Kinetic Study on Pyrolysis of Gentamicin Residue

2014 ◽  
Vol 955-959 ◽  
pp. 2803-2808
Author(s):  
Ren Ping Liu ◽  
Rui Yao ◽  
Hui Li
Keyword(s):  
Activation Energy ◽  
High Temperature ◽  
Thermochemical Conversion ◽  
Pyrolysis Kinetics ◽  
Heating Rates ◽  
Exponential Factor ◽  
Thermogravimetric Analyzer ◽  
Basic Work ◽  
Mechanism Function ◽  
Kinetics Of

Gentamicin bacteria residue contains high organic compound. The technology of thermochemical conversion can effectively solve the problem of bulk gentamicin residue disposal, research on pyrolysis kinetics of the reaction is the basic work for thermochemical conversion . In this paper, Pyrolysis experiments were carried out in a thermogravimetric analyzer under inert conditions and operated at different heating rates (5, 10, 20 K/min).Two different kinetic models, the iso-conversional Ozawa–Flynn–Wall (Ozawa) models and Satava method were applied on TGA data of gentamicin residue to calculate the kinetic parameters including activation energy, pre-exponential factor and Mechanism function. The results showed that: gentamicin bacteria residue lost most weight of it between 100-650 °C , about 74.23% of the whole sample can decompose under high temperature. The pyrolysis function for gentamicin residue should be G(α) =[-ln(1-α)]3.

scholarly journals Pyrolysis kinetics and thermal decomposition behavior of polycarbonate - a TGA-FTIR study

2014 ◽  
Vol 18 (3) ◽  
pp. 833-842 ◽  
Author(s):  
Esin Apaydin-Varol ◽  
Sevgi Polat ◽  
Ayse Putun
Keyword(s):  
Activation Energy ◽  
Fourier Transform ◽  
Reaction Order ◽  
Fourier Transform Infrared ◽  
Pyrolysis Kinetics ◽  
Heating Rates ◽  
Exponential Factor ◽  
Thermogravimetric Analyzer ◽  
Fourier Transform Infrared Spectrometer ◽  
Infrared Spectrometer

This study covers the thermal degradation of polycarbonate by means of Thermogravimetric Analyzer coupled with Fourier transform infrared spectrometer (TGA-FTIR). Thermogravimetric analysis of polycarbonate was carried out at four different heating rates of 5, 10, 15, and 20?C per minute from 25?C to 1000?C under nitrogen atmosphere. The results indicated that polycarbonate was decomposed in the temperature range of 425-600?C. The kinetic parameters, such as activation energy, pre-exponential factor and reaction order were determined using five different kinetic models; namely Coast-Redfern, Friedman, Kissinger, Flynn-Wall-Ozawa (FWO), and Kissinger-Akahira-Sunose (KAS). Overall decomposition reaction order was determined by Coats-Redfern method as 1.5. Average activation energy was calculated as 150.42, 230.76, 216.97, and 218.56 kJ/mol by using Kissinger, Friedman, FWO, and KAS models, respectively. Furthermore, the main gases released during the pyrolysis of polycarbonate were determined as CO2, CH4, CO, H2O, and other lower molecular weight hydrocarbons such as aldehydes, ketones and carbonyls by using thermogravimetric analyzer coupled with Fourier transform infrared spectrometer.

scholarly journals Thermogravimetric Kinetics of Selected Energy Crops Pyrolysis

Energies ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3977
Author(s):  
Magdalena Matusiak ◽  
Radosław Ślęzak ◽  
Stanisław Ledakowicz
Keyword(s):  
Activation Energy ◽  
Energy Crops ◽  
Pyrolysis Kinetics ◽  
Heating Rates ◽  
Exponential Factor ◽  
Miscanthus Giganteus ◽  
Temperature Ranges ◽  
The Given ◽  
Kinetics Of ◽  
Derivative Thermogravimetry

The main purpose of this paper was to compare the pyrolysis kinetics of three types of energy crops: Miscanthus giganteus, Sida hermaphrodita, and Sorghum Moench. Studies were conducted in thermobalance. Feedstock samples were heated up from ambient temperature to 600 °C under an inert argon atmosphere. Three heating rates of β = 5, 10, and 20 °C/min were applied. Reactions occurring in the given temperature ranges were grouped together into so-called lumps identified by the deconvolution of derivative thermogravimetry (DTG) curves that corresponded to biomass compositions (hemicellulose, cellulose, and lignin). For the estimation of the activation energy and pre-exponential factor, the Friedman and Ozawa–Flynn–Wall methods were used. The final kinetic parameters were determined by nonlinear regression assuming that thermal decomposition proceeded via three parallel independent reactions of the nth order. The activation energy of hemicellulose, cellulose and lignin was determined to be in the range of 92.9–97.7, 190.1–192.5, and 170–175.2 kJ/mol, respectively. The reaction order was in the range of 3.35–3.99 for hemicellulose, 1.38–1.93 for cellulose, and 3.97–3.99 for lignin. The obtained results allow us to estimate the pyrolytic potential of energy crops selected for this study, and can be used in designing efficient pyrolizers for these materials.

scholarly journals Thermal Analysis On The Kinetics Of Magnesium-Aluminum Layered Double Hydroxides In Different Heating Rates

2015 ◽  
Vol 60 (2) ◽  
pp. 1357-1359 ◽  
Author(s):  
Y. Hongbo ◽  
C. Meiling ◽  
W. Xu ◽  
G. Hong
Keyword(s):  
Activation Energy ◽  
Thermal Analysis ◽  
Layered Double Hydroxides ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Exponential Factor ◽  
Thermal Kinetic Parameters ◽  
Double Hydroxides ◽  
Kinetics Of ◽  
Dsc Curves

Abstract The thermal decomposition of magnesium-aluminum layered double hydroxides (LDHs) was investigated by thermogravimetry analysis and differential scanning calorimetry (DSC) methods in argon environment. The influence of heating rates (including 2.5, 5, 10, 15 and 20K/min) on the thermal behavior of LDHs was revealed. By the methods of Kissinger and Flynn-Wall-Ozawa, the thermal kinetic parameters of activation energy and pre-exponential factor for the exothermic processes under non-isothermal conditions were calculated using the analysis of corresponding DSC curves.

Pyrolysis of Sugarcane Bagasse: A Consecutive Reactions Kinetic Model from TGA Experiments

2010 ◽  
Vol 660-661 ◽  
pp. 593-598 ◽  
Author(s):  
Kássia Graciele dos Santos ◽  
Taisa S. Lira ◽  
Valéria V. Murata ◽  
Marco Gianesella ◽  
Marcos A.S. Barrozo
Keyword(s):  
Kinetic Model ◽  
Sugarcane Bagasse ◽  
Room Temperature ◽  
Linear Method ◽  
Pyrolysis Kinetics ◽  
Heating Rates ◽  
Exponential Factor ◽  
Consecutive Reactions ◽  
Kinetics Of ◽  
Good Agreement

The pyrolysis kinetics of sugarcane bagasse in nitrogen flow was studied by thermogravimetric analysis from room temperature to 1173 K at different heating rates (1.5, 3, 5, 10, 15, 20, 30 and 50 K/min). As there are three distinct devolatilization peaks in the DTG curve, each peak was associated to thermal decomposition of an individual biomass subcomponent (hemicellulose, cellulose and lignin). The kinetic model adopted was a consecutive reactions model. The kinetic parameters of the pyrolysis process, such as activation energy and pre-exponential factor, were calculated by least squares non-linear method and Scilab are used as the simulation tool. The simulated results showed a good agreement with the experimental data and the parameters found are similar to reported by the literature.

Thermogravimetric Analysis of KCl-Pretreated Soybean Stalk

2015 ◽  
Vol 1092-1093 ◽  
pp. 118-121
Author(s):  
Dong Yu Chen ◽  
Qing Yu Liu
Keyword(s):  
Activation Energy ◽  
Thermogravimetric Analysis ◽  
Metal Salts ◽  
Pyrolysis Kinetics ◽  
Ozawa Method ◽  
Heating Rates ◽  
Energy Value ◽  
Lower Activation ◽  
Higher Temperature ◽  
Kinetics Of

To study the influence of KCl pretreating on the pyrolysis kinetics of soybean stalk, the pyrolysis of soybean stalk pretreated by different concentration KCl solutions were performed by nonisothermal thermogravimetric analysis (TGA) at five different heating rates. The Ozawa method was employed to calculate the activation energy. The results showed that the pyrolysis process of the soybean stalk pretreated by 3% and 10% KCl solution can be separated into four stages (water loss, depolymerization and vitrification, thermal decomposition, and carbonization). With the heating rate increasing, the main pyrolysis zone of the TG (thermogravimetric) and DTG curves move to the higher temperature region, and the maximum pyrolysis rate and its corresponding temperature increase too. A small amount of metal salts addition is conducive to the formation of volatile, and a certain amount of metal salts can improve the charcoal yield. More KCl additive makes the lower activation energy value, and the obtained activation energy value increases with the reaction degree.

Study on Thermal Decomposition Kinetics of Nano-Cr(OH)3 Powder

2014 ◽  
Vol 692 ◽  
pp. 377-380 ◽  
Author(s):  
Feng Pan ◽  
Zai Yuan Li ◽  
Chun Ji Li
Keyword(s):  
Activation Energy ◽  
Thermal Decomposition ◽  
Shape Factor ◽  
Decomposition Analysis ◽  
Decomposition Kinetics ◽  
Peak Shape ◽  
Exponential Factor ◽  
Mechanism Function ◽  
Kinetics Of ◽  
Tga Analysis

Abstract. This paper studies on the thermal decomposition analysis kinetics of nanometer powders. The DTA-TG-DTG curves obtain by SDT 2960 Simultaneous DSC-TGA analysis apparatus. Under the condition of N2atmosphere operation and rise temperature velocity was 10°C·min-1. The mechanism function dα/dt=κ(1-α)nis used to calculate the kinetics factors. Reaction progressionnwas obtained by calculation of the kissinger peak shape factor method. The results showed that the apparent activation energy of nano-Ni(OH)2was 254.027 KJ·mol-1, the pre-exponential factor was 3.062×1036, the reaction progression was obtained as 1.560, the kinetic equation is dα/dt=3.062×1036exp(-30554.166/T)(1-α)1.560

Study on Kinetics of Nano-Ni(OH)2 Powder Ethanol Desorption Process

2014 ◽  
Vol 1015 ◽  
pp. 509-512
Author(s):  
Feng Pan ◽  
Zai Yuan Li ◽  
Chun Ji Li
Keyword(s):  
Activation Energy ◽  
Thermal Analysis ◽  
Shape Factor ◽  
Peak Shape ◽  
Desorption Process ◽  
Exponential Factor ◽  
Mechanism Function ◽  
Thermal Analysis Kinetics ◽  
Kinetics Of ◽  
Tga Analysis

This paper studies on the thermal analysis kinetics of nanometer powders ethanol desorption process.The DTA-TG-DTG curves obtain by SDT 2960 Simultaneous DSC-TGA analysis apparatus. Under the condition of N2atmosphere operation and rise temperature velocity was 10°C·min-1. The mechanism functionis used to calculate the kinetics factors. Reaction progressionnwas obtained by calculation of the kissinger peak shape factor method. The results showed that the apparent activation energy of nano-Ni(OH)2was 73.210 kJ·mol-1, the pre-exponential factor was 2.349×1012, the reaction progression was obtained as 1.2767, the kinetic equation is

scholarly journals Comparison of the dehydration kinetics of solid state compounds of 2-methoxybenzylidenepyruvate with some divalent metal ions

2010 ◽  
Vol 35 (1) ◽  
pp. 7-18
Author(s):  
M. Kobelnik ◽  
C. A. Ribeiro ◽  
D. S. Dias ◽  
G. A. Bernabé ◽  
M. S. Crespi
Keyword(s):  
Activation Energy ◽  
Solid State ◽  
Nitrogen Atmosphere ◽  
Divalent Metal ◽  
Point Of View ◽  
Conversion Degree ◽  
Divalent Metal Ions ◽  
Heating Rates ◽  
Exponential Factor ◽  
Kinetics Of

Divalent metal complexes of ligand 2-methoxybenzylidenepyruvate with Fe, Co, Ni, Cu and Zn as well as sodium salt were synthesized and investigated in the solid state. TG curves of these compounds were obtained with masses sample of 1 and 5mg under nitrogen atmosphere. Different heating rates were used to characterize and study these compounds from the kinetic point of view. The activation energy and pre-exponential factor were obtained applying the Wall-Flynn-Ozawa method to the TG curves. The obtained data were evaluated and the values of activation energy (Ea / kJ mol-1) was plotted in function of the conversion degree (α). The results show that due to mass sample, different activation energies were obtained. The results are discussed mainly taking into account the linear dependence between the activation energy and the pre exponential factor, where was verified the effect of kinetic compensation (KCE) and possible linear relations between the dehydrations steps of these compounds.

Pyrolysis Kinetics Equation of Larch Bark

2013 ◽  
Vol 772 ◽  
pp. 313-318
Author(s):  
Hong Shuang Du ◽  
Xiang Yu Li ◽  
Xue Yong Ren ◽  
Yan Xue Han
Keyword(s):  
Mass Loss ◽  
Mass Loss Rate ◽  
Kinetic Equations ◽  
Nitrogen Atmosphere ◽  
Pyrolysis Kinetics ◽  
Heating Rates ◽  
Linear Temperature ◽  
Exponential Factor ◽  
Kinetics Of ◽  
Pyrolysis Kinetic

The larch bark was examined by non-isothermal means to determine the mass loss kinetics of the thermal decomposition with linear temperature programming in nitrogen atmosphere. In this work, mechanism equation of = was used forCoats-Redfern integral methodat the different heating rates. The apparent activation energy, pre-exponential factor and the pyrolysis kinetic equations at the different heating rates were obtained. The pyrolysis temperature area was divided into two separate temperature regions for the pyrolysis kinetic equation and the two components were decomposed respectively at the two separate temperature regions. The global mass loss rate of the bark is considered as controlled respectively by the reactions of the two components respectively during the lower and higher temperature ranges. The kinetics of the two components are found to abide by the mechanism equation of =, which gave the best fits to the experimental data. The obtained kinetic equations of the bark at the different heating rates were additionally validated by the reasonable agreement between the experimental and calculated results.

scholarly journals Thermal Decomposition Mechanism of GIS Basin Insulator and Kinetic Parameters-Based Lifetime Prediction Methodology

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 653
Author(s):  
Peng Ren ◽  
Qingmin Li ◽  
Honglei Liu ◽  
Yunpeng Li ◽  
Peng Peng ◽  
...  
Keyword(s):  
Activation Energy ◽  
Reaction Mechanism ◽  
Kinetic Parameters ◽  
Thermal Decomposition Mechanism ◽  
Heating Rates ◽  
Computational Accuracy ◽  
Exponential Factor ◽  
Analysis Experiment ◽  
Mechanism Function ◽  
Pyrolysis Kinetic

To reliably detect the latent defects and accurately evaluate the remaining life of gas insulated switchgear (GIS) basin insulators, more effective detection and characterization methods need to be explored. The study of pyrolysis kinetic parameters based on the intrinsic characteristics of materials provides a new way to solve this problem. First, an integral expression model of the reaction mechanism function with four parameters is proposed in this paper, which can represent various existing reaction mechanism functions with better universality and more application fields. Then, on the basis of the temperature transformation equation, an improved method for calculating the activation energy is presented, which shows higher computational accuracy than the existing methods. Further, based on a non-isothermal kinetic equation, the structure of the experimental function is given. It is a method for solving the pyrolysis reaction mechanism function of insulating materials, which can also be used to calculate the pre-exponential factor simultaneously. The thermogravimetric analysis experiment is carried out on a certain basin insulator sample at different heating rates. The pyrolysis kinetic state parameters, including the activation energy, reaction mechanism function and pre-exponential factor of the basin insulator, are calculated. Finally, the life prediction method of basin insulators is established, and the key factors affecting the life of insulators are discussed.

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