Effects of Sawdust Content and Alkali Treatment on Mechanical and Flame Retarding Properties of Sawdust/Recycled High Density Polyethylene Composites

2014 ◽  
Vol 970 ◽  
pp. 79-83
Author(s):  
Rapisa Jarapanyacheep ◽  
Kasama Jarukumjorn

Sawdust/recycled high density polyethylene (rHDPE) composites were prepared and their mechanical properties, flammability and morphology were investigated. Sawdust was used at contents of 30, 40 and 50 wt%. With increasing sawdust content, tensile strength and elongation at break of the composites decreased whereas tensile modulus increased. Flexural properties showed the same trend as tensile properties. Flammability of the composites enhanced with increasing sawdust content. Mechanical properties of alkali treated sawdust/rHDPE composites were higher than those of untreated sawdust/rHDPE composites at all sawdust contents. Moreover, alkali treatment improved flame retardancy of the composites. SEM micrographs showed that alkali treatment enhanced the interfacial adhesion between sawdust and rHDPE matrix.

Author(s):  
Innocent Ochiagha Eze ◽  
Isaac O. Igwe ◽  
Okoro Ogbobe ◽  
Emmanuel Enyioma Anyanwu ◽  
Ikenna Nwachukwu

The effects of pineapple leaf powder (PALP) on the mechanical properties of high density polyethylene (HDPE) composites were studied. HDPE and PALP composites were prepared by injection moulding technique. The filler (PALP) contents investigated were 2, 4, 6, 8, and 10 wt% for each formulation. Results of the mechanical tests carried out on the HDPE/PALP composites showed that the tensile strength, tensile modulus, flexural strength, abrasion resistance, and hardness of the composites increased with increases in filler content for all the filler contents investigated while the elongation at break (EB) for PALP/HDPE composites was found to decrease with increases in filler content for all the filler contents investigated. The tensile strength of PALP/HDPE composites was increased by 6.49% at 2 wt% filler content, and 30.39% at 10 wt% filler content. It was also observed, from the results, that the elongation at break of PALP/HDPE composites was decreased by 2.40% at 2 wt% filler content, and 10.24% at 10 wt% filler content. The present study has highlighted the utility of pineapple leaf powder (PALP) as reinforcing filler in HDPE compounding. Pineapple leave which is an agricultural waste has been shown to have potential as a cheap, more readily available and more environmentally friendly filler.


2017 ◽  
Vol 756 ◽  
pp. 35-43
Author(s):  
Martin Bednarik ◽  
Adam Skrobak ◽  
Vaclav Janostik

This study deals with the effect of high doses of ionizing beta radiation (132, 165 and 198 kGy) on mechanical properties (tensile strength, tensile modulus and elongation) of low and high density polyethylene under thermal loading. The measurement results of this study indicate that with an increasing dose of radiation grows tensile strength and modulus of low and high density polyethylene. For all examined materials were also observed changes in elongation.


Author(s):  
Innocent Ochiagha Eze ◽  
Isaac O. Igwe ◽  
Okoro Ogbobe ◽  
Henry C. Obasi ◽  
U. Luvia Ezeamaku ◽  
...  

The effects of compatibilizer (maleic anhydride-graft-polyethylene) on the mechanical properties of pineapple leaf powder (PALP) filled high density polyethylene (HDPE) composites were studied. HDPE and PALP composites in the presence, or absence of the compatibilizer, maleic anhydride -graft- polyethylene (MA-g-PE) were prepared by injection moulding technique. The filler (PALP) contents investigated were 2, 4, 6, 8, and 10 wt%, while the MA-g-PE content was 3 wt% of the filler content for each formulation. The result of the mechanical tests carried out on the HDPE/PALP composites showed that the tensile strength, tensile modulus, abrasion resistance, and hardness of the composites increased as the filler content increases both in the presence, or absence of the compatibilizer (MA-g-PE) for all the filler contents investigated, while the elongation at break (EB) for PALP/HDPE composites was found to decrease as the filler content increases both in the presence, or absence of MA-g-PE for all the filler contents investigated. It was also observed that PALP/HDPE composites in the presence of MA-g-PE exhibited better mechanical properties than that of PALP/HDPE composites in the absence of MA-g-PE for all the filler contents investigated. The present study has proved that the mechanical properties of PALP/HDPE composites can be enhanced by incorporating a compatibilizer (MA-g-PE) into their formulations. This is so because the chemical composition of the compatibilizer (MA-g-PE) allows it to react with the fibre surface, thereby forming a bridge of chemical bonds between the fibre and matrix.


2013 ◽  
Vol 750-752 ◽  
pp. 858-862
Author(s):  
Cheng You Ma ◽  
Yan Mei Ma ◽  
Zhi He ◽  
Chen Yan ◽  
Dong Jiang

Double block copolymers of polyethersulfone (PES)/polycarbonate (PC) were used as a compatibilizer for a blend of PES/PC. The morphology, thermal properties, mechanical properties, etc. of the resulting ternary blend systems were investigated. The addition of the compatibizer improved the compatibility between PES and PC. It was found that the interfacial adhesion was enhanced; the size of the dispersed phase was reduced. This resulted in an improvement of elongation at break and tenacity of PES/PC blends, while the tensile modulus slightly increased, and tensile strength was almost constant.


2017 ◽  
Vol 25 (4) ◽  
pp. 299-308 ◽  
Author(s):  
M.A. Abedini Najafabadi ◽  
S. Nouri Khorasani ◽  
J. Moftakharian Esfahani

This study investigates the effect of the addition of nanoclay (Cloisite 20A) on some mechanical properties, % relative brightness (ΔLrel) and total colour change (ΔEab) of high density polyethylene (HDPE)/pistachio shell flour (PSF) composites when exposed to accelerated weathering conditions. X-ray diffraction (XRD) patterns of samples containing 3 and 6 per hundred composite (phc) of nanoclay indicated partial exfoliation and intercalation. The tensile modulus and tensile strength of HDPE/PSF composites (without nanoclay) decreased when the exposure time increased to 1500 h, while the tensile modulus and tensile strength increased. For samples with nanoclay, ΔLrel and ΔEab increased upon accelerated weathering conditions up to 500 h, and thereafter remained constant. But results show that ΔLrel and ΔEab increased significantly upon accelerated weathering exposure in HDPE/PSF samples up to 1500 h. Scanning electron microscopy (SEM) results after 1500 h exposure to weathering condition showed signs of the presence of cracks in samples without nanoclay, unlike the samples with nanoclay.


2012 ◽  
Vol 626 ◽  
pp. 828-833 ◽  
Author(s):  
Ai Ling Pang ◽  
Hanafi Ismail

The mechanical properties of polypropylene (PP)/waste tire dust (WTD)/kenaf (KNF) composites with and without 3-aminopropyltriethoxysilane (APTES) coupling agent were investigated. The composites were prepared using a Thermo Haake Polydrive internal mixer, where different KNF loading (0, 5, 10, 15, 20 phr) were used. The results revealed that the tensile modulus increased with increasing KNF loading but tensile strength and elongation at break were found decreased. Composites with APTES give higher tensile strength and modulus but lower elongation at break than composites without APTES. The presence of APTES enhanced the interfacial adhesion between PP/WTD matrices and KNF which result in higher tensile strength and modulus of the composites. These findings were supported by the morphological study of the tensile fractured surfaces of the composites.


2014 ◽  
Vol 679 ◽  
pp. 292-299
Author(s):  
Mohamad Kahar Ab Wahab ◽  
H. Ismail ◽  
N.Z. Noriman ◽  
H. Kamarudin ◽  
A.M. Mustafa Al Bakri

Effects of citric acid on the mechanical properties of thermoplastic tapioca starch/high density polyethylene/natural rubber (HDPE/NR/TPS) blends were investigated. The ratio between HDPE/NR was fixed at 70/30 and used as a matrix system. TPS loadings with and without modification with citric acid (CA) were varied from 0% to 30wt%. Mechanical and physical properties of blends were evaluated as a function of TPS loadings modified with and without CA. The tensile strength, Young’s modulus and elongation at break were found to decrease with increasing TPS content. However an improvement in the tensile strength for TPS modified with CA at 5%, 10% and 20% TPS loadings was observed. The degree of TPS adhesion and dispersion in HDPE/NR blends were determined by scanning electron microscope (SEM).Keywords; HDPE/NR/TPS, citric acid, tensile properties, morphology.


2019 ◽  
Vol 800 ◽  
pp. 210-215
Author(s):  
Walid Fermas ◽  
Mustapha Kaci ◽  
Remo Merijs Meri ◽  
Janis Zicans

In this paper, the effect of unmodified halloysite nanotubes (HNTs) content on the chemical structure and the thermal and mechanical properties of blends based on starch-grafted-polyethylene (SgP) and high density polyethylene (HDPE) (70/30 w/w) nanocomposites was investigated at various filler content ratios, i.e. 1.5, 3 and 5 wt.%. The study showed the occurrence of chemical interactions between the polymer matrix and HNTs through OH bonding. Further, the addition of HNTs to the polymer blend led to an increase in the crystallization temperature of the nanocomposite samples, in particular at higher filler contents i.e. 3 and 5 wt.%, while the melting temperature remained almost unchanged. Tensile and flexural properties of the nanocomposite samples were however improved compared to the virgin blend with respect to the HNTs content ratio.


2015 ◽  
Vol 754-755 ◽  
pp. 201-204
Author(s):  
Ragunathan Santiagoo ◽  
Sam Sung Ting ◽  
Azlinda Abdul Ghani ◽  
Hanafi Ismail ◽  
Awiezan Mislan

The compatibilizer effect of ENR-50 on the tensile properties of high density polyethylene (HDPE)/recycled acrylonitrile butadiene rubber (NBRr)/banana skin powder (BSP)/ composites has been studies. HDPE/NBRr/BSP composites were prepared by melt mixing technique using twin-screw at 180 °C for 9 minutes at rotor speed 50 rpm. The six different composites studied were 100/0/5, 80/20/5, 70/30/5, 60/40/5, 50/50/5, and 40/60/5. As for compatibilized composite a fix 5 wt% of ENR-50 was evaluated. The specimens were analysed for tensile strength and elongation at break (Eb). The results showed that tensile strength and the elongation at break were decreases with the increasing of NBRr loading. However for ENR-50 compatibilized composites, higher tensile strength and elongation at break was recorded. The ENR-50 was found to be an excellent compatibilizer for HDPE/NBRr/BSP composites.


2011 ◽  
Vol 380 ◽  
pp. 290-293
Author(s):  
Bing Tao Wang ◽  
Ping Zhang ◽  
De Gao

In situ melt copolycondensation was proposed to prepare biodegradable copolyester nanocomposites based on degradable components poly(L-lactic acid) (PLA), rigid segments poly(butylene terephthalate) (PBT), and nanoparticles polyhedral oligomeric silsesquioxanes (POSS). The morphologies and dispersions of two POSS nanoparticles (POSS-NH2 and POSS-PEG) in the copolyester PLABT matrix and their effects on the mechanical properties were investigated. The results demonstrated that the morphologies and dispersions of POSS-NH2 and POSS-PEG showed quite different characteristics. POSS-PEG took better dispersion in the PLABT, while POSS-NH2 had poor dispersions and formed crystalline microaggregates. Due to the good dispersion and strong interfacial adhesion of POSS-PEG with the matrix, the tensile strength and Young’s modulus were greatly improved from 6.4 and 9.6 MPa for neat PLABT up to 11.2 and 70.7 MPa for PLABT/POSS-PEG nanocomposite. Moreover, the incorporation of POSS-PEG could impart macromolecular chains good flexibility and improve the mobility of the chains, so the the elongation at break of PLABT/POSS-PEG nanocomposite dramatically increased from 190 to 350 % compared with neat PLABT.


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