scholarly journals Mineral stability, brine development and rock-fluid reaction at repository-relevant temperatures (<i>T</i> < 200 °C) in the potential host rock rock salt

2021 ◽  
Vol 1 ◽  
pp. 101-102
Author(s):  
Michael Mertineit ◽  
Michael Schramm

Abstract. For a repository of heat generating radioactive waste, the thermal behaviour of the host rock and the impact of temperature increase on rock properties is of general importance. In the German Site Selection Act (2017), the maximum temperature of the container surface is preliminarily limited to 100 ∘C but this limit might change in the future based on scientific and technological findings. Rock salt, as one of the possible host rocks, consists predominantly of halite with varying amounts of accessory minerals (e.g., Hudec and Jackson, 2007); however, some lithological units within a salt deposit, e.g. potash seams, show a different mineralogical composition with high amounts of potash minerals. Most of them are not very stable regarding temperature resistance and stress, contain water in the crystal lattice, and therefore react sensitively to changes in the environment. The melting point of most evaporated minerals is higher than the expected temperatures in a repository but dehydration and partial melting might occur at relevant temperatures, depending on the confining pressure. For example, the temperature of dehydration of carnallite is ca. 80 ∘C at 0.1 MPa confining pressure but increases to ca. 145 ∘C at 10 MPa confining pressure (Kern and Franke, 1986). The melting point of carnallite increases from ca. 145∘C/8MPa to ca. 167∘C/24MPa, which corresponds to a depth of ca. 1000 m. Depending on the mineral paragenesis and composition of saline solutions, different minerals develop with increasing temperature. For instance, a salt rock with an initial composition of kieserite + kainite + carnallite + solution R (25 ∘C) reacts solely to kieserite and solution R, when the temperature increases to 78 ∘C. A rock with a composition of kieserite + carnallite + bischofite + solution Z (25 ∘C) reacts to kieserite + carnallite from 25 to 50 ∘C, from 50 to 73 ∘C only kieserite is stable, and at temperatures >73 ∘C kieserite and bischofite develop (Usdowski and Dietzel, 1998). For the construction of an underground repository, the mineralogical composition of the host rocks and fluids have to be evaluated carefully and play an important role for the site selection and design of the underground facility.

2021 ◽  
Vol 1 ◽  
pp. 73-74
Author(s):  
Lukas Pollok ◽  
Mareike Henneberg

Abstract. Suitable host rocks for a repository for high-level radioactive waste (HLW) in Germany include not only clay and crystalline rocks but also rock salt formations in so-called flat and steep bedding (StandAG, 2017). Favourable repository relevant properties of rock salt are, e.g. the high heat conductivity, low porosity and permeability, and its viscoplastic deformation behaviour. Thicker salt deposits can be attributed to the formation of approx. 700 salt structures that have formed under various geological conditions in the North German Basin (NGB) over the last 250 million years. According to their shape and genesis, salt structures are classified as salt pillows (considered as flat bedding) or salt diapirs (steep bedding). Out of a total of 74 sub-areas in rock salt, 60 sub-areas in salt diapirs consisting of Permian evaporates were identified within the first phase of the German site selection procedure (BGE, 2020). At the current stage of the site selection process, a conservative approach has been adopted and the internal structure of the salt structures have not yet been taken into account for further classification of the identified sub-areas. However, the interior of the salt structures not only consists of rock salt but also of varying proportions of clay, carbonate and anhydrite rocks, as well as potassium salts formed by progressive evaporation of marine brines. Multi-phase salt tectonics has led to the folding of these differently composed layers and to complex internal structures. Therefore, detailed knowledge of the salt structure compositions is necessary to identify suitable rock salt areas for the designation of the containment providing rock zone. As a result of decades of research through extensive salt and potash mining, cavern storage and exploration for final waste disposal, Permian salt rocks represent a well-studied host rock in Germany. The use of different exploration methods and multidisciplinary data evaluation have led to a comprehensive understanding of the internal composition of some well-studied salt structures. Systematic studies have shown that several factors have influenced the formation of salt structures as well as their external shapes, sizes, and spatial distribution (e.g., Pollok et al., 2020). Furthermore, the amount and distribution of suitable host rocks varies greatly in different salt structures and is closely related to their internal structure. Since the interior of salt structures has not been considered in the site selection process so far, a classification of salt structures (or sub-areas) into certain types with varying internal composition and complexity is presented. By examining their lithofacial composition, genesis, and structural geological position within the basin, it is possible to narrow down these types to specific areas in the NGB. Without the acquisition of additional exploration data in this phase of the site selection process, this salt structure classification provides important data for the legally demanded assessment of the overall favourable geological situation.


2019 ◽  
Vol 23 (Suppl. 3) ◽  
pp. 997-1003 ◽  
Author(s):  
Zhongguang Sun ◽  
Jinyang Fan ◽  
Fei Wu ◽  
Jie Chen

Investigating the dilatancy of host rock during stress re-distribution is of great sig?nificance for underground engineering, especially underground salt cavern storages. To formulate the dilatancy variation, some measurements were conducted via unloading tests with ever-reduced confining pressure and constant axial pressure. The results demonstrated that the initial confining pressure had little influence on the dilatancy of rock salt. A larger axis pressure can promote the dilatancy of rock salt. A higher temperature would accelerate the dilatancy rate and augment the total volumetric expansion. A dilatancy-damage model was established by using theoretical deduction and numerical fitting, which showed a good agreement with test data.


Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 195 ◽  
Author(s):  
Wenheng Liu ◽  
Xiaodong Liu ◽  
Jiayong Pan ◽  
Kaixing Wang ◽  
Gang Wang ◽  
...  

The Qingshanbao complex, part of the uranium metallogenic belt of the Longshou-Qilian mountains, is located in the center of the Longshou Mountain next to the Jiling complex that hosts a number of U deposits. However, little research has been conducted in this area. In order to investigate the origin and formation of mafic enclaves observed in the Qingshanbao body and the implications for magmatic-tectonic dynamics, we systematically studied the mineralogy, petrography, and geochemistry of these enclaves. Our results showed that the enclaves contain plagioclase enwrapped by early dark minerals. These enclaves also showed round quartz crystals and acicular apatite in association with the plagioclase. Electron probe analyses showed that the plagioclase in the host rocks (such as K-feldspar granite, adamellite, granodiorite, etc.) show normal zoning, while the plagioclase in the mafic enclaves has a discontinuous rim composition and shows instances of reverse zoning. Major elemental geochemistry revealed that the mafic enclaves belong to the calc-alkaline rocks that are rich in titanium, iron, aluminum, and depleted in silica, while the host rocks are calc-alkaline to alkaline rocks with enrichment in silica. On Harker diagrams, SiO2 contents are negatively correlated with all major oxides but K2O. Both the mafic enclaves and host rock are rich in large ion lithophile elements such as Rb and K, as well as elements such as La, Nd, and Sm, and relatively poor in high field strength elements such as Nb, Ta, P, Ti, and U. Element ratios of Nb/La, Rb/Sr, and Nb/Ta indicate that the mafic enclaves were formed by the mixing of mafic and felsic magma. In terms of rare earth elements, both the mafic enclaves and the host rock show right-inclined trends with similar weak to medium degrees of negative Eu anomaly and with no obvious Ce anomaly. Zircon LA-ICP-MS (Laser ablation inductively coupled plasma mass spectrometry) U-Pb concordant ages of the mafic enclaves and host rock were determined to be 431.8 5.2 Ma (MSWD (mean standard weighted deviation)= 1.5, n = 14) and 432.8 4.2 Ma (MSWD = 1.7, n = 16), respectively, consistent with that for the zircon U-Pb ages of the granite and medium-coarse grained K-feldspar granites of the Qingshanbao complex. The estimated ages coincide with the timing of the late Caledonian collision of the Alashan Block. This comprehensive analysis allowed us to conclude that the mafic enclaves in the Qingshanbao complex were formed by the mixing of crust-mantle magma with mantle-derived magma due to underplating, which caused partial melting of the ancient basement crust during the collisional orogenesis between the Alashan Block and Qilian rock mass in the early Silurian Period.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Emily J. Wilkins ◽  
Peter D. Howe ◽  
Jordan W. Smith

AbstractDaily weather affects total visitation to parks and protected areas, as well as visitors’ experiences. However, it is unknown if and how visitors change their spatial behavior within a park due to daily weather conditions. We investigated the impact of daily maximum temperature and precipitation on summer visitation patterns within 110 U.S. National Park Service units. We connected 489,061 geotagged Flickr photos to daily weather, as well as visitors’ elevation and distance to amenities (i.e., roads, waterbodies, parking areas, and buildings). We compared visitor behavior on cold, average, and hot days, and on days with precipitation compared to days without precipitation, across fourteen ecoregions within the continental U.S. Our results suggest daily weather impacts where visitors go within parks, and the effect of weather differs substantially by ecoregion. In most ecoregions, visitors stayed closer to infrastructure on rainy days. Temperature also affects visitors’ spatial behavior within parks, but there was not a consistent trend across ecoregions. Importantly, parks in some ecoregions contain more microclimates than others, which may allow visitors to adapt to unfavorable conditions. These findings suggest visitors’ spatial behavior in parks may change in the future due to the increasing frequency of hot summer days.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Virgílio A. Bento ◽  
Andreia F. S. Ribeiro ◽  
Ana Russo ◽  
Célia M. Gouveia ◽  
Rita M. Cardoso ◽  
...  

AbstractThe impact of climate change on wheat and barley yields in two regions of the Iberian Peninsula is here examined. Regression models are developed by using EURO-CORDEX regional climate model (RCM) simulations, forced by ERA-Interim, with monthly maximum and minimum air temperatures and monthly accumulated precipitation as predictors. Additionally, RCM simulations forced by different global climate models for the historical period (1972–2000) and mid-of-century (2042–2070; under the two emission scenarios RCP4.5 and RCP8.5) are analysed. Results point to different regional responses of wheat and barley. In the southernmost regions, results indicate that the main yield driver is spring maximum temperature, while further north a larger dependence on spring precipitation and early winter maximum temperature is observed. Climate change seems to induce severe yield losses in the southern region, mainly due to an increase in spring maximum temperature. On the contrary, a yield increase is projected in the northern regions, with the main driver being early winter warming that stimulates earlier growth. These results warn on the need to implement sustainable agriculture policies, and on the necessity of regional adaptation strategies.


Materials ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 1818
Author(s):  
Di-Si Wang ◽  
Bo Liu ◽  
Sheng Yang ◽  
Bin Xi ◽  
Long Gu ◽  
...  

China is developing an ADS (Accelerator-Driven System) research device named the China initiative accelerator-driven system (CiADS). When performing a safety analysis of this new proposed design, the core behavior during the steam generator tube rupture (SGTR) accident has to be investigated. The purpose of our research in this paper is to investigate the impact from different heating conditions and inlet steam contents on steam bubble and coolant temperature distributions in ADS fuel assemblies during a postulated SGTR accident by performing necessary computational fluid dynamics (CFD) simulations. In this research, the open source CFD calculation software OpenFOAM, together with the two-phase VOF (Volume of Fluid) model were used to simulate the steam bubble behavior in heavy liquid metal flow. The model was validated with experimental results published in the open literature. Based on our simulation results, it can be noticed that steam bubbles will accumulate at the periphery region of fuel assemblies, and the maximum temperature in fuel assembly will not overwhelm its working limit during the postulated SGTR accident when the steam content at assembly inlet is less than 15%.


2021 ◽  
Vol 13 (2) ◽  
pp. 323
Author(s):  
Liang Chen ◽  
Xuelei Wang ◽  
Xiaobin Cai ◽  
Chao Yang ◽  
Xiaorong Lu

Rapid urbanization greatly alters land surface vegetation cover and heat distribution, leading to the development of the urban heat island (UHI) effect and seriously affecting the healthy development of cities and the comfort of living. As an indicator of urban health and livability, monitoring the distribution of land surface temperature (LST) and discovering its main impacting factors are receiving increasing attention in the effort to develop cities more sustainably. In this study, we analyzed the spatial distribution patterns of LST of the city of Wuhan, China, from 2013 to 2019. We detected hot and cold poles in four seasons through clustering and outlier analysis (based on Anselin local Moran’s I) of LST. Furthermore, we introduced the geographical detector model to quantify the impact of six physical and socio-economic factors, including the digital elevation model (DEM), index-based built-up index (IBI), modified normalized difference water index (MNDWI), normalized difference vegetation index (NDVI), population, and Gross Domestic Product (GDP) on the LST distribution of Wuhan. Finally, to identify the influence of land cover on temperature, the LST of croplands, woodlands, grasslands, and built-up areas was analyzed. The results showed that low temperatures are mainly distributed over water and woodland areas, followed by grasslands; high temperatures are mainly concentrated over built-up areas. The maximum temperature difference between land covers occurs in spring and summer, while this difference can be ignored in winter. MNDWI, IBI, and NDVI are the key driving factors of the thermal values change in Wuhan, especially of their interaction. We found that the temperature of water area and urban green space (woodlands and grasslands) tends to be 5.4 °C and 2.6 °C lower than that of built-up areas. Our research results can contribute to the urban planning and urban greening of Wuhan and promote the healthy and sustainable development of the city.


2008 ◽  
Vol 580-582 ◽  
pp. 319-322 ◽  
Author(s):  
Manabu Tanaka ◽  
Kentaro Yamamoto ◽  
Tashiro Shinichi ◽  
John J. Lowke

Study of current attachment at thermionic cathode for TIG arc at atmospheric pressure is attempted from numerical calculations of arc-electrodes unified model. The calculations show that the maximum temperature of arc plasma close to the cathode tip for W-2% ThO2 reaches 19,000 K and it is the highest value in comparison with the other temperatures for W-2% La2O3 and W-2% CeO2, because the current attachment at the cathode tip is constricted by a centralized limitation of liquid area of ThO2 due to its higher melting point. The calculations also show that, in cases of W- 2% La2O3 and W-2% CeO2, the liquid areas of La2O3 and Ce2O3 are widely expanded at the cathode tip due to their lower melting points and then produce uniform current attachments at the cathode. It is concluded that the current attachment at thermionic cathode is strongly dependent on work function, melting point and Richardson constant of emitter materials.


2013 ◽  
Vol 135 (11) ◽  
Author(s):  
Edwin Peraza-Hernandez ◽  
Darren Hartl ◽  
Edgar Galvan ◽  
Richard Malak

Origami engineering—the practice of creating useful three-dimensional structures through folding and fold-like operations on two-dimensional building-blocks—has the potential to impact several areas of design and manufacturing. In this article, we study a new concept for a self-folding system. It consists of an active, self-morphing laminate that includes two meshes of thermally-actuated shape memory alloy (SMA) wire separated by a compliant passive layer. The goal of this article is to analyze the folding behavior and examine key engineering tradeoffs associated with the proposed system. We consider the impact of several design variables including mesh wire thickness, mesh wire spacing, thickness of the insulating elastomer layer, and heating power. Response parameters of interest include effective folding angle, maximum von Mises stress in the SMA, maximum temperature in the SMA, maximum temperature in the elastomer, and radius of curvature at the fold line. We identify an optimized physical realization for maximizing folding capability under mechanical and thermal failure constraints. Furthermore, we conclude that the proposed self-folding system is capable of achieving folds of significant magnitude (as measured by the effective folding angle) as required to create useful 3D structures.


2021 ◽  
Vol 13 (12) ◽  
pp. 2249
Author(s):  
Sadia Alam Shammi ◽  
Qingmin Meng

Climate change and its impact on agriculture are challenging issues regarding food production and food security. Many researchers have been trying to show the direct and indirect impacts of climate change on agriculture using different methods. In this study, we used linear regression models to assess the impact of climate on crop yield spatially and temporally by managing irrigated and non-irrigated crop fields. The climate data used in this study are Tmax (maximum temperature), Tmean (mean temperature), Tmin (minimum temperature), precipitation, and soybean annual yields, at county scale for Mississippi, USA, from 1980 to 2019. We fit a series of linear models that were evaluated based on statistical measurements of adjusted R-square, Akaike Information Criterion (AIC), and Bayesian Information Criterion (BIC). According to the statistical model evaluation, the 1980–1992 model Y[Tmax,Tmin,Precipitation]92i (BIC = 120.2) for irrigated zones and the 1993–2002 model Y[Tmax,Tmean,Precipitation]02ni (BIC = 1128.9) for non-irrigated zones showed the best fit for the 10-year period of climatic impacts on crop yields. These models showed about 2 to 7% significant negative impact of Tmax increase on the crop yield for irrigated and non-irrigated regions. Besides, the models for different agricultural districts also explained the changes of Tmax, Tmean, Tmin, and precipitation in the irrigated (adjusted R-square: 13–28%) and non-irrigated zones (adjusted R-square: 8–73%). About 2–10% negative impact of Tmax was estimated across different agricultural districts, whereas about −2 to +17% impacts of precipitation were observed for different districts. The modeling of 40-year periods of the whole state of Mississippi estimated a negative impact of Tmax (about 2.7 to 8.34%) but a positive impact of Tmean (+8.9%) on crop yield during the crop growing season, for both irrigated and non-irrigated regions. Overall, we assessed that crop yields were negatively affected (about 2–8%) by the increase of Tmax during the growing season, for both irrigated and non-irrigated zones. Both positive and negative impacts on crop yields were observed for the increases of Tmean, Tmin, and precipitation, respectively, for irrigated and non-irrigated zones. This study showed the pattern and extent of Tmax, Tmean, Tmin, and precipitation and their impacts on soybean yield at local and regional scales. The methods and the models proposed in this study could be helpful to quantify the climate change impacts on crop yields by considering irrigation conditions for different regions and periods.


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