Development of Dielectric Elastomer Actuators - Part II: Preparation of the High Dielectric Constant Film Actuators Containing BaTiO3 Particles

2012 ◽  
Vol 557-559 ◽  
pp. 1869-1874 ◽  
Author(s):  
Takeshi Fukuda ◽  
Zhi Wei Luo ◽  
Aya Ito

Dielectric elastomer actuators with high dielectric constant and flexibility were prepared. These actuators were fabricated by the composite of barium titanate (BaTiO3) and polyester-type thermosetting polyurethane (TSU), which was molecularly-designed to become less hard segment content. In this study, the effects of particle size, volume fraction and manufacturing method of BaTiO3 were investigated. In addition, the mechanically-stretched effect in composites was also evaluated. It turned out that the electrical breakdown strength increased with the increase of particle size of BaTiO3 and in volume fraction as well as the use of BaTiO3 synthesized by the oxalate method. In addition, prestrain of composites also raised the electrical breakdown strength. However, the addition of BaTiO3 to polyurethane didn’t contribute to the actuation under a lower electric field.

2010 ◽  
Vol 20 (19) ◽  
pp. 3280-3291 ◽  
Author(s):  
Martin Molberg ◽  
Daniel Crespy ◽  
Patrick Rupper ◽  
Frank Nüesch ◽  
Jan-Anders E. Månson ◽  
...  

Materials ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 1687 ◽  
Author(s):  
Liang Jiang ◽  
Yanfen Zhou ◽  
Yuhao Wang ◽  
Zhiqing Jiang ◽  
Fang Zhou ◽  
...  

Dielectric elastomer (DE) composites with high electrical breakdown strength and large voltage-induced deformation were developed by retaining pre-stretched thermoplastic polyurethane (TPU) fibers in ethylene vinyl acetate copolymer (EVA). The microstructure of the candidate E-TPU fiber membrane and EVA coated E-TPU (E-TPU/EVA) film were characterized by scanning electron microscopy (SEM). The quasi-static and dynamic mechanical property, and the electromechanical properties, including the dielectric constant, dielectric loss tangent, and electromechanical sensitivity, of the DE composites were evaluated. Initially, tensile tests demonstrated that the DE composites based on E-TPU/EVAs had a higher elongation at break of above 1000% but a low elastic modulus of approximately 1.7 MPa. Furthermore, dielectric spectroscopy showed that the E-TPU/EVA had a dielectric constant of 4.5 at the frequency of 1000 Hz, which was 1.2 times higher than that of pure EVA film. Finally, it was found from electromechanical test that the voltage induced strain of E-TPU/EVA rose to 6%, nearly 3 times higher than that of pure TPU film, indicating an excellent electromechanical property. The DE composites developed have demonstrated the potential to be good candidate materials in the fields of artificial intelligence, biomimicry and renewable energy.


2013 ◽  
Vol 685 ◽  
pp. 331-335 ◽  
Author(s):  
Raj Kumar Sahu ◽  
Karali Patra

Elastomers have low elastic modulus, high specific energy density, light weight, high dielectric constant and high electrical breakdown strength. Due to these properties, elastomers are currently recognized as the future materials for actuator technology and actuators based on these materials are known as dielectric elastomer actuators (DEA). Based on Maxwell stress principle, these actuators transform electric energy directly into mechanical work. Modeling large actuation of this material depends on accurate estimation of E-modulus which varies with strain. In this work, E-modulus values at different strain are estimated based Mooney-Rivlin & Ogden Models. The model predicted values of E-modulus are compared with experimentally estimated values of E-modulus and found to be in good agreement.


e-Polymers ◽  
2011 ◽  
Vol 11 (1) ◽  
Author(s):  
Rui Li ◽  
Chuanxi Xiong ◽  
Lijie Dong

AbstractA novel all-polymeric material with high dielectric constant (k) has been developed by blending poly(vinylidene fluoride) (PVDF) with polyacrylamide (PAM). The dependence of the dielectric constant on frequency and polymer volume fraction was investigated. When the weight fraction of PAM is 1wt%, the dielectric constant of the blend could be up to 24, and the dielectric loss tanδ can be lowered to 0.06. The SEM investigations suggest that the enhanced dielectric behavior originates from significant interfacial interactions of polymer-polymer. XRD and FTIR demonstrate that blending PAM with PVDF affects the crystalline behavior of each component. Our finding suggests that the created high-k polymeric blends represent a novel type of material that are flexible and easy to process, and is of relatively high dielectric constant and high breakdown strength; moreover find applications as flexible electronics.


2012 ◽  
Vol 557-559 ◽  
pp. 1852-1856 ◽  
Author(s):  
Takeshi Fukuda ◽  
Zhi Wei Luo ◽  
Aya Ito

Dielectric elastomer actuators with enhanced flexibility were prepared by thermosetting polyurethane (TSU) consisting of polypropylene glycol (PPG) as an active hydrogen component and toluene diisocyanate (TDI) as an isocyanate component. The improvement was achieved by less hard segment content, i.e. less isocyanate index, the synthesized film actuators were compared with the actuator softened using a plasticizer. It was found that the film actuators prepared by this method had significant advantages in actuation under a lower electric field as well as the increase of electrical breakdown strength and of strain. Furthermore, the mechanically-stretched effect of the films was also evaluated. It turned out that prestrain up to 200% was effective in the increase of electrical breakdown strength while maintaining the actuation under a lower electric field. However, prestrain over 200% caused a decrease in actuation under a lower electric field.


RSC Advances ◽  
2017 ◽  
Vol 7 (59) ◽  
pp. 37148-37157 ◽  
Author(s):  
Mengnan Ruan ◽  
Dan Yang ◽  
Wenli Guo ◽  
Shuo Huang ◽  
Yibo Wu ◽  
...  

Barium titanate (BT) particles, BT-KH570 particles, and polar plasticizer tri-n-butyl phosphate (TBP) were added into BIIR matrix to form a dielectric elastomer composite, which had a high dielectric constant, good mechanical properties, and large actuated strain.


2020 ◽  
Vol 8 (44) ◽  
pp. 23330-23343
Author(s):  
Haibin Sun ◽  
Xueying Liu ◽  
Suting Liu ◽  
Bing Yu ◽  
Nanying Ning ◽  
...  

A silicone dielectric elastomer with simultaneous high dielectric constant, fast and efficient self-healing ability at mild conditions was prepared by constructing supramolecular network assembled by coordination bonds and hydrogen bonds.


2017 ◽  
Vol 07 (01) ◽  
pp. 1750007 ◽  
Author(s):  
Gang Liu ◽  
Wentao Jiang ◽  
Jingyong Jiao ◽  
Li Liu ◽  
Ziyang Wang ◽  
...  

Ba[Formula: see text]Sr[Formula: see text]TiO3 ceramics with or without ZnO have been prepared by traditional solid state reaction method. The XRD analysis showed that the doped Zn[Formula: see text] ions diffused into the BST crystal lattice, resulting in the variation of dielectric properties. Especially the dielectric constant at Curie point decreased with doping ZnO content when it is lower than 0.5[Formula: see text]mol%. Due to the promotion of sintering, doping ZnO can enhance the density of ceramics but increase grain size. However, ZnO is a kind of semiconductor and can lead to the decrease in electrical breakdown strength value.


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