimal curing conditions of the Kevlar/epoxy nanocomposites. Three different nanofillers (namely Multi walled Carbon nanotubes (MWCNT), Silicon Carbide (SiC) and Aluminum Oxide (Al2O3)) are incorporated in different weight percentage. Differential Scanning Calorimetry (DSC) and Thermo-Gravimetric Analysis (TGA) tests are carried out to determine the thermal stability and optimal curing conditions. Mechanical performance is investigated by conducting flexure, and drop weight tests. The results show that, the optimal curing temperature for maximizing the mechanical properties is at 170°C. Peeling off the Kevlar layers are observed for nanocomposite samples cured under 100°C. Mechanical strength of the composites is enhanced by optimizing the curing conditions and nanofiller contents.

scholarly journals Feasibility of Utilizing Waste Polyethylene Terephthalate as Replacement in Asphalt binder Mixture

2021 ◽  
Vol 2 (1) ◽  
pp. 47-57 ◽  
Author(s):  
Bashir.A Almahdi ◽  
Abobaker G. F. Ahmeda ◽  
Ibrahim Adwan ◽  
Mohd Azizul Ladin
Keyword(s):  
Polyethylene Terephthalate ◽  
Mechanical Performance ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Road Construction ◽  
Waste Material ◽  
Partial Replacement ◽  
Modified Bitumen ◽  
Bitumen Content ◽  
Waste Polyethylene

The feasibility of utilizing waste material for road construction is encouraging as it can decrease waste material harmful to the environment. Hence, a more sustainable method and a meticulous study of the available admixtures utilized to substitute standard asphalt binders with waste material must be conducted. However, there are several concerns and doubts about the real situation arising from the chemical and physical traits, as well as the mechanical performance issuing from the integration of waste material within the asphalt pavement to alleviate roads surface's permanent deformation. This investigation was carried out to study physical improvements made on ACW-14 bitumen by adding waste Polyethylene Terephthalate (PET) to serve as a partial replacement for bitumen content compared to normal, conventional 80/100 bitumen physical and rheological behavior. PET percentage added to the bitumen content was 10%, 8%, 6%, 4% and 2% of optimum bitumen content weight. The outcomes concluded that the best performance of bitumen on its density, VTM, VFB, flow, stability, and stiffness was achieved when 5.8% of Optimum Modified-Bitumen Content using PET. All the results obtained have been compared according to JKR Standards results, and the conclusion has fulfilled these requirements.

scholarly journals Biocomposites of Bio-Polyethylene Reinforced with a Hydrothermal-Alkaline Sugarcane Bagasse Pulp and Coupled with a Bio-Based Compatibilizer

Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2158
Author(s):  
Nanci Vanesa Ehman ◽  
Diana Ita-Nagy ◽  
Fernando Esteban Felissia ◽  
María Evangelina Vallejos ◽  
Isabel Quispe ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Water Absorption ◽  
Sugarcane Bagasse ◽  
Thermo Gravimetric Analysis ◽  
Decomposition Temperature ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Cradle To Gate ◽  
Bagasse Pulp

Bio-polyethylene (BioPE, derived from sugarcane), sugarcane bagasse pulp, and two compatibilizers (fossil and bio-based), were used to manufacture biocomposite filaments for 3D printing. Biocomposite filaments were manufactured and characterized in detail, including measurement of water absorption, mechanical properties, thermal stability and decomposition temperature (thermo-gravimetric analysis (TGA)). Differential scanning calorimetry (DSC) was performed to measure the glass transition temperature (Tg). Scanning electron microscopy (SEM) was applied to assess the fracture area of the filaments after mechanical testing. Increases of up to 10% in water absorption were measured for the samples with 40 wt% fibers and the fossil compatibilizer. The mechanical properties were improved by increasing the fraction of bagasse fibers from 0% to 20% and 40%. The suitability of the biocomposite filaments was tested for 3D printing, and some shapes were printed as demonstrators. Importantly, in a cradle-to-gate life cycle analysis of the biocomposites, we demonstrated that replacing fossil compatibilizer with a bio-based compatibilizer contributes to a reduction in CO2-eq emissions, and an increase in CO2 capture, achieving a CO2-eq storage of 2.12 kg CO2 eq/kg for the biocomposite containing 40% bagasse fibers and 6% bio-based compatibilizer.

scholarly journals MECHANICAL PERFORMANCE OF ASPHALT MIXTURE CONTAINING CUP LUMP RUBBER

2019 ◽  
Vol 81 (6) ◽  
Author(s):  
Norfazira Mohd Azahar ◽  
Norhidayah Abdul Hassan ◽  
Ramadhansyah Putra Jaya ◽  
Hasanan Md. Nor ◽  
Mohd Khairul Idham Mohd Satar ◽  
...  
Keyword(s):  
Mechanical Performance ◽  
Resilient Modulus ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Mixture ◽  
Modified Asphalt ◽  
Dynamic Creep ◽  
Aging Conditions ◽  
Public Work Department ◽  
Indirect Tensile

The use of cup lump rubber as an additive in asphalt binder has recently become the main interest of the paving industry. The innovation helps to increase the natural rubber consumption and stabilize the rubber price. This study evaluates the mechanical performance of cup lump rubber modified asphalt (CMA) mixture in terms of resilient modulus, dynamic creep and indirect tensile strength under aging conditions. The CMA mixture was prepared using dense-graded Marshall-designed mix and the observed behavior was compared with that of conventional mixture. From the results, both mixtures passed the volumetric properties as accordance to Malaysian Public Work Department (PWD) specification. The addition of cup lump rubber provides better resistance against permanent deformation through the enhanced properties of resilient modulus and dynamic creep. Furthermore, the resilient modulus of CMA mixture performed better under aging conditions.  

Synthesis, characterization and corrosion protection properties of polyN-(p-bromophenyl)-2-methacrylamide-co-glycidyl methacrylate on low nickel stainless steel

2011 ◽  
Vol 31 (2-3) ◽  
Author(s):  
Sakvai Mohammed Safiullah ◽  
Deivasigamani Thirumoolan ◽  
Kottur Anver Basha ◽  
K. Mani Govindaraju ◽  
Dhanraj Gopi ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Corrosion Protection ◽  
Glycidyl Methacrylate ◽  
Electrochemical Impedance ◽  
Thermo Gravimetric Analysis ◽  
Gel Permeation Chromatography ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Protection Efficiency ◽  
Ft Ir

Abstract The synthesis of copolymers from different feed ratios of N-(p-bromophenyl)-2- methacrylamide (PBPMA) and glycidyl methacrylate (GMA) was achieved by using free radical solution polymerization technique and characterized using FT-IR, 1H and 13C NMR spectroscopy. The thermal stability of the synthesized copolymers was studied using thermo-gravimetric analysis (TGA) and differential scanning calorimetry (DSC). The molecular weight of the copolymer is determined by gel permeation chromatography (GPC). The corrosion performances of low nickel stainless steel specimens dip coated with different composition of copolymers were investigated in 0.5 M H2SO4 using potentiodynamic polarization and electrochemical impedance spectroscopic (EIS) techniques. The polarization and impedance measurements showed different corrosion protection efficiency with change in composition of the copolymers. It was found that the corrosion protection properties are owing to the barrier effect of the polymer layer covered on the low nickel stainless steel surfaces. However, it is observed that the mole ratio of PBPMA and GMA plays a major role in the protective nature of the copolymer.

Graphene Nanoplates Filled Nylon 6,6 Nanocomposites, Morphological, Thermal, Mechanical and Solvent Uptake Study

2019 ◽  
Vol 41 (3) ◽  
pp. 388-388
Author(s):  
Khalid Saeed Khalid Saeed ◽  
Tariq Shah and Ahmad Hassan Tariq Shah and Ahmad Hassan
Keyword(s):  
Thermo Gravimetric Analysis ◽  
Neutral Red ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Nucleation Effect ◽  
Morphological Studies ◽  
Solvent Uptake ◽  
Nylon 6,6 ◽  
Dsc Analyses ◽  
Graphene Nanoplates

Effect of graphene nanoplates (GNPs) on the properties of Nylon 6,6 (Nyl 6,6) is investigated in present study. The morphological studies presented that the GNPs were dispersed inside the Nyl 6,6 matrix. The thermo gravimetric analysis (TGA) illustrated that the thermal degradation of nanocomposites samples were started at the range of 350-393 oC, which was appreciably higher than neat Nyl 6,6 (360 oC). The differential scanning calorimetry (DSC) analyses revealed that the crystallization temperature (Tc) of GNPs/Nyl 6,6 increased as increased the addition of GNPs, which might be due to the nucleation effect of GNPs. The mechanical properties of Nyl 6,6 was enhanced by incorporation of GNPs upto the addition of an optimal quantity of filler (5%wt GNPs) into the polymer matrix. The stress yield and Young’s modulus of 5%wt GNPs/Nyl 6,6 was 96.79 and 1.54, N/nm2, respectively. Both Nyl 6,6 and nanocomposites samples were also used for the adsorption of Neutral red chloride (NRC) dye, which significantly remove the dye from the aqueous solution. The neat nylon 6,6 and GNPs (5 and 10 wt%)/Nyl 6,6 adsorbed about 88.49, 93.15, and 93.60% within 2 h, respectively.

Characterization of Novel Solid Dispersions of Moringa oleifera Leaf Powder Using Thermo-Analytical Techniques

Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2230
Author(s):  
Nontsikelelo Noxolo Tafu ◽  
Victoria A. Jideani
Keyword(s):  
Solid Dispersion ◽  
Moringa Oleifera ◽  
Solid Dispersions ◽  
Intermolecular Hydrogen Bond ◽  
Thermo Gravimetric Analysis ◽  
Analytical Techniques ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Hydrogen Bond Interactions ◽  
Leaf Powder

Moringa oleifera leaf powder (MOLP) has been identified as the most important functional ingredient owing to its rich nutritional profile and healthy effects. The solubility and functional properties of this ingredient can be enhanced through solid dispersion technology. This study aimed to investigate the effects of polyethylene glycols (PEGs) 4000 and 6000 as hydrophilic carriers and solid dispersion techniques (freeze-drying, melting, solvent evaporation, and microwave irradiation) on the crystallinity and thermal stability of solid-dispersed Moringa oleifera leaf powders (SDMOLPs). SDMOLPs were dully characterized using powder X-ray diffraction (PXRD), differential scanning calorimetry (DSC), thermo-gravimetric analysis (TGA), and Fourier transform infrared spectroscopy (FTIR). The PXRD results revealed that the solid dispersions were partially amorphous with strong diffraction peaks at 2θ values of 19° and 23°. The calorimetric and thermogravimetric curves showed that PEGs conferred greater stability on the dispersions. The FTIR studyrevealed the existence of strong intermolecular hydrogen bond interactions between MOLP and PEG functional groups. MOLP solid dispersions may be useful in functional foods and beverages and nutraceutical formulations.

Decellularized liver-regenerative 3D printing biomaterials for cell-based liver therapies via a designed procedure combined with papain-containing reagent treatments and supercritical fluids

2021 ◽  
pp. 1-8
Author(s):  
Ching-Cheng Huang
Keyword(s):  
3D Printing ◽  
Thermo Gravimetric Analysis ◽  
Extraction Process ◽  
Gravimetric Analysis ◽  
Collagen Scaffolds ◽  
Scanning Calorimetry ◽  
Porcine Liver ◽  
Good Thermal Stability ◽  
Decellularized Liver ◽  
Liver Collagen

BACKGROUND: The biologic scaffolds derived from decellularized tissues and organs have been successfully developed in a variety of preclinical and/or clinical studies. OBJECTIVE: The new decellularized liver-regenerative 3D printing biomaterials were designed and prepared for cell-based liver therapies. METHODS: An extraction process was employed to remove the tissue and cellular molecules from porcine liver via pretreatment of supercritical fluid of carbon dioxide (ScCO2). Varying porosities of the decellularized liver tissues were created using papain-containing reagent treatments after ScCO2. RESULTS: The resulting liver-regenerative 3D printing biomaterials of decellularized liver collagen scaffolds were characterized by Fourier transform infrared spectroscopy, thermo-gravimetric analysis, differential scanning calorimetry and scanning electron microscopy. CONCLUSIONS: The decellularized liver collagen scaffolds with good thermal stability (>150 °C) were obtained and employed as liver-regenerative 3D printing biomaterials for cell-based liver therapies.

The Influence of Nickel Oxide Nanoparticle Dispersion on the Thermo Stability of Lubricant Oil

2019 ◽  
Vol 19 (01) ◽  
pp. 1850044
Author(s):  
K. Ramachandran ◽  
P. Navaneethakrishnan ◽  
M. Sivaraja
Keyword(s):  
Thermo Gravimetric Analysis ◽  
Gravimetric Analysis ◽  
Nanoparticle Dispersion ◽  
Nio Nanoparticles ◽  
Scanning Calorimetry ◽  
Lubricant Oil ◽  
Nickel Oxide Nanoparticle ◽  
Nanoparticles Dispersion ◽  
Thermo Stability

The homogeneous and substantial dispersion of nanoparticles into base fluids is vital since the final properties of any nanolubricant are estimated by their quality of stability. This paper addresses the effect of NiO nanoparticles dispersion into SN500 lubricant oil and its nonisothermal thermo stability. The dispersion of NiO nanoparticles is achieved by ultrasonication method. The thermo stability is estimated by Thermo Gravimetric Analysis (TGA), Differential Thermal Analysis (DTA) and Differential Scanning Calorimetry (DSC). The result shows that the thermo stability of base fluid enhances up to 0.3[Formula: see text]wt.% particle concentration then it decreases due to agglomeration of dispersed nanoparticles. The findings recommend that 0.1[Formula: see text]wt.% and 0.3[Formula: see text]wt.% of NiO-nanolubricant can be used for the temperature-dependent applications up to 200∘C.

scholarly journals Assessments on the Performance of Asphalt Mixtures Prepared with Adhesion Promoters

2019 ◽  
Vol 8 (3S3) ◽  
pp. 332-339
Keyword(s):  
Mechanical Performance ◽  
Water Immersion ◽  
Asphalt Binder ◽  
Asphalt Mixture ◽  
Asphalt Mixtures ◽  
Adhesion Promoters ◽  
Modified Asphalt ◽  
Service Characteristics ◽  
Bonding Properties ◽  
Mechanical Performances

Asphalt pavement is typically susceptible to moisture damage. However, it could be improved with the incorporation of additives or modifiers through binder modifications. The objective of the study is to assess the effect of adhesion promoters, namely PBL and M5000, onto the Hot Mix Asphalt (HMA). The performance of asphalt mixture has been assessed in terms of the service characteristics, the bonding properties, and mechanical performances. The service characteristics were assessed through the Workability Index (WI) and Compaction Energy Index (CEI) to evaluate the ease of asphalt mixture during the mixing and compaction stage. The bonding properties of the modified asphalt mixtures were determined using the boiling water test and static water immersion test to signify the degree of coating after undergoing specific conditioning period and temperature. The mechanical performances of the modified asphalt mixture were evaluated via Marshall stability, semi-circular bending, and modified Lottman tests. All specimens were prepared by incorporating adhesion promoters at the dosage rates of 0.5% and 1.0% by weight of asphalt binder. From the investigation, the bonding properties significantly improved for the modified asphalt mixture compared to the control mixture. The WI of the modified asphalt mixture increased while the CEI decreased in comparison to the control specimen. This implies the workability of modified asphalt mixture is better and requires less energy to be compacted. Modified asphalt mixture generally had better mechanical performance. Therefore, it can be deduced that the asphalt mixture with adhesion promoters have better overall performance than the control mixture.

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