Nucleation Agent Choice of Li2O–Al2O3–SiO2 Glass Ceramic Having Ideal Micro Spherical Crystal Grains

2011 ◽  
Vol 311-313 ◽  
pp. 1332-1335
Author(s):  
Hao Lv ◽  
Yao Ming Ding ◽  
Ai Mei Liu ◽  
Ju Fang Tong ◽  
Xu Nong Yi ◽  
...  
Keyword(s):  
Glass Ceramic ◽  
Crystallization Behavior ◽  
Nucleating Agent ◽  
Nucleating Agents ◽  
X Ray Diffraction ◽  
Nucleation Agent ◽  
X Ray ◽  
Spherical Crystal ◽  
Crystal Grains ◽  
Scanning Electron

The nucleation and crystallization of Li2O-Al2O3-SiO2(LAS) glass ceramic with one(P2O5, TiO2, ZnF2) and two nucleating agents(P2O5+TiO2, P2O5+ZnF2) are investigated by the differential thermal analysis(DTA)，X-ray diffraction(XRD) and the scanning electron microscopy(SEM). Research results show that the LAS glass ceramic with nucleating agent of P2O5can obtain ideal micro spherical crystal grains and the crystallization behavior can be better controlled.

Crystallization Behavior of PLA/PEG/Nucleating Agent Blends

2013 ◽  
Vol 807-809 ◽  
pp. 578-581 ◽  
Author(s):  
Jin Xu Dai ◽  
Qiang Yang ◽  
Bao Jian Liu
Keyword(s):  
Crystal Structure ◽  
Polyethylene Glycol ◽  
Crystallization Behavior ◽  
Crystallization Rate ◽  
Nucleating Agent ◽  
Nucleating Agents ◽  
X Ray Diffraction ◽  
X Ray ◽  
Crystallization Ability ◽  
Co Precipitation

A series of PLA blends were prepared by solution co-precipitation of polylactide (PLA), polyethylene glycol (PEG) and different crystallization nucleating agents. The crystallization behavior of blends was investigated by differential scanning calorimeter (DSC) and X-ray diffraction (XRD). The results showed that the crystallization ability of PLA blends was accelerated by plasticizer PEG, but the crystal structure of the obtained PLA blends was imperfect; the crystal structure and crystallization rate of the PLA blends were improved with the addition of nucleating agent, moreover, the crystallinity was 34.1% and 36.5%, respectively.

scholarly journals Effect of different nucleating agent on crystallization kinetics and morphology of polypropylene

e-Polymers ◽  
2019 ◽  
Vol 19 (1) ◽  
pp. 32-39 ◽  
Author(s):  
Yanjie An ◽  
Sihan Wang ◽  
Rui Li ◽  
Dezhu Shi ◽  
Yuxin Gao ◽  
...  
Keyword(s):  
Crystallization Kinetics ◽  
Crystallization Behavior ◽  
Polarized Light ◽  
Nucleating Agent ◽  
Crystallization Time ◽  
Nucleating Agents ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Half Crystallization Time

AbstractThe effects of phosphate nucleating agent (NA), carboxylate nucleating agent (MD), rosin type nucleating agent (WA) and sorbitol nucleating agent (NX) on crystallization behavior of isotactic polypropylene were investigated by fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), differential scanning calorimetry (DSC) and polarized light microscopy (PLM). The results showed that different structure nucleating agents significantly affected the crystallization kinetics, rate and temperature of polypropylene. Among them, half crystallization time of NX nucleating agent was the shortest, which was 53.4 seconds, and the crystallization temperature was the highest, reaching 129.8°C.

Research on compatibility and surface of high impact bio-based polyamide

2021 ◽  
pp. 095400832110055
Author(s):  
Yang Wang ◽  
Yuhui Zhang ◽  
Yuhan Xu ◽  
Xiucai Liu ◽  
Weihong Guo
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Differential Scanning Calorimetry ◽  
Crystallization Behavior ◽  
High Impact ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Scanning Electron

The super-tough bio-based nylon was prepared by melt extrusion. In order to improve the compatibility between bio-based nylon and elastomer, the elastomer POE was grafted with maleic anhydride. Scanning Electron Microscopy (SEM) and Thermogravimetric Analysis (TGA) were used to study the compatibility and micro-distribution between super-tough bio-based nylon and toughened elastomers. The results of mechanical strength experiments show that the 20% content of POE-g-MAH has the best toughening effect. After toughening, the toughness of the super-tough nylon was significantly improved. The notched impact strength was 88 kJ/m2 increasing by 1700%, which was in line with the industrial super-tough nylon. X-ray Diffraction (XRD) and Differential Scanning Calorimetry (DSC) were used to study the crystallization behavior of bio-based PA56, and the effect of bio-based PA56 with high crystallinity on mechanical properties was analyzed from the microstructure.

Core–shell structures with metallic silver as nucleation agent of low expansion phases in BaO/SrO/ZnO/SiO2 glasses

CrystEngComm ◽  
2019 ◽  
Vol 21 (29) ◽  
pp. 4373-4386 ◽  
Author(s):  
Christian Thieme ◽  
Michael Kracker ◽  
Katrin Thieme ◽  
Christian Patzig ◽  
Thomas Höche ◽  
...  
Keyword(s):  
Scanning Transmission Electron Microscopy ◽  
Nucleating Agent ◽  
Shell Structures ◽  
Metallic Silver ◽  
X Ray Diffraction ◽  
Nucleation Agent ◽  
X Ray ◽  
Transmission Electron ◽  
Scanning Transmission

The role of silver as a nucleating agent in BaO/SrO/ZnO/SiO2 glasses is studied with a range of microstructure-characterization techniques, such as scanning transmission electron microscopy, ultraviolet-visible spectroscopy, and X-ray diffraction.

MgO-Al2O3-SiO2 Glass-Ceramic Prepared by Sol-Gel Method

2010 ◽  
Vol 92 ◽  
pp. 131-137 ◽  
Author(s):  
Qiu Hua Yuan ◽  
Pei Xin Zhang ◽  
Li Gao ◽  
Hai Lin Peng ◽  
Xiang Zhong Ren ◽  
...  
Keyword(s):  
Glass Ceramic ◽  
Crystallization Behavior ◽  
Glass Powder ◽  
Sol Gel ◽  
Glass Ceramics ◽  
Green Body ◽  
Sintering Process ◽  
X Ray Diffraction ◽  
Sio2 Glass ◽  
X Ray

The crystallization behavior of MgO-Al2O3-SiO2 glass-ceramics by sol-gel technology was investigated by using x-ray diffraction (XRD), differential thermal analysis (DTA), Scanning electron microscopy (SEM). The results showed that: (1)α-cordierite phase was precipitated when the green body was calcined at 1050°C, and α-cordierite of high purity and stability could be formed at 1100°C; (2) Adding an appropriate amount of low melting point glass powder into the green body may provide liquid-phase environment during the sintering process, which will help enhance the tightness density of glass-ceramic, and thus improve its flexural strength.

Crystallization Properties of Nucleated Poly(lactic acid)

2012 ◽  
Vol 549 ◽  
pp. 322-326 ◽  
Author(s):  
Yong Chen ◽  
Qiang Dou
Keyword(s):  
Lactic Acid ◽  
Crystallization Behavior ◽  
Polarized Light ◽  
Nucleating Agent ◽  
Poly Lactic Acid ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Crystallization Properties ◽  
Melting And Crystallization

The effect of a nucleating agent (NT-C) on the crystallization behavior of poly(lactic acid) (PLA) was studied. The melting and crystallization behavior and spherulitic morphology of the nucleated PLA were investigated by means of differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD) and polarized light microscopy (PLM). It is found that the crystallization temperature and crystallinity increase, the spherulitic size decrease for the nucleated PLA. But the crystal structure of the nucleated PLA is not changed.

Controlled Growth and Self-Assembly of CaCO3 Superstructures between the Organic-Water Interfaces

2010 ◽  
Vol 434-435 ◽  
pp. 597-600
Author(s):  
Xiao Hong Liang ◽  
Jun Hui Xiang ◽  
Fu Shi Zhang ◽  
Li Xing ◽  
Bo Song ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Calcium Carbonate ◽  
Self Assembly ◽  
Crystallization Behavior ◽  
Gas Diffusion ◽  
The Self ◽  
Assembly Process ◽  
X Ray Diffraction ◽  
X Ray ◽  
Scanning Electron

In this paper, the crystallization behavior of calcium carbonate between the organic-water interfaces using a slow gas-diffusion procedure is studied. The organic-water interfaces can control the crystallization of calcium carbonate to form a flower-shaped superstructure. The precipitates of calcium carbonate were identified by X-ray diffraction (XRD) and scanning electron microscopy (SEM). A possible mechanism about the self-assembly process of CaCO3 crystals has been analyzed. It is found that the morphology of CaCO3 superstructure depends on the properties of organic solvent. This paper also presents the influence of surfactant monolayer, between the biphase interfaces, on the CaCO3 superstructure. This study suggests that it is possible to control morphogenesis of calcium carbonate by a combination of a surfactant monolayer with the organic-water interfaces.

Effects of Phosphorus and Fluorine on the Crystallization and Structure of CaO-A12O3-SiO2 System Glass-Ceramic

2008 ◽  
Vol 368-372 ◽  
pp. 1412-1414 ◽  
Author(s):  
Jin Shu Cheng ◽  
Hui Guang Qiu ◽  
Hong Li ◽  
Jun Xie
Keyword(s):  
Electron Microscopy ◽  
Thermal Analysis ◽  
Scanning Electron Microscopy ◽  
Glass Ceramic ◽  
Glass Ceramics ◽  
X Ray Diffraction ◽  
X Ray ◽  
Yellow Phosphorus ◽  
Crystallization Of Glass ◽  
Scanning Electron

CaO-A12O3-SiO2 (CAS) system glass-ceramics were prepared by sintering with certain amount of yellow phosphorus slag. The effects of phosphorus and fluorine on the nucleation, crystallization and structure of CAS system glass-ceramics were investigated by differential thermal analysis, X-ray diffraction, scanning electron microscopy and other measuring methods. Glass-ceramics of CAS system with 42.32wt% yellow phosphorus slag were obtained by nucleating at 615°C for 1 hour and crystallizing at 926°C for 2 hours. The results showed that the introduction of phosphorus and fluorine promoted the nucleation and crystallization of glass-ceramics, lowering the crystallizing temperature. The main crystal phase of glass-ceramics was β-wollastonite. The density of the glass-ceramic was 2.695g/cm3.

scholarly journals Properties Enhancement of High Molecular Weight Polylactide Using Stereocomplex Polylactide as a Nucleating Agent

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1725
Author(s):  
Purba Purnama ◽  
Muhammad Samsuri ◽  
Ihsan Iswaldi
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
Crystallization Behavior ◽  
Testing Machine ◽  
Nucleating Agent ◽  
Mechanical And Thermal Properties ◽  
Nucleating Agents ◽  
Thermal And Mechanical Properties ◽  
X Ray ◽  
Universal Testing

As one of the most attractive biopolymers nowadays in terms of their sustainability, degradability, and material tune-ability, the improvement of polylactide (PLA) homopolymer properties by studying the utilization of stereocomplex polylactide (s-PLA) effectively and efficiently is needed. In this sense, we have studied the utilization of s-PLA compared to poly D-lactide (PDLA) homopolymers as a nucleating agent for PLA homopolymers. The mechanical and thermal properties and crystallization behavior of PLA homopolymers in the presence of nucleating agents have been evaluated using a universal testing machine, differential scanning calorimeter, and X-ray diffractometer instruments, respectively. PDLA and s-PLA materials can be used to increase the thermal and mechanical properties of poly L-lactide (PLLA) homopolymers. The s-PLA materials increased the mechanical properties by increasing crystallinity of the PLLA homopolymers. PLLA/s-PLA enhanced mechanical properties to a certain level (5% s-PLA content), then decreased them due to higher s-PLA materials affecting the brittleness of the blends. PDLA homopolymers increased mechanical properties by forming stereocomplex PLA with PLLA homopolymers. Non-isothermal and isothermal evaluation showed that s-PLA materials were more effective at enhancing PLLA homopolymer properties through nucleating agent mechanism.

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