scholarly journals ALKYLATION OF 2-AMINOADAMANTANE WITH ALKANOLS USING CATALYSIS BY COLLOIDAL NICKEL PARTICLES

2021 ◽  
pp. 53-56
Author(s):  
V. M. Mokhov ◽  
Yu. V. Popov ◽  
S. E. Latyshova ◽  
N. A. Tankabekyan ◽  
E. N. Zhoglo
Keyword(s):  
Nickel Nanoparticles ◽  
Secondary Amines ◽  
Homogenous Catalysis ◽  
Nickel Particles

The alkylation of 2-aminoadamantane with alkanols catalysed by quasi-homogenous catalysis by nickel nanoparticles proceeds at 140-160 ºС with foundation of secondary amines with 57-78 % yields.

RF Plasma Synthesis of Nickel Nanoparticles from Liquid Precursor

2011 ◽  
Vol 412 ◽  
pp. 231-234 ◽  
Author(s):  
Liu Yang Bai ◽  
Fang Li Yuan ◽  
Hai Bao Zhang ◽  
Jin Lin Li
Keyword(s):  
Nickel Nanoparticles ◽  
Average Diameter ◽  
Metallic Nickel ◽  
Rf Plasma ◽  
Plasma Synthesis ◽  
Liquid Precursor ◽  
Nickel Particles ◽  
Conductive Film ◽  
Tap Density ◽  
Xrd Patterns

Nickel nanoparticles were synthesized from liquid precursor via H-plasma reduction route. XRD patterns revealed that pure metallic nickel powders could be obtained when nickel ammine complex aqueous solution was used as precursor. FESEM showed that the products are composed of well-dispersed nanospheres with an average diameter less than 100 nm. The tap density is about 3.85g/cm3, and the sheet resistance of the conductive film prepared using the nickel particles is about 58mΩ.

Uniformly distributed nickel nanoparticles created by heating the carbon nanotube

2003 ◽  
Vol 18 (3) ◽  
pp. 604-608 ◽  
Author(s):  
Zaoli Zhang ◽  
Min Gao
Keyword(s):  
Electron Diffraction ◽  
Nickel Nanoparticles ◽  
Arc Discharge ◽  
Energy Dispersive Spectrometer ◽  
Scanning Transmission Electron Microscope ◽  
Face Centered Cubic ◽  
Transmission Electron ◽  
Nickel Particles ◽  
Scanning Transmission ◽  
Face Centered

Uniformly distributed nanoparticles created by heating carbon nanotubes synthesized by arc-discharge were studied by electron diffraction, high-resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), and x-ray energy dispersive spectrometer (EDS). The nanoparticles have diameters in the range of 3–15 nm. Electron diffraction pattern and HRTEM images analysis both show that the nanoparticles can be nickel or diamond. EELS and EDS analysis in a dedicated scanning transmission electron microscope showed that the nanoparticles are face-centered-cubic nickel particles rather than diamond nanocrystals. The mechanism of formation of nickel nanoparticles below its melting point is discussed.

Synthesis of Nickel Nanoparticles/Multiwalled Carbon Nanotubes Composites with Pre-Treated Multiwalled Carbon Nanotubes as Modifier

2013 ◽  
Vol 760-762 ◽  
pp. 789-792
Author(s):  
Qiao Feng Guo ◽  
Tan Wang ◽  
Chun Hua Han ◽  
Dong Yu Zhao
Keyword(s):  
Carbon Nanotubes ◽  
Multiwalled Carbon Nanotubes ◽  
Nickel Nanoparticles ◽  
Test Results ◽  
Multiwalled Carbon ◽  
Uniform Size ◽  
Reducing Gas ◽  
Nickel Particles ◽  
Cyclic Voltammetry Test ◽  
Average Size

A simple synthetic route to create Nickel nanoparticles/MWCNT composites (NiNPs/MWNTs) is reported. The process is concise, no additional surfactant or other reducing gas was employed. TEM, SEM, XRD and EDX were used to examine the morphology of the nickel particles. In this experiment, the hydrothermal method using ethylene glycol as a solvent has been well dispersed, uniform size and smaller particle size of the nickel nanoparticles with average size about 50 nm. By cyclic voltammetry test results show that with good electrical properties, Ni / MCNTs.

Effect of Reaction Temperature on the Morphology of Carbon Nanofibers

2011 ◽  
Vol 306-307 ◽  
pp. 1247-1251
Author(s):  
Li Yan Yu ◽  
Li Na Sui ◽  
Hong Zhou Dong ◽  
Li Feng Dong
Keyword(s):  
Carbon Nanofibers ◽  
Nickel Catalyst ◽  
Carbon Fibers ◽  
Low Temperatures ◽  
Critical Parameter ◽  
Catalytic Pyrolysis ◽  
Nickel Nanoparticles ◽  
Catalyst Nanoparticles ◽  
Nickel Particles ◽  
Size And Morphology

Carbon nanofibers with various morphologies were synthesized by the catalytic pyrolysis of acetylene using nickel catalyst nanoparticles at different reaction temperatures. Experimental results demonstrate that temperature is a critical parameter for controlling the size and morphology of carbon fibers. Twin coiled fibers and linearly bifurcating fibers emanating from nickel particles were formed at 400 °C; whereas, only linear carbon nanofibers were obtained at reaction temperatures of 450 °C, 500 °C, and 550 °C. At low temperatures, nickel nanoparticles remain in the middle of two fibers, while nickel particles are positioned at one end of the linear fibers at high temperatures.

Electron distribution change of small nickel particles encaged in X zeolite in presence of Ce3+ ions, related to their catalytic properties

1986 ◽  
Vol 83 ◽  
pp. 619-621 ◽  
Author(s):  
F. Vergand ◽  
B. Iraqi ◽  
C. Bonnelle ◽  
E. Ramaroson ◽  
M.F. Guilleux ◽  
...  
Keyword(s):  
Electron Distribution ◽  
Catalytic Properties ◽  
Distribution Change ◽  
Nickel Particles ◽  
X Zeolite

MORPHOPHYSIOLOGICAL FEATURES OF WHEAT (Triticum aestivum L.) SEEDLINGS UPON EXPOSURE TO NICKEL NANOPARTICLES

2018 ◽  
Vol 53 (3) ◽  
pp. 578-586 ◽  
Author(s):  
P.N. Tsygvintsev ◽  
◽  
L.I. Goncharova ◽  
K.V. Manin ◽  
V.M. Rachkova ◽  
...  
Keyword(s):  
Triticum Aestivum ◽  
Nickel Nanoparticles ◽  
Triticum Aestivum L

Acceptorless amine dehydrogenation and transamination using Pd-doped layered double hydroxides

2018 ◽  
Author(s):  
Diana Ainembabazi ◽  
Nan An ◽  
Jinesh Manayil ◽  
Kare Wilson ◽  
Adam Lee ◽  
...  
Keyword(s):  
Layered Double Hydroxides ◽  
Oxidation States ◽  
Secondary Amines ◽  
Primary Amines ◽  
Acid Dissolution ◽  
Oxidative Amination ◽  
Strong Function ◽  
Excellent Activity ◽  
High Yields ◽  
Double Hydroxides

<div> <p>The synthesis, characterization, and activity of Pd-doped layered double hydroxides (Pd-LDHs) for for acceptorless amine dehydrogenation is reported. These multifunctional catalysts comprise Brønsted basic and Lewis acidic surface sites that stabilize Pd species in 0, 2+, and 4+ oxidation states. Pd speciation and corresponding cataytic performance is a strong function of metal loading. Excellent activity is observed for the oxidative transamination of primary amines and acceptorless dehydrogenation of secondary amines to secondary imines using a low Pd loading (0.5 mol%), without the need for oxidants. N-heterocycles, such as indoline, 1,2,3,4-tetrahydroquinoline, and piperidine, are dehydrogenated to the corresponding aromatics with high yields. The relative yields of secondary imines are proportional to the calculated free energy of reaction, while yields for oxidative amination correlate with the electrophilicity of primary imine intermediates. Reversible amine dehydrogenation and imine hydrogenation determine the relative imine:amine selectivity. Poisoning tests evidence that Pd-LDHs operate heterogeneously, with negligible metal leaching; catalysts can be regenerated by acid dissolution and re-precipitation.</p> </div> <br>

Microwave-assisted Synthesis of Polymethoxychalcone Mannich Bases and Their Antiproliferative Activity

2019 ◽  
Vol 16 (2) ◽  
pp. 117-121 ◽  
Author(s):  
Peipei Han ◽  
Wenhua Zhou ◽  
Mingxia Chen ◽  
Qiuan Wang
Keyword(s):  
Cell Lines ◽  
Cancer Cell ◽  
Antiproliferative Activity ◽  
Mannich Base ◽  
Cancer Cell Lines ◽  
Secondary Amines ◽  
Conventional Heating ◽  
Microwave Assisted ◽  
Ic50 Values ◽  
Antiproliferative Activities

A series of eight polymethoxychalcone Mannich base derivatives 2a-2h was synthesized via the microwave-assisted Mannich reaction of natural product 2&#039;-hydroxy-3,4,4&#039;,5,6&#039;-pentamethoxychalcone (1) with various secondary amines and formaldehyde. Compared to conventional heating method (80&#176;C), the microwave-assisted method (700W, 65&#176;C) is efficient with short reaction time (0.5-1 h) and good yields (74-88%). The antiproliferative activities of eight Mannich base derivatives were evaluated in vitro on a panel of three human cancer cell lines (Hela, HCC1954 and SK-OV-3) by CCK-8 assay. The results showed that all of the Mannich base derivatives exhibited potential antiproliferative activities on tested cancer cell lines with the IC50 values of 9.13-48.51 &#181;M. Some active compounds exhibited more activity as compared to positive control cis-Platin. Among them, compound 2b revealed to have the strongest antiproliferative activity against all the three cancer cell lines with IC50 values ranging from 9.13 to 11.24 &#181;M.

The Development of Tyrosyl-DNA Phosphodyesterase 1 (TDP1) Inhibitors Based on the Amines Combining Aromatic/Heteroaromatic and Monoterpenoid Moieties

2019 ◽  
Vol 16 (5) ◽  
pp. 597-605 ◽  
Author(s):  
Evgenii Mozhaitsev ◽  
Evgenii Suslov ◽  
Yuliya Demidova ◽  
Dina Korchagina ◽  
Konstantin Volcho ◽  
...  
Keyword(s):  
Dna Repair ◽  
Tumor Cell ◽  
13C Nmr ◽  
Inhibitory Activity ◽  
Secondary Amines ◽  
Repair Enzyme ◽  
1H And 13C Nmr ◽  
Chemical Structures ◽  
Natural Substances ◽  
Micromolar Range

Background: Inhibition of the DNA repair enzyme, tyrosyl-DNA phosphodiesterase 1 (TDP1), may increase the efficacy of cancer drugs that cause damage to tumor cell DNA. Among the known TDP1 inhibitors, there are compounds containing moieties of natural substances, e.g., monoterpenoids. In this work, we synthesized several compounds containing aromatic/ heteroaromatic amines and monoterpenoid groups and assessed their TDP1 inhibition potential. Methods: Structures of all the synthesized compounds were confirmed by 1H and 13C NMR as well as HRMS. The TDP1 inhibitory activity of the amines was determined by real-time fluorescence oligonucleotide biosensor. Results: The synthesized secondary amines had TDP1 inhibitory activity IC50 in the range of 0.79-9.2 µM. The highest activity was found for (–)-myrtenal derivatives containing p-bromoaniline or m-(trifluoromethyl)aniline residue. Conclusion: We synthesized 22 secondary amines; of these, 17 amines are novel chemical structures. Many of the amines inhibit TDP1 activity in the low micromolar range. Therefore, these compounds are promising for further study of their antiproliferative activity in conjunction with DNA damaging drugs.

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