Poly(Vinyl Alcohol) Fiber Reinforced High Density Poly(Ethylene) Composites: Dynamic Mechanical Thermal Analysis

2018 ◽  
Vol 773 ◽  
pp. 46-50 ◽  
Author(s):  
Achmad Chafidz ◽  
Umi Rofiqah ◽  
Tintin Mutiara ◽  
Muhammad Rizal ◽  
Mujtahid Kaavessina ◽  
...  
Keyword(s):  
Thermal Analysis ◽  
Storage Modulus ◽  
Dynamic Mechanical Thermal Analysis ◽  
Vinyl Alcohol ◽  
High Density ◽  
Poly Vinyl Alcohol ◽  
Dynamic Mechanical ◽  
Melt Compounding ◽  
Twin Screw ◽  
Pva Fiber

In the present work, high density polyethylene (HDPE)/poly (vinyl alcohol) (PVA) fiber composites with four different PVA fiber loadings (i.e. 0, 5, 10, 20 wt%) have been prepared via melt compounding method using a twin-screw extruder. The composites were characterized for their morphology by using a scanning electron microscopy (SEM). Whereas, the dynamic mechanical thermal analysis (DMTA) was carried out by using an oscillatory rheometer. The DMTA test was carried out under torsion mode using temperature sweep test on rectangular composites samples. The DMTA results showed that the storage modulus (G¢) of the composites were higher than that of the neat HDPE and increased with increasing PVA fiber loadings. This indicated that there was a considerable stiffness enhancement of the composites. For example, at temperature of 60°C, the increases of stiffness (i.e. storage modulus) of the composites were approximately 3, 31, and 54% for PVAC-5, 10, and 20, respectively. Whereas, at higher temperature (i.e. 120°C), the increases were about 4, 50, and 98% for PVAC-5, 10, and 20, respectively. These results indicated that even at higher temperatures, the enhancement of storage modulus of the composites was still high.

Enhancing Mechanical Properties of Polyvinyl Alcohol Fiber Reinforced High Density Polyethylene Composites

2018 ◽  
Vol 777 ◽  
pp. 27-31
Author(s):  
Achmad Chafidz ◽  
Ariany Zulkania ◽  
Tintin Mutiara ◽  
Prima A. Handayani ◽  
Muhammad Rizal
Keyword(s):  
Mechanical Properties ◽  
Polyvinyl Alcohol ◽  
Tensile Test ◽  
High Density Polyethylene ◽  
High Density ◽  
Sem Images ◽  
Melt Compounding ◽  
Twin Screw ◽  
Pva Fiber ◽  
Surface Morphologies

In this work, high density polyethylene (HDPE)/polyvinyl alcohol (PVA) fiber composites have been fabricated via melt compounding by employing a twin-screw extruder. The resulted composites samples of four different PVA loadings (i.e. 0, 5, 10, 20 wt%) were then characterized via tensile test to investigate the effect of PVA loadings on their mechanical properties (i.e. modulus elasticity, tensile strength, toughness, and strain at break). Additionally, the surface morphologies of the composites (i.e. cryo-fractured and tensile fractured samples) were also studied by using a scanning electron microscopy (SEM). The SEM micrographs on the cryo-fractured sample showed that PVA fibers were perfectly embedded and well blended in HDPE matrix. Whereas, the SEM images of tensile-fractured samples showed that there was a fibrillation effect on the neat HDPE, while in the composites sample, there was an evident of broken fibers. Additionally, from the tensile test results, the modulus elasticity of the composites has increased by approximately 16, 39, and 81% (as compared to the neat HDPE) for PVAC-5, PVAC-10, and PVAC-20, respectively. Whereas, the toughness and strain at break of the composites have decreased.

Thermal Properties of High Density Polyethylene/Poly(Vinyl Alcohol) Fiber Composites Prepared Using Laboratory Mixing Extruder

2021 ◽  
Vol 315 ◽  
pp. 114-119
Author(s):  
Achmad Chafidz M.S. ◽  
Dewi Selvia Fardhyanti ◽  
Megawati ◽  
Prima Astuti Handayani ◽  
Muhammad Rizal
Keyword(s):  
Thermal Properties ◽  
Vinyl Alcohol ◽  
High Density Polyethylene ◽  
Crystallinity Index ◽  
Fiber Composites ◽  
High Density ◽  
Poly Vinyl Alcohol ◽  
Scanning Calorimetry ◽  
Pva Fiber ◽  
Melting And Crystallization

This paper focuses on the preparation of High Density Polyethylene/Poly (Vinyl Alcohol) Fiber composites which was fabricated via melt blending/compounding method using a Laboratory Mixing Extruder (LME). The effect of PVA fiber concentrations (i.e. 0, 5, 10, 20, 30 wt%) on the thermal properties (i.e. melting and crystallization) of the composites was investigated. The thermal properties of the composites were analysed using a Differential Scanning Calorimetry (DSC). The DSC analysis results exhibited that the presence of PVA fiber did not considerably change the melting and crystallization properties of the composites. The melting temperature (Tm) of all the composites samples were similar, which was in the range of 130 - 131 °C. The highest Tm was belong to sample PVAC-20 (i.e. 20 wt% PVA fiber). In the other hand, the crystallinity index (Xc) of the HPDE/PVA fiber composites decreased with the increase of PVA fiber concentrations. The Xc of the composites decreased from 56.7 % for PVAC-0 to 49.8 % for PVAC-20. Additionally, in term of crystallization behavior of the composites, the effect of PVA loadings on the crystallization temperature (Tc) of the composites was also not significant. The Tc of all composites samples were similar, which was about 115 °C. It can be suggested that the addition of PVA fiber did not affect the crystallization process of the matrix.

Dynamic Mechanical Thermal Analysis of High Density Polyethylene Reinforced with Nanodiamond, Carbon Nanotube and Graphite Nanoplatelet

2018 ◽  
Vol 917 ◽  
pp. 27-31 ◽  
Author(s):  
Santosh Kumar Sahu ◽  
Nitesh Dhar Badgayan ◽  
Sutanu Samanta ◽  
Pattela Srinivasa Rama Sreekanth
Keyword(s):  
Thermal Analysis ◽  
Dynamic Mechanical Thermal Analysis ◽  
Dynamic Properties ◽  
Loss Modulus ◽  
Graphite Nanoplatelets ◽  
Tem Analysis ◽  
Dynamic Mechanical ◽  
Twin Screw ◽  
Multi Walled Carbon Nanotubes ◽  
Surface Modified

Present work reports on Dynamic Mechanical Thermal Analysis (DMTA) of HDPE reinforced with surface modified 0D (Nanodiamonds-NDs), 1D (Multi Walled Carbon Nanotubes-MWCNTs) and 2D (Graphite nanoplatelets-GNPs) nanofillers. Composite samples were prepared using twin screw injection moulding machine. Dynamic properties like storage, loss modulus and tan delta were investigated as a function of temperature and at constant oscillation of 1 Hz. Optimum properties were exhibited by 0.1 CNT/HDPE during a temperature swept from 30 to 110 oC. The storage modulus and loss modulus of 0.1 CNT/HDPE increased by 57 and 28% on comparison with pure HDPE. 0.1 CNT/HDPE exhibited highest ascent during tan delta evaluation confirming good damping property. TEM analysis was carried out to investigate the morphology of ND, MWCNT and GNP.

Poly(Vinyl Alcohol) Fiber Reinforced High Density Poly(Ethylene) Composites: Melting and Crystallization Behavior

2018 ◽  
Vol 773 ◽  
pp. 100-105
Author(s):  
Umi Rofiqah ◽  
Achmad Chafidz ◽  
Lilis Kistriyani ◽  
Mujtahid Kaavessina ◽  
Muhammad Rizal ◽  
...  
Keyword(s):  
Vinyl Alcohol ◽  
Crystallization Behavior ◽  
Crystallinity Index ◽  
Fiber Composites ◽  
High Density ◽  
Peak Temperature ◽  
Poly Vinyl Alcohol ◽  
Scanning Calorimetry ◽  
Poly Ethylene ◽  
Pva Fiber

In the present study, high density poly(ethylene) (HDPE)/poly(vinyl alcohol) (PVA) fiber composites were prepared via melt blending technique using a co-rotating twin screw extruder (TSE). The effect of four different PVA fiber concentrations (i.e. 0, 5, 10, 20 wt%) on the melt and crystallization behavior of the HDPE/PVA fiber composites were investigated. The surface morphology of the composites was analyzed by a scanning electron microscopy (SEM). Whereas, the melt and crystallization behavior of the composites were analyzed by a differential scanning calorimetry (DSC). The SEM analysis on the cryo-fractured surface of the HDPE/PVA fiber composites exhibited that the PVA fibers were well blended/distributed in the HDPE matrix. Additionally, the DSC test results showed that the addition of PVA fiber in the HDPE matrix did not significantly change the melting peak temperature (Tm) of the composites. Furthermore, a slight decrease of the crystallization peak temperature (Tc) can be observed when the PVA fiber was incorporated in the HDPE matrix, which indicated a weak nucleation ability of the PVA fibers in the HDPE crystallization process. The same trend was also observed for the crystallinity index (Xc). The crystallinity index of the composites decreased with increasing PVA fiber loadings.

scholarly journals Microstructural Analysis of SiO2/Polyethylene Nanocomposites on Local and Macroscopic Scales

2007 ◽  
Vol 16 (2) ◽  
pp. 096369350701600
Author(s):  
B. Lehmann ◽  
J. Sustacha ◽  
A.K. Schlarb ◽  
K. Friedrich ◽  
M.Q. Zhang ◽  
...  
Keyword(s):  
Thermal Analysis ◽  
Surface Modification ◽  
Dynamic Mechanical Thermal Analysis ◽  
Material Properties ◽  
High Density Polyethylene ◽  
Filler Content ◽  
Microstructural Analysis ◽  
Local Scale ◽  
High Density ◽  
Dynamic Mechanical

High density polyethylene filled with nano-SiO2 of different face modification and content is investigated by nanoindentation, microindentation, scratching and dynamic mechanical thermal analysis. The results of the nanoindentation are compared with respect to more macroscopic measurements in order to obtain information if the surface modification and/or the filler content significantly changes the material properties on a local scale.

THE STRUCTURAL DEVELOPMENT OF NYLON6/LAYERED SILICATE NANOCOMPOSITE DURING ZONE-DRAWING

2006 ◽  
Vol 20 (25n27) ◽  
pp. 4577-4582
Author(s):  
SUNG SOO HAN ◽  
YANG-WHAN CHO ◽  
SOO-YOUNG PARK
Keyword(s):  
Thermal Analysis ◽  
Dynamic Mechanical Thermal Analysis ◽  
Crystalline Phase ◽  
Layered Silicate ◽  
Phase Region ◽  
Structural Development ◽  
X Ray ◽  
Dynamic Mechanical ◽  
X Ray Scattering ◽  
Degree Of Orientation

The structural development of nylon6/layered silicate nanocomposite during zone-drawing was studied using X-ray scattering and dynamic mechanical thermal analysis. The γ form, which was favored in the pressed film, was converted into the α form during zone-drawing. The newly developed α form, during zone-drawing, has a better orientation than the existing γ form, thus supporting the claim that the α form crystallizes away from the polymer-silicate inter-phase region during drawing. The degree of orientation of the layered silicate, projected along the TD direction, increases with the increase of the draw ratio, suggesting that the layered silicate has become straighter during zone-drawing, although the layered silicate within the zone-drawn film buckled perpendicular to the draw direction. The β transition of the dynamic mechanical thermal analysis is independent of the crystalline phase, although the α transition is strongly dependent upon the crystalline phase. This can be explained by the free volume that exists in the inter-phase between the γ lamellar and the layered silicate.

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