ZnO Photocatalysts Modified with Eu2O3 and Sm2O3

2020 ◽  
Vol 850 ◽  
pp. 35-40
Author(s):  
Pāvels Rodionovs ◽  
Jānis Grabis

In this study ZnO photocatalysts with different loading of Eu2O3 and Sm2O3 were prepared vie microwave-assisted hydrothermal method. The prepared samples were investigated by using XRD, SEM and BET analysis. The photocatalytic activity was determined by degradation of methylene blue (MB) under Osram Vitalux illumination. Prepared ZnO photocatalysts shown high photocatalytic activity under solar light simulated radiation. After 30 minute of irradiation more than 95 % of initial MB solution was degraded. The effect of pH and photocatalyst dosage was investigated. The reusability of photocatalysts was also studied.

RSC Advances ◽  
2020 ◽  
Vol 10 (39) ◽  
pp. 23024-23037 ◽  
Author(s):  
Fengxia Zhang ◽  
Wenjing Li ◽  
Tianyi Jiang ◽  
Xuemei Li ◽  
Yuanyuan Shao ◽  
...  

Three novel visible-light-driven composite photocatalysts were synthesized by hydrothermal method. The effects of introducing PDIs with different structures into TiO2 were evaluated by assaying the photodegradation rate of methylene blue.


2019 ◽  
Vol 56 ◽  
pp. 152-157 ◽  
Author(s):  
Abdelouahab Noua ◽  
Hichem Farh ◽  
Rebai Guemini ◽  
Oussama Zaoui ◽  
Tarek Diab Ounis ◽  
...  

Nickel oxide (NiO) thin films were successfully deposited by sol-gel dip-coating method on glass substrates. The structural, morphological and optical properties in addition to the photocatalytic activity of the prepared films were investigated. The results show that the films have a polycrystalline NiO cubic structure with dense NiO grains and average optical transmittance in the visible region. The photocatalytic properties of the films were studied through the degradation of methylene blue and 89% of degradation was achieved for 4.5h of solar light irradiation exposure which indicates the capability of NiO photocatalytic activity.


2011 ◽  
Vol 194-196 ◽  
pp. 385-388
Author(s):  
Hong Juan Wang ◽  
Feng Qiang Sun ◽  
Ming Zhong Ren ◽  
Qing Wei Guo

Nanoporous SnO2with high photocatalytic activity has been successfully prepared by a photochemical method, using SnCl2aqueous solution as a precursor. The as-synthesized sample was characterized by XRD, N2 adsorption-desorption and UV-vis. The photocatalytic activity of the sample was evaluated by degrading methylene blue (MB) aqueous solution under the UV light source and was compared with that of the commercial titania (Degussa P25). The results showed that the produced SnO2can degrade MB solution quickly and has comparative photocatalytic performance with P25 for degrading MB. This facile method supplies an effective way to prepare SnO2photocatalyst.


Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1349
Author(s):  
Liaochuan Jiang ◽  
Xingyuan Gao ◽  
Shaoling Chen ◽  
Jangam Ashok ◽  
Sibudjing Kawi

At present, TiO2 is one of the most widely used photocatalytic materials. However, the narrow response range to light limits the photocatalytic performance. Herein, we reported a successful construction of self-doped R-WO3/R-TiO2/CC nanocomposites on flexible carbon cloth (CC) via electrochemical reduction to increase the oxygen vacancies (Ovs), resulting in an enhanced separation efficiency of photo-induced charge carriers. The photocurrent of R-WO3/R-TiO2/CC at −1.6 V (vs. SCE) was 2.6 times higher than that of WO3/TiO2/CC, which suggested that Ovs could improve the response to sunlight. Moreover, the photocatalytic activity of R-WO3/TiO2/CC was explored using methylene blue (MB). The degradation rate of MB could reach 68%, which was 1.3 times and 3.8 times higher than that of WO3/TiO2/CC and TiO2/CC, respectively. Furthermore, the solution resistance and charge transfer resistance of R-WO3/R-TiO2/CC were obviously decreased. Therefore, the electrochemical reduction of nanomaterials enabled a promoted separation of photogenerated electron–hole pairs, leading to high photocatalytic activity.


2021 ◽  
Vol 18 (2) ◽  
pp. 3-8
Author(s):  
Aura S. Merlano ◽  
Ángel Salazar

Este estudio reporta una síntesis fácil, libre de surfactantes y asistida por microondas para la producción de nanopartículas de óxido de zinc (ZnO). Se investigó el efecto del valor del pH sobre las propiedades químicas, ópticas, morfológicas y fotocatalíticas de las nanopartículas de ZnO. Las nanopartículas se caracterizaron mediante microscopía electrónica de barrido (SEM), espectroscopía infrarroja por transformada de Fourier (FTIR), espectroscopía de rayos X por dispersión de energía (EDS) y espectroscopía UV-visible (UV-Vis). El análisis SEM muestra que el tamaño de las partículas disminuye con el aumento del valor de pH. Los espectros UV-Vis muestran picos de absorción excitónica alrededor de 334-359 nm. Se encontró que la brecha de energía de las muestras disminuye con el aumento del valor de pH. Finalmente, se evaluó la eficiencia fotocatalítica de los nanomateriales de ZnO mediante la degradación de naranja de metileno (MO) bajo irradiación de luz UV-A y se logró una eficiencia de degradación del colorante del 93.04% para la muestra de ZnO con pH-13. Los resultados experimentales confirman que la ruta propuesta para producir ZnO es fácil, reproducible y amigable con el medio ambiente. Además, el nano ZnO tiene un gran potencial como fotocatalizador para eliminar compuestos orgánicos.


2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Ji-guo Huang ◽  
Xue-ting Guo ◽  
Bo Wang ◽  
Lin-yang Li ◽  
Mei-xia Zhao ◽  
...  

The undoped and Mo-doped TiO2nanoparticles were synthesized by sol-gel method. The as-prepared samples were characterized by X-ray diffraction (XRD), diffuse reflectance UV-visible absorption spectra (UV-vis DRS), X-ray photoelectron spectra (XPS), and transmission electron microscopy (TEM). The photocatalytic activity was evaluated by photocatalytic degradation of methylene blue under irradiation of a 500 W xenon lamp and natural solar light outdoor. Effects of calcination temperatures and Mo doping amounts on crystal phase, crystallite size, lattice distortion, and optical properties were investigated. The results showed that most of Mo6+took the place of Ti4+in the crystal lattice of TiO2, which inhibited the growth of crystallite size, suppressed the transformation from anatase to rutile, and led to lattice distortion of TiO2. Mo doping narrowed the band gap (from 3.05 eV of TiO2to 2.73 eV of TiMo0.02O) and efficiently increased the optical absorption in visible region. Mo doping was shown to be an efficient method for degradation of methylene blue under visible light, especially under solar light. When the calcination temperature was 550°C and the Mo doping amount was 2.0%, the Mo-doped TiO2sample exhibited the highest photocatalytic activity.


Molecules ◽  
2019 ◽  
Vol 24 (24) ◽  
pp. 4481 ◽  
Author(s):  
Rosa M. Huertas ◽  
Maria C. Fraga ◽  
João G. Crespo ◽  
Vanessa J. Pereira

This work described a new sustainable method for the fabrication of ceramic membranes with high photocatalytic activity, through a simple sol-gel route. The photocatalytic surfaces, prepared at low temperature and under solvent-free conditions, exhibited a narrow pore size distribution and homogeneity without cracks. These surfaces have shown a highly efficient and reproducible behavior for the degradation of methylene blue. Given their characterization results, the microfiltration photocatalytic membranes produced in this study using solvent-free conditions are expected to effectively retain microorganisms, such as bacteria and fungi that could then be inactivated by photocatalysis.


Langmuir ◽  
2011 ◽  
Vol 27 (6) ◽  
pp. 2946-2952 ◽  
Author(s):  
Tieping Cao ◽  
Yuejun Li ◽  
Changhua Wang ◽  
Changlu Shao ◽  
Yichun Liu

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