Research on the Scale Inhibition Performance of AA/SAS Binary Polymer

2013 ◽  
Vol 448-453 ◽  
pp. 3949-3953
Author(s):  
Shan Fa Tang ◽  
Hui Liao ◽  
Lei Tian ◽  
Xiao Jie Wang ◽  
Xiao Yang Lei ◽  
...  

The binary polymer AA/SAS was synthesized by acrylic acid (AA) and sodium allylsulfonate (SAS), named as AS and its structure was characterized. Its scale inhibition performance was also investigated for single CaCO3, CaSO4 scales, and composite scales in simulated formation water containing Ca2+, Mg2+, Ba2+ and Sr2+. The results indicate that when adding 50mg/L of the inhibitor, it is 85.05% efficient for CaCO3 inhibition and 98.85% for CaSO4, but only 49.05% and 51.58% for BaSO4 and SrSO4 separately. The scale inhibition performance is obvious in the simulated formation water with high concentration of calcium (1300mg/L) and low barium ion (100mg/L ), the inhibition efficiency are both above 85% at a dosage of 80mg/L. And it can fairly satisfy the demand of inhibiting composite scales (CaCO3 scale, CaSO4 scale, BaSO4 scale and SrSO4 scale), when AS and CT was combined at a mass ratio of 2:1 in high calcium , barium and strontium ions contained formation water, being 95.3% efficient at the dosage of 100mg/L.

2012 ◽  
Vol 554-556 ◽  
pp. 223-226 ◽  
Author(s):  
Shan Fa Tang ◽  
Wei Zou ◽  
Yu Juan Xiong ◽  
Xue Yang ◽  
Lei Tian

The terpolymer was synthesized by maleic anhydride (MA), acrylic acid (AA) and methyl acrylate (MAC) and the structure was also conformed. Its scale inhibition effect was also studied in high barium and strontium ion concentration aqueous medium and simulated formation water (Ca2+, Mg2+, Ba2+, Si2+) condition. The results indicate that when additive amount of AA/MAC/MA is 60 mg/L, the inhibition rate is up to 100% and 80% for BaSO4 scale and SrSO4 scale respectively, but only 50% for calcium scale. And the scale inhibition rate moderately increases with the dosage increasing. The scale inhibition effect of AA/MAC/MA is also very obvious in simulated formation water containing low calcium ions (400 mg/L) and high barium ions (500 mg/L) as well as strontium ions (500 mg/L). It can satisfy the need of restraining composite scale (BaSO4 scale and SrSO4 scale as well as CaSO4 scale) in high calcium and barium strontium ion aqueous medium when compounded with calcium scale inhibitors CY and CX respectively.


2015 ◽  
Vol 814 ◽  
pp. 278-285
Author(s):  
Ming Zhu ◽  
Cheng Qiang Ren ◽  
Yuan Yuan Meng ◽  
Li Liu ◽  
Yun Ping Zheng

The deposition of BaSO4scale is always found in the oilfield. It is difficult to be removed. Therefore, it plays a negative role to the production. The effects of temperature and water chemistry on BaSO4scale have been investigated by using the conductivity method in this work. An environment-friendly copolymer was prepared to control the scaling of BaSO4. The copolymer was proved by static scale inhibition method, and weight-loss test that it has excellent scale inhibition performance and corrosion inhibition efficiency. Furthermore, FTIR spectra was used to prove that the scale inhibitor was polyepoxysuccinic acid (PESA).


2012 ◽  
Vol 535-537 ◽  
pp. 1180-1184
Author(s):  
Mao Dong Li ◽  
Bin Zeng ◽  
Lin Yang ◽  
Jun Ming Zhao ◽  
Yu Hui Du ◽  
...  

The static scale inhibition method will be used to evaluate the scale inhibition performance of HEDP. In order to study the corrosion inhibition of 20A steel with additive of HEDP in the industrial boiler water medium,the total iron ions in the solution are determined through autoclave static experiments. The results indicated that the scale inhibition efficiency,in the simulation boiler water with a certain concentration ratio and temperature,reached the maximum when CHEDP is 7 mg/L. It has a good corrosion inhibition effect on the 20A steel when the HEDP concentration exceeds 15ppm.


2011 ◽  
Vol 311-313 ◽  
pp. 1097-1101
Author(s):  
Qiang Ke ◽  
Fa Shu Liang

In response to the serious barium / strontium – scale in oilfields, we simulated oilfield conditions and investigated the scale inhibition performance of several common scale inhibitors to barium and strontium, by following the protocol from Evaluation Methods of Anti-Scale Agent for Oilfield Use, Petroleum Gas Standards of People’s Republic of China SY/T 5673. The most effective scale inhibitor CD-1 was screened out. With CD-1 as barium / strontium scale inhibitor in the static anti-scale analytical experiments, the dependence of scale inhibition performance on scale inhibitor concentration, saltiness, temperature, time and the system pH was investigated. The application conditions of barium / strontium scale inhibitor in real petroleum and gas field was obtained. Under the optimized application conditions, the mixture scale inhibitor had better scale inhibition efficiency than CD-1 alone.


2017 ◽  
Vol 70 (8) ◽  
pp. 933 ◽  
Author(s):  
Mingjin Tang ◽  
Jianbo Li ◽  
Zhengrong Ye ◽  
Zimin Kou ◽  
Luoping Fu

A polymer, β-MEA, was synthesised from β-cyclodextrin (β-CD), 3-chloro-2-methylpropene (MAC), epoxysuccinic acid (ESA), and 2-acrylamido-2-methyl propane sulfonic acid (AMPS) with a (NH4)2S2O8-NaHSO3 redox initiator system by aqueous solution radical polymerisation. β-MEA was characterised by means of IR spectroscopy, time-of-flight mass spectrometry, gel permeation chromatography, and thermogravimetric analysis. Its structure, molecular weight, thermal stability, scale and corrosion inhibition performance and mechanism were investigated. The results verified that β-MEA achieves a better scale inhibition efficiency for BaSO4 compared with poly(aspartic acid) (PASP) (100 % cf. 94.9 % at a concentration of 20 mg L−1) and a better corrosion inhibition efficiency of N80 carbon steel in saline water compared with PESA (91.2 % cf. 79.7 % at a concentration of 1 g L−1). The BaSO4 was characterised by scanning electron microscopy (SEM) and X-ray diffraction to investigate the crystal morphology of the scale. Primary research on the mechanism for corrosion inhibition was carried by SEM-chemical analysis.


2021 ◽  
Author(s):  
Zhiwei David Yue ◽  
Andrew Slocum ◽  
Xiaohong Lucy Tian ◽  
Linping Ke ◽  
Megan Westerman ◽  
...  

Abstract After fracturing, it is common practice to leave offshore wells shut-in from days to weeks for operational purposes. During the recent historic decline of demand for global crude, a trend has been witnessed to shut in even newly fractured wells under design for an extended period. The cause of these extended shut-ins can be attributed to various factors including operational logistics as well as economic factors. The shut-in extension brings some unique scaling challenges for well designs. In this paper, an integrated scale inhibitor (SI)/fracturing fluid package is presented with detailed laboratory prerequisites data to validate its efficacy for long-term scale protection during the extended shut-in. Utilizing seawater in offshore fracturing can provide significant cost savings to an operation. Unfortunately, in regions with barium-rich formations, the use of seawater brings tremendous barite scaling risk. In order to solve this challenge, the investigation focused on the selection of the most effective inhibitors for long-term barite inhibition under the simulated reservoir conditions. Along with the scale inhibitor selection, the crosslinked gel had to be carefully optimized to eliminate any potential negative interference the gel additives could impart to the performance of the inhibitor. Furthermore, the inhibitor was tested in the crosslinking system to meet optimum rheology requirements. Utilizing the broken gel containing the designed inhibitor package, barite precipitation could be prevented for months under the simulated testing conditions. Due to high levels of sulfate from seawater and the barium originating from the formation, barite scale formed immediately upon mixing of the two types of water in absence of the appropriate scale inhibitors. Solid scale products featuring slow releasing of the inhibitor ingredients was proven insufficient for this application. With extensive laboratory screening, the candidate chemistry demonstrated great brine-calcium tolerance, superior scale inhibition performance for both sulfate and carbonate scales, and the minimum interferences for the crosslinking engineering to meet necessary proppant carrying capacity. To mimic the gel-breaking process and heterogeneous bleeding from the formation water, the inhibitor was crosslinked with the gel at various loading rates (1 gpt to 10 gpt) and broken at the elevated reservoir temperature, then mixed with the different ratios of the formation water. Reliable scale inhibition performance was achieved for an extended period of time for up to six weeks. Incorporating SI into the fracturing stimulation package is a convenient method for operators to include a scale-control program into well-defined fracturing designs with minimal adjustment and also add significant cost-saving for offshore logistics and rig time (Fitzgerald, et al., 2008). The scale inhibitor product presented in this paper shows a superior solution to protect assets from scale deposition for an extended shut-in period.


Crystals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 275
Author(s):  
Kun Sheng ◽  
Honghua Ge ◽  
Xin Huang ◽  
Yi Zhang ◽  
Yanfang Song ◽  
...  

The formation of CaCO3 crystals on the cathode surface and the scale-inhibition performance of scale inhibitor 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on the cathode surface were studied by methods of solution analysis, gravimetric analysis, SEM, FTIR, and XRD techniques. They were then compared with the results of the formation and suppression of CaCO3 crystals in aqueous solution. PBTCA had a good solution-scale-inhibition performance and good lattice-distortion effects on CaCO3 crystals in solution, which could change the CaCO3 from calcite to vaterite and aragonite crystals. The solution-scale-inhibition efficiency exceeded 97% when the PBTCA concentration reached 8 mg/L. Under cathodic polarization conditions, the surface-scale-inhibition efficiency of the cathode and solution-scale-inhibition efficiency near the cathode surface both exceed 97% at polarization potential of −1V. The addition of PBTCA significantly reduced the amount of CaCO3 crystals formed on the cathode surface and had good surface and solution-scale-inhibition effect. However, the lattice-distortion effect of PBTCA on CaCO3 crystals disappeared on the cathode surface, and the resulting CaCO3 contained only calcite crystals. The high-scale-inhibition effect of PBTCA under cathodic polarization was mainly due to the inhibition of the formation of calcium carbonate crystals by PBTCA, and not because of the lattice distortion of CaCO3 crystals.


2011 ◽  
Vol 361-363 ◽  
pp. 1982-1986 ◽  
Author(s):  
Li Jun Fu ◽  
Yu Zeng Zhao ◽  
Hong Hua Ge ◽  
Yong Sheng Li

An environment-friendly and multifunctional agent for industry circulation cooling water, polyaspartic acid derivatives with dihydroxyl group(DHPAP) was synthesized in aqueous solution. The FTIR spectrum of DHPAP was analyzed. Static experiments were carried out to validate scale inhibition performance of DHPAP. The scale inhibition ratios exceed 90% when 8 and 10 mg/L DHPAP under solution temperatures of 80 and 60°C, respectively. The scale inhibition ratios increase by increasing the DHPAP concentration with 6 and 8 mg/L under heating times of 10 and 6h, respectively. And the scale inhibition ratios are over 90%.


RSC Advances ◽  
2016 ◽  
Vol 6 (95) ◽  
pp. 92943-92952 ◽  
Author(s):  
Henghui Huang ◽  
Qi Yao ◽  
Hualin Chen ◽  
Bailing Liu

In order to improve the scale inhibition efficiency of existing scale inhibitors for industrial water and to reduce the phosphorus pollution of water bodies, a new type of scale inhibitor with a hyper-branched structure has been developed.


2018 ◽  
Vol 34 (4) ◽  
pp. 1749-1754
Author(s):  
ROLAND TOLULOPE LOTO. ◽  
BRYAN UCHE AYOZIE

Investigation of the corrosion inhibition properties of benzonitrile compound on the surface degradation of quenched 420 martensitic steel in 6 M H2SO4 was evaluated through the application of potentiodynamic polarization method, micro analytical study and ATR-FTIR spectroscopic analysis. Experimental data showed optimal inhibition performance of the compound with peak inhibition efficiency of 99.4% with mixed type inhibition but dominant anodic inhibition properties. The inhibiting compound significantly influenced the thermodynamic behaviour of the steel resulting in chemisorption adsorption mechanism onto steel surface in consonance with Langmuir and Freundlich adsorption models with correlation coefficients of 1 and 0.7570. The transmittance of identified functional groups of benzonitrile from ATR-FTIR spectroscopy decreased at extended wavelengths due to surface coverage and adsorption of the compound onto the steel.


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