Advances in Nanotechnology Transition Metal Catalysts in Oxidative Desulfurization (ODS) Processes

Author(s):  
Raffaele Saladino ◽  
Giorgia Botta ◽  
Marcello Crucianelli

Organosulfur compounds show a negative environmental impact because of SOx emissions by combustion of fuel oils. As a consequence, removal of sulfur is becoming a worldwide challenge. The hydrodesulfurization (HDS) process achieves limited performances in the case of refractory S-containing aromatic compounds, such as thiophene and substituted benzothiophenes (BTs), which require highly energy-demanding conditions (high temperature and pressure conditions). Oxidative desulfurization (ODS) is considered the most promising alternative to HDS. During ODS treatment, the organosulfur compounds are oxidized to corresponding sulfoxides and sulfones, which can be successively removed by extraction with polar solvents. Different stoichiometric oxidants have been used in the ODS processes with a different degree of efficacy and environmental impact. The design and development of catalytic procedures can increase the ODS energy efficiency as well as make it more economical and environmentally acceptable. Here we describe the advances in nanostructured organometallic catalysis and biotechology applied to ODS treatment.

2019 ◽  
pp. 122-126
Author(s):  
Tatyana A. Rozhkova ◽  
Eugene A. Sysoeva

The article describes the main provisions of the Government Decrees of the Russian Federation No. 450 dated on April 15, 2017 and No. 1356 dated on November 2017 regarding lighting products. The necessity to introduce the Technical Regulation of the EEU on energy efficiency requirements to power-consuming products in the territory of the EEU is considered in the article. It is shown that introduction of new requirements to energy efficiency and operational characteristics of general use lamps and luminaires, as well as informing consumers on the energy efficiency of the products, are aimed at lowering of power consumption for lighting and negative environmental impact.


2021 ◽  
Vol 9 (3) ◽  
pp. 105179
Author(s):  
Sidra Subhan ◽  
Muhammad Yaseen ◽  
Bashir Ahmad ◽  
Zhangfa Tong ◽  
Fazle Subhan ◽  
...  

Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3504
Author(s):  
Blanka Tundys ◽  
Tomasz Wiśniewski

The aim of the study was to analyze emissions in the supply chain and to identify, based on a literature analysis, which supply chain strategies could contribute to reducing these emissions. A broad spectrum of new supply chain strategy solutions was identified and, based on simulations of selected products, conclusions were drawn and the advantages and disadvantages of theoretical solutions were presented for individual cases. A critical analysis of the literature and simulation methods were used to illustrate the problem presented in this paper, to identify the factors causing greenhouse gas emissions and to draw conclusions in the form of proposals to redesign existing strategies, considering the factors determining the increase in pollution caused by the performed logistics processes. The results of the simulations and the literature analysis indicate that solutions related to the redesign of strategies must consider the specificity of the product and the nature of the chain. Not all proposed strategies are applicable to all chains, and each new strategy must be carefully considered and consider many factors. An important element to reduce the negative environmental impact of chains is a well-thought-out relationship with suppliers, a well-chosen and adapted logistics infrastructure, including means of transport. The presented solutions clearly indicate that the environmental aspect plays an increasingly important role in chain management and influences the applied chain strategies. However, reducing the environmental impact of a chain is not a revolutionary approach and an easy-to-implement strategy change, but a well-thought-out, long-term process that considers the specifics of the products, the possibilities of alternative sourcing and distribution modes, and the need to invest in logistics infrastructure to make it as environmentally neutral as possible.


Fuel ◽  
2018 ◽  
Vol 226 ◽  
pp. 498-507 ◽  
Author(s):  
Lorena P. Rivoira ◽  
Brenda C. Ledesma ◽  
Juliana M. Juárez ◽  
Andrea R. Beltramone

Author(s):  
V.G. Shifrin ◽  
◽  
N.V. Limarenko ◽  
D.V. Trinz ◽  
D.S. Inozemtsev ◽  
...  

This article discusses the problems of the influence of electromagnetic compatibility (EMC) violations of electrical and electronic devices on the surrounding ecosystems. The analysis is carried out and the classification of EMC violations is given, the causes of the compatibility violation are examined, and the economic losses and the negative environmental impact, as a consequence of the considered violations, are analyzed. A classification and generalization of methods to minimize the negative consequences of EMC violations was carried out, criteria for reducing economic losses were considered, methods for preventing and preventing EMC violations of various power and electronic devices were classified. The methods of monitoring the compatibility of devices are considered and recommendations are given for observing the necessary safety and control requirements.


2020 ◽  
Vol 10 (2) ◽  
pp. 70-81
Author(s):  
Santiago Pedro Cabrera ◽  
Yolanda Guadalupe Aranda-Jiménez ◽  
Edgardo Jonathan Suárez-Domínguez ◽  
Rodolfo Rotondaro

This work presents the evaluation of the environmental impact and compressive strength of Compressed Earth Blocks (CEB) stabilized with hydrated aerial lime and Portland cement. For this, 12 series of blocks stabilized with different proportions of lime and cement were manufactured and the Life Cycle Analysis (LCA) methodology was used. After conducting these assays and simulations, it could be concluded that, using earth and sand typical of the city of Santa Fe (Argentina), stabilized with certain percentages of Portland cement between 5 and 10% in weight, CEB can be produced with sufficient levels of strength for them to be used in load-bearing walls, in this way minimizing the negative environmental impact associated with their manufacturing. It is also concluded that the stabilization with aerial lime does not increase the CEB’s compressive strength and, on the contrary, significantly increases their negative impact on the environment.


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