Synthesis and Dielectric Behavior of a New Two-Phase Percolative BaTiO3-Cu/Polyimide Composite

2014 ◽  
Vol 670-671 ◽  
pp. 263-266
Author(s):  
Zhi Long Pan ◽  
Jia Ting Chen ◽  
Shi Liang Ao ◽  
Jian Ping Jia
Keyword(s):  
Dielectric Properties ◽  
Dielectric Loss ◽  
Copper Nanoparticles ◽  
Chemical Reduction ◽  
Ferroelectric Material ◽  
Dielectric Behavior ◽  
Two Phase ◽  
Low Dielectric ◽  
Three Phase ◽  
Effective Dielectric Permittivity

The chemical reduction method was used to deposit copper nanoparticles (about 20nm) on the surface of the barium titanate (BT, r=50nm). Then the dielectric properties and the mechanism of BaTiO3-Cu/polyimide composite were studied. The results showed that the effective dielectric permittivity of the composite with 60 wt% of BT-Cu (less than 13.00 wt% of copper) fillers was greater than 120, and the dielectric loss of which was lower than 0.025. Due to very low dielectric loss, so this composite was a two-phase composite material, different from the three-phase composite (metal-ceramics-poly). It was concluded that copper nanoparticles were deposited on the surface of the BT nanoparticles by chemical bond. Owing to good dielectric properties of as-prepared composite, such new two-phase composites had a potential to become the most important ferroelectric material.

Photosensitive Polyimide having low loss tangent for RF application

2018 ◽  
Vol 2018 (1) ◽  
pp. 000476-000482 ◽  
Author(s):  
Masao Tomikawa ◽  
Hitoshi Araki ◽  
Yohei Kiuchi ◽  
Akira Shimada
Keyword(s):  
Molecular Structure ◽  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
High Frequency ◽  
Low Dielectric Constant ◽  
Low Loss ◽  
Elongation At Break ◽  
Low Dielectric ◽  
The Poor

Abstract Progress of 5G telecommunication and mm radar for autopilot, high frequency operation is required. Insulator materials having low loss at high frequency is desired for the applications. We designed the low dielectric constant, and low dielectric loss materials examined molecular structure of the polyimide and found that permittivity 2.6 at 20GHz, dielectric loss 0.002. Furthermore, in consideration of mechanical properties such as the toughness and adhesion to copper from a point of practical use. Dielectric properties largely turned worse when giving photosensitivity. To overcome the poor dielectric properties, we designed the photosensitive system. After all, we successfully obtained 3.5 of dielectric constant and 0.004 of dielectric loss, and 100% of elongation at break. In addition, we offered a B stage sheet as well as varnish. These materials are applicable to re-distribution layer of FO-WLP, Interposer and other RF applications for microelectronics.

An in situ (K0.5Na0.5)NbO3-doped barium titanate foam framework and its cyanate ester resin composites with temperature-stable dielectric properties and low dielectric loss

2019 ◽  
Vol 3 (4) ◽  
pp. 726-736 ◽  
Author(s):  
Longhui Zheng ◽  
Li Yuan ◽  
Guozheng Liang ◽  
Aijuan Gu
Keyword(s):  
Dielectric Properties ◽  
Dielectric Loss ◽  
Barium Titanate ◽  
Cyanate Ester ◽  
Resin Composites ◽  
Cyanate Ester Resin ◽  
Low Dielectric ◽  
Doped Barium Titanate

High-k composites with temperature-stable dielectric properties and low dielectric loss obtained through building a network with in situ-doped barium titanate foam.

scholarly journals High-performance colossal permittivity materials of (Nb + Er) co-doped TiO2 for large capacitors and high-energy-density storage devices

2016 ◽  
Vol 18 (35) ◽  
pp. 24270-24277 ◽  
Author(s):  
Mei-Yan Tse ◽  
Xianhua Wei ◽  
Jianhua Hao
Keyword(s):  
Dielectric Properties ◽  
Dielectric Loss ◽  
High Performance ◽  
High Energy ◽  
High Energy Density ◽  
Secondary Phases ◽  
Storage Devices ◽  
Low Dielectric ◽  
Colossal Permittivity ◽  
Co Doped

Our work shows contributions to the high-performance dielectric properties, including a CP of up to 104–105 and a low dielectric loss down to 0.03 in (Er0.5Nb0.5)xTi1−xO2 materials with secondary phases.

A versatile foaming platform to fabricate polymer/carbon composites with high dielectric permittivity and ultra-low dielectric loss

2019 ◽  
Vol 7 (1) ◽  
pp. 133-140 ◽  
Author(s):  
Biao Zhao ◽  
Mahdi Hamidinejad ◽  
Chongxiang Zhao ◽  
Ruosong Li ◽  
Sai Wang ◽  
...  
Keyword(s):  
Dielectric Properties ◽  
Dielectric Loss ◽  
Dielectric Permittivity ◽  
Carbon Composite ◽  
Carbon Composites ◽  
Low Dielectric ◽  
Composite Foams ◽  
High Dielectric Permittivity ◽  
High Dielectric

A microcellular structure can effectively tune the dielectric properties of PVDF/carbon composite foams.

Dielectric Behavior of CaCu3Ti4O12–Polyethylene Composites with a Low Dielectric Loss

2017 ◽  
Vol 41 (1) ◽  
pp. 7-16
Author(s):  
Mukhlis M. Ismail ◽  
Balkees Aldabbagh ◽  
Logean Q. Ibrhium ◽  
Z. Cheng ◽  
Lin Zhang
Keyword(s):  
Dielectric Loss ◽  
Dielectric Behavior ◽  
Low Dielectric ◽  
Polyethylene Composites

scholarly journals Effect of TeO2 addition on the dielectric properties of CaCu3Ti4O12 ceramics derived from the oxalate precursor route

2013 ◽  
Vol 03 (04) ◽  
pp. 1350028 ◽  
Author(s):  
P. Thomas ◽  
K. B. R. Varma
Keyword(s):  
Dielectric Properties ◽  
Dielectric Loss ◽  
Room Temperature ◽  
X Ray Diffraction ◽  
Oxalate Precursor ◽  
X Ray ◽  
Practical Applications ◽  
Low Dielectric ◽  
Precursor Route ◽  
Tan Δ

CaCu 3 Ti 4 O 12 (CCTO) ceramics which has perovskite structure gained considerable attention due to its giant permittivity. But it has high tan δ (0.1 at 1 kHz) at room temperature, which needs to be minimized to the level of practical applications. Hence, TeO 2 which is a good glass former has been deliberately added to CCTO nanoceramic (derived from the oxalate precursor route) to explore the possibility of reducing the dielectric loss while maintaining the high permittivity. The structural, morphological and dielectric properties of the pure CCTO and TeO 2 added ceramics were studied using X-ray diffraction, Scanning Electron Microscope along with Energy Dispersive X-ray Analysis (EDX), spectroscopy and Impedance analyzer. For the 2.0 wt.% TeO 2 added ceramics, there is a remarkable difference in the microstructural features as compared to that of pure CCTO ceramics. This sample exhibited permittivity values as high as 7387 at 10 KHz and low dielectric loss value of 0.037 at 10 kHz, which can be exploited for the high frequency capacitors application.

Polyimide composites composed of covalently bonded BaTiO3@GO hybrids with high dielectric constant and low dielectric loss

RSC Advances ◽  
2016 ◽  
Vol 6 (90) ◽  
pp. 86817-86823 ◽  
Author(s):  
Leipeng Liu ◽  
Yihe Zhang ◽  
Fengzhu Lv ◽  
Wangshu Tong ◽  
Ling Ding ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Dielectric Loss ◽  
High Dielectric Constant ◽  
Low Dielectric ◽  
Three Phase ◽  
Covalently Bonded ◽  
Polyimide Composites ◽  
High Dielectric

Novel flexible three-phase high-k polyimide composites were fabricated by the incorporation of covalently bonded BaTiO3@GO hybrids in which the BaTiO3@GO hybrids were prepared by the reaction of amino modified BaTiO3 particles and GO.

Dielectric Properties of Li-Doped CaCu3Ti4O12 Ceramics

2011 ◽  
Vol 687 ◽  
pp. 251-256 ◽  
Author(s):  
Ying He ◽  
Huai Wu Zhang ◽  
Yuan Xun Li ◽  
Wei Wei Ling ◽  
Yun Yan Wang ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Secondary Phase ◽  
Doping Amount ◽  
Spectroscopy Analysis ◽  
Low Dielectric ◽  
Tan Δ ◽  
High Dielectric ◽  
Impedance Spectroscopy Analysis

CaCu3Ti4O12 ceramics doped with 0-2.0 wt% Li2CO3 were prepared by the solid-state reaction, and their electric and dielectric properties were investigated. It is found that these ceramics had the properties of high dielectric constant and comparatively low dielectric loss. At the doping amount of 0.5 wt%, the dielectric constant is kept to be 105 with weak frequency dependence below 105 Hz, and its loss tangent (tan δ) is suppressed below 0.1 between 300 Hz-5 kHz (with the minimum value of 0.06 at 1 kHz from 218 K to 338 K). The impedance spectroscopy analysis confirms that the decrease of dielectric loss is mainly due to the increase of resistance in the grain boundary, which may be related to the influence of Ti4O7 secondary phase. Our result indicates that doping Li2CO3 is an efficient method to optimize the dielectric properties of CaCu3Ti4O12.

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