scholarly journals STUDY OF THE INFLUENCE OF DISPERSITY AND CHEMICAL COMPOSITION OF NICKEL RENEUAL ALLOYS ON THE SPECIFICITY OF REDUCTION OF ADAMANTANE-CONTAINING UNSATURED NITRILE

2021 ◽  
pp. 64-70
Author(s):  
I. A. Novakov ◽  
B. S. Orlinson ◽  
E. N. Saveliev ◽  
E. A. Alykova ◽  
A. M. Pichugin ◽  
...  
Keyword(s):  
Grain Size ◽  
Aluminum Alloy ◽  
Double Bond ◽  
Chemical Composition ◽  
Size Composition ◽  
Nitrile Group ◽  
Hydroxyl Group ◽  
Nickel Aluminum ◽  
Simultaneous Reduction ◽  
Unsaturated Nitrile

The regularities of the reduction of adamantane-containing unsaturated nitrile-nickel-aluminum alloy are investigated. It has been shown that under the conditions of synthesis it is possible to carry out the simultaneous reduction of both the double bond and the nitrile group. It was found that the reduction of nitriles containing 1 hydroxyl group in the position leads to a significant decrease in the rate of the process. The effect of the grain size composition of the alloy and damping additives on the reduction of unsaturated nitriles has been studied.

scholarly journals Influence of inter-annual variability of river runoff on the bottom sediments of the Razdolnaya River estuary, Primorye, Russia

2020 ◽  
Author(s):  
В.М. ШУЛЬКИН
Keyword(s):  
Grain Size ◽  
Chemical Composition ◽  
Bottom Sediments ◽  
River Runoff ◽  
Total Concentration ◽  
Outer Part ◽  
River Estuary ◽  
Size Composition ◽  
Amur Bay ◽  
The North

Изучены вариации гранулометрического и химического состава верхнего двухсантиметрового слоя донных отложений эстуария р. Раздольная, отобранных трижды в течение 2015–2019 гг., когда водный и твердый стоки реки выросли в 2–3 и 5–6 раз соответственно по сравнению с 2014 г. Показано, что значительный вынос осадочного материала сопровождается увеличением на 10–20 % доли пелитовых (<0,01мм) фракций в отложениях внешней части эстуария в северной части Амурского залива. Вариации гранулометрического состава являются главным контролирующим фактором и определяют 67 % общей изменчивости химического состава осадков эстуария. Еще 20 % изменчивости обусловлены примесью загрязненных отложений залива, содержащих повышенную концентрацию Сорг., Hg, Zn, Pb, Cd, Ag, Cu, Mo, V, а также восстановительным диагенезом, приводящим к обеднению осадков марганцем и кобальтом на разрезе река–море. Установить влияние коагуляционных процессов в зоне смешения на валовый состав донных отложений эстуария р. Раздольная не удалось. Grain size and chemical composition have been studied of the upper 2 cm layer of bottom sediments of the Razdolnaya River estuary sampled thrice in 2015–2019. It was a period when the river runoff increased by 2–3 and 5–6 times for the water and suspended solids, respectively, compared to 2014. It has been shown that significant subtraction of sedimentary material is accompanied by 10–20 % increase of pellite fractions (grain size <0.01 mm) in the deposits of the outer part of anestuary in the North part of the Amur Bay. Grain size composition is the main controlling factor determining 67 % of the total variability of the chemical composition of estuarine bottom sediments. Another 20 % of variability are due to the admix of polluted sediments of the Amur Bay, containing an increased concentration of Corg., Hg, Zn, Pb, Cd, Ag, Cu, Mo, V, as well as diagenesis, leading to depletion of sediments by the Mn and Co on a river-sea section. It is not possible to establish the influence of coagulation processes in the mixing zone on total concentration of trace elements in the bottom sediments of Razdolnaya River estuary.

REDUCTIONS WITH NICKEL-ALUMINUM ALLOY AND AQUEOUS ALKALI. IV. THE CARBON-CARBON DOUBLE BOND

1944 ◽  
Vol 09 (2) ◽  
pp. 175-177 ◽  
Author(s):  
ERWIN SCHWENK ◽  
DOMENICK PAPA ◽  
BRADLEY WHITMAN ◽  
HELEN F. GINSBERG
Keyword(s):  
Aluminum Alloy ◽  
Double Bond ◽  
Aqueous Alkali ◽  
Nickel Aluminum ◽  
Carbon Double Bond

Grain size composition of broken rocks under different conditions of blasting

2019 ◽  
Vol 8 ◽  
pp. 83-94 ◽  
Author(s):  
B.R. Rakishev ◽  
◽  
A.A. Orynbay ◽  
A.M. Auezova ◽  
A.E. Kuttybaev ◽  
...  
Keyword(s):  
Grain Size ◽  
Size Composition ◽  
Grain Size Composition

ANALYSIS OF THE MODERN GRAIN-SIZE COMPOSITION VARIABILITY OF THE ANAPA BAY-BAR BEACH SEDIMENTS

2018 ◽  
Author(s):  
В. Крыленко ◽  
V. Krylenko ◽  
Р. Косьян ◽  
R. Kos'yan ◽  
М. Крыленко ◽  
...  
Keyword(s):  
Grain Size ◽  
Bottom Sediments ◽  
Size Structure ◽  
Size Composition ◽  
Potential Danger ◽  
Grain Size Composition ◽  
Beach Sediments ◽  
Sediment Particles ◽  
Sand Material

The results of realized in 2010 field researches of the spatial and time grain-size structure variability of beach and bottom sediments of the bay-bar Anapskaya southern part are presented in this paper. Irretrievable carrying out of sediment particles to depths more than 7 m intensifies with their size decrease to 0,1 mm. As over 70 % bottom and about 60 % beach sediments are presented by fractions less 0,16 mm on bay-bar Anapskaya southern part, namely at this part there is sand material massive carrying out to depth. Potential danger of the investigated site geosystem degradation is revealed.

Combinatorial Synthesis of Novel 9R-Acyloxyquinine Derivatives as Insecticidal Agents

2020 ◽  
Vol 23 (2) ◽  
pp. 111-118
Author(s):  
Zhiping Che ◽  
Jinming Yang ◽  
Di Sun ◽  
Yuee Tian ◽  
Shengming Liu ◽  
...  
Keyword(s):  
Natural Products ◽  
Double Bond ◽  
Insecticidal Activity ◽  
Structural Modification ◽  
Combinatorial Synthesis ◽  
Hydroxyl Group ◽  
Botanical Insecticide ◽  
Mythimna Separata ◽  
Lead Compounds

Background: It is one of the effective ways for pesticide innovation to develop new insecticides from natural products as lead compounds. Quinine, the main alkaloid in the bark of cinchona tree as well as in plants in the same genus, is recognized as a safe and potent botanical insecticide to many insects. The structural modification of quinine into 9R-acyloxyquinine derivatives is a potential approach for the development of novel insecticides, which showed more toxicity than quinine. However, there are no reports on the insecticidal activity of 9Racyloxyquinine derivatives to control Mythimna separata. Methods: Endeavor to discover biorational natural products-based insecticides, 20 novel 9Racyloxyquinine derivatives were prepared and assessed for their insecticidal activity against M. separata in vivo by the leaf-dipping method at 1 mg/mL. Results: Among all the compounds, especially derivatives 5i, 5k and 5t exhibited the best insecticidal activity with final mortality rates of 50.0%, 57.1%, and 53.6%, respectively. Conclusion: Overall, a free 9-hydroxyl group is not a prerequisite for insecticidal activity and C9- substitution is well tolerated; modification of out-ring double-bond is acceptable, and hydrogenation of double-bond enhances insecticidal activity; Quinine ring is essential and open of it is not acceptable. These preliminary results will pave the way for further modification of quinine in the development of potential new insecticides.

scholarly journals A Physical-Based Plane Stress Constitutive Model for High Strength AA7075 under Hot Forming Conditions

Metals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 314
Author(s):  
Fulong Chen ◽  
Haitao Qu ◽  
Wei Wu ◽  
Jing-Hua Zheng ◽  
Shuguang Qu ◽  
...  
Keyword(s):  
Grain Size ◽  
Aluminum Alloy ◽  
Plane Stress ◽  
Metal Forming ◽  
Electron Backscatter Diffraction ◽  
High Strength ◽  
Material Model ◽  
Hot Forming ◽  
Industrial Processing ◽  
Average Grain Size

Physicallybased constitutive equations are increasingly used for finite element simulations of metal forming processes due to the robust capability of modelling of underlying microstructure evolutions. However, one of thelimitations of current models is the lack of practical validation using real microstructure data due to the difficulties in achieving statistically meaningful data at a sufficiently large microstructure scale. Particularly, dislocation density and grain size governing the hardening in sheet deformation are of vital importance and need to be precisely quantified. In this paper, a set of dislocation mechanics-based plane stress material model is constructed for hot forming aluminum alloy. This material model is applied to high strength 7075 aluminum alloy for the prediction of the flow behaviorsconditioned at 300–400 °C with various strain rates. Additionally, an electron backscatter diffraction (EBSD) technique was applied to examine the average grain size and geometrical necessary dislocation (GND) density evolutions, enabling both macro- and micro- characteristics to be successfully predicted. In addition, to simulate the experienced plane stress states in sheet metal forming, the calibrated model is further extended to a plane stress stateto accuratelypredict the forming limits under hot conditions.The comprehensively calibrated material model could be used for guidinga better selection of industrial processing parameters and designing process windows, taking into account both the formed shape as well as post formed microstructure and, hence, properties.

Effects of Intensity of Alternating Electromagnetic Field on Microstructure and Property of ZL114A Aluminum Alloy Castings

2013 ◽  
Vol 278-280 ◽  
pp. 429-432
Author(s):  
Qing Song Yan ◽  
Yong Li ◽  
Gang Lu ◽  
Bai Ping Lu ◽  
Bo Wen Xiong ◽  
...  
Keyword(s):  
Grain Size ◽  
Electromagnetic Field ◽  
Aluminum Alloy ◽  
Mechanical Performance ◽  
Great Influence ◽  
Current Intensity ◽  
Alloy Castings

Through analyzing and testing the microstructure and property of ZL114A aluminum alloy castings under the condition of alternating electromagnetic field, the effects of the intensity of alternating electromagnetic field on the microstructure and property of ZL114A aluminum alloy castings are studied. The results showed the intensity of alternating electromagnetic field had a great influence on the microstructure and property of ZL114A aluminum alloy castings. With the increase of the intensity of alternating electromagnetic field, the grain size of ZL114A aluminum alloy was more and more small, under the 10A current intensity, the grain was the finest. Whereas, with the increase of the intensity of alternating electromagnetic field further, the grain is more and more big. Meanwhile, in a certain rang of current intensity, the mechanical performance of ZL114A aluminum alloy had been improved comprehensively, its tensile intensity was improved 10MPa and the elongation was increased by 30%.

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