The Technique of Recycling Alkaline Zincate Zinc Plating Waste Liquid in Laboratory

2014 ◽  
Vol 556-562 ◽  
pp. 580-583
Author(s):  
Da Yong Li ◽  
Lei Shi

It introduces a kind of technique method that recycling alkaline zincate zinc plating waste liquid in laboratory, involving the fields in electroplating and comprehensive utilization of waste liquid. This method is introduced that with adopting materials such as HCl, NaOH, H2O2, activated carbon, dithiocarbamate diethyl ester, chloroform, ammonia and baking furnace, incinerator, pH test paper, for treatment of the waste liquid through some processes like neutralization, filtration, chemistry precipitation, extraction, distillation, burning, so that some recycled substances in it can be reused such as distilled water, zinc oxide, and as to those can not be recycled, carry on the harmlessization handle by incineration or deep bury.

2014 ◽  
Vol 556-562 ◽  
pp. 290-293
Author(s):  
Lei Shi ◽  
Da Yong Li

It introduces a kind of technique method that recycling sylvite zinc plating waste liquid laboratory, involving the fields in electroplating and comprehensive utilization of waste liquid. It includes the following steps: first add hydrogen peroxide and activated carbon into waste liquid to remove the organic matter in it, and then reduce the solution’s temperature with refrigeration film, and filter out the solid contents. Add NaOH solid, NaHSO3 into the solution, through chemical reactions, precipitate the heavy metal element, and finally get distilled water through distillation. It can make the recycled materials be reused, such as distilled water, boric acid, etc., and as to nonrecyclables, such as heavy metal ions (Cu2+, Cr3+), bury them deep that disposing harmless.


2021 ◽  
Vol 16 (1) ◽  
pp. 136-147
Author(s):  
Allwar Allwar ◽  
Asih Setyani ◽  
Ulul Sugesti ◽  
Khusna Afifah Fauzani

Oil palm shell was used as a precursor for preparation of activated carbon using different chemical activations (potassium hydroxide (KOH), zinc chloride (ZNCl2), and phosphoric acid (H3PO4)). Each activated carbons (AC) was mixed with nano-zinc oxide to form a composite. From the gas sorption analyzer, it is showed that nitrogen adsorption isotherms show Type II for ZnO/AC-KOH and ZnO/AC-ZnCl2 corresponding to the micro- and mesoporous structures, respectively. However, the nitrogen adsorption isotherm of ZnO/AC-H3PO4 exhibits the Type I with predominantly microporous structures. The SEM micrographs produced unsmooth surface and different pore sizes. The XRD patterns at 2θ of 25.06° and 26.75° were come from amorphous activated carbon. The peak intensity of ZnO was weak due to low concentration of zinc precursor. However, the ZnO of ZnO/AC-ZnCl2 showed strongly peak intensity. The effectiveness of the composites was examined for phenol removal determined by UV-Vis Spectrophotometer method. The equilibrium adsorption follows the Langmuir and Freundlich models according to the best correlation coefficient (R2). The kinetic model was only obtained for the pseudo-second-order with the best linearity of the correlation coefficient (R2). The results of this study showed that the oil palm shell has a great potential for ZnO/AC with excellent adsorptive property. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 


Jurnal Kimia ◽  
2016 ◽  
Author(s):  
Ni Putu Diantariani ◽  
Iryanti Eka Suprihatin ◽  
Ida Ayu Gede Widihati

Research on  photodegradation of textile dyes  of methylene blue (MB) and congo red (CR) using ZnO-Activated Carbon composite and ultraviolet (UV) light has been done. This research included synthesis zinc oxide (ZnO), synthesis ZnO-Activated Carbon, and the application of composite to degrade textile dyes of MB and CR. In this research studied the effect of pH, concentration and time of UV radiation  towards photodegradation percentages  of dyes. Then it determined the rate and the effectivity of photodegradation of MB and CR dyes using ZnO-Activated Carbon composite. The result showed that  photodegradation of MB reach optimal condition at pH 11 with radiation time 4 hour, whereas CR is at pH 5 with the same radiation time. The more initial concentration of MB and CR applicated, the lower of photodegradation percentages. Constanta of photodegradation rate of MB and CR dyes using ZnO-Activated Carbon composite are 0.8316 and 1.4938 hour-1 respectively. ZnO-Activated Carbon composite as a photocatalyst can degrade effectively MB and CR dyes with photodegradation percentages of 99.40±0.23 % and 99.61±0.24% respectively.


Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5667
Author(s):  
Priyanka Shrestha ◽  
Manoj Kumar Jha ◽  
Jeevan Ghimire ◽  
Agni Raj Koirala ◽  
Rajeshwar Man Shrestha ◽  
...  

Zinc oxide (ZnO) nanorods incorporated activated carbon (AC) composite photocatalyst was synthesized using a hydrothermal process. The AC was prepared from lapsi (Choerospondias axillaris) seed stone, an agricultural waste product, found in Nepal by the chemical activation method. An aqueous suspension of AC with ZnO precursor was subjected to the hydrothermal treatment at 140 °C for 2 h to decorate ZnO rods into the surface of AC. As-obtained ZnO nanorods decorated activated carbon (ZnO/AC) photocatalyst was characterized by various techniques, such as scanning electron microscopy (SEM), X-ray diffraction (XRD), and photoluminescence (PL) spectroscopy. Results showed that highly crystalline hexagonal ZnO nanorods were effectively grown on the surface of porous AC. The photocatalytic property of the as-prepared ZnO/AC composite was studied by degrading methylene blue (MB) dye under UV-light irradiation. The ZnO/AC composite showed better photocatalytic property than that of the pristine ZnO nanorods. The enhanced photocatalytic performance in the case of the ZnO/AC composite is attributed to the combined effects of ZnO nanorods and AC.


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