A Study on the Factors Affecting the Uniformity of Urea and Exhaust Gas Using an SCR Simulator

2020 ◽  
Vol 399 ◽  
pp. 145-153
Author(s):  
Munseok Choe ◽  
Dogyeong Kang ◽  
Dooseuk Choi
Keyword(s):  
Negative Pressure ◽  
Exhaust Pipe ◽  
Exhaust Gas ◽  
Mixing Ratio ◽  
Gas Temperature ◽  
Flow Uniformity ◽  
Factors Affecting ◽  
Exhaust Gas Temperature ◽  
Scr System ◽  
Type Mixer

As it is difficult to confirm mixed shape and mixing ratio which depend on the actual mixer inside the SCR, the present study on mixed shape and mixing ratio has been conducted by producing an SCR system simulator. Total 19 sensors were installed and the system was designed not to allow formation of a negative pressure inside the exhaust pipe. The experiment was conducted setting engine rpm, temperature, mixer shape, and distance as the experiment variables. As a result of the experiment, in the case of non-mixer type, a phenomenon was found where urea became locally packed as the exhaust gas and urea were not mixed and, when an R-type mixer was applied, urea was formed being spread on the whole. It was also confirmed that uniformity index was increased by 8 % in average when an R-type mixer was used in comparison to that of the non-mixer type, and the non-mixer type failed to achieve flow uniformity of 90 % or higher while the case where an R-type mixer was used could achieve it when the distance was 20 cm or bigger. Based on such a result, changes in the uniformity of urea and exhaust gas depending on existence of a mixer, exhaust gas temperature, engine rpm, and distance could be confirmed. It is thought that additional studies are required to be conducted later on the effect of a change in the mixer shape on flow uniformity.

Modeling and simulation of marine SCR system based on Modelica

2022 ◽  
pp. 146808742110722
Author(s):  
Jie Shi ◽  
Yuanqing Zhu ◽  
Hui Peng ◽  
Haoyu Yan ◽  
Tinghui Li ◽  
...  
Keyword(s):  
Flow Rate ◽  
Great Influence ◽  
Slip Rate ◽  
Urea Solution ◽  
Bench Test ◽  
Stoichiometric Ratio ◽  
Exhaust Gas ◽  
Gas Temperature ◽  
Exhaust Gas Temperature ◽  
Scr System

With the increasing awareness of global marine environmental protection, the emission of ship exhaust pollutants is strictly restricted. Selective catalytic reduction (SCR) technology is the mainstream technology to reduce ship NOx emission and make it meet IMO tier III regulations. A SCR reaction kinetic model based on Modelica language was established by Dymola software to predict the denitration efficiency, ammonia slip rate, and other parameters of SCR system. According to the functional structure of marine SCR system, the SCR system model is divided into urea injection module, mixer module, and SCR reactor module. The model was verified by SCR system bench test of WD10 diesel engine, which proved that the model can preferably reflect the actual situation. Using the established model, the effects of temperature, flow rate, NH3/NOx Stoichiometric Ratio (NSR), and cell density on the denitration performance of SCR system were analyzed. The results showed that the exhaust gas temperature and NSR have a great influence on the denitration efficiency. The injection amount of urea solution in marine SCR system should be based on the exhaust gas temperature and exhaust flow rate.

Large Two-Stroke Marine Diesel Engine Operation with a High-Pressure SCR System in Heavy Weather Conditions

2020 ◽  
pp. 1-15 ◽  
Author(s):  
Michael I. Foteinos ◽  
George I. Christofilis ◽  
Nikolaos P. Kyrtatos
Keyword(s):  
High Pressure ◽  
Weather Conditions ◽  
Irregular Waves ◽  
Ship Motions ◽  
Exhaust Gas ◽  
Time Varying ◽  
Gas Temperature ◽  
Marine Diesel ◽  
Exhaust Gas Temperature ◽  
Scr System

The transient performance of a direct-drive large two-stroke marine diesel engine, installed in a vessel operating in a seaway with heavy weather, is investigated via simulation. The main engine of the ship is equipped with a selective catalytic reduction (SCR) after treatment system for compliance with the latest International Maritime Organization (IMO) rules for NOx reduction, IMO Tier III. Because of limitations of exhaust gas temperature at the inlet of SCR systems and the low temperature exhaust gases produced by marine diesel engines, in marine applications, the SCR system is installed on the high-pressure side of the turbine. When a ship sails in heavy weather, it experiences a resistance increase, wave-induced motions, and a time-varying flow field in the propeller, induced by ship motions. This results in a fluctuation of the propeller torque demand and, thus, a fluctuation in engine power and exhaust gas temperature, which can affect engine and SCR performance. To investigate this phenomenon and take into account the engine–propeller interaction, the entire propulsion plant was modeled, namely, the slow-speed diesel propulsion engine, the high-pressure SCR system, the directly driven propeller, and the ship's hull. To simulate the transient propeller torque demand, a propeller model was used, and torque variations due to ship motions were taken into account. Ship motions in waves and wave-added resistance were calculated for regular and irregular waves using a 3D panel code. The coupled model was validated against available measured data from a shipboard propulsion system in good weather conditions. The model was then used to simulate the behavior of a Tier III marine propulsion plant during acceleration from low to medium load, in the presence of regular and irregular waves. The effect of the time-varying propeller demand on the engine and the SCR system was investigated. 1. Introduction The effect of waves on a marine propulsion system is a complex phenomenon involving interactions between different subsystems of the propulsion plant, i.e., the prime mover, the propeller, and the ship's hull. Ships sailing in heavy weather conditions experience a resistance increase, wave-induced motions, and a time-varying flow field in the propeller. This leads to a fluctuation of the propeller torque demand which results in a fluctuation in engine-produced power and exhaust gas temperature.

Compound Control Strategy Based on Active Disturbance Rejection for Selected Catalytic Reduction systems

2015 ◽  
Vol 137 (5) ◽  
Author(s):  
Jinbiao Ning ◽  
Fengjun Yan
Keyword(s):  
Control Strategy ◽  
Disturbance Rejection ◽  
Catalytic Reduction ◽  
Exhaust Gas ◽  
Gas Temperature ◽  
Model Uncertainties ◽  
Compound Control ◽  
Active Disturbance Rejection ◽  
Exhaust Gas Temperature ◽  
Scr System

Urea-based selected catalytic reduction (SCR) systems are effective ways in diesel engine after-treatment systems to meet increasingly stringent emission regulations. To achieve high NOx reduction efficiency and low NH3 slip, the control of the SCR system becomes more challenging, especially in transient operating conditions with model uncertainties. To effectively address this issue, this paper proposed a compound control strategy with a switching mechanism between an active disturbance rejection (ADR) controller and a zero-input controller. The ADR controller estimates and rejects the total (internal and external) disturbances from the SCR system when the exhaust gas temperature is high and its variation is small. The zero-input controller is used to lower ammonia surface coverage ratio to avoid high ammonia slip when exhaust gas temperature suddenly rises. The proposed control strategy is validated through a high-fidelity GT-Power simulation for a light-duty diesel engine over steady states and federal test procedure (FTP-75) test cycle. Its effectiveness is demonstrated especially in rapidly transient conditions with model uncertainties.

scholarly journals Ammonium-Salt Formation and Catalyst Deactivation in the SCR System for a Marine Diesel Engine

Catalysts ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 21 ◽  
Author(s):  
Yuanqing Zhu ◽  
Qichen Hou ◽  
Majed Shreka ◽  
Lu Yuan ◽  
Song Zhou ◽  
...  
Keyword(s):  
Diesel Engine ◽  
Decomposition Reaction ◽  
Marine Diesel Engine ◽  
Exhaust Gas ◽  
Gas Temperature ◽  
Scr Catalyst ◽  
Marine Diesel ◽  
Fast Scr ◽  
Exhaust Gas Temperature ◽  
Scr System

Due to the low temperature and complex composition of the exhaust gas of the marine diesel engine, the working requirements of the selective catalytic reduction (SCR) catalyst cannot be met directly. Moreover, ammonium sulfate, ammonium nitrate, and other ammonium deposits are formed at low temperatures, which block the surface or the pore channels of the SCR catalyst, thereby resulting in its reduction or even its loss of activity. Considering the difficulty of the marine diesel engine bench test and the limitation of the catalyst sample test, a one-dimensional simulation model of the SCR system was built in this paper. In addition, the deactivation reaction process of the ammonium salt in the SCR system and its influencing factors were studied. Based on the gas phase and the surface reaction kinetics, the models of the urea decomposition, the surface denitrification, the nitrate deactivation, and the sulfate deactivation were both constructed and verified in terms of accuracy. Moreover, the formation/decomposition reaction pathway and the catalytic deactivation of ammonium nitrate and ammonium bisulfate, as well as the composition concentration and the exhaust gas temperature range were correspondingly clarified. The results showed that within a certain range, the increase of the NO2/NOx ratio was conducive to the fast SCR reaction and the NH4NO3 formation’s reaction. Increasing the exhaust gas temperature also raised the NO2/NOx ratio, which was beneficial to both the fast SCR reaction and the NH4NO3 decomposition reaction, respectively. Furthermore, the influence of the SO2 concentration on the denitrification efficiency decreased with the increase of the exhaust gas temperature because of increasing SCR reaction rate and reversibility of ammonia sulfate formation, and when the temperature of the exhaust gas was higher than 350 °C, the activity of the catalyst was almost unaffected by ammonia sulfate.

Lime kiln conversion from coke to natural gas operation – an option in direction of sustainable energy

2020 ◽  
pp. 431-434
Author(s):  
Oliver Arndt
Keyword(s):  
Natural Gas ◽  
New Technology ◽  
Exhaust Gas ◽  
Gas Temperature ◽  
Gaseous Fuels ◽  
Lime Kiln ◽  
Lime Kilns ◽  
Co2 Balance ◽  
Exhaust Gas Temperature

This paper deals with the conversion of coke fired lime kilns to gas and the conclusions drawn from the completed projects. The paper presents (1) the decision process associated with the adoption of the new technology, (2) the necessary steps of the conversion, (3) the experiences and issues which occurred during the first campaign, (4) the impacts on the beet sugar factory (i.e. on the CO2 balance and exhaust gas temperature), (5) the long term impressions and capabilities of several campaigns of operation, (6) the details of available technologies and (7) additional benefits that would justify a conversion from coke to natural gas operation on existing lime kilns. (8) Forecast view to develop systems usable for alternative gaseous fuels (e.g. biogas).

scholarly journals Exhaust Gas Temperature Measurements in Diagnostics of Turbocharged Marine Internal Combustion Engines Part I Standard Measurements

2015 ◽  
Vol 22 (1) ◽  
pp. 47-54 ◽  
Author(s):  
Zbigniew Korczewski
Keyword(s):  
Internal Combustion Engines ◽  
Internal Combustion ◽  
Technical Condition ◽  
Temperature Measurements ◽  
Injection System ◽  
Exhaust Gas ◽  
Combustion Engines ◽  
Gas Temperature ◽  
Measuring Signal ◽  
Exhaust Gas Temperature

Abstract The article discusses the problem of diagnostic informativeness of exhaust gas temperature measurements in turbocharged marine internal combustion engines. Theoretical principles of the process of exhaust gas flow in turbocharger inlet channels are analysed in its dynamic and energetic aspects. Diagnostic parameters are defined which enable to formulate general evaluation of technical condition of the engine based on standard online measurements of the exhaust gas temperature. A proposal is made to extend the parametric methods of diagnosing workspaces in turbocharged marine engines by analysing time-histories of enthalpy changes of the exhaust gas flowing to the turbocompressor turbine. Such a time-history can be worked out based on dynamic measurements of the exhaust gas temperature, performed using a specially designed sheathed thermocouple. The first part of the article discusses possibilities to perform diagnostic inference about technical condition of a marine engine with pulse turbocharging system based on standard measurements of exhaust gas temperature in characteristic control cross-sections of its thermal and flow system. Selected metrological issues of online exhaust gas temperature measurements in those engines are discusses in detail, with special attention being focused on the observed disturbances and thermodynamic interpretation of the recorded measuring signal. Diagnostic informativeness of the exhaust gas temperature measurements performed in steady-state conditions of engine operation is analysed in the context of possible evaluations of technical condition of the engine workspaces, the injection system, and the fuel delivery process.

Energetic Based Organic Fluid Selection for a Solid Oxide Fuel Cell-Organic Rankine Cycle Combined System

2012 ◽  
Vol 622-623 ◽  
pp. 1162-1167
Author(s):  
Han Fei Tuo
Keyword(s):  
Fuel Cell ◽  
Solid Oxide Fuel Cell ◽  
Heat Recovery ◽  
Waste Heat ◽  
Solid Oxide ◽  
Exhaust Gas ◽  
Oxide Fuel ◽  
Gas Temperature ◽  
Selection For ◽  
Exhaust Gas Temperature

In this study, energetic based fluid selection for a solid oxide fuel cell-organic rankine combined power system is investigated. 9 dry organic fluids with varied critical temperatures are chosen and their corresponding ORC cycle performances are evaluated at different turbine inlet temperatures and exhaust gas temperature (waste heat source) from the upper cycle. It is found that actual ORC cycle efficiency for each fluid strongly depends on the waste heat recovery performance of the heat recovery vapor generator. Exhaust gas temperature determines the optimal fluid which yields the highest efficiency.

Experimental Study of Natural Gas Fuel Temperature Influence on Radiation Enhancement and Emission

2010 ◽  
Author(s):  
S. Mohammad Javadi ◽  
Pourya Nikoueeyan ◽  
Mohammad Moghiman ◽  
M. Ebrahim Feyz
Keyword(s):  
Radiation Intensity ◽  
Flame Temperature ◽  
Photovoltaic Module ◽  
Exhaust Gas ◽  
Gas Temperature ◽  
Fuel Temperature ◽  
Flame Radiation ◽  
Exhaust Gases ◽  
No Formation ◽  
Exhaust Gas Temperature

The enhancement of the flame radiation in gas fueled burners not only improves the thermal efficiency, but also can suppress the rate of NO emission due to reducing the flame temperature. In this experimental investigation, the effect of inlet gas temperature on the flame radiation intensity and the rate of NO formation are studied. To serve this aim, with increasing the temperature of inlet methane to the burner up to 310°C, the variations of CO and NO level in exhaust gases and also the exhaust gas temperature are recorded by gas analyzer device. In each case, the flame radiation intensity was also measured by a photovoltaic module. The results revealed that by increasing the inlet gas temperature up to 250°C, the NO concentration and the exhaust gases temperature are raising. But when the inlet gas temperature exceeds from 250°C and reaches to 310°C, the flame luminosity gradually increases which results in 70 percent growth in flame radiation and 10 percent drop in exhaust gas temperature. The results of the preheating of inlet air also show the same behavior.

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