Evaluation the Impact of Mineralogical Composition of Reservoir Rocks on Wettabiliity during Surfactant Flooding Processes

2021 ◽  
Author(s):  
H. Esfandiari ◽  
S.R. Shadizadeh ◽  
R. Abdollahi
Keyword(s):  
Mineralogical Composition ◽  
Surfactant Flooding ◽  
Reservoir Rocks ◽  
The Impact

The Study of the Oil Unit Connectivity for Microscopic Displacement Efficiency by CT Scan

2012 ◽  
Vol 529 ◽  
pp. 560-563
Author(s):  
Hui Lu ◽  
Sheng Lai Yang ◽  
Yan Bin Zhang ◽  
Li Xie ◽  
Ke Hou Zhou ◽  
...  
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
High Efficiency ◽  
Viscosity Ratio ◽  
Surfactant Flooding ◽  
Displacement Efficiency ◽  
Reservoir Rocks ◽  
Cylinder Model ◽  
Main Factors ◽  
The Impact

In this paper, the main factors that affect the displacement efficiency were experimental studied by means of the physical cylinder model filled with sand, based on the high efficiency of oil displacing water in the process of hydrocarbon accumulation. After eliminating of some factors that affect displacement efficiency, such as viscosity ratio, wettability and reservoir heterogeneity and so on, the research founds that the crude oil unit connectivity, that is continuity of displaced phase, has a significant impact on the displacement efficiency. The experimental results show that the crude oil unit connectivity is more than wettability, and not less than viscosity, as the factors of the impact of displacement efficiency. If the crude oil unit connectivity is serious damaged, even if the wettability of reservoir rocks was changed by improving the viscosity of injected water, its effect of enhanced oil recovery should not be obvious. In fact, this is main reason that the effect of current the EOR method such as polymer flooding, surfactant flooding and stuff was not obvious. It is expected that the research results will be useful in the displacement efficiency of waterflooding that is controlled by the crude oil unit connectivity.

scholarly journals Physico-chemical variability and heavy metal pollution of surface sediment in a non-channeled section of Dilúvio Stream (Southern Brazil) and the influence of channeled section in sediment pollution

2019 ◽  
Vol 14 (1) ◽  
pp. 1 ◽  
Author(s):  
Pedro Alexandre Sodrzeieski ◽  
Leonardo Capeleto de Andrade ◽  
Tales Tiecher ◽  
Flávio Anastácio de Oliveira Camargo
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Total Concentration ◽  
Mineralogical Composition ◽  
Sediment Pollution ◽  
Anthropogenic Influence ◽  
Southern Brazil ◽  
Physico Chemical ◽  
Chemical Variability ◽  
The Impact

Dilúvio Stream flows through an area with a great population density in Porto Alegre, Southern Brazil. The anthropogenic influence in the surroundings impacted negatively the quality of the sediments of Dilúvio Stream and Lake Guaíba. This study evaluated the physico-chemical variability of surface sediments in a non-channeled section of Dilúvio Stream. Additionally, we compared the concentration of several heavy metals in this section with data from previous studies in the margins of Lake Guaíba near the outflow of Dilúvio Stream in order to evaluate the impact of urbanization on sediment pollution. The pH, bulk density, particle-size distribution, electrical conductivity, organic carbon, assimilable phosphorus, total nitrogen, mineralogical composition (X-ray diffractogram) and pseudo total concentration of several metals (Fe, Al, Ca, Mg, Na, K, Mn, Ba, Zn, V, As, Pb, Cu, Cr, Co, Ni, Cd, Mo, and Se) were evaluated. The results showed that the sediments in the non-channeled section of Dilúvio Stream are predominantly sandy, with heavy metal contents below the quality reference values. Quartz and feldspar predominated in all sites. The concentration of Zn, Pb, Cu, Cr, and Ni were lower than that observed in the margins of Lake Guaíba near the outflow of Dilúvio Stream, possibly due to pollution input throughout the channeled section. The Dilúvio Stream shows indications of an anthropogenic influence in the heavy metals concentration through the channeled area.

Influence of Different Types of Fine Aggregate on Cement Composites Resistance to High Temperatures

2014 ◽  
Vol 1000 ◽  
pp. 126-129 ◽  
Author(s):  
Tomáš Melichar ◽  
Jiří Bydžovský
Keyword(s):  
Mineralogical Composition ◽  
Mechanical Tests ◽  
Basic Material ◽  
Fine Aggregate ◽  
Cement Composites ◽  
Cement Mortars ◽  
Different Types ◽  
Natural Aggregates ◽  
The Impact

The paper discusses the impact of several selected aggregates on the basic material characteristics of cement composites. Both artificial and natural aggregates (four types in total) with different mineralogical composition were evaluated. The specimens were exposed to environments with the temperature up to 1000°C and then subjected to physico-mechanical tests. For the follow-up development of polymer-cement mortars, we selected two types of aggregates – fly ash aggloporite (FAA) and amphibolite (AMA).

Mobilization, release and speciation of arsenic in an As-contaminated gold mine spoil under varied soil redox conditions

2020 ◽  
Author(s):  
Albert Kobina Mensah ◽  
Bernd Marschner ◽  
Jianxu Wang ◽  
Sabry M. Shaheen ◽  
Jörg Rinklebe
Keyword(s):  
Extraction Procedure ◽  
Mineralogical Composition ◽  
Redox Conditions ◽  
Mine Spoil ◽  
Residual Fraction ◽  
Reductive Dissolution ◽  
Gold Mine ◽  
Soil Redox ◽  
Reducing Conditions ◽  
The Impact

<p>Redox-induced release dynamics of arsenic (As) in an abandoned geogenic arsenic-contaminated gold mine spoil in Ghana has never been studied. Therefore, our aim was to investigate the effects of varied soil redox conditions on mobilisation and speciation of As from an abandoned highly contaminated gold mine spoil (with 4,283 mg As/kg soil) using an automated biogeochemical microcosm set-up. We also studied the impact of redox potential (E<sub>H</sub>)-dependent changes of pH, Fe, Mn, Al, S, Cl<sup>-</sup>, SO<sub>4</sub><sup>2-</sup>, DOC, DIC, DC, DN and SUVA on the release dynamics of As. As mineralogical composition and speciation were further determined using a synchrotron-based X-ray absorption spectroscopy (XANES). Linear combination fits of XANES results indicated that scorodite (FeAsSO<sub>4</sub>) and arsenopyrite (FeAsS) are the two major As-containing minerals in the studied mine spoil. Geochemical fractionation using sequential extraction procedure indicated greater proportions of the extracted As in the amorphous iron oxide fraction III (1390.13 mg kg<sup>-1</sup>, 32.5% of the total As) and residual fraction V (2591.67 mg kg<sup>-1</sup>, 60.5% of the total As). Concentrations of dissolved Fe and SUVA were higher during reducing conditions and decreased under oxidising conditions and both showed negative significant relationships with E<sub>H</sub> (E<sub>H </sub>and SUVA: r = -0.76, <em>P <</em> 0.01; E<sub>H</sub> and Fe: r = -0.75). Mobilisation of As was greater under reducing conditions (dissolved As = 136.68 mg/L) than in oxidising environments (dissolved As = 8.06 mg/L). The release of As under low E<sub>H</sub> can be explained by the associated reductive dissolution of Fe oxides, as demonstrated by the high positive significant relationship between Fe and As (r = +0.97, <em>P <</em> 0.01). Dissolved As release dynamics can also be linked to desorption of aromatic carbon compounds on the surfaces of dissolved organic carbon, as demonstrated by the high positive significant correlation between SUVA and As (r = +0.573, <em>P <</em> 0.01). Further, the release dynamics of dissolved As was also affected by changes in pH (r = -0.4, <em>P <</em> 0.05), but were not affected by redox-induced dynamics of Mn, Al, S, Cl<sup>-</sup>, SO<sub>4</sub><sup>2-</sup>, DOC, DIC, DC, DN. We conclude that conditions such as flooding and high rainfall in this contaminated mine spoil could create reducing conditions, leading to reductive dissolution of the arsenopyrite As-bearing primary mineral and may lead to higher As release into the groundwater, translocation into the food chain with potential impacts on human health.</p><p><strong>Keywords</strong>: Arsenopyrite, redox chemistry, arsenic mobilisation, gold mine spoil, reductive and oxidative dissolution.</p>

scholarly journals MODERN METHODS OF INVESTIGATION PHASE AND ELEMENTAL COMPOSITION OF THE CORE

2013 ◽  
pp. 151-154
Author(s):  
M. Smirny ◽  
M. Epishev
Keyword(s):  
Shale Gas ◽  
Mineralogical Composition ◽  
Optimization Techniques ◽  
X Ray Diffraction ◽  
X Ray ◽  
Design And Optimization ◽  
Reservoir Rocks ◽  
The Core ◽  
Modern Methods ◽  
Methods Of Treatment

Successful problem solving design and optimization techniques hydrocarbon largely depends on the mineralogical composition of reservoir rocks. It mineralogical composition directly determines the applicability of certain methods of treatment reagent wells are needed, such as shale gas. In this article we have shown excellence and effectiveness of the X-ray diffraction analysis in combination with elemental analysis for problems of geological services.   

scholarly journals Mineral stability, brine development and rock-fluid reaction at repository-relevant temperatures (<i>T</i> < 200 °C) in the potential host rock rock salt

2021 ◽  
Vol 1 ◽  
pp. 101-102
Author(s):  
Michael Mertineit ◽  
Michael Schramm
Keyword(s):  
Melting Point ◽  
Rock Salt ◽  
Site Selection ◽  
Host Rock ◽  
Mineralogical Composition ◽  
Confining Pressure ◽  
Maximum Temperature ◽  
General Importance ◽  
Host Rocks ◽  
The Impact

Abstract. For a repository of heat generating radioactive waste, the thermal behaviour of the host rock and the impact of temperature increase on rock properties is of general importance. In the German Site Selection Act (2017), the maximum temperature of the container surface is preliminarily limited to 100 ∘C but this limit might change in the future based on scientific and technological findings. Rock salt, as one of the possible host rocks, consists predominantly of halite with varying amounts of accessory minerals (e.g., Hudec and Jackson, 2007); however, some lithological units within a salt deposit, e.g. potash seams, show a different mineralogical composition with high amounts of potash minerals. Most of them are not very stable regarding temperature resistance and stress, contain water in the crystal lattice, and therefore react sensitively to changes in the environment. The melting point of most evaporated minerals is higher than the expected temperatures in a repository but dehydration and partial melting might occur at relevant temperatures, depending on the confining pressure. For example, the temperature of dehydration of carnallite is ca. 80 ∘C at 0.1 MPa confining pressure but increases to ca. 145 ∘C at 10 MPa confining pressure (Kern and Franke, 1986). The melting point of carnallite increases from ca. 145∘C/8MPa to ca. 167∘C/24MPa, which corresponds to a depth of ca. 1000 m. Depending on the mineral paragenesis and composition of saline solutions, different minerals develop with increasing temperature. For instance, a salt rock with an initial composition of kieserite + kainite + carnallite + solution R (25 ∘C) reacts solely to kieserite and solution R, when the temperature increases to 78 ∘C. A rock with a composition of kieserite + carnallite + bischofite + solution Z (25 ∘C) reacts to kieserite + carnallite from 25 to 50 ∘C, from 50 to 73 ∘C only kieserite is stable, and at temperatures >73 ∘C kieserite and bischofite develop (Usdowski and Dietzel, 1998). For the construction of an underground repository, the mineralogical composition of the host rocks and fluids have to be evaluated carefully and play an important role for the site selection and design of the underground facility.

Numerical Simulations of Surfactant Flooding in Carbonate Reservoirs: The Impact of Geological Heterogeneities Across Scales

2021 ◽  
Author(s):  
Jackson Pola ◽  
Sebastian Geiger ◽  
Eric Mackay ◽  
Christine Maier ◽  
Ali Al-Rudaini
Keyword(s):  
Oil Recovery ◽  
Carbonate Reservoir ◽  
Spontaneous Imbibition ◽  
Numerical Dispersion ◽  
Surfactant Flooding ◽  
Production Forecast ◽  
Geological Heterogeneity ◽  
Grid Coarsening ◽  
The Impact ◽  
The Way

Abstract We demonstrate how geological heterogeneity impacts the effectiveness of surfactant-based enhanced oil recovery (EOR) at larger (inter-well and sector) scales when upscaling small (core) scale heterogeneity and physicochemical processes. We used two experimental datasets of surfactant-based EOR where spontaneous imbibition and viscous displacement, respectively dominate recovery. We built 3D core-scale simulation models to match the data and parameterize surfactant models. The results were deployed in high-resolution models that preserve the complexity and heterogeneity of carbonate formations in the inter-well and sector scale. These larger-scale models were based on two outcrop analogues from France and Morroco, respectively, which capture the reservoir architectures inherent to the productive carbonate reservoir systems in the Middle East. We then assessed and quantified the error in production forecast that arises due to upscaling, upgridding, and simplification of geological heterogeneity. Simulation results showed a broad range of recovery predictions. The variability arises from the choice of surfactant model parameterization (i.e., spontaneous imbibition vs viscous displacement) and the way the heterogeneity in the inter-well and sector models was upscaled and simplified. We found that the parameterization of surfactant models has a significant impact on recovery predictions. Oil recovery at the larger scale was observed to be higher when using the parametrization derived from viscous displacement experiments compared to parameterization from spontaneous imbibition experiments. This observation clearly demonstrated how core-scale processes impact recovery predictions at the larger scales. Also, the variability in recovery prediction due to the choice of surfactant model was as large as the variability arising from upscaling and upgridding. Upscaled and upgridded models overestimated recovery because of the simplified geology. Grid coarsening exacerbated this effect because of the increased numerical dispersion. These results emphasize the need to use correctly configured surfactant models, appropriate grid resolution that minimizes numerical dispersion, and properly upscaled reservoir models to accurately forecast surfactant floods. Our findings present new insights into how the uncertainty in production forecasts during surfactant flooding depends on the way surfactant models are parameterized, how the reservoir geology is upscaled, and how numerical dispersion is impacted by grid coarsening.

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