Effect of Temperature on Adsorption of Di-n-Butyl Phthalate Easter in Soil Minerals

2014 ◽  
Vol 1065-1069 ◽  
pp. 27-30
Author(s):  
Min Ling Gao ◽  
Xiao Jun Ma ◽  
Fei Lian ◽  
Wen Hua Song ◽  
Kai Zhang
Keyword(s):  
Adsorption Capacity ◽  
Adsorption Isotherms ◽  
Thermodynamic Data ◽  
Physical Adsorption ◽  
Adsorption Behavior ◽  
Effect Of Temperature ◽  
Soil Minerals ◽  
Adsorption Amount ◽  
Butyl Phthalate ◽  
Adsorption Intensity

The aim of this study was to investigate the effect of temperature on adsorption behavior of di-n-butyl phthalate (DBP) in kaoline and montmorillonite. Adsorption isotherms experiments were conducted at 288, 298 and 308 K, respectively. Results showed that adsorption capacity decreased and adsorption intensity enhanced with temperature increased in both minerals. Adsorption amount was larger in montmorillonite than in kaoline. Thermodynamic data indicated the process was a spontaneous and exothermal process and the dominant affection was physical adsorption.

Adsorption of Cu(II) from Aqueous Solution by Peanut Shell

2011 ◽  
Vol 347-353 ◽  
pp. 1852-1855 ◽  
Author(s):  
Zheng Jun Gong ◽  
Cong Cong Tang ◽  
Cai Yun Sun ◽  
Lu Tang ◽  
Jun Chen
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Adsorption Isotherms ◽  
Batch Adsorption ◽  
Present System ◽  
Peanut Shell ◽  
Optimum Conditions ◽  
Langmuir Adsorption ◽  
Adsorption Data ◽  
Adsorption Intensity

A natural peanut shell was used as adsorbent for removal of Cu(Ⅱ) from aqueous solution. Optimum conditions for the elimination of Cu(Ⅱ) from aqueous solution were established by means of a batch adsorption technique. The applicability of the Langmuir and Freundlich adsorption isotherms for the present system was tested. The Langmuir adsorption capacity Qmax (mg/g) is 39.68 and the equilibrium constant b is 0.00776. The Freundlich adsorption capacity k is 0.978 and adsorption intensity n is 1.65. The goodness of fitness was obtained with the Langmuir and Freundlich adsorption isotherms from the equilibrium adsorption data.

Development of bio-derived nanostructured coordination polymers based on cardanol–formaldehyde polyurethanes with ‘d5’ Mn(ii) and ‘d10’ Zn(ii) metal nodes: synthesis, characterization and adsorption behavior

RSC Advances ◽  
2016 ◽  
Vol 6 (55) ◽  
pp. 50070-50082 ◽  
Author(s):  
Shabnam Khan ◽  
Laxmi Laxmi ◽  
Fahmina Zafar ◽  
Nahid Nishat
Keyword(s):  
Thermal Stability ◽  
Adsorption Capacity ◽  
Coordination Polymers ◽  
Renewable Resources ◽  
Adsorption Behavior

Using renewable resources like cardanol aiming towards development of bio-derived coordination polymers with nanoporous layered morphology, amorphous/crystalline behavior, and better thermal stability having moderate adsorption capacity towards dye.

scholarly journals Exploratory study to assess the impact of chitosan /bentonite ratio on the metal removal capacity of chitosan modified bentonite clay

2016 ◽  
Vol 18 (2) ◽  
pp. 437-443 ◽  
Keyword(s):  
Physical Properties ◽  
Adsorption Capacity ◽  
Adsorption Isotherms ◽  
Exploratory Study ◽  
Metal Removal ◽  
Bentonite Clay ◽  
Settling Rate ◽  
Modified Bentonite ◽  
Removal Capacity ◽  
The Impact

<div> <p>Adsorption is one of the methods that can be used for metal removal. In this study five metals were used cadmium, chromium, lead, copper and Nickel (Cd, Cr, Pb, Cu, and Ni) over a concentration range from 0.8 to about 7 mg l<sup>-1</sup> for each metal. Adsorbents were prepared with increasing chitosan to bentonite ratio from 0 to 0.67 g chitosan/g bentonite. The study showed that adsorption of metals on plain bentonite and chitosan modified bentonite can fit well with Langmuir and Freundlich adsorption isotherms. Furthermore, the bentonite adsorption capacity will decrease with the increase of chitosan/bentonite ratio. This study concluded that bentonite is a good adsorbent. However, the applicability of bentonite as potential adsorbent may be limited by its physical properties such as slow settling rate and difficulty to use it as an adsorbent in adsorption columns. Despite the decrease of maximum theoretical adsorption capacity as a result of chitosan modification, the addition of small amount of chitosan can improve the physical characteristics of bentonite clay to be used as an adsorbent.&nbsp;</p> </div> <p>&nbsp;</p>

Effect of Modification with Nitric Acid and Hydrogen Peroxide on Chromium (VI) Adsorption by Activated Carbon Fiber

2012 ◽  
Vol 518-523 ◽  
pp. 2099-2103
Author(s):  
Guang Zhou Qu ◽  
Hai Bing Ji ◽  
Ran Xiao ◽  
Dong Li Liang
Keyword(s):  
Hydrogen Peroxide ◽  
Activated Carbon ◽  
Nitric Acid ◽  
Carbon Fiber ◽  
Adsorption Capacity ◽  
Adsorption Kinetics ◽  
Ph Value ◽  
Activated Carbon Fiber ◽  
Order Kinetic ◽  
Adsorption Amount

The activated carbon fiber (ACF) was treated by different concentration nitric acid (HNO3) and hydrogen peroxide (H2O2) oxidization to enhance its adsorption capacity to hexavalent chromium (Cr6+) ion. The adsorption amount and adsorption kinetics of Cr6+ion on ACFs, and the surface chemical groups were investigated. The results showed that the modified ACFs with 1% HNO3and 10% H2O2had a better adsorption capacity, respectively. The adsorption amount of ACFs was affected strongly solution pH value, and decreased significantly with increasing of the pH value. The adsorption kinetics indicated that the adsorption rates of Cr6+ ion on different modified ACFs were well fitted with the pseudo-second-order kinetic model. After 1% HNO3and 10% H2O2modification, respectively, the total acidic oxygen-containing groups on ACFs surface had an increase obviously, which might be enhance the adsorption amount of Cr6+ion on ACFs.

scholarly journals Effect of Cow Dung, Biogas Slurry and Vermicompost on Phosphorus Adsorption Behavior of Soil

2015 ◽  
Vol 7 (3) ◽  
pp. 167-175 ◽  
Author(s):  
M. Seafatullah ◽  
M. A Hoque ◽  
M. S. Islam ◽  
M. M. Islam ◽  
M. N. Islam
Keyword(s):  
Adsorption Capacity ◽  
Soil Phosphorus ◽  
Phosphate Fertilizer ◽  
Phosphorus Release ◽  
Adsorption Behavior ◽  
Cow Dung ◽  
Biogas Slurry ◽  
Fertilizer Management ◽  
Phosphorus Fertilizer ◽  
Phosphorus Adsorption

One of the approaches for phosphorus fertilizer management is controlling the soil phosphorus adsorption behavior. To examine the effect on phosphorus adsorption behavior, three amended soil samples were prepared by mixing 10% (w/w in dry basis) cow dung, biogas slurry and vermicompost with soil. Phosphorus adsorption behavior was examined by using Langmuir, and Temkin adsorption isotherms. Initially, biogas slurry and vermicompost increased the maximum phosphorus adsorption capacity (MPAC) of soil from 461 µg g-1 (control) to 558.0357 and 586.17 µg g-1 respectively, and then decreased steadily and reached 429.92 and 398.41 µg g-1 respectively in five weeks.  Whereas in case of cow dung, MPAC was initially decreased, then reached maximum in 17 days and ultimately decreased. Thus application of cow dung along with phosphate fertilizer seems to increase the loss of the fertilizer through runoff and leaching. Conversely, biogas slurry and vermicompost prevent phosphorus loss by regulating phosphorus release through initial enhancement followed by gradual decrease in phosphorus adsorption capacity of soil. Both biogas slurry and vermicompost can be considered as good soil amendments as they have the ability to control the release of phosphorus fertilizer as per the need of the plants.

Removal of VOCs Using Sludge-Based Adsorbents

2012 ◽  
Vol 599 ◽  
pp. 305-308 ◽  
Author(s):  
Ping Fang ◽  
Chao Ping Cen ◽  
Hong Tao Zhang ◽  
Zi Jun Tang ◽  
Ding Sheng Chen ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Physical Adsorption ◽  
Low Cost ◽  
Fixed Bed ◽  
Cost Effective ◽  
Langmuir Adsorption Isotherm ◽  
Fixed Bed Reactor ◽  
Dynamic Adsorption ◽  
Langmuir Adsorption ◽  
Isotherm Equations

Efficient and cost-effective sludge-based adsorbents were developed and the adsorption of VOCs on the sludge-based adsorbents was studied in a fixed bed reactor. The results indicate that the adsorption of VOCs on sludge-based adsorbents is typical physical adsorption, the dynamic adsorption capacity of VOCs on adsorbents sharply increases as the VOCs concentration is increased at first, then increasing gradually, at last retains stable with the change of VOCs concentration. The dynamic adsorption capacity of sludge-based adsorbents for VOCs is O-Xylene > Butylcetate > Toluene > Ethylacetate > Benzene > Propanone > n-Hexane, the maximum dynamic adsorption capacity is 0.247, 0.225, 0.192, 0.186, 0.180, 0.176, 0.133g/g, respectively. Meanwhile the adsorption of VOCs on sludge-based adsorbents corresponds to the Langmuir adsorption isotherm equations. The sludge-based adsorbent is a low-cost alternative to activated carbon for VOCs treatment, and this technology is a promising method for the VOCs removal.

Adsorption Behavior of Annatto Dye on Cotton Fabrics Modified by Sericin

2012 ◽  
Vol 441 ◽  
pp. 111-115 ◽  
Author(s):  
Lan Zhou ◽  
Jian Zhong Shao ◽  
Li Qin Chai ◽  
Guo Dong Fu
Keyword(s):  
Surface Modification ◽  
Zeta Potential ◽  
Adsorption Capacity ◽  
Positive Charge ◽  
Cotton Fabrics ◽  
Adsorption Behavior ◽  
Cotton Fibers ◽  
Adsorption Studies

Sericin was investigated as modifier for surface modification on cotton fibers. The measurement of zeta potential was initially used to indicate the effectiveness of the modification. It was found that the sericin largely developed the positive charge on cotton fibers following a decrease in the pH. Adsorption studies of the annatto dye on the modified cotton fibers showed that sericin enhanced the adsorption capacity of the annatto dye on cotton fibers. The results of the zeta potential and the adsorption revealed that the uptake of annatto dye on modified cotton fibers occurred via electrostatic attractions between the anion of the dye and the cationic segments on the modified cotton fibers.

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