Immobilized Bio-Beads with Activated Carbon Fiber for Removal of Benzene

2010 ◽  
Vol 96 ◽  
pp. 93-98 ◽  
Author(s):  
Xiu Li Liu ◽  
Lin Zhao ◽  
She Jiang Liu ◽  
Lu Hua You

Two kinds of new immobilized bio-beads in gel were produced with calcium alginate, polyvinyl alcohol and activated carbon fiber. Scanning electron microscopy was used to detect the microstructure and MB were applied to enhance degradation of benzene. It shows that activated carbon fiber was a excellent carrier material to increase MB stability and enhance the degradation of benzene by changing the microsructure. CA-MB in this study was characteristic of loose interface, intensely homogeneous holes and well-reusability. 80% of benzene could be reduced after120h and removal tallied with one-order knetics.Otherwise,for PVA-MB, it possed more compact ouside and irregular tunnles and poles inside.Benzene removal process was analysed to compose of absorption and biodegradation.The immobilization inoculum of 137.77mg/L was optimal with the most stabilities and the best degradation capability for both CA-MB and PVA-MB. Moreover, it is the addition of ACF as encapsulated carrier that made CA-MB superior to PVA-MB in benzene removal and reutilization.

2013 ◽  
Vol 33 (3) ◽  
pp. 257-263 ◽  
Author(s):  
Sreekumar Parambathmadhom Appu ◽  
Sadhan Kumar De ◽  
Massihullah J. Khan ◽  
Mamdouh A. Al-Harthi

Abstract Starch plasticized with glycerol and blended with polyvinyl alcohol (PVA) is recommended for use as a biodegradable material. The present article reports the results of studies of the natural weather ageing of starch/PVA blends having various amounts of glycerol in natural weather conditions of Saudi Arabia, with special reference to morphology and thermal behavior. Neat PVA has been used as a control to understand its behavior in its blend with starch. Differential scanning calorimeter studies indicated that an increase in the exposure time of samples to natural environment increases the crystallinity of PVA due to the breakage of intermolecular hydrogen bonding, thus facilitating the removal of the amorphous portion of the polymers in the blend. Thermogravimetric analysis revealed that an increase in glycerol content enhanced the degradation of the polymer, which is corroborated with the findings from the surface morphology using scanning electron microscopy and Fourier transfer infrared spectroscopy analyses.


BioResources ◽  
2017 ◽  
Vol 12 (4) ◽  
pp. 8641-8652
Author(s):  
Jing Geng ◽  
Lu-Fei Li ◽  
Wen-Liang Wang ◽  
Jian-Min Chang ◽  
Chang-Lei Xia ◽  
...  

Characteristics of the char produced in the co-pyrolysis of used rubber and larch sawdust were studied in the conversion of low-valued pyrolysis char into value-added activated carbon using two-step co-pyrolysis, namely pyrolysis and activation processes. The physicochemical characteristics of the chars were examined by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), and scanning electron microscopy (SEM). The results revealed that after the two-step co-pyrolysis, the upgraded carbon had BET surface areas ranging from 600 m2 g−1 to 900 m2 g−1, which were higher than the requirements for activated carbon (American Water Works Association B600 standard). Additionally, as the sawdust/rubber ratio increased, the BET value increased accordingly. A possible reaction mechanism is proposed based on the experimental results during the activation process.


Membranes ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 827
Author(s):  
Syeda Samia Nayab ◽  
M. Asad Abbas ◽  
Shehla Mushtaq ◽  
Bilal Khan Niazi ◽  
Mehwish Batool ◽  
...  

A rapid increase in population worldwide is giving rise to the severe problem of safe drinking water availability, necessitating the search for solutions that are effective and economical. For this purpose, membrane technology has shown a lot of promise but faces the challenge of fouling, leading to a reduction in its lifetime. In this study, ultrafiltration polyethersulfone membranes were synthesized in two different concentrations, 16% wt. and 20% wt., using the phase inversion method. Chitosan and activated carbon were incorporated as individual fillers and then as composites in both the concentrations. A novel thiolated chitosan/activated carbon composite was introduced into a polyethersulfone membrane matrix. The membranes were then analyzed using Attenuated Total Reflection–Fourier-Transform Infrared spectroscopy (ATR-FTIR), Scanning Electron Microscopy (SEM), optical profilometry, gravimetric analysis, water retention, mechanical testing and contact angle. For membranes with the novel thiolated chitosan/activated carbon composite, Scanning Electron Microscopy micrographs showed better channels, indicating a better permeability possibility, reiterated by the flux rate results. The flux rate and bovine serum albumin flux were also assessed, and the results showed an increase from 105 L/m2h to 114 L/m2h for water flux and the antifouling determined by bovine serum albumin flux increased from 23 L/m2h to 51 L/m2h. The increase in values of water uptake from 22.84% to 76.5% and decrease in contact angle from 64.5 to 55.7 showed a significant increase in the hydrophilic character of the membrane.


1994 ◽  
Vol 3 (4) ◽  
pp. 096369359400300
Author(s):  
G. Carotenuto ◽  
A. Gallo ◽  
L. Nicolais

The wetting kinetics of a solid surface by a molten metal decrease with increase of its roughness. The topography of the growing copper coating, produced on carbon fiber surface by electroplating from a sulphat bath, has been studied by scanning electron microscopy. The smoothes surface is produced after 200÷300 milliampere-hour of plating.


2012 ◽  
Vol 466-467 ◽  
pp. 458-462
Author(s):  
Ying Jie Zhang ◽  
Shu Fen Xu ◽  
Xia Liao ◽  
Rong Yang ◽  
Da Peng Li

A new heterogeneous Fenton-like catalyst of Fe/S/GAC was prepared by granular activated carbon (GAC) soaked in solution of (NH4)2S2O8 and Fe(NO3)3. The effect of the concentration of (NH4)2S2O8 , Fe(NO3)3, drying temperature and different catalysts on the catalytic reactivity of catalyst was discussed. The removal rate of Orange IV was used to express the catalytic reactivity of the catalyst. The prepared catalysts were characterized by X-ray diffraction (XRD), specific surface area (BET) and scanning electron microscopy (SEM). The removal rate of Orange IV followed second-order kinetics. The catalyst of Fe/S/GAC has higher catalytic activity than that of Fe/GAC.


2019 ◽  
Vol 11 (41) ◽  
pp. 5311-5319 ◽  
Author(s):  
Veysel Berkdemir ◽  
Şerife Tokalıoğlu ◽  
Süleyman Yıldız ◽  
Şaban Patat

In this study, an activated carbon@Fe/Mn/O composite was synthesized and characterized by X-ray diffraction, scanning electron microscopy coupled with energy dispersive X-ray spectroscopy, Brunauer, Emmett, and Teller surface area and zeta potential measurements.


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