scholarly journals Karakterisasi Asap Cair Hasil Pirolisis Sampah Kantong Plastik sebagai Bahan Bakar Bensin

2020 ◽  
Vol 5 (2) ◽  
pp. 96
Author(s):  
I Dewe Ketut Anom ◽  
John Z Lombok
Keyword(s):  
Negative Impact ◽  
Chemical Properties ◽  
Calorific Value ◽  
Gasoline Fraction ◽  
Fuel Oil ◽  
Fraction Liquid ◽  
Liquid Smoke ◽  
Plastic Bag ◽  
Physical And Chemical

Plastic bag waste is garbage that is difficult to degrade in nature. Hoarding plastic bag waste can reduce soil fertility because it cannot be broken down by microorganisms quickly. Burning plastic bag waste can produce toxic gases and have a negative impact on human health and the environment. To solve the problem, the plastic bag waste is converted into liquid smoke as fuel oil. The method used to convert the plastic bag waste into liquid smoke is pyrolysis. The fractionation of liquid smoke at temperatures below 200oC produces 36.20% clear liquid which has similar properties to gasoline fuel. Characterization of the physical and chemical properties of the gasoline fraction liquid smoke has a density of 0.76 g/mL; a viscosity of 0.80 cP; boiling point at 146.9oC; flash point at 30.60oC; a calorific value of 10,520 cal/g; with the octane number of 98 RON. GC-MS analysis shows that the gasoline fraction liquid smoke consists of 45 chemical compounds which can be classified into alkanes, alkenes, cycloalkanes and alcohols.  

Fuel Briquettes from Sisal Waste in Thailand

2017 ◽  
Vol 866 ◽  
pp. 168-171
Author(s):  
Udomdeja Polyium ◽  
Amornrat Pigoolthong
Keyword(s):  
Moisture Content ◽  
Chemical Properties ◽  
Calorific Value ◽  
Volatile Matter ◽  
Ash Content ◽  
Physical And Chemical Properties ◽  
Fixed Carbon ◽  
Physical And Chemical ◽  
And Chemical Properties

The research aims to develop fuel briquettes from sisal waste material mixed with bagasse. Sisal wastes were collected from Hub Kapong Royal Project Phetchaburi Province Thailand. These material were mixed according to the ratios of 90:10, 80:20, 70:30, 60:40 and 50:50 respectively. Characterization of physical and chemical properties of fuel briquettes were determined by percentage moisture content, percentage ash content, percentage volatile matter, percentage fixed carbon, and calorific value with the standard number ASTM 3173, ASTM D 3175, ASTM D 3174, ASTM D 3177 and ASTM D 3286 respectively. The results show that percentage moisture content values of 9.98 - 18.14, percentage volatile matter values of 42.59 - 68.04, percentage ash content values of 16.05 -25.41, percentage fixed carbon values of 5.93 - 13.86 and calorific values of 1,820.52 - 2,485.19 kcal/kg. Fuel briquettes to be used as a fuel substitute for firewood and charcoal.

scholarly journals Physical and chemical characterization of African catfish smoked sausage with different liquid smoke concentrations and immersion durations

2021 ◽  
Vol 322 ◽  
pp. 04001
Author(s):  
Ernawati ◽  
Moh. Awaludin Adam ◽  
Irawati Mei Widiastuti ◽  
Era Insivitawati
Keyword(s):  
Relative Concentration ◽  
Chemical Properties ◽  
Chemical Characterization ◽  
Product Diversification ◽  
African Catfish ◽  
Liquid Smoke ◽  
Physical And Chemical ◽  
And Chemical Properties

Product diversification is needed to increase selling and marketing prices. One of them is the African catfish sausage product. Liquid smoke has been used commercially by the food industry. This study aimed to determine the physical and chemical properties of smoked African catfish after adding different concentrations of liquid smoke and immersion duration. The chemical analysis measured the levels of protein, fat, and phenol. The results showed that sausage with a concentration of 20% liquid and soaking for 30 minutes was the best treatment with a protein content of 43.8 ± 0.34%, a fat of 12.33 ± 0.61%, and phenol 292.74 ppm. Determination of the compound using GC-MS found that the most dominant compound in the smokeless sausage was 2-hexanone, 3,3 dimethyl with a relative concentration of 32.42%. The dominant compound in the besttreated sausage was Furan, tetrahydro-2,2-dimethyl- with a relative concentration of 19%. Liquid smoke penetration is clearly visible in the microstructure of smoked sausages, both in the best-treated smoked sausages and commercial sausages. Scanning Electron Microscope (SEM) magnification of 2.500x shows that the best emulsified smoked sausages have a flatter structure, smaller droplets, and are more refined than smokeless sausages or commercial smoked sausages.

scholarly journals Recent Progress in the Synthesis and Characterization of Diarylethene-based MOFs

2014 ◽  
Vol 70 (a1) ◽  
pp. C1223-C1223
Author(s):  
Jason Benedict ◽  
Ian Walton ◽  
Dan Patel ◽  
Jordan Cox
Keyword(s):  
Chemical Properties ◽  
Building Blocks ◽  
Synthesis And Characterization ◽  
Next Generation ◽  
Design Synthesis ◽  
Thermally Induced ◽  
Potential Applications ◽  
External Stimuli ◽  
Physical And Chemical

Metal-organic Frameworks (MOFs) remain an extremely active area of research given the wide variety of potential applications and the enormous diversity of structures that can be created from their constituent building blocks. While MOFs are typically employed as passive materials, next-generation materials will exhibit structural and/or electronic changes in response to applied external stimuli including light, charge, and pH. Herein we present recent results in which advanced photochromic diarylethenes are combined with MOFs through covalent and non-covalent methods to create photo-responsive permanently porous crystalline materials. This presentation will describe the design, synthesis, and characterization of next-generation photo-switchable diarylethene based ligands which are subsequently used to photo-responsive MOFs. These UBMOF crystals are, by design, isostructural with previously reported non-photoresponsive frameworks which enables a systematic comparison of their physical and chemical properties. While the photoswitching of the isolated ligand in solution is fully reversible, the cycloreversion reaction is suppressed in the UBMOF single crystalline phase. Spectroscopic evidence for thermally induced cycloreversion will be presented, as well as a detailed analysis addressing the limits of X-ray diffraction techniques applied to these systems.

scholarly journals AVALIAÇÃO DA ESTRUTURA ELETRÔNICA DA FASE MONOCLINICA DO ÓXIDO DE NIÓBIO COM BASE NO USO DE DIFERENTES FUNCIONAIS DE DENSIDADE

Química Nova ◽  
2021 ◽  
Author(s):  
Kamila Ody ◽  
João Jesus ◽  
Carlos Cava ◽  
Anderson Albuquerque ◽  
Ary Maia ◽  
...  
Keyword(s):  
Density Functional ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Density Functionals ◽  
Monoclinic Structure ◽  
Functional Theory ◽  
Periodic Models ◽  
Physical And Chemical ◽  
And Chemical Properties

ASSESSMENT OF THE ELECTRONIC STRUCTURE OF THE MONOCLINIC PHASE OF NIOBIUM OXIDE BASED ON THE USE OF DIFFERENT DENSITY FUNCTIONALS. Niobium oxides, Nb2O5, are considered semiconductor materials with very attractive physical and chemical properties for applications in many areas, such as catalysis, sensors, medical, aerospace, etc. Especially, the characterization of Nb2O5-based nanostructures with monoclinic structure has received much attention in recent years. However, despite the great importance of this system, some of its fundamentals properties are still not fully understood. Hence, this work aims to apply the theoretical methodologies through Density Functional Theory (DFT) calculations in periodic models based on the use of different density functionals (like B1WC, B3PW, B3LYP, PBE0, PBESOL0, SOGGAXC, and WC1LYP) to investigate the physical and chemical properties of the monoclinic structure of Nb2O5. The band structures, energy bandgap, density of state, and vibrational properties, as well as order-disorder effects on the monoclinic structure of Nb2O5 are investigated in this study. Our theoretical results show a better agreement with experimental data for the B3LYP functional and hence lead to new perspectives on the deeper physicochemical understanding of the monoclinic Nb2O5. From these computational tools, it is possible to unravel the relations between structure and properties, which may contribute to the future development of new devices and applications based on these materials.

scholarly journals Characterization of gelatins from Nile tilapia skins preserved by freezing and salting

2019 ◽  
Vol 40 (6) ◽  
pp. 2581
Author(s):  
Adriana Cristina Bordignon ◽  
Maria Luiza Rodrigues de Souza ◽  
Eliane Gasparino ◽  
Edson Minoru Yajima ◽  
Jesuí Vergílio Visentainer ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Nile Tilapia ◽  
Saturated Fatty Acids ◽  
Chemical Properties ◽  
Monounsaturated Fatty Acids ◽  
Gel Strength ◽  
Physical And Chemical Properties ◽  
Physical And Chemical ◽  
And Chemical Properties

After Nile tilapia skin was preserved using the methods of freezing and dry salting, characteristics of skin gelatin were evaluated with regard to yield, rheological features and physical and chemical properties. Preservation was performed after filleting, at which time skins were either frozen (-18°C) for 7 days or salted (25°C) for 7 days. Although no differences (p > 0.05) were observed with respect to humidity, protein, lipid, ash and calcium levels, gelatin from salted skins had a higher concentration of iron relative to frozen skins. Further, twenty-three fatty acids were detected in salted skins compared with merely three found in skin derived gelatin. Of amino acids found, glycine, alanine, proline and arginine were the most abundant. Hydroxyproline abundance in salted and frozen skin gelatin were 8.76% and 8.71%, respectively. In addition, salted skin gelatins had a greater accumulation of saturated fatty acids and lower rates of monounsaturated fatty acids. Salted skin gelatin had the highest yield (18g × 100g-1), gel strength (200 g) and viscosity (19.02mPas) when compared to the yield (17g × 100g-1), gel strength (12.7g) and viscosity (9.16 mPas) of frozen skins. Results show that gelatin from dry salted skin had the best yield and also had relatively better rheological properties, more iron, and better coloration relative to gelatin obtained from frozen skins of Nile tilapia.

scholarly journals Study of the properties of drinking water for Kirkuk city and its pollution in some areas

2018 ◽  
Vol 162 ◽  
pp. 05008
Author(s):  
Iman Hussein Zainulabdeen
Keyword(s):  
Drinking Water ◽  
Negative Impact ◽  
Chemical Properties ◽  
World Health ◽  
Total Hardness ◽  
Physical And Chemical Properties ◽  
Health Organization ◽  
Physical And Chemical ◽  
Treatment Water ◽  
And Chemical Properties

This study was conducted to demonstrate the difference between drinking water quality for seven different areas of Kirkuk city with the treatment water in the main and three sub storages tanks, affected with drinking water pipe lines, supplying system Alternate and continuous and also pipes across the construction work’s areas. The physical and chemical properties (turbidity, pH, conductivity, Alkalinity, Total hardness, calcium, magnesium, chloride, sulfate, TDS (Total dissolve solids), TSS (Total suspended solids), sodium and potassium) for raw water and treated water in the Storages in addition to the supplying water from seven different areas in Kirkuk were analyzed, samples taken at a rate nine times during the month of March. Results showed that Drinking water of Dumez, Wasti, Shorja, Imam Qasim and Arubaa polluted with turbidity with an average levels of (8.68, 6.04, 7.41, 6.95, 7.64) NTU respectively, over the limit allowed by IBWA (International Bottled Water Association), 2012 and WHO (World Health Organization), 2006. The turbidity in the main and sub storages have reached (4.04, 4.09, 4.47, 4.16) NTU respectively, while other physical and chemical properties were within the allowed limits for human use. The pollution in those areas caused by the alternative supplying system of treatment water and it has negative impact on the pipelines, it includes constriction work in areas also where pipelines exist.

Characterization of Shivirtui Zeolite Modified with Aluminum Oxyhydroxide Nanofibers

2019 ◽  
Vol 942 ◽  
pp. 40-49
Author(s):  
Yulia Murashkina ◽  
Olga B. Nazarenko
Keyword(s):  
Chemical Properties ◽  
Nitrogen Adsorption ◽  
X Ray Diffraction ◽  
Scanning Electronic Microscopy ◽  
Electronic Microscopy ◽  
X Ray ◽  
Physical And Chemical ◽  
And Chemical Properties ◽  
Aluminum Oxyhydroxide

Natural zeolite of Shivirtui deposit (Russia) was modified with nanofibers of aluminum oxyhydroxide AlOOH. Aluminum oxyhydroxide nanofibers were produced at the heating and oxidation of aluminum powder with water. The properties of modified zeolite were investigated by means of X-ray diffraction, transmission electronic microscopy, scanning electronic microscopy, low-temperature nitrogen adsorption, thermal analysis, and Fourier transform infrared spectroscopy. It was found that water content in the modified sample of zeolite was about 15 %. Based on the study of the physical and chemical properties, shivirtui zeolite modified with nanofibers of aluminum oxyhydroxide can be proposed for use as a flame-retardant additive to polymers.

scholarly journals Characterization of Engineering Plastics Plasticized Using Supercritical CO2

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 134
Author(s):  
Masaki Watanabe ◽  
Yoshihide Hashimoto ◽  
Tsuyoshi Kimura ◽  
Akio Kishida
Keyword(s):  
Molecular Weight ◽  
Supercritical Co2 ◽  
Chemical Properties ◽  
Molding Process ◽  
Test Pieces ◽  
Engineering Plastics ◽  
Transition Points ◽  
Physical And Chemical ◽  
And Chemical Properties

The purpose of this study was to evaluate the physical and chemical properties of engineering plastics processed using supercritical CO2. First, we prepared disk-shaped test pieces via a general molding process, which were plasticized using supercritical CO2 at temperatures lower than the glass-transition points of engineering plastics. Amorphous polymers were plasticized, and their molecular weight remained nearly unchanged after treatment with supercritical CO2. The mechanical strength significantly decreased despite the unchanged molecular weight. The surface roughness and contact angle increased slightly, and electrical properties such as the rate of charging decreased significantly. These results suggest that supercritical CO2 could be used for a new molding process performed at lower temperatures than those used in general molding processes, according to the required properties.

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