Preparation and Adsorption Properties of Starch-g-Polyacrylamide/Montmorillonite Nanocomposites

2015 ◽  
Vol 1120-1121 ◽  
pp. 343-346
Author(s):  
Cai Ning Zhang ◽  
Xu Man Wang
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Adsorption Capacity ◽  
Crosslinking Agent ◽  
Adsorption Properties ◽  
Experimental Results ◽  
Solution Polymerization ◽  
Preparation Conditions ◽  
Montmorillonite Nanocomposites

By means of solution polymerization, a series of cross-linked starch-g-polyacrylamide/ montmorillonite (St-g-PAM/MMT) nanocomposites were prepared and used to adsorb methylene blue (MB). The effects of different preparation conditions on the adsorption capacity of the nanocomposites were investigated. The experimental results demonstrated that the prepared St-g-PAM/MMT nanocomposites were effective adsorbents for removal of MB from aqueous solution. Furthermore, adsorption capacity increased with the MMT contents up to 14% and decreased as the MMT contents further increased. Adsorption capacity increased with the increasing of the ratio of starch to acrylamide, whereas adsorption capacity decreased with the increasing of crosslinking agent contents.

Environmentally Friendly Magnetic Nanoparticles for Efficient Removal of Methylene Blue and Cr(VI) from Water

NANO ◽  
2020 ◽  
Vol 15 (10) ◽  
pp. 2050126 ◽  
Author(s):  
Rui Wang ◽  
Kanglong Chen ◽  
Si Peng ◽  
Qiu-Yue Wang ◽  
Shuang-Hui Huang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Magnetic Nanoparticles ◽  
Adsorption Capacity ◽  
Organic Dyes ◽  
Adsorption Properties ◽  
Batch Adsorption ◽  
Efficient Removal ◽  
Environmental Friendliness ◽  
Isotherm Equation

The poor environmental friendliness, low adsorption capacity and nonreusability of adsorbents are still challenging for the removal of pollutants in aqueous solution. Herein, novel polypeptide-functionalized silica-coated magnetic nanoparticles (PS-MNPs), Fe3O4@SiO2@PLL nanoparticles, with good environmental friendliness, excellent adsorption capability and economic reusability were designed and prepared for efficient removal of methylene blue (MB) and Cr(VI) ion (Cr2O[Formula: see text]. The chem-physical properties of Fe3O4@SiO2@PLL nanoparticles, such as chemical structure, nanosize, nanomorphology, crystalline structure, magnetization and thermo-oxidative degradation behavior were fully investigated in this study. In addition, the adsorption properties of the Fe3O4@SiO2@PLL nanoparticles for MB and Cr(VI) ion in aqueous solution were explored by batch adsorption experiments. Based on the experimental results, the Fe3O4@SiO2@PLL nanoparticles demonstrated excellent adsorption capacity for removal of both MB and Cr(VI) ion that the theoretical maximum adsorption capacities of the nanoparticles were 301.2[Formula: see text]mg [Formula: see text] g[Formula: see text] for MB and 164.7[Formula: see text]mg [Formula: see text] g[Formula: see text] for Cr(VI), respectively. The adsorption process could be better fitted by pseudo-second-order model, and matched well with the Langmuir isotherm equation. Moreover, the Fe3O4@SiO2@PLL nanoparticles could be easily regenerated by desorbing metal ions and organic dyes from the adsorbents with appropriate eluents, and showed good adsorption capacity after five recycles. In brief, the as-prepared PS-MNPs exhibited improved environmental friendliness, excellent adsorption properties and high regeneration efficiency, which could be used as a potential adsorbent for different kinds of contaminants removal.

Morphology dependent adsorption of methylene blue on trititanate nanoplates and nanotubes prepared by the hydrothermal treatment of TiO2

2016 ◽  
Vol 75 (2) ◽  
pp. 350-357
Author(s):  
Graham Dawson ◽  
Wei Chen ◽  
Luhua Lu ◽  
Kai Dai
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Surface Area ◽  
Pore Volume ◽  
Hydrothermal Reaction ◽  
Low Cost ◽  
High Surface ◽  
High Surface Area ◽  
High Capacity ◽  
Adsorption Properties

The adsorption properties of two nanomorphologies of trititanate, nanotubes (TiNT) and plates (TiNP), prepared by the hydrothermal reaction of concentrated NaOH with different phases of TiO2, were examined. It was found that the capacity for both morphologies towards methylene blue (MB), an ideal pollutant, was extremely high, with the TiNP having a capacity of 130 mg/g, higher than the TiNT, whose capacity was 120 mg/g at 10 mg/L MB concentration. At capacity, the well-dispersed powders deposit on the floor of the reaction vessel. The two morphologies had very different structural and adsorption properties. TiNT with high surface area and pore volume exhibited exothermic monolayer adsorption of MB. TiNP with low surface area and pore volume yielded a higher adsorption capacity through endothermic multilayer adsorption governed by pore diffusion. TiNP exhibited a higher negative surface charge of −23 mV, compared to −12 mV for TiNT. The adsorption process appears to be an electrostatic interaction, with the cationic dye attracted more strongly to the nanoplates, resulting in a higher adsorption capacity and different adsorption modes. We believe this simple, low cost production of high capacity nanostructured adsorbent material has potential uses in wastewater treatment.

scholarly journals Study on the adsorption of methylene blue from aqueous solution using hydrogel glucomannan/graphene oxide

2021 ◽  
Vol 10 (1) ◽  
pp. 59-66
Author(s):  
Son Le Lam ◽  
Phu Nguyen Vinh ◽  
Hieu Le Trung ◽  
Tan Le Thua ◽  
Nhan Dang Thi Thanh ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Graphene Oxide ◽  
Adsorption Capacity ◽  
Organic Dyes ◽  
Dye Adsorption ◽  
Order Kinetic ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order

Glucomannan/graphene oxide (GM/GO) hydrogel was synthesized by using calcium hydroxide as the crosslinker. The synthesized material was characterized by using IR, XRD, SEM, EDX and RAMAN technology. The composite hydrogel was used for removal of organic dyes from aqueous solution. The results showed that the GM/GO hydrogel had a porous structure and a high adsorption capacity toward methylene blue (MB). The pseudo-second-order kinetic model could fit the rate equation of MB adsorption onto the GM/GO hydrogel. The adsorption of MB onto GM/GO hydrogel was a spontaneous process. In addition, the equilibrium adsorption isotherm data indicated that equilibrium data were fitted to the Langmuir isotherm and the maximum dye adsorption capacity was 198,69 mg.g-1. Moreover, the hydrogel was stable and easily recovered and adsorption capacity was around 97% of the initial saturation adsorption capacity after being used five times.

scholarly journals Effect of synthesis conditions  on  methylene blue adsorption capacity of electrochemically preparated graphene

2020 ◽  
Vol 9 (3) ◽  
pp. 9-14
Author(s):  
Hao Pham Van ◽  
Linh Ha Xuan ◽  
Oanh Phung Thi ◽  
Hong Phan Ngoc ◽  
Huy Nguyen Nhat ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Adsorption Capacity ◽  
Functional Groups ◽  
Photoelectron Spectroscopy ◽  
Graphene Nanosheets ◽  
Electrochemical Exfoliation ◽  
X Ray ◽  
Synthesis Conditions ◽  
Mb Adsorption

This report presents the effect of synthesis conditions on the synthesis of graphene nanosheets via electrochemical exfoliation method for adsorbing methylene blue from aqueous solution. Oxygen-containing functional groups and defects in the material were characterized by Raman and X-ray photoelectron spectroscopy (XPS). As a result, by using voltage of 15 V, (NH4)2SO4 (5%, 250 mL) and KOH (7.5%, 250 mL), the obtained material showed the highest MB adsorption capacity due to the high densities of oxygen-containing groups and defects comparison to other conditions.

Experimental Study on the Adsorption of MB on Novel Photocatalyst Yeast/ZnS Hybrid Microspheres

2014 ◽  
Vol 924 ◽  
pp. 129-133
Author(s):  
Hai Gang Gou ◽  
Wei Sheng Guan ◽  
Li Yang ◽  
Zhao Qi Wang ◽  
Yang Zhi Zhu
Keyword(s):  
Experimental Study ◽  
Methylene Blue ◽  
Adsorption Capacity ◽  
Experimental Results ◽  
Yeast Cells ◽  
Isotherm Modeling ◽  
Adsorption Performance

Employing yeast cells as carriers,a novel cell-loaded photocatalyst yeast/ZnS (YC/ZnS) was successfully synthesized. The adsorption performance of methylene blue on the YC/ZnS microspheres was studied. Experimental results showed that the optimized adsorption conditions were 23°C,pH7 and the YC/ZnS dosage 4.5g/L. Under these conditions,the adsorption capacity of YC/ZnS could reach 471.2μg/g. Isotherm modeling revealed that Freundlich equations described well the adsorption of methylene blue onto YC/ZnS.

scholarly journals Acetone fractionation: a simple and efficient method to improve the performance of lignin for dye pollutant removal

RSC Advances ◽  
2019 ◽  
Vol 9 (61) ◽  
pp. 35895-35903
Author(s):  
Hao Li ◽  
Ze Yuan ◽  
Yuyu Xing ◽  
Jiarong Li ◽  
Jing Fang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Adsorption Capacity ◽  
Efficient Method ◽  
Pollutant Removal ◽  
Cationic Dye ◽  
Acetone Fractionation

In this work, it was found that the adsorption capacity of lignin to cationic dye (methylene blue, MB) from aqueous solution could be significantly improved by simple acetone fractionation.

scholarly journals Graphene Oxide Adsorption Enhanced by Attapulgite to Remove Pb (II) from Aqueous Solution

2019 ◽  
Vol 9 (7) ◽  
pp. 1390 ◽  
Author(s):  
Bigui Wei ◽  
Xiabing Cheng ◽  
Gang Wang ◽  
Hua Li ◽  
Xiaosan Song ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Graphene Oxide ◽  
Adsorption Capacity ◽  
High Efficiency ◽  
Separation Efficiency ◽  
Hydrothermal Reaction ◽  
Adsorption Properties ◽  
Maximum Adsorption Capacity

To improve the adsorption and separation efficiency of lead-containing wastewater by graphene oxide (GO), attapulgite (ATP) was used through a simple hydrothermal reaction. The prepared GO was characterized by SEM, TEM, FTIR, and XPS. The adsorption properties of the prepared GO were investigated. The maximum adsorption capacity of Pb2+ on as-prepared GO at pH 5 and 25 °C was 450.9 mg/g. It is concluded that the as-prepared GO can be used as a high-efficiency adsorbent for lead-containing wastewater.

Comparing Different Kinds of Materials for Adsorption of Methylene Blue

2014 ◽  
Vol 651-653 ◽  
pp. 1331-1334 ◽  
Author(s):  
Yan Peng Shi ◽  
Shun Xian Zhong ◽  
Meng Lu Wu ◽  
Jian Rong Chen
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Adsorption Capacity ◽  
Human Beings ◽  
Nanometer Materials ◽  
New Type ◽  
The Difference

Methylene blue is an organic dyestuff and damaged to human beings. Graphene-based composite is a new type of nanometer materials and with outstanding adsorption capacity of methylene blue than other materials in aqueous solution. This paper summarized and compared the difference among graphene, graphene-based composites and other materials in removing methylene blue in aqueous solution.

Study on Adsorption of Methylene Blue by the Montmorillonite/poly(γ-Glutamic Acid) Composite

2012 ◽  
Vol 554-556 ◽  
pp. 333-338
Author(s):  
Cai Ning Zhang ◽  
Xu Man Wang
Keyword(s):  
Methylene Blue ◽  
Glutamic Acid ◽  
Adsorption Capacity ◽  
Adsorption Mechanism ◽  
Experimental Results ◽  
Methylene Blue Solution ◽  
Adsorption Time ◽  
Initial Concentration ◽  
Ph Values ◽  
Blue Solution

The composite was prepared with montmorillonite (MMT) and poly(γ-glutamic acid) (γ-PGA). Applied the composite as the sorbent, methylene blue as the adsorbate, the influences of the initial concentrations of methylene blue, adsorption time and pH values of the solution on the adsorption capacity of methylene blue by the composite were studied. The experimental results showed that the adsorption capacity of methylene blue by MMT/γ-PGA composite both increased with the increasing of initial concentration of methylene blue and the prolonging of adsorption time, and then approached saturation respectively. The adsorption capacity of methylene blue by MMT/γ-PGA composite increased with the increasing of pH values of methylene blue solution. Meanwhile, the study of adsorption mechanism demonstrated that the adsorption of methylene blue by MMT/γ-PGA composite was Langmuir type, and the adsorption equation wasΓ=0.204c/(1+0.381C).

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