Experimental Investigation of Mechanical Behavior of Carbon-Nanotube Reinforced Cement Mortar

2011 ◽  
Vol 142 ◽  
pp. 217-220
Author(s):  
Li Wu Chang ◽  
Jin Chao Yue ◽  
Yu Zhou Sun

In this study, effective dispersion of different amount of multiwall carbon nanotubes was achieved using a surfactant and in combination with the use of ultrasonic energy. The effects of surfactant and surfactant concentration on the plain cement mortar were investigated. Moreover, the mechanical behaviors of the carbon-nanotube reinforced composites were also analyzed. Experimental results indicate that the application of ultrasonic energy is absolutely necessary to produce a satisfactory dispersion of MWCNTs, and there exists an optimum weight ratio of surfactant to MWCNTs. It is found that the proper dispersion of MWCNTs can remarkably improve the flexural strength, compressive strength, and the toughness of the cement mortar composites.

2020 ◽  
Vol 9 (1) ◽  
pp. 1445-1455
Author(s):  
Song Gao ◽  
Jianlin Luo ◽  
Jigang Zhang ◽  
Fei Teng ◽  
Chao Liu ◽  
...  

Abstract Water and sand were used as the medium of multiwall carbon nanotube (MCNT) and prepared MCNT aqueous suspension and MCNT suspension-coated sand, respectively; afterwards, they were introduced into cement mortar (MNT/CM, MNTSM), respectively. Next, mechanical strengths and piezoresistive properties (DC resistivities (ρ v), AC impedances (Z r)) under cyclic loadings (σ c) of two types of MNT/CM and MNTSM nanocomposites were investigated to explore the intrinsic and self-sensing behaviors. Results reveal that MCNT can be evenly and well-coated on sand, which favors to achieve its intrinsic self-sensing property. Although the fraction changes in ρ v and Z r under the same σ c of MNTSM are both lower than those of MNT/CM, the stress sensitivity of MNTSM is only −1.16%/MPa (DC resistivity), −1.55%/MPa (AC impedance); its sensing linearity and stability (2.53, 2.45%; 2.73, 2.67%) are superior to those of MNT/CM (4.94, 2.57%; 3.78, 2.96%). Piezoresistivity using AC impedance technique is helpful to acquire balanced sensing sensitivity and stability while applied as intrinsic sensors in infrastructure.


2007 ◽  
Vol 85 (10) ◽  
pp. 645-650 ◽  
Author(s):  
Maoqi Feng ◽  
Richard J Puddephatt

Chemical vapor deposition (CVD) of Ni, Pd, and Pt films and of Ni/Pd and Pd/Pt bimetallic films on multiwall carbon nanotubes (MWCNTs) can be effected at low temperature if the nanotubes are pretreated by CVD of titanium carbide. In the absence of the pretreatment, the CVD leads to formation of isolated nanoparticles of the nickel-group metals. The metallized MWCNTs are curved or kinked, as a result of the interaction with the metal. Preliminary oxidation of the carbon nanotubes allows easier metallization, and the bending of the metallated nanotubes is not observed in this case.Key words: Chemical vapor deposition, platinum, palladium, nickel, carbon, nanotube.


2013 ◽  
Vol 737 ◽  
pp. 183-190 ◽  
Author(s):  
Anne Zulfia ◽  
Sutopo ◽  
Bangkit Indriyana ◽  
M.E. Albar ◽  
S. Rohman

Polypropylene can be improved an electrical conductivity by addition of carbon and multiwall carbon nanotube (MWCNT) as well as combination with copper (Cu) powder. Multiwall carbon nanotube used from 0.1 wt%, 0.5 wt% to 1 wt% while the addition of Cu powder into PP/C was various from 0.1 wt%, 0.2wt% to 0.5wt% respectively. This research focuses on material design of composite based on polymer and carbon to improve an electrical conductivity according to electrical conductivity requirement for bipolar plate. Bipolar plate is one of the components in PEMFC constituted a crucial component that collects and transfers electron from the anode to the cathode, therefore it should possess high electrical conductivity. The main discussion in this research is to analyze the role of multiwall carbon nano tube (MWCNT) and copper on electrical conductivity of polymer composites produced. Functional groups analysis using Fourier Transform Infrared Spectroscopy (FTIR) was also carried out to investigate whether carbon has been mixed perfectly within polypropylene. It is found that the effect of adding a small amount of MWCNT and Cu have improved their electrical conductivity of composites up to 15.62 S/cm.


Author(s):  
Leila Samandari-Masouleh ◽  
Navid Mostoufi ◽  
AA Khodadadi ◽  
Y. Mortazavi ◽  
Morteza Maghrebi

Abstract A kinetic modeling of longitudinal and depth profiles of multiwall carbon nanotubes (MWCNTs) synthesis using xylene and ferrocene in a floating catalyst (FC) reactor is hereby reported. Both amorphous and arrays of carbon nanotubes (CNTs) are formed, whose ratio sharply increases along a growth window and from the bottom to top of the arrays. A model is presented for the rate of CNTs synthesis as well as the rate of amorphous carbon formation which undesirably forms on the nanotube walls and reduces nanotubes quality and synthesis efficiency. Based on the amounts of amorphous carbons and CNTs formed in the reactor, kinetic parameters of formation of these species from xylene were estimated. It is shown that, as the temperature increases, the weight ratio of amorphous carbon to CNTs shows minimum at 970 K. The ratio increases with decreasing the amount of deposited iron. Increasing pressure and carrier gas is found to have marginal effects on producing CNTs with lower amounts of amorphous carbon. Higher surface density of CNTs (number of CNTs per surface area) and their diameter, result in a significantly higher amount of amorphous carbon deposition.


2008 ◽  
Vol 61 ◽  
pp. 65-74 ◽  
Author(s):  
Tissaphern Mirfakhrai ◽  
Ji Young Oh ◽  
Mikhail Kozlov ◽  
Shao Li Fang ◽  
Mei Zhang ◽  
...  

Carbon nanotubes have attracted extensive attention in the past few years because of their appealing mechanical and electronic properties. Yarns made through spinning multiwall carbon nanotubes (MWNTs) have been reported. Here we study the application of these yarns as electrochemical actuators, and as force sensors. MWNT yarns are mechanically strong with tensile strengths reaching one GPa. When charge is stored in the yarns they change in length. This is thought to be because of a combination of electrostatic and quantum chemical effects. We report strains up to 0.6 %. The charged yarns can also generate current and change in voltage in response to a change in the applied tension. Electrostatic and quantum effects contributing to actuation are introduced along with the effect of the yarn geometry on actuation and other contributing factors.


2016 ◽  
Vol 53 (2) ◽  
pp. 215-230 ◽  
Author(s):  
JJ Espadas-Escalante ◽  
F Avilés ◽  
PI Gonzalez-Chi ◽  
AI Oliva

The thermal conductivity and fire response of multiwall carbon nanotube/polyurethane foam composites are investigated for ∼45 kg/m3 foams with multiwall carbon nanotube concentrations of 0.1, 1, and 2 wt.%. The thermal conductivity of such nanocomposites shows a modest increase with increased multiwall carbon nanotube content, which is explained by a high value of interfacial thermal resistance, as predicted by existent thermal models. A strong correlation between multiwall carbon nanotube content, foam’s cellular morphology, and fire behavior was observed. The flame propagation speed increases with the addition of 0.1 wt.% multiwall carbon nanotubes and then reduces as the multiwall carbon nanotube content increases. The mass lost after flame extinction reduces with the addition of multiwall carbon nanotubes, suggesting an increased resistance to flame attack due the multiwall carbon nanotube presence.


2013 ◽  
Vol 740 ◽  
pp. 449-454
Author(s):  
Ping Li ◽  
Low Aik Seng ◽  
Jin Lin ◽  
Yin Xi Jiang ◽  
Ong Guat Choon

Dispersion stability of carbon nanotubes (CNTs) is a challenging issue in the preparation of nanocomposites. This paper reports the enhancement of dispersion stability of multiwall carbon nanotubes (MWCNTs) in four solvents using two surfactants and four polymeric dispersants. The dispersion stability of MWCNTs, in term of Instability Index, was characterized by an accelerated stability analyser. The two polymeric dispersants with ionic anchoring groups and solvent-compatible chains showed the best dispersion stability as they provide polar anchoring and steric barrier which enhance the dispersion stabilisation of MWCNTs in various solvents.


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