Utilization of Nano Silica as Cement Paste in Mortar and Porous Concrete Pavement

2015 ◽  
Vol 1113 ◽  
pp. 135-139 ◽  
Author(s):  
Mohd Yusak Mohd Ibrahim ◽  
Putra Jaya Ramadhansyah ◽  
Hainin Mohd Rosli ◽  
Mohd Haziman Wan Ibrahim ◽  
M.N. Fadzli

The high percentage of porosity in porous concrete pavement tends to decrease its strength. In concrete industry, nano silica is one of the most popular materials that will improve the properties of cementitious materials. This paper, prepared to review the effect of nano silica in cement paste and mortar related to porous concrete pavement. It was found that, by incorporating nano silica with the right composition in cement paste and mortar, it will improve their mechanical properties. By incorporating nano silica in the mixture, it can be predicted that the strengthening effect of nano silica would be further enhanced in porous concrete because the nano silica improve not only the cement paste, but also the interface between paste and aggregate.

Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1617 ◽  
Author(s):  
Hyeonseok Jee ◽  
Jaeyeon Park ◽  
Erfan Zalnezhad ◽  
Keunhong Jeong ◽  
Seung Min Woo ◽  
...  

In recent years, nano-reinforcing technologies for cementitious materials have attracted considerable interest as a viable solution for compensating the poor cracking resistance of these materials. In this study, for the first time, titanium nanotubes (TNTs) were incorporated in cement pastes and their effect on the mechanical properties, microstructure, and early-age hydration kinetics was investigated. Experimental results showed that both compressive (~12%) and flexural strength (~23%) were enhanced with the addition of 0.5 wt.% of TNTs relative to plain cement paste at 28 days of curing. Moreover, it was found that, while TNTs accelerated the hydration kinetics of the pure cement clinker phase (C3S) in the early age of the reaction (within 24 h), there was no significant effect from adding TNTs on the hydration of ordinary Portland cement. TNTs appeared to compress the microstructure by filling the cement paste pore of sizes ranging from 10 to 100 nm. Furthermore, it could be clearly observed that the TNTs bridged the microcracks of cement paste. These results suggested that TNTs could be a great potential candidate since nano-reinforcing agents complement the shortcomings of cementitious materials.


2021 ◽  
Vol 10 (1) ◽  
pp. 1395-1409
Author(s):  
Changjiang Liu ◽  
Xin Su ◽  
Yuyou Wu ◽  
Zhoulian Zheng ◽  
Bo Yang ◽  
...  

Abstract Nano-silica (NS) is one of the most important nanomaterials in recent years. It is used as a new cement-based composite reinforcement in building materials because of its high volcanic ash activity. In order to achieve the goal of carbon peaking and carbon neutralization, combined with the research idea of cementitious materials-reducing admixture for concrete, under the condition of reducing the amount of cement in concrete by 20%, the influence of different dosages of NS on the setting time and mechanical properties of concrete was analyzed. In addition, the shrinkage performance, impermeability, and resistance to chloride-ion permeability of concrete were also studied. The results show that under the same curing conditions and ages, when the NS dosage is 2.5%, the compressive strength and splitting tensile strength of the specimen after 28 days of curing are the highest, reaching 40.87 and 3.8 MPa, which show an increase by 6.6 and 15.15%. The shrinkage performance of concrete increases with the increase in NS dosage. In addition, when the NS dosage is 2.0%, the durability of concrete has also been greatly improved. The impermeability of concrete increased by 18.7% and the resistance to chloride-ion permeability increased by 14.7%. Through microscopic analysis it was found that NS can promote the hydration reaction, generate more hydration products such as calcium silicate hydrate (C–S–H), enhance the interfacial adhesion between the matrix and the aggregate, and form a closer interfacial transition zone. Moreover, the addition of NS also reduces the cumulative pore volume in concrete, refines the pore size, and makes the internal structure of concrete denser.


Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3711
Author(s):  
Mohammad Fahimizadeh ◽  
Ayesha Diane Abeyratne ◽  
Lee Sui Mae ◽  
R. K. Raman Singh ◽  
Pooria Pasbakhsh

Crack formation in concrete is one of the main reasons for concrete degradation. Calcium alginate capsules containing biological self-healing agents for cementitious materials were studied for the self-healing of cement paste and mortars through in vitro characterizations such as healing agent survivability and retention, material stability, and biomineralization, followed by in situ self-healing observation in pre-cracked cement paste and mortar specimens. Our results showed that bacterial spores fully survived the encapsulation process and would not leach out during cement mixing. Encapsulated bacteria precipitated CaCO3 when exposed to water, oxygen, and calcium under alkaline conditions by releasing CO32− ions into the cement environment. Capsule rupture is not required for the initiation of the healing process, but exposure to the right conditions are. After 56 days of wet–dry cycles, the capsules resulted in flexural strength regain as high as 39.6% for the cement mortar and 32.5% for the cement paste specimens. Full crack closure was observed at 28 days for cement mortars with the healing agents. The self-healing system acted as a biological CO32− pump that can keep the bio-agents retained, protected, and active for up to 56 days of wet-dry incubation. This promising self-healing strategy requires further research and optimization.


Author(s):  
Mohd Ibrahim Mohd Yusak ◽  
Mohd Ezree Abdullah ◽  
Ramadhansyah Putra Jaya ◽  
Mohd Rosli Hainin ◽  
Mohd Haziman Wan Ibrahim

2021 ◽  
Vol 8 ◽  
Author(s):  
Xiuzhi Zhang ◽  
Liming Lin ◽  
Mengdi Bi ◽  
Hailong Sun ◽  
Heng Chen ◽  
...  

This paper investigates the effect of supplementary cementitious materials (SCMs) on the fresh and mechanical properties of nano-silica modified cement-based materials (NSMCBM) based on the response surface method (RSM). Fly ash (FA), ground granulated blast-furnace slag (GGBFS), and silica fume (SF) were selected and the Box-Behnken design (BBD) method was used to design mix proportion. Besides, the quadratic term model was used to describe the relationship between independent variables and responses including fluidity, yield stress, plastic viscosity, thixotropy, and 3, 7, 28, and 56 d compressive strength. Based on the quadratic term model, the response surface of each response was drawn to understand the influence of SCMs. Results showed that FA had significant effect on fluidity and thixotropy while three kinds of SCMs had extremely significant effect on plastic viscosity. Response surface plot showed that NS could increase the plastic viscosity of NSMCBM to 1.445 Pa•s (M16). However, the addition of FA and GGBFS decreased the plastic viscosity to 0.9 Pa•s, which was comparable with the reference sample (M17). Such value was 37.7% lower than that of M16. Meanwhile, NS complemented the reduction of compressive strength caused by SCMs. Thus, the synergy effect of SCMs and NS could improve both fresh and mechanical properties. At last, multi-objective optimization was utilized to optimize the proportion of SCMs considering the interaction between SCMs to achieve desirable parameters.


2020 ◽  
Vol 2 (4) ◽  
Author(s):  
Maathar Al Qasimi ◽  
Dhafer Mana Al Zulayq ◽  
Mostafa Seifan ◽  

Additive manufacturing is a recent revolution in the construction field since cementitious materials became printable. This extrusion technique has enabled the construction of very complex geometry with a reduction in costs, time and labour interventions. This study aims to evaluate the possibility of reinforcing 3D printable cementitious composites with the use of nano and micro materials, particularly nano silica, micro silica and microfibrillated cellulose (MFC) which are known for their ability to enhance the fresh and hardened properties of cement-based composites. Rheology property test, flowability and mechanical properties are the types of tests performed to evaluate the fresh and hardened properties of mortar modified with the rested additives. The results show the addition of MFC of 0.4% (of total solid matter) can significantly enhance the mechanical property. In addition, the presence of MFC (at 0.4% of total solid matter) can reduce the pressure required to extrude the mortar, enabling a steady state extrusion. It was also found that 1% nano silica addition significantly improves the mechanical properties and minimizes segregation in the failure surface.


Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6960
Author(s):  
Musa Adamu ◽  
Yasser E. Ibrahim ◽  
Mohamed E. Al-Atroush ◽  
Hani Alanazi

Calcium carbide residue (CCR) is the end-product of production of acetylene gas for the applications such as welding, lighting, ripening of fruits, and cutting of metals. Due to its high pH value, disposing of CCR as a landfill increases the alkalinity of the environment. Therefore, due to its high calcium content, CCR is mostly blended with other pozzolanic materials, together with activators as binders in the cement matrix. In this study, cement was partially substituted using CCR at 0%, 7.5%, 15%, 22.5% and 30% by weight replacement, and nano silica (NS) was utilized as an additive by weight of binder materials at 0%, 1%, 2%, 3% and 4%. The properties considered were the slump, the compressive strength, the flexural strength, the splitting tensile strength, the modulus of elasticity, and the water absorption capacity. The microstructural properties of the concrete were also examined through FESEM and XRD analysis. The results showed that both CCR and NS increase the concrete’s water demand, hence reducing its workability. Mixes containing up to 15% CCR only showed improved mechanical properties. The combination of CCR and NS significantly improved the mechanical properties and decreased the concrete’s water absorption through improved pozzolanic reactivity as verified by the FESEM and XRD results. Furthermore, the microstructure of the concrete was explored, and the pores were refined by the pozzolanic reaction products. The optimum mix combination was obtained by replacing 15% cement using CCR and the addition of 2% NS by weight of cementitious materials. Therefore, using a hybrid of CCR and NS in concrete will result in reduction of cement utilization in concrete, leading to improved environmental sustainability and economy.


2016 ◽  
Vol 9 (1) ◽  
pp. 146-154 ◽  
Author(s):  
Intisar Kuli ◽  
Taher M. Abu-Lebdeh ◽  
Elham H. Fini ◽  
Sameer A. Hamoush

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