Analysis of Phosphogypsum’s Physical and Chemical Properties and Making of Anhydrite Cement from Phosphogypsum

2013 ◽  
Vol 275-277 ◽  
pp. 2131-2135 ◽  
Author(s):  
Jie Zhou ◽  
Lin Yang ◽  
Qian Lin ◽  
Jian Xin Cao

The phosphogypsum (PG) sample produced as the waste of the phosphoric acid fertilizer plant from Guizhou, China was studied for its properties and as a material for anhydrite cement. The impurity content, type and distribution, as well as thermal behavior and solubility of the PG were carefully studied by XRD, DTA techniques and gravimetric determination. The China Standard GB175-2007. The mineralogical studies were physical properties of the sample were studied as per the determined by XRD. The results showed that the impurities of PG are mainly water-soluble P2O5, F, organics and P2O5 and F in the gypsum lattice which has entered in to solid solution with gypsum as well as the insoluble Ca3(PO4)2 and CaF2. Experimental datum showed that a suitable anhydrite can be produced by heating PG at 1000 °C and PG up to 60% used can be as a main raw material in production of anhydrite cement.

2018 ◽  
Vol 74 (1-2) ◽  
pp. 25-33 ◽  
Author(s):  
Zahid Iqbal ◽  
Muhammad Ishaq ◽  
Adnan Aslam ◽  
Wei Gao

AbstractPrevious studies show that certain physical and chemical properties of chemical compounds are closely related with their molecular structure. As a theoretical basis, it provides a new way of thinking by analyzing the molecular structure of the compounds to understand their physical and chemical properties. The molecular topological indices are numerical invariants of a molecular graph and are useful to predict their bioactivity. Among these topological indices, the eccentric-connectivity index has a prominent place, because of its high degree of predictability of pharmaceutical properties. In this article, we compute the closed formulae of eccentric-connectivity–based indices and its corresponding polynomial for water-soluble perylenediimides-cored polyglycerol dendrimers. Furthermore, the edge version of eccentric-connectivity index for a new class of dendrimers is determined. The conclusions we obtained in this article illustrate the promising application prospects in the field of bioinformatics and nanomaterial engineering.


2018 ◽  
Vol 70 (2) ◽  
pp. 385-392 ◽  
Author(s):  
Hui Cen ◽  
Ardian Morina ◽  
Anne Neville

Purpose Ageing has been known to affect the performance of lubricants. However, there is a lot of debate as to whether ageing is beneficial or detrimental to the wear performance of lubricants. Design/methodology/approach The purpose of this research is to evaluate the effect of ageing on the viscosity, total acid number and Fourier-transform infrared spectroscopy information of a series of lubricants. The tribological performance (friction and wear) of the aged lubricants is also studied, followed by X-ray photoelectron spectroscopy analysis on the selected post-test samples to study the tribochemical features of the tribofilm. Findings The results show that ageing has a different impact on lubricants and tribological performances based on the physical and chemical properties. Originality/value These findings will be compared with the research on the role of water in lubricant ageing (Part II of this study).


2020 ◽  
Vol 21 (20) ◽  
pp. 7577
Author(s):  
Noriyuki Uchida ◽  
Takahiro Muraoka

Peptide-based fibrous supramolecular assemblies represent an emerging class of biomaterials that can realize various bioactivities and structures. Recently, a variety of peptide fibers with attractive functions have been designed together with the discovery of many peptide-based self-assembly units. Cross-linking of the peptide fibers is a key strategy to improve the functions of these materials. The cross-linking of peptide fibers forming three-dimensional networks in a dispersion can lead to changes in physical and chemical properties. Hydrogelation is a typical change caused by cross-linking, which makes it applicable to biomaterials such as cell scaffold materials. Cross-linking methods, which have been conventionally developed using water-soluble covalent polymers, are also useful in supramolecular peptide fibers. In the case of peptide fibers, unique cross-linking strategies can be designed by taking advantage of the functions of amino acids. This review focuses on the current progress in the design of cross-linked peptide fibers and their applications.


Author(s):  
Juliany Barbosa de Pinho ◽  
Aloisio Bianchini ◽  
Pedro Silvério Xavier Pereira ◽  
Letycia Cunha Nunes ◽  
Rodrigo Fernandes Daros ◽  
...  

From the pyrolysis process, biochar is a carbon rich and recalcitrant organic material with potential for long term carbon sequestration because of its aromatic structure. However, the physical and chemical properties of the biochar vary due to the diversity of raw material and the conditions of production. The present study aimed to evaluate the biochar from the sugarcane bagasse at different temperatures and under two conditions of pyrolysis. The biochar was produced at two final temperatures 200°C (1 hour); 250°C (1h) and 250°C (2h), with pyrolysis of an oxidizing and non-oxidizing atmosphere for both. PH, cation exchange capacity (CTC), carbon content (C), Nitrogen (N), hydrogen (H), H:C, C:N and ash ratios were evaluated. The contents of C, H, N and the atomic ratios H:C and C:N were higher in Biochar produced in a non-oxidizing atmosphere (BNO). However, the content of ash, pH and CTC were higher in Biochar produced in oxidizing atmospheres (BO). One can conclude the direct influence of the pyrolysis condition.


In article the possibility of receiving the metallized concentrates from ferriferous ores with the low content of iron, for the purpose of preparation them to metallurgical processing is considered. It is shown that the following factors have significant effect on effectiveness of process of receiving the metallized concentrates: composition of ore, physical and chemical properties of ore, possibility of receiving pellets, type and consumption of reducer, etc.


1938 ◽  
Vol 16b (2) ◽  
pp. 46-53 ◽  
Author(s):  
Blythe Alfred Eagles ◽  
Olga Okulitch ◽  
Arthur Stephen Kadzielawa

The influence of three distinct activators prepared from tomatoes, yeast, or liver, on the metabolism of two species of lactic acid bacteria has been studied. One of these activators is Bios II A, and the other two have been shown to be components constituting Bios II B. On the basis of their physical and chemical properties, it is suggested that the growth stimulants required by the lactic acid bacteria are identical with certain of the heat-stable accessory food factors of the Vitamin-B complex essential for the growth of animals.


Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4212 ◽  
Author(s):  
Sergey Reshetnikov ◽  
Irina Kurzina ◽  
Alesia Livanova ◽  
Eugene Meshcheryakov ◽  
Lyubov Isupova

The effect of alkali metal (Li, Na, K) incorporation on the morphology and water vapor uptake properties of mesoporous Al2O3 has been studied. The modification of the raw material, pseudoboehmite, represented a mixture of low-temperature phases (γ + η + χ)-Al2O3, and has been done at low-temperature that does not change the phase ratio. A decrease in specific surface values and an average pores size increase were observed as a result of the introduction of metal cations by impregnation and subsequent thermal treatment. The influence of the content of the modifying metal on the adsorption ability of the obtained samples in relation to water vapours has been studied. It has been established that alkaline modification Al2O3 with the lithium cations did not result in adsorption ability improvement, whereas samples that were modified with sodium or potassium in the amount of 1.2 weight % and 2.6 weight %, respectively, possess a higher equilibrium capacity (by ~40%), as compared to that of the initial sample (Al2O3), and a sufficiently high adsorption rate.


2019 ◽  
Vol 2019 ◽  
pp. 1-12 ◽  
Author(s):  
F. Anguebes-Franseschi ◽  
A. Bassam ◽  
M. Abatal ◽  
O. May Tzuc ◽  
C. Aguilar-Ucán ◽  
...  

Amazon sailfin catfish (Pterygoplichthys pardalis) is considered one of the greatest threats to the biodiversity of continental aquatic systems, causing serious economic and environmental problems in the regions. In this work, the production of biodiesel from Amazon sailfin catfish biomass oil is studied. The physical and chemical properties of biofuel produced were evaluated under the specifications of the European standard EN-14214 by using gas chromatography-mass spectrometry, infrared spectroscopy, and atomic absorption spectrometry analyses. The results show that the biodiesel complies with all the specifications of the standard, except the content of polyunsaturated methyl esters. The yields obtained from oil and biodiesel were 9.67 and 90.71% (m/m), respectively. The methyl ester concentrations study identified 17 components where 47.003% m/m corresponded to methyl esters with saturated chains, whereas 34.394% m/m was attributed to monosaturated methyl esters and the remaining (18.624% m/m) to polysaturated methyl esters. Finally, mineral analysis by atomic absorption showed the absence of heavy metals Cd, Ni, and Pb, as well as low concentrations of Ni, Fe, Cu, and Zn, demonstrating that the quality of the fuel is not compromised. The study indicates the feasibility of manufacturing biodiesel using Amazon sailfin catfish biomass oil as a low-cost raw material. It represents an environmental option to mitigate a global problem of atmospheric pollution, and at the same time, it shows a commercial alternative to reduce the ecological impact caused by this fish in the diverse ecosystems to which it has spread. In addition, the great adaptability of this fish provides the possibility of a profitable process to have very high rates of reproduction and growth, allowing the generation of large amounts of biomass for the production of biodiesel.


2017 ◽  
Vol 5 (28) ◽  
pp. 5608-5615 ◽  
Author(s):  
Jianqiao Zhang ◽  
Chen Cai ◽  
Shumaila Razzaque ◽  
Irshad Hussain ◽  
Qun-Wei Lu ◽  
...  

Gold nanoclusters are used as excellent scaffolds for the development of chemical and biological sensors due to their outstanding physical and chemical properties.


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