scholarly journals Effect of nano-silica as cementitious materials-reducing admixtures on the workability, mechanical properties and durability of concrete

2021 ◽  
Vol 10 (1) ◽  
pp. 1395-1409
Author(s):  
Changjiang Liu ◽  
Xin Su ◽  
Yuyou Wu ◽  
Zhoulian Zheng ◽  
Bo Yang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Building Materials ◽  
Setting Time ◽  
Microscopic Analysis ◽  
Chloride Ion ◽  
Cementitious Materials ◽  
Hydration Reaction ◽  
Ion Permeability ◽  
Nano Silica ◽  
Durability Of Concrete

Abstract Nano-silica (NS) is one of the most important nanomaterials in recent years. It is used as a new cement-based composite reinforcement in building materials because of its high volcanic ash activity. In order to achieve the goal of carbon peaking and carbon neutralization, combined with the research idea of cementitious materials-reducing admixture for concrete, under the condition of reducing the amount of cement in concrete by 20%, the influence of different dosages of NS on the setting time and mechanical properties of concrete was analyzed. In addition, the shrinkage performance, impermeability, and resistance to chloride-ion permeability of concrete were also studied. The results show that under the same curing conditions and ages, when the NS dosage is 2.5%, the compressive strength and splitting tensile strength of the specimen after 28 days of curing are the highest, reaching 40.87 and 3.8 MPa, which show an increase by 6.6 and 15.15%. The shrinkage performance of concrete increases with the increase in NS dosage. In addition, when the NS dosage is 2.0%, the durability of concrete has also been greatly improved. The impermeability of concrete increased by 18.7% and the resistance to chloride-ion permeability increased by 14.7%. Through microscopic analysis it was found that NS can promote the hydration reaction, generate more hydration products such as calcium silicate hydrate (C–S–H), enhance the interfacial adhesion between the matrix and the aggregate, and form a closer interfacial transition zone. Moreover, the addition of NS also reduces the cumulative pore volume in concrete, refines the pore size, and makes the internal structure of concrete denser.

Research Progress on the Hydration of Portland Cement with Calcined Clay and Limestone

2021 ◽  
Vol 1036 ◽  
pp. 240-246
Author(s):  
Jin Tang ◽  
Su Hua Ma ◽  
Wei Feng Li ◽  
Hui Yang ◽  
Xiao Dong Shen
Keyword(s):  
Mechanical Properties ◽  
Portland Cement ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Research Progress ◽  
Hydration Reaction ◽  
Hydration Products ◽  
Early Hydration ◽  
Calcined Clay ◽  
Dense Microstructure

The use of calcined clay and limestone as supplementary cementitious materials, can have a certain influence on the hydration of Portland cement. This paper reviewed the influence of limestone and calcined clay and the mixture of limestone and calcined clay on the hydration of cement. Both limestone and calcined clay accelerate the hydration reaction in the early hydration age and enhance the properties of cement. Limestone reacts with C3A to form carboaluminate, which indirectly stabilized the presence of ettringite, while calcined clay consumed portlandite to form C-(A)-S-H gel, additional hydration products promote the densification of pore structure and increase the mechanical properties. The synergistic effect of calcined clay and limestone stabilize the existence of ettringite and stimulate the further formation of carboaluminate, as well as the C-(A)-S-H gel, contributed to a dense microstructure.

scholarly journals Effect of TiO2 Nanoparticles on Physical and Mechanical Properties of Cement at Low Temperatures

2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Li Wang ◽  
Hongliang Zhang ◽  
Yang Gao
Keyword(s):  
Mechanical Properties ◽  
Low Temperatures ◽  
Cement Hydration ◽  
Setting Time ◽  
Physical And Mechanical Properties ◽  
Xrd Analysis ◽  
Cementitious Materials ◽  
Strength Test ◽  
Hydration Degree ◽  
Time Test

Low temperature negatively affects the engineering performance of cementitious materials and hinders the construction productivity. Previous studies have already demonstrated that TiO2 nanoparticles can accelerate cement hydration and enhance the strength development of cementitious materials at room temperature. However, the performance of cementitious materials containing TiO2 nanoparticles at low temperatures is still unknown. In this study, specimens were prepared through the replacement of cement with 1 wt.%, 2 wt.%, 3 wt.%, 4 wt.%, and 5 wt.% TiO2 nanoparticles and cured under temperatures of 0°C, 5°C, 10°C, and 20°C for specific ages. Physical and mechanical properties of the specimens were evaluated through the setting time test, compressive strength test, flexural strength test, hydration degree test, mercury intrusion porosimetry (MIP), X-ray diffraction (XRD) analysis, thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM) in order to examine the performance of cementitious materials with and without TiO2 nanoparticles at various curing temperatures. It was found that low temperature delayed the process of cement hydration while TiO2 nanoparticles had a positive effect on accelerating the cement hydration and reducing the setting time in terms of the results of the setting time test, hydration degree test, and strength test, and the specimen with the addition of 2 wt.% TiO2 nanoparticles showed the superior performance. Refined pore structure in the MIP tests, more mass loss of CH in TGA, intense peak appearance associated with the hydration products in XRD analysis, and denser microstructure in SEM demonstrated that the specimen with 2 wt.% TiO2 nanoparticles exhibited preferable physical and mechanical properties compared with that without TiO2 nanoparticles under various curing temperatures.

scholarly journals Characterizing the Performance of Ternary Concrete Mixtures Involving Slag and Metakaolin

2020 ◽  
Vol 5 (2) ◽  
pp. 14
Author(s):  
Matthew S. Sullivan ◽  
Mi G. Chorzepa ◽  
Stephan A. Durham
Keyword(s):  
Mechanical Properties ◽  
Thermal Expansion ◽  
Fly Ash ◽  
Coefficient Of Thermal Expansion ◽  
Drying Shrinkage ◽  
Chloride Ion ◽  
Cementitious Materials ◽  
Ternary Mixtures ◽  
Modulus Of Rupture ◽  
Ternary Blends

Ternary blends of cementitious materials are investigated. A cement replacement level of 45% is used for all ternary mixtures consisting of 15% metakaolin and 30% slag replacements. Three metakaolin and two blast furnace slag, referred to as ‘slag’ for short, products commercially available are used to compare performance in ternary blends. A mixture with a 45% fly ash replacement is included to serve as a benchmark for performance. The control mixture contains 422 kg of cement per cubic meter of concrete, and a water-to-cementitious material ratio of 0.43 is used for all mixtures with varying dosages of superplasticizer to retain workability. Mixtures are tested for mechanical properties, durability, and volumetric stability. Mechanical properties include compression, split-cylinder tension, modulus of rupture, and dynamic Young’s modulus. Durability measures are comprised of rapid chloride-ion penetrability, sulfate resistance, and alkali–silica reactivity. Finally, the measure of dimensional stability is assessed by conducting drying shrinkage and coefficient of thermal expansion tests. Results indicate that ternary mixtures including metakaolin perform similarly to the control with respect to mechanical strength. It is concluded that ternary blends perform significantly better than both control and fly ash benchmark in tests measuring durability. Furthermore, shrinkage is reduced while the coefficients of thermal expansion are slightly higher than control and the benchmark.

Utilization of Nano Silica as Cement Paste in Mortar and Porous Concrete Pavement

2015 ◽  
Vol 1113 ◽  
pp. 135-139 ◽  
Author(s):  
Mohd Yusak Mohd Ibrahim ◽  
Putra Jaya Ramadhansyah ◽  
Hainin Mohd Rosli ◽  
Mohd Haziman Wan Ibrahim ◽  
M.N. Fadzli
Keyword(s):  
Mechanical Properties ◽  
Cement Paste ◽  
Cementitious Materials ◽  
Concrete Pavement ◽  
Strengthening Effect ◽  
Nano Silica ◽  
Porous Concrete ◽  
The Right

The high percentage of porosity in porous concrete pavement tends to decrease its strength. In concrete industry, nano silica is one of the most popular materials that will improve the properties of cementitious materials. This paper, prepared to review the effect of nano silica in cement paste and mortar related to porous concrete pavement. It was found that, by incorporating nano silica with the right composition in cement paste and mortar, it will improve their mechanical properties. By incorporating nano silica in the mixture, it can be predicted that the strengthening effect of nano silica would be further enhanced in porous concrete because the nano silica improve not only the cement paste, but also the interface between paste and aggregate.

scholarly journals Mechanical Performance and Microscopic Mechanism of Coastal Cemented Soil Modified by Iron Tailings and Nano Silica

Crystals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1331
Author(s):  
Xinjiang Song ◽  
Haibo Xu ◽  
Deqin Zhou ◽  
Kai Yao ◽  
Feifei Tao ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Mechanical Performance ◽  
Hydration Reaction ◽  
Unconfined Compression ◽  
Nano Silica ◽  
Microscopic Mechanism ◽  
Clay Particles ◽  
Soil Cement ◽  
Cement Soil

In order to explore the effect of composite materials on the mechanical properties of coastal cement soil, cement soil samples with different iron tailings and nano silica contents were prepared, and unconfined compression and scanning electron microscope tests were carried out. The results show that: (1) The compressive strength of cement soil containing a small amount of iron tailings is improved, and the optimum content of iron tailings is 20%. (2) Nano silica can significantly improve the mechanical properties of iron tailings and cement soil (TCS). When the content of nano silica is 0.5%, 1.5%, and 2.5%, the unconfined compressive strength of nano silica- and iron tailings-modified cement soil (STCS) is 24%, 137%, and 323% higher than TCS, respectively. (3) Nano silica can promote the hydration reaction of cement and promote the cement hydration products to adhere to clay particles to form a relatively stable structure. At the same time, nano silica can fill the pores in TCS and improve the compactness of STCS.

scholarly journals Effect of Sodium Aluminate Dosage as a Solid Alkaline Activator on the Properties of Alkali-Activated Slag Paste

2021 ◽  
Vol 2021 ◽  
pp. 1-13
Author(s):  
Bin Chen ◽  
Jun Wang ◽  
Jinyou Zhao
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Setting Time ◽  
Sodium Aluminate ◽  
Hydration Reaction ◽  
Hydration Products ◽  
Alkali Activated Slag ◽  
Alkaline Activator ◽  
Activated Slag ◽  
Alkali Activated

Extensive research into alkali-activated slag as a green gel material to substitute for cement has been done because of the advantages of low-carbon dioxide emissions and recycling of industrial solid waste. Alkali-activated slag usually has good mechanical properties, but the too fast setting time restricted its application and promotion. Changing the composition of alkaline activator could optimize setting time, usually making it by adding sodium carbonate or sodium sulfate but this would cause insufficient hydration reaction power and hinder compressive strength growth. In this paper, the effect of sodium aluminate dosage as an alkaline activator on the setting time, fluidity, compressive strength, hydration products, and microstructures was studied through experiments. It is fair to say that an appropriate amount of sodium aluminate could obtain a suitable setting time and better compressive strength. Sodium aluminate provided enough hydroxyl ions for the paste to promote the hydration reaction process that ensured obtaining high compressive strength and soluble aluminium formed precipitate wrapped on the surface of slag to inhibit the hydration reaction process in the early phase that prolonged setting time. The hydration mechanism research found that sodium aluminate played a key role in the formation of higher cross-linked gel hydration products in the late phase of the process. Preparing an alkali-activated slag with excellent mechanical properties and suitable setting time will significantly contribute to its application and promotion.

scholarly journals Combined effects of nano-silica and silica fume on the mechanical behavior of recycled aggregate concrete

2021 ◽  
Vol 10 (1) ◽  
pp. 819-838
Author(s):  
Tang Yunchao ◽  
Chen Zheng ◽  
Feng Wanhui ◽  
Nong Yumei ◽  
Li Cong ◽  
...  
Keyword(s):  
Silica Fume ◽  
Structural Engineering ◽  
Tensile Tests ◽  
Cementitious Materials ◽  
Recycled Aggregate Concrete ◽  
Supplementary Cementitious Materials ◽  
Recycled Aggregate ◽  
Hydration Reaction ◽  
Nano Silica ◽  
Aggregate Concrete

Abstract Recycled aggregate concrete (RAC) is an environmentally friendly material. However, owing to inherent characteristics of the recycled aggregate (RA), it is difficult to promote and apply it in structural engineering. Silica fume (SF) and nano-silica (NS) have different characteristics as additives for RAC. It has been proven that adding SF only enhances the strength of RAC at a later stage, and NS can improve the early strength of RAC owing to its high pozzolanic activity. In this study, to further improve the properties of RAC, two types of additives were combined into RAC, which was named SF-NS-modified RAC (SSRAC). Compression and split tensile tests were conducted to analyze the mechanical properties of SSRAC at different curing ages. The results indicated that the combined addition of NS and SF improved the performance of RAC at early and later curing ages. Scanning electron microscopy and X-ray diffraction analyses were performed to explore the NS and SF mechanism. The results indicated that SF and NS in SSRAC had a good pozzolanic effect and underwent a secondary hydration reaction with calcium hydroxide to increase the production of calcium silicate hydrate, resulting in an increase in the properties of the interface transition zone. Finally, 6% SF and 2 or 3% NS are recommended as supplementary cementitious materials for RAC.

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