Synthesis and Application of Isothiazolinone as Durable Antibacterial

2011 ◽  
Vol 331 ◽  
pp. 265-269
Author(s):  
De Jia Kong ◽  
Zhen Dong Liu ◽  
Yan Li Li
Keyword(s):  
Escherichia Coli ◽  
1H Nmr ◽  
Cotton Fabrics ◽  
Esi Ms ◽  
Antibacterial Performance ◽  
Orthogonal Experiments ◽  
Washing Durability ◽  
Finishing Process ◽  
Staphyloccocus Aureus ◽  
Reactive Groups

A new antibacterial with two reactive groups was synthesized from isothiazolin-3-one and characterized by 1H-NMR and ESI-MS. Through the orthogonal experiments the optimal finishing process was got, that was bath ratio 1:20, Na2SO4 20 g/L, NaHCO315 g/L, T1:60°C, T2:70°C, t1:10 min, t2:20 min, t3:30 min (as shown in fig.1). The antibacterial evaluations of treated cotton fabrics showed that the antibacterial rates for Escherichia coli and Staphyloccocus aureus were 95.64% and 97.83% respectively, and 88.13% and 90.05% respectively after 30 washing cycles. The results indicated that the treated fabric had excellent antibacterial performance and washing durability.

Synthesis and Application of a Reactive Water-Soluble Antibacterial

2012 ◽  
Vol 627 ◽  
pp. 248-251
Author(s):  
Zhi Min Sun ◽  
De Jia Kong ◽  
Yan Li Li ◽  
Hao Dong ◽  
Zhen Dong Liu
Keyword(s):  
1H Nmr ◽  
Cotton Fabric ◽  
Cotton Fabrics ◽  
Water Soluble ◽  
Esi Ms ◽  
Antibacterial Performance ◽  
Orthogonal Experiments ◽  
Washing Durability ◽  
Finishing Process

A new reactive water-soluble isothiazolinone antibacterial was synthesized and characterized by 1H-NMR and ESI-MS. Through the orthogonal experiments, the optimal finishing process for cotton fabric was got, that was the bath ratio 1:20, Na2SO4 20 g/L, NaHCO3 15 g/L, t1: 30 min, t2: 50 min, T1: 50oC, T2: 95oC. The antibacterial evaluations of treated cotton fabrics showed that the antibacterial rate for S. aureus was 92.92%, and 86.04% after 50 washing cycles. The results indicated that the treated fabric had excellent antibacterial performance and washing durability.

Application of Two Reactive Water-Soluble Antibacterials on Polyester/Cotton Blend Fabrics

2013 ◽  
Vol 821-822 ◽  
pp. 642-645 ◽  
Author(s):  
Qing Pan ◽  
Zhi Min Sun ◽  
De Jia Kong ◽  
Xiao Ning Wang ◽  
Zheng Wu ◽  
...  
Keyword(s):  
Water Soluble ◽  
Antibacterial Performance ◽  
Orthogonal Experiments ◽  
Washing Durability ◽  
Finishing Process ◽  
Staphyloccocus Aureus

Two reactive antibacterials were applied to finish for polyester/cotton (T/C) blend fabrics (20/80) and (35/65) and the optimal finishing process was obtained by orthogonal experiments. The finished fabrics were undergone the evaluation of antibacterial performance. For both of the two antibacterials and two T/C fabrics, the lowest inhibition rates for Staphyloccocus aureus were 85.97% and 79.19% after 50 washing cycles. The results indicated that the treated fabric had good antibacterial performance and washing durability.

Synthesis of Fluoro-Containing Superhydrophobic Cotton Fabric with Washing Resistant Property Using Nano-SiO2 Sol-Gel Method

2010 ◽  
Vol 121-122 ◽  
pp. 23-26 ◽  
Author(s):  
Li Fen Hao ◽  
Qiu Feng An ◽  
Wei Xu ◽  
Qian Jin Wang
Keyword(s):  
Silica Nanoparticles ◽  
Cotton Fabric ◽  
Sol Gel ◽  
Cotton Fabrics ◽  
Water Repellent ◽  
Water Contact ◽  
Gel Method ◽  
Sol Gel Method ◽  
Washing Durability ◽  
Reactive Groups

A superhydrophobic complex coating for cotton fabrics based on silica nanoparticles and new fluoroalkylsiloxane polymer was reported here. The complex thin film was prepared through sol-gel method using cotton fabrics as a substrate. Silica nanoparticles in the coating made the textile surface much rougher, and new fluoroalkylsiloxane polymer with reactive groups on the top layer of the surface lowered the surface free energy and enhanced the binding between silica nanoparticles and the fluoro-containing polymer. Textiles coated with this coating showed excellent water repellent property, and water contact angle (CA) increased from 138° on the pure fluoroalkylsiloxane polymer treated cotton fabric up to 156.5° on complex one. Moreover, this superhydrophobic complex coating possesses favorable washing durability and its CA still retain 106° after 20 times of soaping operations.

scholarly journals Improving the Dyeability and Anti-Wrinkle Properties of Cotton Fabric via Oxidized Raffinose

2021 ◽  
Vol 11 (10) ◽  
pp. 4641
Author(s):  
Jiangfei Lou ◽  
Jinfang Zhang ◽  
Dan Wang ◽  
Xuerong Fan
Keyword(s):  
Catalyst Concentration ◽  
Structural Characteristics ◽  
Cotton Fabrics ◽  
Difficult Problem ◽  
Curing Temperature ◽  
Dyeing Performance ◽  
Finishing Process ◽  
Combined Mechanism ◽  
Recovery Angle ◽  
Butanetetracarboxylic Acid

In the anti-wrinkle finishing of cotton fabrics, the decreased dyeability of the finished fabrics has always been a difficult problem. A new anti-wrinkle finishing mode was developed to solve this problem by changing the finishing sequence of fabric dyeing and anti-wrinkle. In this research, the partial oxidization of raffinose with sodium periodate generated multiple aldehydes, which acted as multifunctional cross-linkers and endowed cotton fabrics with anti-wrinkle and hydrophilic properties. The structural characteristics of oxyRa were analyzed by FTIR and 13C-NMR. Through response surface methodology (RSM), the finishing model of oxyRa was established from the influencing factors of catalyst concentration, pH, curing temperature and time, and the optimized finishing process: the catalyst concentration was 20.12 g/L, pH was 4.32, curing temperature was 150 °C and curing time was 120 s. Under this condition, the predicted wrinkle recovery angle (WRA) of the finished fabric was up to 249.76°, Tensile strength (TS) was 75.62%, Whiteness index (WI) was 70.69. Importantly, comparing the anti-wrinkle and dyeing performance of the fabric with anti-wrinkle and then dyeing and anti-wrinkle after dyeing, the oxyRa-treated fabrics showed better dyeing properties compared with previously reported dimethyldihydroxyethylene urea (DMDHEU), glutaraldehyde (GA), and 1,2,3,4-butanetetracarboxylic acid (BTCA). Analysis of the combined mechanism of different finishing agents and cellulose, demonstrated the reason why oxyRa can be used to change the order of dyeing and anti-wrinkle finishing.

Interior vs. Exterior Incorporation of Silver Nanoparticles in Cotton Fiber and Washing Durability

2021 ◽  
Vol 8 (6) ◽  
pp. 1-12
Author(s):  
Sunghyun Nam ◽  
Sonia E. Chavez ◽  
Matthew B. Hillyer ◽  
Brian D. Condon ◽  
Hongqing Shen ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Cotton Fabric ◽  
Cotton Fiber ◽  
Detergent Solution ◽  
Ag Nps ◽  
Antibacterial Performance ◽  
The Poor ◽  
Washing Durability ◽  
Textile Products

The popular use of silver nanoparticles (Ag NPs) in commercial textile products that inhibit odor- and/or infection-causing bacteria has continuously raised concerns about their washing durability. The poor durability not only deteriorates the antibacterial performance, but also results in unwanted leaching of NPs into washing solutions. In this study, we showed how the incorporation location of Ag NPs—interior vs. exterior of cotton fiber—governs their durability against consecutive simulated home launderings. The superior washing durability of interior NPs was confirmed. The Ag losses after 50 laundering cycles for interior and exterior systems were 16% and 63% in water and 24% and 78% in detergent solution, respectively. The cotton fabric containing interior NPs predominantly released ionic Ag, whereas the fabric containing exterior NPs released particulate Ag.

scholarly journals Secondary metabolites of three endemic Centaurea L. species

2014 ◽  
Vol 79 (11) ◽  
pp. 1355-1362 ◽  
Author(s):  
Vele Tesevic ◽  
Ivana Aljancic ◽  
Slobodan Milosavljevic ◽  
Vlatka Vajs ◽  
Iris Djordjevic ◽  
...  
Keyword(s):  
Quantitative Analysis ◽  
Nmr Spectroscopy ◽  
Secondary Metabolites ◽  
Sesquiterpene Lactone ◽  
1H Nmr ◽  
13C Nmr ◽  
1H Nmr Spectroscopy ◽  
13C Nmr Spectroscopy ◽  
Esi Ms ◽  
Aerial Parts

The aerial parts of three endemic Centaurea L. species, namely C. tomorosii Micevski, C. soskae Hayek and C. galicicae Micevski, afforded sesquiterpene lactone cnicin (1) and seven flavonoids: apigenin (2), isokaempferide (3), hispidulin (4), eupatorin (5), cirsimaritin (6), santaflavone (7) and salvigenin (8). The structures of the isolated compounds were determined by UV, 1H NMR and 13C NMR spectroscopy and HR-ESI-MS spectrometry. 1H NMR spectroscopy was used as a method for quantitative analysis of sesquiterpene lactone cnicin.

scholarly journals Inactivation of Escherichia coli and Staphyloccocus aureus in Litchi Juice by Dimethyl Dicarbonate (DMDC) Combined With Nisin

2014 ◽  
Vol 3 (3) ◽  
pp. 1 ◽  
Author(s):  
Yuanshan Yu ◽  
Yujuan Xu ◽  
Jijun Wu ◽  
Gengsheng Xiao ◽  
Jing Wen ◽  
...  
Keyword(s):  
Escherichia Coli ◽  
Synergistic Effect ◽  
Ph Value ◽  
Inactivation Rate ◽  
Gram Positive ◽  
Gram Negative ◽  
E Coli ◽  
Complete Inactivation ◽  
Staphyloccocus Aureus ◽  
Addition Level

<p>Inactivation of Gram-negative <em>Escherichia coli</em> and Gram-positive <em>Staphyloccocus aureus</em> in litchi juice by DMDC combined with nisin was individually investigated. A 1.66 log cycles reduction of<em> E. coli </em>and 2.03 log cycles reduction of <em>S. aureus </em>in litchi juice (pH 4.5) added without nisin was achieved as exposed to 150 mg/l DMDC at 30 °C for 1 h, and the inactivation rate of <em>E. coli </em>and <em>S. aureus</em> during initial 1 h was far greater than during the remaining 5 h. As exposed to 150 mg/l DMDC at 30 °C for 1 h, the inactivation of <em>E. coli</em> and <em>S. aureus</em> in the litchi juice showed a trend toward increase with increasing of nisin addition level in the range from 0 to 200 IU/ml. Moreover, DMDC and nisin exhibited a synergistic effect on the inactivation of <em>E. coli</em> and <em>S. aureus</em> in litchi juice, and the inactivation of<em> E. coli</em> and <em>S. aureus</em> in the litchi juice also depends on the temperature of litchi juice, pH value of litchi juice and DMDC concentration when treated with DMDC and nisin. In addition, <em>E. coli</em> showed higher resistance to nisin as comparing with <em>S. aureus</em>. After <em>E. coli</em> and <em>S. aureus</em> in the litchi juice of pH 4.0 were individually treated with 150 mg/l DMDC combined with 200 IU/ml nisin at 30 °C for 1 h, a complete inactivation of <em>S. aureus</em> (6.59 log cycles) was achieved, but only 3.52 log cycles reduction of <em>E. coli</em> was observed.</p>

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