Preparation of Acid-Resistant Ultramarine Pigment by Dense Silica Coating Process

2011 ◽  
Vol 233-235 ◽  
pp. 246-249 ◽  
Author(s):  
Si Fang Li ◽  
Miao Liu
Keyword(s):  
Photoelectron Spectroscopy ◽  
Acid Resistance ◽  
Silica Coating ◽  
Sem Analysis ◽  
Solid Content ◽  
Operating Conditions ◽  
Blue Pigment ◽  
Orthogonal Experimental Design ◽  
Coating Process ◽  
Ultramarine Blue

Acid-resistant ultramarine blue pigment with a silica shell was prepared by dense silica coating process. From X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM) analysis, it was confirmed that silica in the coating is attached on the ultramarine particles surface by characterizing the composition of elements and the microstructure on the surface of the silica coated particles. Orthogonal experimental design was applied to optimize the operating conditions of the coating process. The best acid resistance for the coated ultramarine blue reached the ninth grade under the following conditions: silica adding rate of 5 g/h, solid content of 6 g/l in the slurry and coating time of 2.5 h.

Enhancement of Acid Resistance for Ultramarine Blue by Silica Coatings

2011 ◽  
Vol 291-294 ◽  
pp. 163-166
Author(s):  
Miao Liu ◽  
Si Fang Li ◽  
Daniel Umereweneza
Keyword(s):  
Coating Layer ◽  
Acid Resistance ◽  
Sodium Metasilicate ◽  
Solid Content ◽  
Mass Ratio ◽  
Silica Coatings ◽  
Ultramarine Blue ◽  
Ft Ir ◽  
Silica Precursor ◽  
Ft Ir Spectroscopy

The acid resistance of ultramarine blue was greatly enhanced by silica coatings. Sodium metasilicate nonahydrate was used as silica precursor and ammonium chloride was used to react with it. Fourier transform infrared (FT-IR) spectroscopy was used to characterize surface structure on the coating layer. The effects of coating conditions on acid resistances of the coated ultramarine blue were investigated. The acid resistance was evaluated by immersing the pigment in 10 wt% hydrochloric acid. The results showed the optimal mass ratio of silicate to ultramarine was 3.75 and the proper solid content was 60 g/L. Under above conditions, the silica coated ultramarine blue exhibited an acid resistance of 8, while the uncoated ultramarine blue only showed an acid resistance of 1.

A Transient 3D CFD Model of a Progressive Cavity Pump

2016 ◽  
Author(s):  
K. R. Mrinal ◽  
Md. Hamid Siddique ◽  
Abdus Samad
Keyword(s):  
Oil And Gas ◽  
Complex Geometry ◽  
Transient Behavior ◽  
Oil And Gas Industry ◽  
High Viscosity ◽  
Solid Content ◽  
Operating Conditions ◽  
Cfd Model ◽  
Ansys Fluent ◽  
Flow Variables

A progressive cavity pump (PCP) is a positive displacement pump and has been used as an artificial lift method in the oil and gas industry for pumping fluid with solid content and high viscosity. In a PCP, a single-lobe rotor rotates inside a double-lobe stator. Articles on computational works for flows through a PCP are limited because of transient behavior of flow, complex geometry and moving boundaries. In this paper, a 3D CFD model has been developed to predict the flow variables at different operating conditions. The flow is considered as incompressible, single phase, transient, and turbulent. The dynamic mesh model in Ansys-Fluent for the rotor mesh movement is used, and a user defined function (UDF) written in C language defines the rotor’s hypocycloid path. The mesh deformation is done with spring based smoothing and local remeshing technique. The computational results are compared with the experiment results available in the literature. Thepump gives maximum flowrate at zero differential pressure.

scholarly journals In Vitro Effect of Replicated Porous Polymeric Nano-MicroStructured Biointerfaces Characteristics on Macrophages Behavior

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1913
Author(s):  
Luminita Nicoleta Dumitrescu ◽  
Madalina Icriverzi ◽  
Anca Bonciu ◽  
Anca Roșeanu ◽  
Antoniu Moldovan ◽  
...  
Keyword(s):  
Inflammatory Response ◽  
Photoelectron Spectroscopy ◽  
Polyvinylidene Fluoride ◽  
Surface Characteristics ◽  
Sem Analysis ◽  
Chemical Structures ◽  
Microstructured Surface ◽  
Inflammatory Conditions ◽  
Vitro Effect

In the last decades, optimizing implant properties in terms of materials and biointerface characteristics represents one of the main quests in biomedical research. Modifying and engineering polyvinylidene fluoride (PVDF) as scaffolds becomes more and more attractive to multiples areas of bio-applications (e.g., bone or cochlear implants). Nevertheless, the acceptance of an implant is affected by its inflammatory potency caused by surface-induced modification. Therefore, in this work, three types of nano-micro squared wells like PVDF structures (i.e., reversed pyramidal shape with depths from 0.8 to 2.5 microns) were obtained by replication, and the influence of their characteristics on the inflammatory response of human macrophages was investigated in vitro. FTIR and X-ray photoelectron spectroscopy analysis confirmed the maintaining chemical structures of the replicated surfaces, while the topographical surface characteristics were evaluated by AFM and SEM analysis. Contact angle and surface energy analysis indicated a modification from superhydrophobicity of casted materials to moderate hydrophobicity based on the structure’s depth change. The effects induced by PVDF casted and micron-sized reversed pyramidal replicas on macrophages behavior were evaluated in normal and inflammatory conditions (lipopolysaccharide treatment) using colorimetric, microscopy, and ELISA methods. Our results demonstrate that the depth of the microstructured surface affects the activity of macrophages and that the modification of topography could influence both the hydrophobicity of the surface and the inflammatory response.

Deposition of Cobalt Doped Zinc Oxide Thin Film Nano-Composites Via Pulsed Electron Beam Ablation

MRS Advances ◽  
2016 ◽  
Vol 1 (6) ◽  
pp. 433-439 ◽  
Author(s):  
Asghar Ali ◽  
Patrick Morrow ◽  
Redhouane Henda ◽  
Ragnar Fagerberg
Keyword(s):  
Zinc Oxide ◽  
Electron Beam ◽  
Binding Energy ◽  
Photoelectron Spectroscopy ◽  
Xrd Analysis ◽  
Sem Analysis ◽  
Oxide Thin Film ◽  
X Ray ◽  
Pulsed Electron Beam ◽  
Deposited Films

AbstractThis study reports on the preparation of cobalt doped zinc oxide (Co:ZnO) films via pulsed electron beam ablation (PEBA) from a single target containing 20 w% Co on sapphire (0001) and silicon (100) substrates. The films have been deposited at various temperatures (350оC, 400оC, 450оC) and pulse frequencies (2 Hz, 4 Hz), under a background argon (Ar) pressure of about 3 mtorr, and an accelerating voltage of 14 kV. The surface morphology has been examined by atomic force microscopy (AFM) and scanning electron microscopy (SEM). According to SEM analysis, the films consist of nano-globules whose size is in the range of 80-178 nm. Energy dispersive x-ray spectroscopy (EDX) reveals that deposition is congruent and the prepared films contain ∼20±5 w% cobalt. It has been found that the nano-globules in the deposited films are cobalt-rich zones containing ∼70 w% Co. From x-ray photoelectron spectroscopy (XPS) analysis, Co 2p3/2 peaks indicate that the deposited films contain CoO (binding energy = 780.5 eV) as well as metallic Co (binding energy = 778.1-778.5 eV). X-ray diffraction (XRD) analysis supports the presence of metallic Co hcp phase (2ϴ = 44.47° and 47.43°) in the films.

Property of Cu2O-CuO/ZSM-5 nanocomposite and degradation process of azo dye AO7 without sacrificial agent (H2O2)

2016 ◽  
Vol 73 (11) ◽  
pp. 2747-2753 ◽  
Author(s):  
Wusong Kong ◽  
Hongxia Qu ◽  
Peng Chen ◽  
Weihua Ma ◽  
Huifang Xie
Keyword(s):  
Catalytic Activity ◽  
Aqueous Solutions ◽  
Photoelectron Spectroscopy ◽  
Oxygen Demand ◽  
Operating Conditions ◽  
Surface Element ◽  
Impregnation Method ◽  
X Ray ◽  
Initial Ph ◽  
Sacrificial Agent

In this study, Cu2O-CuO/ZSM-5 nanocomposite was synthesized by the impregnation method, and its catalytic performance for the destruction of AO7 in aqueous solutions was investigated. The morphology, structure and surface element valence state of Cu2O-CuO/ZSM-5 were characterized by transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy. The operating conditions on the degradation of AO7 by Cu2O-CuO/ZSM-5, such as initial pH values, concentration of AO7 and catalyst dosage were investigated and optimized. The results showed that the sample had good catalytic activity for destruction of AO7 in the absence of a sacrificial agent (e.g. H2O2): it could degrade 91% AO7 in 140 min at 25 °C and was not restricted by the initial pH of the AO7 aqueous solutions. Cu2O-CuO/ZSM-5 exhibited stable catalytic activity with little loss after three successive runs. The total organic carbon and chemical oxygen demand removal efficiencies increased rapidly to 69.36% and 67.3% after 120 min of treatment by Cu2O-CuO/ZSM-5, respectively.

scholarly journals Investigation of Mechanical and Durability Properties of Concrete Mixed with Water Exposed to a Magnetic Field

2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
R. Dharmaraj ◽  
G. K. Arunvivek ◽  
Alagar Karthick ◽  
V. Mohanavel ◽  
Bhagavathi Perumal ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Potable Water ◽  
Acid Resistance ◽  
Sem Analysis ◽  
Durability Properties ◽  
Flexural Tensile Strength ◽  
Chemical Admixtures ◽  
Magnetized Water ◽  
Concrete Mix ◽  
Magnetic Water

Water is a crucial element in the concrete mix and is alone responsible for concrete work ability and cement hydration. The massive quantity of potable water consumed during the production of concrete is a concern. In general, fresh and hard concrete qualities are most influenced by the quantity and water quality. The use of magnetic water in concrete gives many benefits when it comes to increasing its properties. A substantial quantity of water can be saved by substituting potable water with magnetized water in concrete. In this study, the effects of magnetized water on the concrete's mechanical and durability properties were tested. Four different combinations were made using potable water and magnetic water. Mechanical properties including compression, flexural, tensile strength, and SEM analysis were evaluated. Water absorption, acid resistance, and corrosion resistance were all tested as part of the durability tests. According to the results of the experiments, employing magnetic water for concrete preparation and curing enhanced the mechanical properties and durability. Concrete mix MMMC prepared and subjected to curing using magnetized water has a 14.86% greater compressive strength than ordinary concrete. Similarly, tensile and flexural strength of mix MMMC amplified to 14.32% and 14.02%, respectively. Besides, the consumption of chemical admixtures also considerably reduced in magnetized water imbibed concrete.

Coated Magnetic Nanoparticles for Acidic Nuclear Waste Separation

2010 ◽  
Vol 1265 ◽  
Author(s):  
Maninder Kaur ◽  
Hongmei Han ◽  
Andrew Johnson ◽  
Jesof Kaczor ◽  
Andrzej Paszczynski ◽  
...  
Keyword(s):  
Magnetic Nanoparticles ◽  
Solvent Extraction ◽  
Ion Exchange ◽  
Nuclear Waste ◽  
Cost Effective ◽  
Silica Coating ◽  
Coating Process ◽  
Acidic Conditions ◽  
Allylamine Hydrochloride ◽  
Waste Separation

AbstractActinide specific chelator (che) conjugated with magnetic nanoparticles (MNPs) have been developed to separate nuclear waste in acidic conditions. Compared to the traditional nuclear waste treatments, such as solvent extraction and ion exchange, this method is a simple, compact and cost-effective process that generates minimum secondary waste. In this paper, we focus on the coating process of MNPs to achieve a combination of good acidic resistance, high chelator loading density and efficient magnetic separation. An optimized silica coating process before conjugates chelator directly onto MNPs significantly improves the acidic resistance of the MNP-che complex. Chelator loading density is significantly increased by attaching a linear polyamine polymer poly(allylamine hydrochloride) (PAH) to the surface of the MNPs using chemical and physical approaches.

Phase Analysis of Scale Deposition in Boiler Tubes Utilizing Steam-Assisted Gravity Drainage Produced Water

2016 ◽  
Vol 9 (1) ◽  
Author(s):  
Raymond Kuriger ◽  
David Young ◽  
Malcolm Mackenzie ◽  
Hamid Sarv ◽  
Jason Trembly
Keyword(s):  
Heat Transfer ◽  
Produced Water ◽  
Magnesium Silicate ◽  
Solid Content ◽  
Operating Conditions ◽  
Gravity Drainage ◽  
Dissolved Solids ◽  
X Ray ◽  
Steam Assisted Gravity Drainage ◽  
Boiler Tubes

Scale buildup on water-side heat transfer surfaces poses a potential operating challenge for steam-assisted gravity drainage (SAGD) boilers used in the production of bitumen since produced water, which has a high dissolved solid content, is recycled. Scale from deposition of dissolved solids on boiler tubes acts as a thermal insulating layer, decreasing heat transfer and lowering boiler efficiency. Understanding scale deposit composition on heat transfer surfaces is beneficial in the determination of adequate boiler maintenance practices and operating parameters. This research determined the effect of feedwater pH (7.5, 9.0, and 10.0) on scale composition resulting from deposition of dissolved solids under commercially relevant boiler operating conditions at 8.96 MPa (1300 psig) and 37.86 kW/m2 (12,000 Btu/h ft2). Scale deposits were analytically investigated using scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM/EDS), powder X-ray diffraction (XRD), and Raman spectroscopy. At feedwater pH values of 7.5 and 9.0, anhydrite (CaSO4), xonotlite (Ca6Si6O17(OH)2), and pectolite (NaCa2Si3O8(OH)) were detected. At the pH of 10.0, xonotlite and pectolite were identified in the absence of anhydrite. Furthermore, the magnesium silicate phase, serpentine (Mg3Si2O5(OH)4), was also postulated to be present.

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