Preparation of Aluminum Phosphate Low in Acidity and its Application on Fiber Protection

2013 ◽  
Vol 699 ◽  
pp. 470-475
Author(s):  
Qiu Ru Wang ◽  
Ji Chuan Huo ◽  
Yong Lin Lei ◽  
Wei Ai
Keyword(s):  
High Temperature ◽  
Protective Coating ◽  
Chemical Properties ◽  
Aluminum Phosphate ◽  
Phase Reaction ◽  
Sem Images ◽  
High Silica ◽  
Reinforced Fiber ◽  
Pre Treatment ◽  
Physical And Chemical

With excellent physical and chemical properties, aluminum phosphate is a great potential high temperature protective coating of fiber. In this paper, a kind of aluminum phosphate low in acidity was prepared from aluminum isopropoxide (AIP) and diammonium phosphate ((NH4)2HPO4) by hydrothermal and liquid-phase reaction methods respectively. The performance of aluminum phosphate prepared by the two methods was comparatively evaluated using FTIR, XRD, TG techniques. As a protective coating, aluminum phosphate was applied to the pre-treatment of high silica reinforced fiber cloth. After added 1% MgO, The SEM images indicated that aluminum phosphate prepared by hydrothermal method could cover the surface of the fiber more uniformly. The mechanical testing results showed that tensile strength of the obtained coated material was improved at high temperature.

scholarly journals Influence of the Bottom Color Modification and Material Color Modification Process on the Performance of Modified Poplar

Coatings ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 660
Author(s):  
Qingqing Liu ◽  
Di Gao ◽  
Wei Xu
Keyword(s):  
Chemical Properties ◽  
Target Color ◽  
Modification Process ◽  
Red Color ◽  
The Difference ◽  
Pre Treatment ◽  
Physical And Chemical ◽  
Surface Differentiation ◽  
Color Modification ◽  
And Chemical Properties

According to the old surface coating process of European and American furniture, the surface of modified poplar is first differentiated pre-treatment, and then the bottom color modification and material color modification are respectively applied to the modified poplar after the surface differentiation treatment. The visual physical quantity and physical and chemical properties were measured and compared with mahogany, which is commonly used in old furniture in Europe and America to explore the effect of colorants and coloring steps, as well as different surface pretreatments on the coloring effect. Finally, it is concluded that continuous coloring operations can narrow the difference in brightness and red color value in the coloring layer of modified poplar and mahogany. Continuous coloring operations increase the difference between the yellow-green color values of modified poplar and mahogany. Therefore, the coloring difference between modified poplar and mahogany was affected by the colorant and coloring steps. Through color accumulation, the gap between the two in the target color coloring effect can be reduced, thereby reducing the difference between the coloring effect of modified poplar and mahogany.

Influence of Regeneration Condition on Physical and Chemical Properties of High Temperature Coal Gas Desulfurization Sorbent

2014 ◽  
Vol 521 ◽  
pp. 658-661
Author(s):  
Lei Yang ◽  
Shang Guan Ju ◽  
Yu Kun Gao ◽  
Yan Hui Hu
Keyword(s):  
High Temperature ◽  
Circulatory System ◽  
Chemical Properties ◽  
Space Velocity ◽  
Physical And Chemical Properties ◽  
Coal Gas ◽  
Regeneration Condition ◽  
Atmosphere Temperature ◽  
Physical And Chemical ◽  
And Chemical Properties

Physical and chemical properties are closely related to desulfurization, regeneration performance and cycle stability for high temperature coal gas desulfurizer. This review focuses on influence rules of changes in regeneration atmosphere, temperature and space velocity on physical and chemical properties. A large number of experimental researches have shown that regeneration atmosphere, regeneration temperature, space velocity have an important influence on mechanical strength, active component and texture change for high temperature coal gas desulfurizer. The different regeneration atmosphere obviously results in different active ingredients for desulfurization sorbent after regeneration, and regeneration at a higher regeneration temperature will easily cause desulfurizer sintering, as well as small regeneration space velocity can lead to the formation of sulfates. In order to make the circulatory system of sulfidation-regeneration-sulfidation need to the requirements in industrial application, the further research of influence rules of regeneration condition on physical and chemical properties will be crucial.

scholarly journals The novel method to reduce the silica content in lignin recovered from black liquor originating from rice straw

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Nghi H. Do ◽  
Hieu H. Pham ◽  
Tan M. Le ◽  
Jeroen Lauwaert ◽  
Ludo Diels ◽  
...  
Keyword(s):  
Rice Straw ◽  
Black Liquor ◽  
Chemical Properties ◽  
Alkaline Treatment ◽  
Pilot Scale ◽  
Silica Content ◽  
Silica Removal ◽  
High Silica ◽  
Novel Method ◽  
Physical And Chemical

AbstractDifficulties in the production of lignin from rice straw because of high silica content in the recovered lignin reduce its recovery yield and applications as bio-fuel and aromatic chemicals. Therefore, the objective of this study is to develop a novel method to reduce the silica content in lignin from rice straw more effectively and selectively. The method is established by monitoring the precipitation behavior as well as the chemical structure of precipitate by single-stage acidification at different pH values of black liquor collected from the alkaline treatment of rice straw. The result illustrates the significant influence of pH on the physical and chemical properties of the precipitate and the supernatant. The simple two-step acidification of the black liquor at pilot-scale by sulfuric acid 20w/v% is applied to recover lignin at pH 9 and pH 3 and gives a percentage of silica removal as high as 94.38%. Following the developed process, the high-quality lignin could be produced from abundant rice straw at the industrial-scale.

The reliability of radiocarbon dates of different carbon fractions in the Australian tropical savannas: A case study from Sanamere Lagoon, northeast Australia

2020 ◽  
Author(s):  
Maria Rivera-Araya ◽  
Michael Bird ◽  
Cassandra Rowe ◽  
Sean Ulm ◽  
Vladimir Levchenko
Keyword(s):  
Chemical Properties ◽  
Treatment Method ◽  
Tropical Lake ◽  
Tropical Lakes ◽  
Radiocarbon Dates ◽  
Carbon Fractions ◽  
Polycyclic Aromatic ◽  
Organic Fractions ◽  
Pre Treatment ◽  
Physical And Chemical

<p>The selection and pre-treatment of a reliable organic fraction from which to acquire radiocarbon dates is fundamental to obtain accurate chronologies. Sampling from tropical lakes is particularly challenging given the adverse preservation conditions and diagenesis in these environments. Our research is the first to examine and quantify the differences between the radiocarbon date results from different carbon fractions and pretreatments from the same depths from a tropical lake sediment core (1.72 m long) located in north Australia to assess which one(s) are more reliable. Six different organic fractions (bulk organics, pollen concentrate, cellulose, stable polycyclic aromatic carbon (SPAC), charcoal >250 um and charcoal >63 um), for a total of 27 radiocarbon dates, were compared in six different depths along the core. Acid-base-acid (ABA), modified ABA (30 % hydrogen peroxide + ABA), 2chlorOx (a novel cellulose pre-treatment method) and hydrogen pyrolysis (hypy) were used to pre-treat the correspondent organic fractions. The oldest date is 31,295 calibrated years before present (cal yr BP) and the youngest is 2,048 cal yr BP, spanning 29,247 years. The smallest offset between the minimum and the maximum age in a given depth was found to be 975 years (between SPAC and charcoal >63 um) and the largest 16,527 years (between pollen concentrate and SPAC). The SPAC fractions pre-treated with hypy consistently yielded older ages compared to all other fraction in most cases, while bulk organics yielded consistently younger ones. The magnitude and consistency of the offsets and the physical and chemical properties of the tested organic fractions suggest that SPAC is the most reliable fraction to date in tropical lake sediments and that hypy successfully removes contamination sourced from exogenous carbon.</p>

scholarly journals Marine Gelatine from Rest Raw Materials

2018 ◽  
Author(s):  
Ivan Milovanovic ◽  
Maria Hayes
Keyword(s):  
Functional Properties ◽  
Raw Materials ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Film Forming ◽  
Pre Treatment ◽  
Polypeptide Chains ◽  
Physical And Chemical ◽  
By Products ◽  
And Chemical Properties

In recent years, demand for consumption of marine foods, and especially fish, has substantially increased worldwide. The majority of collagen available is sourced from mammalian-derived products. Although fish derived gelatine is a viable alternative to mammalian sourced gelatine, there are some challenges related to the use of fish gelatine including odour, colour, gelling and film forming properties as well as consistency in gelatine amino acid composition. Chemicals used for pre-treatment, as well as extraction conditions such as temperature and time, can influence the length of polypeptide chains that result and the functional properties of the gelatine. Compared to mammalian sources, gelatines derived from fish show notable differences in physical and chemical properties, and great care should be paid to optimization of the production process in order to obtain a product with the best properties for intended applications. The focus of this review is to explore the feasibility of producing gelatine sourced from marine processing by-products using different pre-treatment and extraction strategies with the aim of improving the techno-functional properties of the final product and improving the clean-label status of gelatines. The bioactivities of gelatine hydrolysates are also discussed.

An Instrument Established for the High Temperature Measurement of Ultraviolet-Visible Absorption Spectra of Molten Fluoride Salt Behaving As Coolant in the Molten Salt Reactor

2018 ◽  
Author(s):  
Hongtao Liu ◽  
Yiyang Liu ◽  
Tao Su
Keyword(s):  
High Temperature ◽  
Molten Salts ◽  
Room Temperature ◽  
Chemical Properties ◽  
Molten Salt Reactor ◽  
Physical And Chemical Properties ◽  
Molten Fluoride ◽  
Fluoride Salts ◽  
Physical And Chemical ◽  
And Chemical Properties

Molten salts were widely used in nuclear and solar power field due to the excellent heat transfer and storage. Molten fluoride salts were selected as primary and secondary coolants in the Molten Salt Reactor Experiment (MSRE) developed by Oak Ridge National Laboratory (ORNL). Therefore, it is dramatically important to study the physical and chemical properties of molten fluoride salts that impact on the design of reactor core and thermohydraulics. The molecular structure directly determines the physical and chemical properties of matter, so it is also essential to study the structure of molten salts. Spectroscopy has been proven to be a very useful tool for investigating molten salts structures. However, the standard instrument is inapplicable for measurement of the high temperature molten salts, especially for molten fluoride salts. To obtain the ultraviolet-visible (UV-Vis) absorption spectra of molten salts at high temperature, an instrument was designed to study the structures of molten salts in situ. The instrument is mainly composed of a vertical pit furnace connecting with a glovebox and an assembled cuvette which can operate from room temperature up to 800°C. The assembled cuvette is made of Hastelloy C/N as the main body with a reverse ‘T’ contour and diamond or crystalline CaF2 etc. as the window plates, so it can withstand the corrosion produced by the sample and allow the interest light passing through. The effective spectral range of this instrument is from 200 to 1000 nm. Performances of the instrument are testified by spectral studies on water under room temperature and molten salts under high temperature.

scholarly journals Characterization of PVC-based polymer inclusion membranes with phosphonium ionic liquids

2019 ◽  
Vol 138 (6) ◽  
pp. 4437-4443
Author(s):  
Katarzyna Witt ◽  
Elżbieta Radzymińska-Lenarcik
Keyword(s):  
Ionic Liquids ◽  
Chemical Properties ◽  
Toxic Metal ◽  
Covalent Bond ◽  
Sem Images ◽  
Cyphos Il 101 ◽  
Cyphos Il 104 ◽  
The Stability ◽  
Physical And Chemical ◽  
Phosphonium Ionic Liquids

Abstract Membrane techniques can be used to separate different compounds, i.e., toxic metal ions from waste waters. As any other method of separation, also this one, based on polymer inclusion membranes (PIMs), has certain limitations. One of them is the stability of membranes. In the present paper, the dependence of the physical and chemical properties on composition of PVC-based polymer inclusion membranes doped with phosphonium ionic liquids (CYPHOS IL 101, CYPHOS IL 104, CYPHOS IL 105 and CYPHOS IL 109) was studied. The thermal stability of investigated membranes was examined by thermogravimetry together with differential thermogravimetry analysis. Obtained results showed that studied PIMs are stable to the temperature of about 170 °C. The membrane morphology was examined by attenuated total reflectance Fourier-transform infrared (ATR-FTIR) spectroscopy, as well as scanning electron microscopy (SEM). The visibility of all characteristic bands in the ATR-FTIR spectra confirmed the presence of individual components in the membranes: a polymer, a plasticizer and the carriers. It also suggested that there were no signs of the covalent bond formation between the polymer, the plasticizer and the carrier. Only van der Waals or hydrogen bonds could be present. Moreover, in the SEM images of the investigated PIMs a rough surface without pores was observed.

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